Comparison of theory and experiments for dispersion in homogeneous porous media     

Mark L. Porter  Francisco J. Valdés-Parada  Brian D. Wood 《Advances in water resources》2010

Modeling dispersion in homogeneous porous media with the convection–dispersion equation commonly requires computing effective transport coefficients. In this work, we investigate longitudinal and transverse dispersion coefficients arising from the method of volume averaging, for a variety of periodic, homogeneous porous media over a range of particle Péclet (Pe_p) numbers. Our objective is to validate the upscaled transverse dispersion coefficients and concentration profiles by comparison to experimental data reported in the literature, and to compare the upscaling approach to the more common approach of inverse modeling, which relies on fitting the dispersion coefficients to measured data. This work is unique in that the exact microscale geometry is available; thus, no simplifying assumptions regarding the geometry are required to predict the effective dispersion coefficients directly from theory. Transport of both an inert tracer and non-chemotactic bacteria is investigated for an experimental system that was designed to promote transverse dispersion. We highlight the occurrence of transverse dispersion coefficients that (1) depart from power-law behavior at relatively low Pe_p values and (2) are greater than their longitudinal counterparts for a specific range of Pe_p values. The upscaling theory provides values for the transverse dispersion coefficient that are within the 98% confidence interval of the values obtained from inverse modeling. The mean absolute error between experimental and upscaled concentration profiles was very similar to that between the experiments and inverse modeling. In all cases the mean absolute error did not exceed 12%. Overall, this work suggests that volume averaging can potentially be used as an alternative to inverse modeling for dispersion in homogeneous porous media.  相似文献   

Application of Laser‐Induced Breakdown Spectroscopy and Hyperspectral Images for Direct Evaluation of Chemical Elemental Profiles of Coprolites          下载免费PDF全文

Marco Aurélio Sperança  Francisco Wendel Batista de Aquino  Marcelo Adorna Fernandes  Alejandro Lopez‐Castillo  Renato Lajarim Carneiro  Edenir Rodrigues Pereira‐Filho 《Geostandards and Geoanalytical Research》2017,41(2):273-282

This study demonstrates the application of laser‐induced breakdown spectroscopy (LIBS) and hyperspectral imaging to the investigation of coprolite and fossil samples. Solid samples from the Permian (seven coprolites and one fossil), Cretaceous (one coprolite) and Oligo‐Miocene (two coprolites) periods were directly analysed, and emission spectra from 186 to 1042 nm were obtained in several areas covering coprolite/fossil and rock material. Initial exploratory analyses were performed using principal component analysis with the data set normalised by the norm (Euclidean norm = 1). After identification and selection of emission lines of eleven elements (Al, Ca, Cr, Fe, K, Mg, Mn, Na, Ni, P and Si), the signals were normalised again by the relative intensity of the selected element. Phosphorus was identified mainly in the coprolites, while K and Na were primarily found in the rock material. In several cases, there was a positive correlation between Ca and P. A sample from the Oligo‐Miocene series was also analysed using inductively coupled plasma‐optical emission spectrometry (ICP‐OES) (rock and coprolites were analysed separately). Based on the quantitative results from ICP‐OES, it was confirmed that the tendency was the same as that observed with the results obtained from LIBS directly in the solid sample.  相似文献   

The External Tanger Unit (Intrarif sub-Domain,External Rifian Zones,Morocco): an interdisciplinary study   总被引：1，自引：0，他引：1  

Soufian Maaté  Francisco Javier Alcalá  Francesco Guerrera  Rachid Hlila  Alí Maaté  Manuel Martín-Martín  Giuliana Raffaelli  Francisco Serrano  Mario Tramontana 《Arabian Journal of Geosciences》2017,10(24):556

