The limited role of aquifer heterogeneity on metal reduction in an Atlantic coastal plain determined by push-pull tests     

Brian J. Mailloux  Stephanie Devlin  Mark E. Fuller  T.C. Onstott  Mary F. DeFlaun  Keun-Hyung Choi  Maria Green-Blum  Donald J.P. Swift  John McCarthy  Hailiang Dong 《Applied Geochemistry》2007

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Testing electric field models using ring current ion energy spectra from the Equator-S ion composition (ESIC) instrument     

L. M. Kistler  B. Klecker  V. K. Jordanova  E. Möbius  M. A. Popecki  D. Patel  J. A. Sauvaud  H. Rème  A. M. Di Lellis  A. Korth  M. McCarthy  R. Cerulli  M. B. Bavassano Cattaneo  L. Eliasson  C. W. Carlson  G. K. Parks  G. Paschmann  W. Baumjohann  G. Haerendel 《Annales Geophysicae》1999,17(12):1611-1621

During the main and early recovery phase of a geomagnetic storm on February 18, 1998, the Equator-S ion composition instrument (ESIC) observed spectral features which typically represent the differences in loss along the drift path in the energy range (5–15 keV/e) where the drift changes from being E × B dominated to being gradient and curvature drift dominated. We compare the expected energy spectra modeled using a Volland-Stern electric field and a Weimer electric field, assuming charge exchange along the drift path, with the observed energy spectra for H⁺ and O⁺. We find that using the Weimer electric field gives much better agreement with the spectral features, and with the observed losses. Neither model, however, accurately predicts the energies of the observed minima.  相似文献   

The role of biota in the initiation and growth of islands on the floodplain of the Okavango alluvial fan,Botswana     

T. S. McCarthy  W. N. Ellery  J. M. Dangerfield 《地球表面变化过程与地形》1998,23(4):291-316

A group of islands of varying size on the floodplain of the Okavango alluvial fan, were studied to establish the processes which lead to the initiation and growth of islands. It was found that islands are initiated by the mound-building activities of the termite Macrotermes michaelseni. These termites import fine grained materials to use as a mortar for the construction of epigeal mounds. Their activities create a topographic feature, raised above the level of seasonal flooding, and also change the physical properties and nutrient status of the mound soil. Shrubs and trees are able to colonize these mounds, which results in increased transpiration. As a result, precipitation of calcite and silica from the shallow ground water occurs preferentially beneath the mounds, resulting in vertical and especially lateral growth, causing island expansion. © 1998 John Wiley & Sons, Ltd.  相似文献   

Climate uncertainties and their discontents: increasing the impact of assessments on public understanding of climate risks and choices     

Brenda Ekwurzel  Peter C. Frumhoff  James J. McCarthy 《Climatic change》2011,108(4):791-802

US public awareness of the reality and risks of human-caused climate change remains limited, despite strong evidence presented in the IPCC and other major climate assessments. One contributing factor may be that the immense collective effort to produce periodic climate assessments is typically not well matched with public communication and outreach efforts for these reports, leaving a vacuum to be filled by less authoritative sources. Print and online media coverage provides one metric of the US public reach of selected climate assessments between 2000 and 2010. The number of Lexis-Nexis articles for the search terms “climate change” or “global warming” within 14 days of each report’s release varied significantly over time with a peak occurring in 2007. When compared to background “chatter” relating to climate change, each assessment had widely diverse penetration in the US media (~4% for US National Climate Assessment in 2000; ~17% for Arctic Climate Impacts Assessment in 2004; ~19% and ~10% for Intergovernmental Panel on Climate Change (IPCC) Fourth Assessment Report Working Group I and Working Group II respectively in 2007; ~4% for the US Global Change Research Program (USGCRP) assessment report in 2009; and ~5% for US National Research Council’s America’s Climate Choices reports in 2010). We propose ways to improve the public reach of climate assessments, focusing in particular on approaches to more effectively characterize and communicate the role of uncertainty in human actions as distinct from other sources of uncertainty across the range of possible climate futures.  相似文献   

Assessing Nitrogen Dynamics Throughout the Estuarine Landscape     

Ashley R. Smyth  Suzanne P. Thompson  Kaylyn N. Siporin  Wayne S. Gardner  Mark J. McCarthy  Michael F. Piehler 《Estuaries and Coasts》2013,36(1):44-55

