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721.
Dioxin compounds in the deep-sea rose shrimp Aristeus antennatus (Risso, 1816) throughout the Mediterranean Sea 总被引:1,自引:0,他引:1
Guiomar Rotllant Esteban Abad Francisco Sard Manuela balos Joan B. Company Josep Rivera 《Deep Sea Research Part I: Oceanographic Research Papers》2006,53(12):1895-1906
Polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) are among the more toxic anthropogenic contaminants. They are fat-soluble and accumulate in animal tissues. Exposure to PCDD/Fs can cause several endocrine, reproductive and developmental problems in animals, including human beings. Several studies have demonstrated that fish and invertebrates living in association with sediments are exposed to and accumulate contaminants, but to date there have been no studies of PCDD/Fs contamination in deep-sea regions. Specimens of Aristeus antennatus (Risso, 1816) were collected from depths of 600–2500 m at different points in the Mediterranean Sea, from the western basin off the coast of Barcelona to the central basin off the Peloponnesian Peninsula, with otter trawl gear. Amounts of PCDD/Fs were measured in different animal tissues by high resolution gas chromatography coupled to high resolution mass spectrometry (HRGC–HRMS). This is the first study to report the presence of PCDD/Fs in deep-sea organisms dwelling at depths below 600 m. A. antennatus presented levels of PCDD/Fs of the same order of magnitude, or slightly higher, as those found in shallow-water species (Melicertus kerathurus) with respect to land-generated contamination. This highlights the widespread distribution of these pollutants and the potential threat posed to the biodiversity of fragile and vulnerable ecosystems such as the deep-sea. PCDD/F levels detected in the edible parts (muscle) of the commercial shrimp A. antennatus were clearly below the toxic limit value established by European legislation. Levels followed the trend muscle<ovary<hepatopancreas, according to the lipid content of the organs in question. The specific profile of toxic PCDD/F congeners in the studied Penaeid shrimp specimens was characterized mainly by octachlorodibenzo-p-dioxin (OCDD), 2,3,7,8-tetrachlorodibenzofuran (TCDF) and 2,3,4,7,8-pentachlorodibenzofuran (PeCDF) congeners. Moreover, non 2,3,7,8-substituted congeners bioaccumulated in this species, as observed in shallow-water crustaceans. PCDD/Fs were found in the shrimp A. antennatus throughout the Mediterranean Sea. Total PCDD/Fs burdens were higher in shrimps caught in the western Mediterranean than in those caught at eastern Mediterranean sites. There was a tendency for higher levels of PCDD/F contamination in samples obtained from deeper (2500 m) than from shallower sites (600 m). 相似文献
722.
Sara M. Francisco Henrique Cabral Maria Natividade Vieira Vítor C. Almada 《Estuarine, Coastal and Shelf Science》2006,69(3-4):655
In this paper, we compare the genetic structure and the historical demography of two populations of the sand smelt Atherina boyeri from the rivers Tagus and Mondego (Portugal) with two groups of samples of the closely related marine Atherina presbyter collected on the shore at comparable latitudes. A. presbyter is a pelagic marine inshore fish, while A. boyeri is typically found in coastal lagoons, estuaries and freshwaters bodies. Analysis of mtDNA control region sequences showed that the marine A. presbyter did not display signs of genetic differentiation between sites some hundreds of kilometers apart. On the contrary, A. boyeri showed clear differences between populations. The populations of A. boyeri showed a much lower genetic diversity and younger coalescence times when compared with A. presbyter. We suggest that these differences reflect the interplay between differences in ecology between the two species and the historical impact of the glaciations. While A. presbyter likely moved to the south evading the cold periods, A. boyeri probably went extinct and its populations in Western Europe are recent recolonizations from western Mediterranean refugia. 相似文献
723.
724.
Francisco A. Jimenez Jr Graciano P. Yumul Jr Victor B. Maglambayan 《Resource Geology》2007,57(2):170-179
The Sibutad gold deposit has gold associated in quartz veins. The most important of these is the Lalab orebody, which contains ore‐grade gold, predominantly, in milky quartz veins and veinlets. Here, alteration quartz and fine‐grained crystalline clear and milky quartz were formed from hydrothermal fluids in three stages, namely stages I, II and III. Fluid inclusion microthermometry was carried out on stage I milky quartz, stage II fine‐grained alteration quartz and stage III milky quartz ± barite veins and veinlets. Homogenization temperatures (TH) are >248°C in stage I, 214–232°C in stage II and 186–239°C in stage III. These fluid inclusions have salinity between 1 and 2 wt% NaCl equivalent. In terms of gold assay, stage I drill‐core samples have gold grades 0.53–0.76 g/ton Au, stage II samples have 1.12–3.70 g/ton Au and stage III samples have 9.06–23.88 g/ton Au. This correlation suggests that gold was precipitated from the stage II and III fluids. 相似文献
725.
