Thermodynamics of the xanthoconite-proustite and pyrostilpnite-pyrargyrite phase transition as determined by abrasive stripping voltammetry     

Birgit Lange  Fritz Scholz  Hans-Joachim Bautsch  Ferdinand Damaschun  Gert Wappler 《Physics and Chemistry of Minerals》1993,19(7):486-491

The electrochemical reduction of xanthoconite, proustite, pyrostilpnite, and pyrargyrite was studied by abrasive stripping voltammetry, a technique which is based upon a preliminary mechanical transfer of trace amounts of the mineral onto the surface of a paraffin impregnated graphite electrode. Because the electrochemical reduction proceeds near to reversibility and is very similar for each pair of minerals, the peak potentials in differential pulse voltammetry can be used to calculate the standard enthalpy of phase transformation of xanthoconite to proustite and of pyrostilpnite to pyrargyrite: _T H _{(xanth proust)} ^O = 35.46 ± 14.15 kJ/mol and _T H _{(pyrostilp pyrarg)} ^O = 38.85 ± 6.60 kJ/mol. These values are not accessible otherwise until now.  相似文献   

Tectonic setting, evolution and orogenic gold potential of the late Mesoarchaean Mosquito Creek Basin, North Pilbara Craton, Western Australia   总被引：1，自引：0，他引：1  

L. Bagas  F.P. Bierlein  S. Bodorkos  D.R. Nelson 《Precambrian Research》2008,160(3-4):227-244

The geology, evolution, and metallogenic potential of the Mesoarchaean Mosquito Creek Basin remains poorly understood, despite the presence of several orogenic gold deposits. The basin is dominated by medium- to coarse-grained, poorly sorted and chemically immature sandstone and conglomerates, characterised by very high Cr/Th, high Th/Sc, and low Zr/Sc relative to average continental crust. These features are consistent with the presence of significant mafic rocks in the source terrain(s), a limited role for sediment recycling, and deposition in an increasingly distal passive margin setting on the southeastern edge of the Palaeo- to Mesoarchaean East Pilbara Terrane.New U–Pb SHRIMP data on 358 detrital zircons indicate a conservative maximum depositional age of 2972 + 14/−37 Ma (robust median; 96.1% confidence). Zircon provenance spectra from conglomeratic rocks near the base of the unit are consistent with substantial derivation from the East Pilbara Terrane, but finer-grained sandstones higher in the stratigraphy appear to have been sourced elsewhere, as their zircon age spectra are not well matched by any of the exposed Pilbara terranes.The Mosquito Creek Basin was deformed before and during collision with the northern edge of the Mesoarchaean Kurrana Terrane, which resulted in the development of macroscopic north-verging folds, thrust faulting, and widespread sub-greenschist to greenschist facies metamorphism. This collisional event probably took place at ca. 2900 Ma, based on two identical Pb–Pb model ages of 2905 ± 9 Ma from epigenetic galena associated with vein-hosted gold–antimony mineralization. The metallogenic potential of the Mosquito Creek Basin remains largely unevaluated; however, the possibility of a passive margin setting and continental basement points to relatively limited potential for the formation of major orogenic gold deposits.  相似文献   

Impacts of Unsaturated Zone Properties on Oxygen Transport and Aquifer Reaeration   总被引：1，自引：0，他引：1  

C. Nelson Neale  Joseph B. Hughes  C.H. Ward 《Ground water》2000,38(5):784-794

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Chemical cues released by heterospecific competitors: behavioural responses of native and alien invasive aquatic gastropods     

Jacqueline L. Raw  Nelson A. F. Miranda  Renzo Perissinotto 《Aquatic Sciences - Research Across Boundaries》2015,77(4):655-666

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Air–sea interactions during strong winter extratropical storms     

Jill Nelson  Ruoying He  John C. Warner  John Bane 《Ocean Dynamics》2014,64(9):1233-1246

A high-resolution, regional coupled atmosphere–ocean model is used to investigate strong air–sea interactions during a rapidly developing extratropical cyclone (ETC) off the east coast of the USA. In this two-way coupled system, surface momentum and heat fluxes derived from the Weather Research and Forecasting model and sea surface temperature (SST) from the Regional Ocean Modeling System are exchanged via the Model Coupling Toolkit. Comparisons are made between the modeled and observed wind velocity, sea level pressure, 10 m air temperature, and sea surface temperature time series, as well as a comparison between the model and one glider transect. Vertical profiles of modeled air temperature and winds in the marine atmospheric boundary layer and temperature variations in the upper ocean during a 3-day storm period are examined at various cross-shelf transects along the eastern seaboard. It is found that the air–sea interactions near the Gulf Stream are important for generating and sustaining the ETC. In particular, locally enhanced winds over a warm sea (relative to the land temperature) induce large surface heat fluxes which cool the upper ocean by up to 2 °C, mainly during the cold air outbreak period after the storm passage. Detailed heat budget analyses show the ocean-to-atmosphere heat flux dominates the upper ocean heat content variations. Results clearly show that dynamic air–sea interactions affecting momentum and buoyancy flux exchanges in ETCs need to be resolved accurately in a coupled atmosphere–ocean modeling framework.  相似文献   

