Geochemical characterization and modeling of arsenic behavior in a highly contaminated mining soil     

Sara Bisone  Vincent Chatain  Denise Blanc  Mathieu Gautier  Rémy Bayard  Florence Sanchez  Rémy Gourdon 《Environmental Earth Sciences》2016,75(4):306

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KArMars: A Breadboard Model for In Situ Absolute Geochronology Based on the K–Ar Method Using UV‐Laser‐Induced Breakdown Spectroscopy and Quadrupole Mass Spectrometry          下载免费PDF全文

Damien Devismes  Pierre‐Yves Gillot  Jean‐Claude Lefèvre  Claire Boukari  Francis Rocard  Florence Chiavassa 《Geostandards and Geoanalytical Research》2016,40(4):517-532

We present a breadboard prototype to perform in situ dating applicable to planetary exploration. Based on the K–Ar dating method and using instruments inspired by flight‐proven analytical components, ‘KArMars’ ablated a geological sample under high vacuum with a quadrupled ultraviolet (UV at 266 nm) Nd:YAG laser. During ablation, the K content of the target material was given by laser‐induced breakdown spectroscopy and the released ⁴⁰Ar was measured with a quadrupole mass spectrometer. Because K was measured as a concentration and ⁴⁰Ar as a count of atoms, these values were converted using the ablated mass given by the product of the density and the ablated volume. The uncertainties of the age measurement were < 15%. The quality of the K–Ar measurements was enhanced by the advantages of UV laser ablation such as the minimisation of thermal effects on argon diffusion. This work demonstrates that a specialised instrument inspired by this set‐up could provide in situ absolute geochronology with sufficient precision for scientific investigations, particularly where the crater density counting provides higher uncertainties on Mars.  相似文献   

RAPID applied to the SIM‐France model     

Cédric H. David  Florence Habets  David R. Maidment  Zong‐Liang Yang 《水文研究》2011,25(22):3412-3425

SIM‐France is a large connected atmosphere/land surface/river/groundwater modelling system that simulates the water cycle throughout metropolitan France. The work presented in this study investigates the replacement of the river routing scheme in SIM‐France by a river network model called RAPID to enhance the capacity to relate simulated flows to river gauges and to take advantage of the automated parameter estimation procedure of RAPID. RAPID was run with SIM‐France over a 10‐year period and results compared with those of the previous river routing scheme. We found that while the formulation of RAPID enhanced the functionality of SIM‐France, the flow simulations are comparable in accuracy to those previously obtained by SIM‐France. Sub‐basin optimization of RAPID parameters was found to increase model efficiency. A single criterion for quantifying the quality of river flow simulations using several river gauges globally in a river network is developed that normalizes the square error of modelled flow to allow equal treatment of all gauging stations regardless of the magnitude of flow. The use of this criterion as the cost function for parameter estimation in RAPID allows better results than by increasing the degree of spatial variability in optimization of model parameters. Likewise, increased spatial variability of RAPID parameters through accounting for topography is shown to enhance model performance. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Cycles of humid‐dry climate conditions around the P/E boundary: new stable isotope data from terrestrial organic matter in Vasterival section (NW France)     

Jean‐Yves Storme  Christian Dupuis  Johann Schnyder  Florence Quesnel  Sylvain Garel  Alina I. Iakovleva  Paola Iacumin  Antonietta Di Matteo  Mathieu Sebilo  Johan Yans 《地学学报》2012,24(2):114-122

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Evaluation of the Risk of Marine Slope Instability: A Pseudo-3D Approach for Application to Large Areas     

Nabil Sultan  Pierre Cochonat  Jean François Bourillet  Florence Cayocca 《Marine Georesources & Geotechnology》2013,31(2):107-133

