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141.
The Prairie Pothole Region in the United States contains millions of seasonal, semi-permanent, or permanent lakes and wetlands that typically range in size from 0.1 to 10 ha. These lakes and wetlands are vulnerable to climate change, especially in our study area in South Dakota, in which a period of deluge following a sharp drought considerably expanded the areal extent of prairie pothole lakes during the last decade of the twentieth century. Preliminary estimates of lake areas, determined using LANDSAT 5 and 7 images, had appreciable errors especially for the smallest of these lakes. This article describes a new sub-pixel approach integrated with a CART (Classification and Regression Tree) model using a GIS (Geographical Information System) to quantify mixed water pixels along lake boundaries to improve area estimations for pothole lakes. Errors in estimated area were typically 10% or less for lakes greater than 1 ha in size. An analysis of lakes in our study area demonstrates how lake area changed with the transition from drought to deluge. Small lakes exhibited a distinct seasonal variation in contrast to large lakes that tended to follow precipitation trends more broadly. The total water area of lakes is consistent with broad variation in rainfall. 相似文献
142.
Franklin S. Kinnaman Justine B. Kimball Luis Busso Daniel Birgel Haibing Ding Kai-Uwe Hinrichs David L. Valentine 《Geo-Marine Letters》2010,30(3-4):355-365
The Coal Oil Point seep field located offshore Santa Barbara, CA, consists of dozens of named seeps, including a peripheral ~200 m2 area known as Brian Seep, located in 10 m water depth. A single comprehensive survey of gas flux at Brian Seep yielded a methane release rate of ~450 moles of CH4 per day, originating from 68 persistent gas vents and 23 intermittent vents, with gas flux among persistent vents displaying a log normal frequency distribution. A subsequent series of 33 repeat surveys conducted over a period of 6 months tracked eight persistent vents, and revealed substantial temporal variability in gas venting, with flux from each individual vent varying by more than a factor of 4. During wintertime surveys sediment was largely absent from the site, and carbonate concretions were exposed at the seafloor. The presence of the carbonates was unexpected, as the thermogenic seep gas contains 6.7% CO2, which should act to dissolve carbonates. The average δ13C of the carbonates was ?29.2?±?2.8‰ VPDB, compared to a range of ?1.0 to +7.8‰ for CO2 in the seep gas, indicating that CO2 from the seep gas is quantitatively not as important as 13C-depleted bicarbonate derived from methane oxidation. Methane, with a δ13C of approximately ?43‰, is oxidized and the resulting inorganic carbon precipitates as high-magnesium calcite and other carbonate minerals. This finding is supported by 13C-depleted biomarkers typically associated with anaerobic methanotrophic archaea and their bacterial syntrophic partners in the carbonates (lipid biomarker δ13C ranged from ?84 to ?25‰). The inconsistency in δ13C between the carbonates and the seeping CO2 was resolved by discovering pockets of gas trapped near the base of the sediment column with δ13C-CO2 values ranging from ?26.9 to ?11.6‰. A mechanism of carbonate formation is proposed in which carbonates form near the sediment–bedrock interface during times of sufficient sediment coverage, in which anaerobic oxidation of methane is favored. Precipitation occurs at a sufficient distance from active venting for the molecular and isotopic composition of seep gas to be masked by the generation of carbonate alkalinity from anaerobic methane oxidation. Figure
Processes modulating carbonate formation at Brian Seep (California) during times of high and low sediment burden 相似文献
143.
Compositional variability and air-sea flux of ethane and propane in the plume of a large, marine seep field near Coal Oil Point, CA 总被引:1,自引:1,他引:0
Susan Mau Monica B. Heintz Franklin S. Kinnaman David L. Valentine 《Geo-Marine Letters》2010,30(3-4):367-378
Large quantities of methane (C1), ethane (C2), and propane (C3) emanate from shallow marine seeps near Coal Oil Point (COP), California. Concentrations of these gases were analyzed in the surface water down-current of the seep field over a 15-month period. The variable proportions of C1, C2, and C3 analyzed in gas bubbles emitted from 16 distinct seeps in the COP field encompass much of the variability found in the surface waters down-current. However, waters with disproportionate levels of C1 suggest the presence of additional C1 sources. Based on three spatial surveys, covering areas up to 280 km2, C2 and C3 air-sea fluxes were estimated to be in the order of 3.7 and 1.4 μmol day?1 m?2, respectively. Only 0.6% of C2 and 0.5% of C3 in the dissolved plume originating from the COP seep field are transferred to the atmosphere in the study area, with the fate of the remainder uncertain. 相似文献