The External Tanger Unit represents one of the most complete Cretaceous-Miocene successions in the central areas of the Internal Intrarif sub-Domain (External Rif Zones, Morocco). An interdisciplinary study has been carried out to propose a new characterization of this unit which would allow a better comprehension of the confused and complex relationships among different units of the same sub-domain. The results achieved can be summarized as follows: (1) redefinition of the stratigraphic (litho-, bio-, and chrono-) record and introduction of a new, informal lithostratigraphic terminology; (2) recognition of two main depositional sequences (lower-middle Eocene p.p. and lower Oligocene p.p.-lower Miocene p.p.) separated by extended gaps (latest Cretaceous-early Eocene p.p. and middle Eocene p.p.-early Oligocene p.p.); (3) reconstruction of the evolution of the sedimentary realm, and of the relationships between tectonics and sedimentation; and (4) comparison between the upper Cretaceous-Miocene stratigraphic record and tectonic events of the Intrarif, which is located in the western external portion of the Maghrebian Flysch Basin, and the equivalent sedimentary record of the eastern portion of this basin in the Tunisian Tell. More in general, our results allowed (i) a first reconstruction of the Cretaceous-Miocene main tectono-sedimentary events; (ii) a more detailed location of the sedimentary suite in the external African Margin in the context of a wider palaeogeographic framework; and (iii) the definition of the main stages of the geological evolution of the area.  相似文献   

Functional diversity of fish and invertebrates in coral and rocky reefs of the Eastern Tropical Pacific          下载免费PDF全文

Georgina Ramírez‐Ortiz  Luis E. Calderon‐Aguilera  Hector Reyes‐Bonilla  Arturo Ayala‐Bocos  Luis Hernández  Francisco Fernández Rivera‐Melo  Andres López‐Pérez  Arturo Dominici‐Arosamena 《Marine Ecology》2017,38(4)

To define the functional groups of fish and macroinvertebrates in the Eastern Tropical Pacific (ETP), visual censuses were performed in 18 areas of four biogeographic provinces: Cortés, Mexican, Panamic and Oceanic Islands. A total of 257 fish and macroinvertebrate species were recorded, and from them, 27 morpho‐functional groups (MFGs) were constructed on the basis of trophic level, maximum size, taxonomy and morphology. Biomass, richness, diversity and evenness of MFGs were calculated for each province and compared statistically; a regression analysis between taxonomic and functional diversity was conducted to observe the relationship between these two indicators. There were significant differences in all ecological indices (p < .002), highlighting the high biomass and richness of MFGs in the Cortés and Oceanic Islands provinces (>400 g/m²), associated with the influence of cold currents in the northernmost region and less fishing pressure in protected areas. A decreasing pattern of MFG richness towards the tropics was observed, which demonstrates that in the ETP, the relationship between habitat heterogeneity and species diversity has been translated into functional complexity. The Mexican province was the most functionally diverse (biomass well distributed in the MFG; H′ = 0.46 ± 0.009). Related to this, it is predicted that biomass is biased towards certain functional groups (i.e., large carnivores), which shows that the H′ index of the MFG is not a good indicator of the conservation status of ETP reefs. Finally, regression analysis suggests that functional diversity increases at low species diversity but eventually reaches an asymptote (almost all possible functions are represented).  相似文献   

Shear-induced folding in Arsia Mons aureole: Evidence for low-latitude martian glaciations     

Francisco Anguita  Fernando Moreno 《Earth, Moon, and Planets》1992,59(1):11-22

Folds up to 50 km across have been identified on Arsia Mons aureole. Tharsis Province, Mars. The structures, located on Mars for the first time, are close to Aganippe Fossa and other huge faults which have behaved as left-lateral shear zones and then as extensional features. A tectonic scheme is proposed to explain the folds as shear-induced structures. Folding reveals a layered sequence in the aureole, and that is taken as a definitive evidence for its deposition by ice.If at least some of the Tharsis volcanoes aureoles are basal moraines, their study is critical, as they could contain a record of Mars paleoclimatic fluctuations. Martian past frozen lakes or oceans have been proposed, and some sediments found on the northern plains could have been deposited on the bottom of those basins. If this is so, those formations should be layered sequences and could also bear the traces of tectonic stresses, detectable as folds on Viking imagery. Correlation of these two kinds of evidence seems a promising line to tackle the Martian paleoclimatic problem.  相似文献   