Abstract

This article presents a methodology developed to evaluate the instability of submarine slopes that extend over a large area. Special attention was paid to (1) the complex geometry (bathymetry) and the expanse of the slope, (2) the heterogeneity of the sediment, and (3) the distribution of the pore pressure. The safety factor was considered as a spatially varying quantity. The General Formulation (GLE, Fredlund and Krahn 1977), which fully satisfies equilibrium conditions, was used for evaluating the stability of the marine slope. The submarine slope failure, which occurred on 16 October 1979 during the construction of the new Nice airport, was studied in order to test the developed model. Geotechnical parameters were taken from experimental tests carried out by IFREMER on 19 cores extracted at different depths (from 27 m to 1300 m) (Cochonat, Bourillet, and Savoye, 1993; Mulder et al., 1994). Many scenarios were proposed in order to explain the cause of the Nice slope failure (Habib, 1994). In this article, two of those scenarios were tested. Simulation results are presented and discussed.  相似文献   

Spatial aspects of the residential adjustments of older parents moving to low-income senior housing: A longitudinal study     

Gina M. Sylvestre  Geoffrey C. Smith 《Geoforum》2009,40(5):918-929

The purpose of this paper is to determine the effects of changes in local behaviour settings and individual attributes on the adjustments of older parents moving to government-subsidized senior citizen apartment (SCA) projects. The data were elicited from a sample of 106 residents of 25 SCAs in Winnipeg, Manitoba, who participated in a longitudinal interview survey. The data analysis involved use of bivariate statistical inferential tests and multiple regression frameworks. The findings disclose that the moves had only a moderate impact on parent-child residential separation and interaction. However, statistically significant predictors of four personal state outcomes (self-rated health, morale, depression, self-esteem) of the moves include variables concerning change in the older parent’s personal resources, everyday travel, and subjective appraisals of service, social, and physical components of the local neighbourhood. The findings have important policy implications in relation to the provision of appropriate behaviour settings for senior housing.  相似文献   

Photoelectric photometry of asteroids 9 Metis, 18 Melpomene, 60 Echo, 116 Sirona, 230 Athamantis, 694 Ekard,and 1984 KD     

Kenneth W. Zeigler  William B. Florence 《Icarus》1985,62(3):512-517

Photoelectric observations of seven asteroids were made from Gila Observatory between October 14, 1983, and June 21, 1984. The following synodic rotational periods and amplitudes are reported: 9 Metis, P = 5.04 hr, ΔM = 0.05; 18 Melpomene, P = 11.570 hr, ΔM = 0.22; 60 Echo, P = 25.208 hr, ΔM = 0.22; 116 Sirona, P = 12.028 hr, ΔM = 0.42; 230 Athamantis, P = 23.99 hr, ΔM > 0.20; 694 Ekard, P = 5.925 hr, ΔM = 0.50; 1984 KD, P = 1.97 hr, ΔM = 0.26. The rotational periods reported for asteroid 60 Echo, 116 Sirona, 694 Ekard, and 1984 KD represent completely new results. The synodic rotational period reported for asteroid 1984 KD is tentative and is based largely upon the observations of a single night. The reported synodic periods of the remaining six asteroids are based upon a minimum of 3 nights of photometric observations.  相似文献   

Les « Porphyroı̈des » de Bretagne méridionale : une unité de HP–BT dans la chaı̂ne hercynienneEvidence for HP–LT Hercynian metamorphism within the ‘Porphyroı̈des’ of South Brittany (France)     

Florence Le Hébel  Olivier Vidal  Jean-Robert Kienast  Denis Gapais 《Comptes Rendus Geoscience》2002,334(3):205-211

The so-called ‘Porphyro??des’ Unit of South Brittany is located below units marked by an early HP–LT event (blueschists from the Île de Groix) and above units marked by Upper Carboniferous HT metamorphism. P–T estimates in the Porphyro??des (at Belle-Île-en-Mer), using the phengite–chlorite thermobarometer, indicate pressures around 8 kbar and temperatures of 350–400 °C. These new estimates suggest that the early tectonic history of the ‘Porphyro??des’ should be linked to that of the overlying Blueschists, and imply a much larger areal extension of the HP–LT domain in this part of the Hercynian Belt. To cite this article: F. Le Hébel et al., C. R. Geoscience 334 (2002) 205–211.  相似文献   