Paleohydraulic reconstruction of a 40 ka‐old terrace sequence implies that water discharge was larger than today          下载免费PDF全文

Camille Litty  Robert Duller  Fritz Schlunegger 《地球表面变化过程与地形》2016,41(7):884-898

The evolution of landscapes crucially depends on the climate history. This is particularly evident in South America where landscape responses to orbital climate shifts have been well documented. However, while most studies have focused on inferring temperature variations from paleoclimate proxy data, estimates of water budget changes have been complicated because of a lack of adequate physical information. Here, we present a methodology and related results, which allowed us to extract water discharge values from the sedimentary record of the 40 Ka‐old fluvial terrace deposits in the Pisco valley, western Peru. In particular, this valley hosts a Quaternary cut‐and‐fill succession that we used, in combination with beryllium‐10 (¹⁰Be)‐based sediment flux, gauging records, channel geometries and grain size measurements, to quantitatively assess sediment and water discharge values c. 40 Ka ago in relation to present‐day conditions. We compare these discharge estimates to the discharge regime of the modern Pisco River and find that the water discharge of the paleo‐Pisco River, during the Minchin pluvial period c. 40 Ka ago, was c. 7–8 times greater than the modern Pisco River if considering the mean and the maximum water discharge. In addition, the calculations show that inferred water discharge estimates are mainly dependent on channel gradients and grain size values, and to a lesser extent on channel width measures. Finally, we found that the c. 40 Ka‐old Minchin terrace material was poorer sorted than the modern deposits, which might reflect that sediment transport during the past period was characterized by a larger divergence from equal mobility compared to the modern situation. In summary, the differences in grain size distribution and inferred water discharge estimates between the modern and the paleo‐Pisco River suggests that the 40 Ka‐old Minchin period was characterized by a wetter climate and more powerful flood events. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

10Be‐derived assessment of accelerated erosion in a glacially conditioned inner gorge,Entlebuch, Central Alps of Switzerland     

Fabien Van den Berg  Fritz Schlunegger  Naki Akçar  Peter Kubik 《地球表面变化过程与地形》2012,37(11):1176-1188

Inner gorges often result from the propagation of erosional waves related to glacial/interglacial climate shifts. However, only few studies have quantified the modern erosional response to this glacial conditioning. Here, we report in situ ¹⁰Be data from the 64 km² Entlen catchment (Swiss Alps). This basin hosts a 7 km long central inner gorge with two tributaries that are >100 m‐deeply incised into thick glacial till and bedrock. The ¹⁰Be concentrations measured at the downstream end of the gorge yield a catchment‐wide erosion rate of 0.42 ± 0.04 mm yr^‐1, while erosion rates are consistently lower upstream of the inner gorge, ranging from 0.14 ± 0.01 mm yr^‐1 to 0.23 ± 0.02 mm yr^‐1. However, ¹⁰Be‐based sediment budget calculations yield rates of ~1.3 mm yr^‐1 for the inner gorge of the trunk stream. Likewise, in the two incised tributary reaches, erosion rates are ~2.0 mm yr^‐1 and ~1.9 mm yr^‐1. Moreover, at the erosional front of the gorge, we measured bedrock incision rates ranging from ~2.5 mm yr^‐1 to ~3.8 mm yr^‐1. These rates, however, are too low to infer a post‐glacial age (15–20 ka) for the gorge initiation. This would require erosion rates that are between 2 and 6 times higher than present‐day estimates. However, the downcutting into unconsolidated glacial till favored high erosion rates through knickzone propagation immediately after the retreat of the LGM glaciers, and subsequent hillslope relaxation led to a progressive decrease in erosion rates. This hypothesis of a two‐ to sixfold decrease in erosion rates does not conflict with the ¹⁰Be‐based erosion rate budgets, because the modern erosional time scale recorded by ¹⁰Be cover the past 2–3 ka only. These results point to the acceleration of Holocene erosion in response to the glacial overprint of the landscape. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Pyroclastic dune bedforms: macroscale structures and lateral variations. Examples from the 2006 pyroclastic currents at Tungurahua (Ecuador)     