Evidence of rainfall variations in Southern Brazil from trace element ratios (Mg/Ca and Sr/Ca) in a Late Pleistocene stalagmite 总被引:1,自引:0,他引:1
Francisco W. Cruz Jr. Stephen J. Burns Ivo Karmann Mathias Vuille 《Geochimica et cosmochimica acta》2007,71(9):2250-2263
Trace element ratios in the Bt2 stalagmite from Botuverá cave, Southern Brazil, are explored as a proxy for changes in the local rainfall recharge during the last 116 ky. BP Mg/Ca and Sr/Ca ratios, measured with an electron microprobe, are significantly positively correlated with one another throughout the entire record, and vary in a way that is very consistent with variations of δ18O in the same speleothem during the last glacial period. We suggest that prior calcite precipitation in the vadose zone of the cave system is the main factor affecting the incorporation of Mg and Sr into calcite of the stalagmite. This interpretation is supported by trace element correlation patterns and by results from a hydrochemistry study performed in a cave located in the same region and in a similar environmental setting. Therefore, we conclude that higher (lower) Mg/Ca and Sr/Ca values are associated with lower (higher) levels of recharge into the karstic aquifer, as such conditions lead to an increase (decrease) in the volume of calcite precipitated in the unsaturated zone above the cave during dry (wet) climate periods.Trace element variations point to generally dryer (wetter) conditions during lower (high) phases of summer insolation in the southern hemisphere. These periods coincide with decreased (increased) activity of the South American summer monsoon, as revealed by δ18O stalagmite records. In addition trace element variations show that rather wet conditions persisted throughout most of the last glacial period from approximately 70 to 17 ky BP. We suggest that during this period the glacial boundary conditions, especially ice volume buildup in the northern hemisphere, played an important role for monsoon rainfall intensification in the region. 相似文献
726.
727.
Nemesio M. Pérez Pedro A. Hernández Eleazar Padrón Rafael Cartagena Rodolfo Olmos Francisco Barahona Gladys Melián Pedro Salazar Dina L. López 《Pure and Applied Geophysics》2006,163(4):883-896
On January 16, 2002, short-term unrest occurred at San Miguel volcano. A gas-and-steamash plume rose a few hundred meters
above the summit crater. An anomalous microseismicity pattern, about 75 events between 7:30 and 10:30 hours, was also observed.
Continuous monitoring of CO2 efflux on the volcano started on November 24, 2001, in the attempt to provide a multidisciplinary approach for its volcanic
surveillance. The background mean of the diffuse CO2 emission is about 16 g m-2 d-1, but a 17- fold increase, up to 270 g m-2 d-1, was detected on January 7, nine days before the January 2002 short-term unrest at San Miguel volcano. These observed anomalous
changes on diffuse CO2 degassing could be related to either a sharp increase of CO2 pressure within the volcanic-hydrothermal system or degassing from an uprising fresh gas-rich magma within the shallow plumbing
system of the volcano since meteorological fluctuations cannot explain this observed increase of diffuse CO2 emission. 相似文献
728.
The lowest 17-km long reach of the Huerva River valley, down to its confluence with the Ebro River in Zaragoza city, flows across salt-bearing evaporites of the Ebro Tertiary Basin (NE Spain). Upstream, the horizontally lying Miocene evaporites are interfingered with non-soluble distal alluvial fan facies (shales and sandstones). The proportion of soluble facies in the Huerva River valley increases in a downstream direction towards the basin depocenter. On the basis of the type and magnitude of the paleosubsidence features, the valley has been divided into four reaches. Along reach I, undeformed terrace deposits less than 4 m thick rest on insoluble detrital bedrock. In reaches II and III, dissolution at the alluvium–bedrock boundary has generated local thickening, deformation and paleocollapse structures, which only affect the alluvial mantle. In reach IV, terrace deposits thicken to over 60 m resulting from a large-scale synsedimentary subsidence. In this sector, subsidence locally affects to both the alluvium and the underlying bedrock. This indicates that dissolution acts at the rockhead beneath the alluvial cover (alluvial karst) and within the evaporitic substratum (interstratal karst). The development of an intraevaporitic karst in reach IV is attributed to gypsum and salt dissolution. Irregular terrace gravel bodies (gravel pockets) embedded in a fine-grained matrix associated with paleocollapse structures have been interpreted as liquefaction–fluidization structures resulting from ground acceleration and suction induced by catastrophic collapses. Subsidence is currently active in the region affecting areas with a thin alluvial cover in reaches III and IV. The low subsidence activity in most of Zaragoza city is explained by the presence of thickened (around 50 m) and indurated alluvial deposits. In the surrounding area, numerous buildings in Cadrete and Santa Fe villages have been severely damaged by subsidence. Natural and human-induced subsidence favours the development of slope movements in the gypsum scarp overlooking Cadrete village. Several transport routes including the Imperial Canal (irrigation canal) and the recently completed Madrid–Barcelona high-speed railway are affected by human-induced sinkholes. The paleocollapse structures exposed in the trenches of this railway and a ring road under construction point to hazardous locations underlain by cavities and collapse structures where special protection measures should be applied. Rigid structures are recommended beneath the high-speed railway with sufficient strength to span the larger sinkholes with no deformation. Electronic monitoring devices linked to a warning system can detect subtle subsidence-induced deformations in carriageways or railways. This research demonstrates that the study of the paleokarst helps to understand the processes involved in the present-day subsidence phenomena and their general spatial distribution. 相似文献
729.
