Amino acid nitrogen isotopic fractionation patterns as indicators of heterotrophy in plankton, particulate, and dissolved organic matter   总被引：1，自引：0，他引：1  

Matthew D. McCarthy  Ronald Benner  Marilyn L. Fogel 《Geochimica et cosmochimica acta》2007,71(19):4727-4744

Bulk nitrogen (N) isotope signatures have long been used to investigate organic N source and food web structure in aquatic ecosystems. This paper explores the use of compound-specific δ¹⁵N patterns of amino acids (δ¹⁵N-AA) as a new tool to examine source and processing history in non-living marine organic matter. We measured δ¹⁵N-AA distributions in plankton tows, sinking particulate organic matter (POM), and ultrafiltered dissolved organic matter (UDOM) in the central Pacific Ocean. δ¹⁵N-AA patterns in eukaryotic algae and mixed plankton tows closely resemble those previously reported in culture. δ¹⁵N differences between individual amino acids (AA) strongly suggest that the sharply divergent δ¹⁵N enrichment for different AA with trophic transfer, as first reported by [McClelland, J.W. and Montoya, J.P. (2002) Trophic relationships and the nitrogen isotopic composition of amino acids. Ecology83, 2173-2180], is a general phenomenon. In addition, differences in δ¹⁵N of individual AA indicative of trophic transfers are clearly preserved in sinking POM, along with additional changes that may indicate subsequent microbial reworking after incorporation into particles.We propose two internally normalized δ¹⁵N proxies that track heterotrophic processes in detrital organic matter. Both are based on isotopic signatures in multiple AA, chosen to minimize potential problems associated with any single compound in degraded materials. A trophic level indicator (ΔTr) is derived from the δ¹⁵N difference between selected groups of AA based on their relative enrichment with trophic transfer. We propose that a corresponding measure of the variance within a sub-group of AA (designated ΣV) may indicate total AA resynthesis, and be strongly tied to heterotrophic microbial reworking in detrital materials. Together, we hypothesize that ΔTr and ΣV define a two dimensional trophic “space”, which may simultaneously express relative extent of eukaryotic and bacterial heterotrophic processing.In the equatorial Pacific, ΔTr indicates an average of 1.5-2 trophic transfers between phytoplankton and sinking POM at all depths and locations. The ΣV parameter suggests that substantial variation may exist in bacterial heterotrophic processing between differing regions and time periods. In dissolved material δ¹⁵N-AA patterns appear unrelated to those in POM. In contrast to POM, δ¹⁵N-AA signatures in UDOM show no clear changes with depth, and suggest that dissolved AA preserved throughout the oceanic water column have undergone few, if any, trophic transfers. Together these data suggest a sharp divide between processing histories, and possibly sources, of particulate vs. dissolved AA.  相似文献   

Spatial variability of the Purbeck–Wight Fault Zone—a long-lived tectonic element in the southern UK     

R.K. Westhead  D.J. McCarthy  J.S. Collier  D.J. Sanderson 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(3):436-451

New seamless onshore to offshore bedrock (1:10 k scale) mapping for the Lyme Bay area is used to resolve the westward termination of the Purbeck–Wight Fault Zone (PWFZ) structure, comprising one of the most prominent, long-lived (Variscan–Cimmerian–Alpine) structural lineaments in the southern UK. The study area lies south of the Variscan Frontal Thrust and overlays the basement Variscide Rhenohercynian Zone, in a region of dominant E-W tectonic fabric and a secondary conjugate NW-SE/NE-SW fabric. The PWFZ comprises one of the E-W major structures, with a typical history including Permian to early Cretaceous growth movement (relating to basement Variscan Thrust reactivation) followed by significant Alpine (Helvetic) inversion. Previous interpretations of the PWFZ have been limited by the low resolution (1:250 k scale) of the available offshore BGS mapping, and our study fills this gap. We describe a significant change in structural style of the fault zone from east to west. In the Weymouth Bay area, previous studies demonstrate the development of focussed strain associated with the PWFZ, accompanied by distributed strain, N-S fault development, and potential basement uplift in its hangingwall. In the Lyme Bay area to the west, faulting is dominantly E-W, with N-S faulting absent. Comparison of the newly mapped faulting networks to gravity data suggests a spatial relationship between this faulting variation and basement variability and uplift.  相似文献   

Socio-cultural dimensions of climate change: charting the terrain     

James McCarthy  Chery Chen  David López-Carr  Barbara Louise Endemaño Walker 《GeoJournal》2014,79(6):665-675