Microtremor Analyses at Teide Volcano (Canary Islands,Spain): Assessment of Natural Frequencies of Vibration Using Time-dependent Horizontal-to-vertical Spectral Ratios     

Javier?AlmendrosEmail author  Francisco?Luzón  Antonio?Posadas 《Pure and Applied Geophysics》2004,161(7):1579-1596

We use time-dependent horizontal-to-vertical spectral ratios (HVSR) of microtremors to determine the dominant frequencies of vibration of the geological structures beneath several recording sites in the vicinity of Teide volcano (Canary Islands, Spain). In the microtremors, the time-dependent HVSRs (ratiograms) are a useful tool to discriminate between the presence of real dominant frequencies linked to resonances of the subsurface structure and the spurious appearance of peaks due to local transients. We verified that the results are repeatable, in the sense that microtremors recorded at the same site but at different times yield a very similar HVSR function. Two types of results are found: (1) sites where there is no resonance of the propagating microtremors, and therefore no value of a dominant frequency can be assessed; and (2) sites where a stationary peak in the HVSR is found and a dominant frequency related to resonance of the shallow structure can be estimated. These resonant frequencies show substantial spatial variations even for nearby sites, which reflects the complexity of the shallow velocity structure in the Las Cañadas area. Large dominant frequencies occur near the caldera walls and also at a few locations that coincide with the intersections of the inferred rims of the three calderas forming Las Cañadas. Small dominant frequencies also occur near the caldera rim, and may be due to discontinuities in the caldera wall and/or to local velocity anomalies. Intermediate frequencies are mostly found in the eastern part of the caldera, where a tentative profile of the basement depth has been obtained. Intermediate frequencies have also been measured south of Ucanca and south of Montaña Blanca. In view of the present results, we conclude that the use of ratiograms constitutes an improvement of the HVSR method and provides an appropriate tool to investigate the shallow velocity structure of a volcanic region.  相似文献   

Barcelona's planning strategies: from 'Paris of the South' to the 'Capital of West Mediterranean'     

Francisco Javier Monclús 《GeoJournal》2000,51(1-2):57-63

Planning strategies in Barcelona are linked to its capital city aspirations. Like other European cities, capitals and non-capitals, Barcelona throughout the course of the 20th century has drawn upon a number of different planning strategies, directed towards reinforcing its prestige at both a national and international level. During this period Barcelona has sought to become Spain's second capital, the cultural capital, the industrial capital, capital of Catalonia, capital of the West Mediterranean, etc. Always in competition with Madrid, the aspirations of capital status ranking have been ambiguous. The dream of the great monumental Barcelona of the start of the century tried to emulate the European capital cities (especially Paris). By contrast more recent strategies emphasise the new role that Barcelona can play within a south-west European macro-region. The subject raised in this paper then is two-fold. On the one hand the continuity or not in the capital aspiration starting from the recuperation of Catalonia's autonomy, with its corresponding urbanistic and architectonic connotations. On the other hand the originality and analogies between strategies carried out in Barcelona, in relation to other European cities, capitals and non-capitals.  相似文献   

The current tectonic motion of the Northern Andes along the Algeciras Fault System in SW Colombia   总被引：2，自引：1，他引：2  

Francisco Velandia  Jorge Acosta  Roberto Terraza  Henry Villegas 《Tectonophysics》2005,399(1-4):313

Riedel, synthetic and antithetic type faults, principal displacement zones (PDZ), pull-apart basins (such as lazy-S shaped releasing bend, extensive and rhomboidal shaped and releasing sidestep basins) and minor folds located oblique to the main trace of the Algeciras Fault System (AFS) are interpreted from Landsat TM 5 images and geological mapping. These tectonic features are affecting Quaternary deposits and are related to major historical earthquakes and recent registered seismic events, indicating neotectonic activity of the structure.The AFS is classified as a right lateral wrench complex structure, with an important vertical component in which sedimentary cover and basement rocks are involved. In addition, the system represents a simple shear caused by the oblique convergence between the Nazca Plate and the northern Andes. The transpressive boundary in SW Colombia was previously located along the Eastern Frontal Fault System. However, this paper shows that the AFS constitutes the actual boundary of the current transpressive regime along the Northern Andes, which begins at the Gulf of Guayaquil in Ecuador and continues into Colombia and Venezuela.  相似文献   