Miguel Orozco Antonio M lvarez-Valero Francisco M Alonso-Chaves John P Platt 《Tectonophysics》2004,385(1-4):85-104
Detailed structural analysis of the Sierra de Lújar in the western Alpujarras region (Betic Cordilleras, S Spain), a very representative area of the terrain known as the Alborán Domain, has revealed the existence of a very large N-vergent recumbent syncline which involves the whole mountain massif and neighbouring areas. The Lújar syncline and, probably, the associated recumbent anticline which crops out southeast of Sierra de Lújar show a great variation in the orientation of the hinge line. Although having a curved shape, the hinge line is contained in a plane whose attitude coincides with the main attitude of the axial-plane crenulation foliation (Sc), suggesting that it is a sheath fold.The strongly deformed overturned limb of the syncline is cut by two low-angle normal faults displacing towards the north. Similarity in the kinematics between the faults and the fold, and the association between the faults and the high-strain zone in the overturned limb of the fold, suggest that they are related. Regional constraints on the age of the crenulation cleavage and the low-angle normal faults indicate that they formed during the early Miocene late-orogenic extensional event in the Alborán Domain.We propose an alternate explanation for the structure of the Alpujarras region in which the Lújar syncline forms part of a recumbent syncline–anticline pair that extends along much of the Alpujarride outcrop in the southern Betic Cordillera. In several places, the fold is disrupted by low-angle normal faults, and it is overlain by an upper Alpujárride extensional sheet mainly composed of medium- to high-grade metamorphic rocks. We suggest that all these structures arose from the extensional deformation under decreasing temperature conditions of a previously thickened and metamorphosed orogenic crust. 相似文献
730.
Raul Benito Javier Garcia-Guinea Francisco J. Valle-Fuentes Paloma Recio 《Journal of Geochemical Exploration》1998,62(1-3)
The mordenite ore deposit of Los Escullos has a surface area of 106 m2 with an average thickness of 5 m and estimated reserves of 7,500,000 tons of mordenite–bentonite. It is made up of horizontal layers of interbedded epiclastic tuffs with volcanic bentonitised materials which have been subjected to hydromagmatic activity. The layers are essentially composed of bentonite and mordenite with lesser amounts of quartz, cristobalite, biotite, plagioclase, chlorite, amphiboles, titanomagnetite, ilmenite and calcite. The harder layers display a higher proportion of plagioclase crystals and are enriched in Al2O3, CaO, Fe2O3, TiO2, P2O5, Cu, Zn, Co, Cr, Ni and V, while the more altered layers contain larger contents of SiO2, K2O and Y. The amount of sodium increases (from 2% to 4%) relative to depth. Alteration processes resulted in a reduction in the contents of CaO, K2O and MnO and increase in Na2O and MgO. The beds of volcanic ash-tuffs have been devitrified by hydrothermal solutions giving rise to bentonites and sodium- and silica-rich residual fluids which have partly crystallized as mordenite and cristobalite. The raw material (mordenite–bentonite) can be improved removing biotite (magnetic separation) and plagioclase and quartz (by floating methods); however, the mordenite–bentonite mineral assemblage is practically impossible to separate due to the size of the crystals (average 0.5 μm under SEM–EDAX). In turn, this upgraded raw material has very useful properties (total area=520 m2/g and cation exchange capacity=70 meq/100 g) which may make it suitable for use in absorption processes (e.g. deodorization, cationic exchange), catalysis and molecular sieving. 相似文献