We have reached a crucial turning point in debates around climate change. A well established scientific consensus regarding the physical causes, dynamics, and at least many likely implications of anthropogenic climate change has thus far failed to result in any substantial movement towards mitigation. For many, then, the most urgent questions regarding climate change are now socio-cultural ones, such as: how do people come to hold and act on certain beliefs regarding environmental conditions and processes; how do institutional forms and histories shape and constrain the views and options of various sorts of actors; and what are relationships among fossil fuels, climate change, and the historical geographies and future trajectories of capitalism? Far from being simpler than physical and life science questions, these social science questions introduce entirely new sorts of actors, dynamics, and methodological challenges into this already complex and dynamic domain. This special issue takes up these topics. In this essay, we chart some of the major contours of contemporary social science thinking regarding climate change and introduce the articles in the special issue. We begin by examining work, from political science and scholarship on the commons, that foregrounds questions of sovereignty, territoriality, and cooperation with respect to environmental governance. Then we examine work from neoclassical economics and radical political economy, which frame climate change in terms of externalities, or contradiction and crisis, respectively. Finally, we examine the rapidly proliferating work exploring how individuals think and feel about these issues, emphasizing concepts of risk, communication, and governmentality.  相似文献   

Testing cold dark matter with the hierarchical build-up of stellar light     

Michael L. Balogh  Ian G. McCarthy  Richard G. Bower  Vincent R. Eke 《Monthly notices of the Royal Astronomical Society》2008,385(2):1003-1014

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Collection of intact sediment cores with overlying water to study nitrogen- and oxygen-dynamics in regions with seasonal hypoxia     

Wayne S. Gardner  Mark J. McCarthy  Stephen A. Carini  Afonso C. Souza  Hou Lijun  Karen S. McNeal  Mary Keith Puckett  Jack Pennington 《Continental Shelf Research》2009,29(18):2207-2213

Settled particles of fresh, labile organic matter may be a significant source of oxygen demand and nutrient regeneration in seasonally-hypoxic regions caused by nutrient inputs into stratified coastal zones. Studying the dynamics of this material requires sediment sampling methods that include flocculent organic materials and overlying water (OLW) at or above the sediment–water interface (SWI). A new coring device (“HYPOX” corer) was evaluated for examining nitrogen- (N) and oxygen-dynamics at the SWI and OLW in the northern Gulf of Mexico (NGOMEX). The HYPOX corer consists of a “Coring Head” with a check-valve, a weighted “Drive Unit,” and a “Lander,” constructed from inexpensive components. The corer collected undisturbed sediment cores and OLW from sediments at NGOMEX sampling sites with underlying substrates ranging from sand to dense clay. The HYPOX corer could be deployed in weather conditions similar to those needed for a multi-bottle rosette water-sampling system with 20 L bottles. As an example of corer applicability to NGOMEX issues, NH₄⁺ cycling rates were examined at hypoxic and control sites by isotope dilution experiments. The objective was to determine if N-dynamics in OLW were different from those in the water column. “Ammonium demand,” as reflected by potential NH₄⁺ uptake rates, was higher in OLW than in waters collected from a meter or more above the bottom at both sites, but the pattern was more pronounced at the hypoxia site. By contrast, NH₄⁺ regeneration rates were low in all samples. These preliminary results suggest that heterotrophic activity and oxygen consumption in OLW in the hypoxic region may be regulated by the availability of NH₄⁺, or other reduced N compounds, rather than by the lack of sufficient labile organic carbon.  相似文献   

土壤碳通量--深土层的长期吸收     

JohnF.MCCARTHY 《地理学报(英文版)》2005,15(2):149-154

1IntroductionEarth'satmosphereisbeingsignificantlyalteredbyhumanactivities.Fossilfueluseandland-usechangesaredrivingtheongoing,rapidriseinatmosphericCO2andotherso-calledgreenhousegases.Concernsaboutthepotentialeffectsonregionalandglobalclimatemotivatethis…  相似文献   

A depositional model for deep‐lacustrine,partially confined,turbidite fans: Early Cretaceous,North Falkland Basin     

Thomas J. H. Dodd  Dave J. McCarthy  Philip C. Richards 《Sedimentology》2019,66(1):53-80