Assessing nitrogen dynamics in the estuarine landscape is challenging given the unique effects of individual habitats on nitrogen dynamics. We measured net N₂ fluxes, sediment oxygen demand, and fluxes of ammonium and nitrate seasonally from five major estuarine habitats: salt marshes, seagrass beds (SAV), oyster reefs, and intertidal and subtidal flats. Net N₂ fluxes ranged from 332?±?116 μmol?N-N₂?m^?2?h^?1 from oyster reef sediments in the summer to ?67?±?4 μmol?N-N₂?m^?2?h^?1 from SAV in the winter. Oyster reef sediments had the highest rate of N₂ production of all habitats. Dissimilatory nitrate reduction to ammonium (DNRA) was measured during the summer and winter. DNRA was low during the winter and ranged from 4.5?±?3.0 in subtidal flats to 104?±?34 μmol?¹⁵NH ₄ ⁺ ?m^?2?h^?1 in oyster reefs during the summer. Annual denitrification, accounting for seasonal differences in inundation and light, ranged from 161.1?±?19.2 mmol?N-N₂?m^?2?year^?1 for marsh sediments to 509.9?±?122.7 mmol?N-N₂?m^?2?year^?1 for SAV sediments. Given the current habitat distribution in our study system, an estimated 28.3?×?10⁶?mol of N are removed per year or 76 % of estimated watershed nitrogen load. These results indicate that changes in the area and distribution of habitats in the estuarine landscape will impact ecosystem function and services.  相似文献   

The Sloan Digital Sky Survey monitor telescope pipeline     

D.L. Tucker  S. Kent  M.W. Richmond  J. Annis  J.A. Smith  S.S. Allam  C.T. Rodgers  J.L. Stute  J.K. Adelman‐McCarthy  J. Brinkmann  M. Doi  D. Finkbeiner  M. Fukugita  J. Goldston  B. Greenway  J.E. Gunn  J.S. Hendry  D.W. Hogg  S.‐I. Ichikawa   . Ivezi&#x;  G.R. Knapp  H. Lampeitl  B.C. Lee  H. Lin  T.A. McKay  A. Merrelli  J.A. Munn  E.H. Neilsen  H.J. Newberg  G.T. Richards  D.J. Schlegel  C. Stoughton  A. Uomoto  B. Yanny 《Astronomische Nachrichten》2006,327(9):821-843

The photometric calibration of the Sloan Digital Sky Survey (SDSS) is a multi‐step process which involves data from three different telescopes: the 1.0‐m telescope at the US Naval Observatory (USNO), Flagstaff Station, Arizona (which was used to establish the SDSS standard star network); the SDSS 0.5‐m Photometric Telescope (PT) at the Apache Point Observatory (APO), NewMexico (which calculates nightly extinctions and calibrates secondary patch transfer fields); and the SDSS 2.5‐m telescope at APO (which obtains the imaging data for the SDSS proper). In this paper, we describe the Monitor Telescope Pipeline, MTPIPE, the software pipeline used in processing the data from the single‐CCD telescopes used in the photometric calibration of the SDSS (i.e., the USNO 1.0‐m and the PT). We also describe transformation equations that convert photometry on the USNO‐1.0m u ′g ′r ′i ′z ′ system to photometry the SDSS 2.5m ugriz system and the results of various validation tests of the MTPIPE software. Further, we discuss the semi‐automated PT factory, which runs MTPIPE in the day‐to‐day standard SDSS operations at Fermilab. Finally, we discuss the use of MTPIPE in current SDSS‐related projects, including the Southern u ′g ′r ′i ′z ′ Standard Star project, the u ′g ′r ′i ′z ′ Open Star Clusters project, and the SDSS extension (SDSS‐II). (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

Sources of molecularly uncharacterized organic carbon in sinking particles from three ocean basins: A coupled ΔC and δC approach     

Leslie A. Roland  Matthew D. McCarthy  Tom Guilderson   《Marine Chemistry》2008,111(3-4):199-213

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Water levels in Lake Ontario 4230–2000 years B.P.: evidence from Grenadier Pond,Toronto, Canada     

Francine M. G. McCarthy  John H. McAndrews 《Journal of Paleolimnology》1988,1(2):99-113

Lake Ontario water levels have been rising for the past 11 500 years due to differential isostatic rebound of the St. Lawrence outlet. Small scale fluctuations in water level superimposed on this general trend have received little study, with the exception of the Nipissing Flood.The transgression of a Grenadier Pond was studied from cores along a transect from the bar that separates the pond from Lake Ontario to the marsh on the north shore. Radiocarbon dates of the transition from swamp peat to pond marl in five cores provide estimates of the rate of water level rise since 4230 years B.P. These estimates are supported by changes in sediment type and in abundance of pollen and seeds of aquatic plants. There were three short intervals of accelerated water level rise in Grenadier Pond, around 4200, 3000, and 2000 years B.P., when water levels rose up to 2 m instantaneously, within the resolution of radiocarbon dating. Sedimentological and paleobotanical data suggest that Grenadier Pond was an open embayment of Lake Ontario until 1970–1850 years B.P., when it was isolated by the bar, and therefore sediments deposited prior to this time reflect water levels in Lake Ontario.Short term departure of up to 2 m from the average rate of water level rise over the past 4000 years, as observed in the record at Grenadier Pond, is of the same range as historically observed departures from the mean lake stage of Lake Ontario. This implies that a threshold discharge exists above which broadening of the outflow channel occurs to accommodate further increase in discharge with little rise in lake level. The intervals of accelerated water level rise in Lake Ontario broadly coincide with periods of cool, wet climate, suggesting that increased moisture may have caused the short term fluctuations in water level.This is the second of a series of papers to be published by this journal that was presented in the paleolimnology sessions organized by R. B. Davis and H. Löffler for the XIIth Congress of the International Union for Quaternary Research (INQUA), which took place in Ottawa, Canada in August 1987. Drs. Davis and Löffler are serving as guest editors of this series.  相似文献   