High resolution simulation of recent Arctic and Antarctic stratospheric chemical ozone loss compared to observations     

Om Prakash Tripathi  Sophie Godin-Beekmann  Franck Lefèvre  Marion Marchand  Andrea Pazmiño  Alain Hauchecorne  Florence Goutail  Hans Schlager  C. Michael Volk  B. Johnson  G. König-Langlo  Stefano Balestri  Fred Stroh  T. P. Bui  H. J. Jost  T. Deshler  Peter von der Gathen 《Journal of Atmospheric Chemistry》2006,55(3):205-226

Simulations of polar ozone losses were performed using the three-dimensional high-resolution (1^∘ × 1^∘) chemical transport model MIMOSA-CHIM. Three Arctic winters 1999–2000, 2001–2002, 2002–2003 and three Antarctic winters 2001, 2002, and 2003 were considered for the study. The cumulative ozone loss in the Arctic winter 2002–2003 reached around 35% at 475 K inside the vortex, as compared to more than 60% in 1999–2000. During 1999–2000, denitrification induces a maximum of about 23% extra ozone loss at 475 K as compared to 17% in 2002–2003. Unlike these two colder Arctic winters, the 2001–2002 Arctic was warmer and did not experience much ozone loss. Sensitivity tests showed that the chosen resolution of 1^∘ × 1^∘ provides a better evaluation of ozone loss at the edge of the polar vortex in high solar zenith angle conditions. The simulation results for ozone, ClO, HNO₃, N₂O, and NO _y for winters 1999–2000 and 2002–2003 were compared with measurements on board ER-2 and Geophysica aircraft respectively. Sensitivity tests showed that increasing heating rates calculated by the model by 50% and doubling the PSC (Polar Stratospheric Clouds) particle density (from 5 × 10⁻³ to 10⁻² cm⁻³) refines the agreement with in situ ozone, N₂O and NO _y levels. In this configuration, simulated ClO levels are increased and are in better agreement with observations in January but are overestimated by about 20% in March. The use of the Burkholder et al. (1990) Cl₂O₂ absorption cross-sections slightly increases further ClO levels especially in high solar zenith angle conditions. Comparisons of the modelled ozone values with ozonesonde measurement in the Antarctic winter 2003 and with Polar Ozone and Aerosol Measurement III (POAM III) measurements in the Antarctic winters 2001 and 2002, shows that the simulations underestimate the ozone loss rate at the end of the ozone destruction period. A slightly better agreement is obtained with the use of Burkholder et al. (1990) Cl₂O₂ absorption cross-sections.  相似文献   

Recurring middle Pleistocene outburst floods in east-central Alaska     

Duane G Froese  Derald G SmithJohn A Westgate  Thomas A AgerShari J Preece  Amanjit SandhuRandolph J Enkin  Florence Weber 《Quaternary Research》2003,60(1):50-62

Recurring glacial outburst floods from the Yukon-Tanana Upland are inferred from sediments exposed along the Yukon River near the mouth of Charley River in east-central Alaska. Deposits range from imbricate gravel and granules indicating flow locally extending up the Yukon valley, to more distal sediments consisting of at least 10 couplets of planar sands, granules, and climbing ripples with up-valley paleocurrent indicators overlain by massive silt. An interglacial organic silt, occurring within the sequence, indicates at least two flood events are associated with an earlier glaciation, and at least three flood events are associated with a later glaciation which postdates the organic silt. A minimum age for the floods is provided by a glass fission track age of 560,000 ± 80,000 yr on the GI tephra, which occurs 8 m above the flood beds. A maximum age of 780,000 yr for the floods is based on normal magnetic polarity of the sediments. These age constraints allow us to correlate the flood events to the early-middle Pleistocene. And further, the outburst floods indicate extensive glaciation of the Yukon-Tanana Upland during the early-middle Pleistocene, likely representing the most extensive Pleistocene glaciation of the area.  相似文献