This paper presents a model of facies distribution within a set of early Cretaceous, deep‐lacustrine, partially confined turbidite fans (Sea Lion Fan, Sea Lion North Fan and Otter Fan) in the North Falkland Basin, South Atlantic. As a whole, ancient deep‐lacustrine turbidite systems are under‐represented in the literature when compared with those documented in marine basins. Lacustrine turbidite systems can form extensive, good quality hydrocarbon reservoirs, making the understanding of such systems crucial to exploration within lacustrine basins. An integrated analysis of seismic cross‐sections, seismic amplitude extraction maps and 455 m of core has enabled the identification of a series of turbidite fans. The deposits of these fans have been separated into lobe axis, lobe fringe and lobe distal fringe settings. Seismic architectures, observed in the seismic amplitude extraction maps, are interpreted to represent geologically associated heterogeneities, including: feeder systems, terminal mouth lobes, flow deflection, sinuous lobe axis deposits, flow constriction and stranded lobe fringe areas. When found in combination, these architectures suggest ‘partial confinement’ of a system, something that appears to be a key feature in the lacustrine turbidite setting of the North Falkland Basin. Partial confinement of a system occurs when depositionally generated topography controls the flow‐pathway and deposition of subsequent turbidite fan deposits. The term ‘partial confinement’ provides an expression for categorising a system whose depositional boundaries are unconfined by the margins of the basin, yet exhibit evidence of internal confinement, primarily controlled by depositional topography. Understanding the controls that dictate partial confinement; and the resultant distribution of sand‐prone facies within deep‐lacustrine turbidite fans, is important, particularly considering their recent rise as hydrocarbon reservoirs in rift and failed‐rift settings.  相似文献   

An isotope dilution method to measure nitrification rates in the northern Gulf of Mexico and other eutrophic waters     

Stephen A. Carini  Mark J. McCarthy  Wayne S. Gardner 《Continental Shelf Research》2010

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Spacecraft potential control aboard Equator-S as a test for Cluster-II     

K. Torkar  W. Riedler  M. Fehringer  F. Rüdenauer  C. P. Escoubet  H. Arends  B. T. Narheim  K. Svenes  M. P. McCarthy  G. K. Parks  R. P. Lin  H. Rème 《Annales Geophysicae》1999,17(12):1582-1591

The payload of Equator-S was complemented by the potential control device (PCD) to stabilise the electric potential of the spacecraft with respect to the ambient plasma. Low potentials are essential for accurate measurements of the thermal plasma. The design of PCD is inherited from instruments for Geotail and Cluster and utilises liquid metal ion sources generating a beam of indium ions at several keV. The set-up of the instrument and its interaction with the plasma instruments on board is presented. When the instrument was switched on during commissioning, unexpectedly high ignition and operating voltages of some ion emitters were observed. An extensive investigation was initiated and the results, which lead to an improved design for Cluster-II, are summarised. The cause of the abnormal behaviour could be linked to surface contamination of some emitters, which will be monitored and cured by on-board procedures in future. The mission operations on Equator-S were not at all affected, because of the high redundancy built into the instrument so that a sufficient number of perfectly operating emitters were available and were turned on routinely throughout the mission. Observations of the effect of spacecraft potential control on the plasma remained limited to just one event on January 8, 1998, which is analysed in detail. It is concluded that the ion beam lead to the predicted improvement of the particle measurements even outside the low density regions of the magnetosphere where the effect of spacecraft potential control would have been much more pronounced, and that the similar instruments for the four Cluster-II spacecraft to be launched in 2000 will be very important to ensure accurate plasma data from this mission.  相似文献   

Dust provenance and its role as a potential fertilizing agent for the Okavango Delta,Botswana     

Marc S. Humphries  Claudia R. Benitez-Nelson  Michael Bizimis  Timothy J. Ralph  Zacchary T. Larkin  Terence S. McCarthy 《地球表面变化过程与地形》2020,45(8):1705-1716

Dust plays a globally important role in supplying biologically essential elements to landscapes underlain by nutrient-poor substrates. Here we show that dust may play a significant role in sustaining productivity in the vast wetlands of the Okavango Delta in southern Africa, one of the world's richest biodiversity hotspots. Dust accumulates preferentially on tree-covered islands in the seasonal swamps of the Delta, creating pockets of fine-grained, nutrient-rich material within the semi-arid landscape of the Kalahari Desert. Strontium and neodymium isotopes reveal that this dust likely originates predominantly from the Makgadikgadi salt pans, located 300 km away, and contributes 10–80% of the fine-grained material present in Okavango island soils. Surface material sourced from the Makgadikgadi Pans contains relatively high amounts of bioavailable phosphorus and iron, potentially influencing Okavango Delta biological productivity. We propose that long-term ecosystem productivity and nutrient availability in the Okavango may be strongly mediated by regional dust inputs. Understanding the influence of dust deposition on nutrient loads and biogeochemical cycling is thus critical for predicting the response of the Okavango Delta to future changes in climate. We suggest that dust inputs may play a significant role in the supply of nutrients to other large, global wetland systems located in dryland environments. © 2020 John Wiley & Sons, Ltd  相似文献