Bottom-water Hypoxia Effects on Sediment–Water Interface Nitrogen Transformations in a Seasonally Hypoxic,Shallow Bay (Corpus Christi Bay,TX, USA)     

Mark J. McCarthy  Karen S. McNeal  John W. Morse  Wayne S. Gardner 《Estuaries and Coasts》2008,31(3):521-531

Bottom-water hypoxia effects on sediment–water interface nitrogen (N) transformations in Corpus Christi Bay (TX, USA) were examined using continuous-flow intact sediment core incubations. Sediment cores were collected from three sites in August 2002 (summer hypoxia) and April 2003 (normoxia). Oxygen (O₂) and hydrogen sulfide (H₂S) depth profiles were generated with microelectrodes. Membrane inlet mass spectrometry was used to measure sediment O₂ demand and net N₂ flux and combined with isotope pairing to determine potential denitrification and N fixation. Potential dissimilatory nitrate reduction to ammonium (DNRA) was measured using high-performance liquid chromatography. Sediment O₂ penetration depths ranged from 5 to 10 mm. H₂S ranged from being present in overlying water and throughout the sediment column in August to not detectable in overlying water or sediment in April. Sediment O₂ demand was higher during bottom-water normoxia conditions versus hypoxia. Sediments were a significant source of \textNH_\text4^{\text +} {\text{NH}}_{\text{4}}^{\text{ + }} to overlying water during hypoxia but not during normoxia. Net N₂ fixation was observed at one station in August and all stations in April. Denitrification rates were significantly higher during hypoxia at two of three sites. Potential DNRA was observed during both oxic states, but rates were significantly higher during hypoxia, which may reflect sulfide enhancement and absence of cation exchange with ^\text14 \textNH_\text4^{\text +} ^{{\text{14}}} {\text{NH}}_{\text{4}}^{\text{ + }} . DNRA may contribute to formation and maintenance of bottom-water hypoxic events in this system. These results show that N transformation pathways and rates change when bottom-water O₂ concentrations drop to hypoxic levels. Since south Texas is a semiarid region with few episodic runoff events, these results indicate that Corpus Christi Bay sediments are a N source most of the year, and denitrification may drive N limitation between episodic runoff events.  相似文献   

Protection of organic carbon in soil microaggregates via restructuring of aggregate porosity and filling of pores with accumulating organic matter   总被引：2，自引：0，他引：2  

John F. McCarthy  Jan Ilavsky 《Geochimica et cosmochimica acta》2008,72(19):4725-4744

We examined relationships between the pore structure of microaggregates and the protection of organic matter (OM) within that structure. By using ultra-small angle X-ray scattering (USAXS) before and after combustion of microaggregates at 350 °C, we took advantage of differences in X-ray scattering contrast among soil minerals, OM, and air to evaluate the distribution of the total- and OM-filled porosity within microaggregates (53-250 μm in diameter). Systematic changes in microaggregate structure were observed for long-term field manipulations of land use (a chronosequence of tallgrass prairie restorations) and agricultural management (conventional tillage versus no-till at two levels of nitrogen fertilization). Our results imply that OM preservation arose from the evolution of the architectural system of microaggregates during their formation and stabilization. Soils and treatments with increasing OM in microaggregates were associated with encapsulation of colloidal OM by minerals, thereby creating protected OM-filled pores at the submicron scale within the microaggregate structure. For example, in the prairie chronosequence, microaggregates from the cultivated soil had the lowest concentration of OM, but 75% of the OM that had survived cultivation was in OM-filled pores. Following restoration, the concentration of OM in microaggregates increased rapidly, but the proportion of OM in OM-filled pores declined initially and then increased over time until 90% of the OM was in OM-filled pores. OM totally encapsulated within the pore structure can create spatial and kinetic constraints on microbial access to and degradation of OM. Encapsulation of OM increases the capacity for its protection relative to sorption on mineral surfaces, and comparison of its extent among treatments suggests important feedback loops. The use of USAXS, which has not previously been applied to the study of soil aggregate structures and the distribution of OM within those structures, provided new information on the mechanisms of OM protection in soil microaggregates, and insights relevant to strategies for enhancing carbon-sequestration in soil through changes in agricultural management practices and land use.  相似文献