Stable isotope study of cave percolation waters in subtropical Brazil: Implications for paleoclimate inferences from speleothems     

Francisco W. Cruz  Jr.  Ivo Karmann  Oduvaldo Viana  Jr.  Stephen J. Burns  Jos A. Ferrari  Mathias Vuille  Alcides N. Sial  Marcelo Z. Moreira 《Chemical Geology》2005,220(3-4):245-262

We analyze the interannual monthly variability of oxygen isotope ratios in data from IAEA stations along the Atlantic coast of South America between 23° and 34° S to evaluate the influence of parameters such as temperature, rainfall amount and moisture source contribution on meteoric water recharging two karst systems in subtropical Brazil. In addition, a 2 year monitoring program performed on soil and cave drip and rimstone pool waters from sampling sites with contrasting discharge values and located at 100 and 300 m below the surface in the Santana Cave System (24°31′ S; 48°43′ W), is used to test the influence of hydrologic and geologic features on the temporal variations of seepage water δ¹⁸O.

Interannual monthly variations in δ¹⁸O of rainfall reflect primarily regional changes in moisture source contribution related to seasonal shifts in atmospheric circulation from a more monsoonal regime in summer (negative values of δ¹⁸O) to a more extratropical regime in winter (positive values of δ¹⁸O). Variations in groundwater δ¹⁸O indicate that the climatic signal of recent rainfall events is rapidly transmitted through the relatively deep karst aquifer to the cave drip waters, regardless of location of collection in the cave. In addition, the data also suggest that water replenishment in the system is triggered by the increase in hydraulic head during periods when recharge exceeds the storage capacity of the soil and epikarst reservoirs. Significant perturbations in the groundwater composition, characterized by more positive values of δ¹⁸O, are probably connected to an increased Atlantic moisture contribution associated with extratropical precipitation. This implies that the δ¹⁸O of speleothems from caves in this region may be a suitable proxy for studying tropical–extratropical interactions over South America, a feature that is intrinsically related to the global atmospheric circulation.  相似文献   

Liquefaction-induced structures in Quaternary alluvial gravels and gravelly sediments, NE Brazil     

Francisco H.R. Bezerra  Vanildo P. da Fonseca  Claudio Vita-Finzi  Francisco P. Lima-Filho  Allaoua Saadi 《Engineering Geology》2005,76(3-4):191-208

We have identified numerous well-preserved elutriation and fluidization structures probably induced by liquefaction in Quaternary gravels and gravelly sediments of braided fluvial channel deposits in the Rio Grande do Norte and Ceará states, northeastern Brazil. They show evidence of upward-directed water escape after sediment deposition and before sediment compaction. Among the several types of structures observed, the most frequent are pillars, pockets and dikes. These structures range in width from a few centimeters to as much as 4 m, and in height from 60 cm to 4 m. Dikes, pillars and pockets are systematically associated. Clastic dikes vented large quantities of sand to the upper layers or the surface; pebbles and cobbles from the host rock sank into the dikes and formed pillars and pockets. Pockets form the root part; pillars form the intermediate part and dike, the upper part of the composite structure. The morphology of the structures in sectional and plan views indicates a 3D geometry composed of a tabular dike and pillar that present a downward continuous transition to a bowl-shaped pocket. This “stratigraphy” of liquefaction features is different from that usually presented in the current literature.

Field data suggest that both the location and the geometry of the features were controlled by sedimentary properties rather than joints and small faults. The size and abundance of these features suggest that they were formed by great events rather than localized mechanisms. Field evidence also indicates that these features are the product of fluidization and elutriation and may have been induced by liquefaction processes associated with seismic shaking. A nonseismic origin related to elutriation processes, however, cannot be ruled out for some of the features.  相似文献