Guilhem Amin Douillet  Benjamin Bernard  Mlanie Bouysson  Quentin Chaffaut  Donald Bruce Dingwell  Lukas Gegg  Inga Hoelscher  Ulrich Kueppers  Clia Mato  Vanille Ariane Ritz  Fritz Schlunegger  Patrick Witting 《Sedimentology》2019,66(5):1531-1559

Pyroclastic currents are catastrophic flows of gas and particles triggered by explosive volcanic eruptions. For much of their dynamics, they behave as particulate density currents and share similarities with turbidity currents. Pyroclastic currents occasionally deposit dune bedforms with peculiar lamination patterns, from what is thought to represent the dilute low concentration and fluid‐turbulence supported end member of the pyroclastic currents. This article presents a high resolution dataset of sediment plates (lacquer peels) with several closely spaced lateral profiles representing sections through single pyroclastic bedforms from the August 2006 eruption of Tungurahua (Ecuador). Most of the sedimentary features contain backset bedding and preferential stoss‐face deposition. From the ripple scale (a few centimetres) to the largest dune bedform scale (several metres in length), similar patterns of erosive‐based backset beds are evidenced. Recurrent trains of sub‐vertical truncations on the stoss side of structures reshape and steepen the bedforms. In contrast, sporadic coarse‐grained lenses and lensoidal layers flatten bedforms by filling troughs. The coarsest (clasts up to 10 cm), least sorted and massive structures still exhibit lineation patterns that follow the general backset bedding trend. The stratal architecture exhibits strong lateral variations within tens of centimetres, with very local truncations both in flow‐perpendicular and flow‐parallel directions. This study infers that the sedimentary patterns of bedforms result from four formation mechanisms: (i) differential draping; (ii) slope‐influenced saltation; (iii) truncative bursts; and (iv) granular‐based events. Whereas most of the literature makes a straightforward link between backset bedding and Froude‐supercritical flows, this interpretation is reconsidered here. Indeed, features that would be diagnostic of subcritical dunes, antidunes and ‘chute and pools’ can be found on the same horizon and in a single bedform, only laterally separated by short distances (tens of centimetres). These data stress the influence of the pulsating and highly turbulent nature of the currents and the possible role of coherent flow structures such as Görtler vortices. Backset bedding is interpreted here as a consequence of a very high sedimentation environment of weak and waning currents that interact with the pre‐existing morphology. Quantification of near‐bed flow velocities is made via comparison with wind tunnel experiments. It is estimated that shear velocities of ca 0·30 m.s^?1 (equivalent to pure wind velocity of 6 to 8 m.s^?1 at 10 cm above the bed) could emplace the constructive bedsets, whereas the truncative phases would result from bursts with impacting wind velocities of at least 30 to 40 m.s^?1.  相似文献   

Ground motion modelling in Tehran based on the stochastic method     

Saman Yaghmaei-Sabegh  Nelson T.K. Lam 《Soil Dynamics and Earthquake Engineering》2010

This paper presents the development of a seismological model for the Tehran area. This modelling approach, which was originally developed in Eastern North America, has been used successfully in other parts of the world including Australia and China for simulating accelerograms and elastic response spectra. Parameters required for input into the model were inferred from seismological and geological information obtained locally. The attenuation properties of the earth crust were derived from the analysis of accelerogram records that had been collated from within the region in a previous study. In modelling local modifications of seismic waves in the upper crust, shear-wave velocity profiles have been constructed in accordance with the power law. Information inferred from micro-zonation studies (for near-surface conditions) and from measurements of teleseismic P-waves reflected from the deeper crusts as reported in the literature has been used to constrain parameters in the power-law relationships. This method of obtaining amplification factors for the upper crust distinguishes this study from earlier studies in the Tehran area (in which site amplification factors were inferred from the H/V ratio of the recorded ground motions). The regional specific seismological model so constructed from the study enabled accelerograms to be simulated and elastic response spectra calculated for a series of magnitude–distance combinations. Importantly, elastic response spectra calculated from the simulated accelerograms have been compared with those calculated from accelerograms recorded from earthquakes with magnitudes ranging between M6.3 and M7.4. The peak ground velocity values calculated from the simulated accelerograms have also been correlated with values inferred from macro-seismic intensity data of 17 historical earthquakes with magnitudes varying between 5.4 and 7.7 and with distances varying between 40 and 230 km. This paper forms part of the long-term strategy of the authors of applying modern techniques for modelling the attenuation behaviour of earthquakes in countries which are lacking in instrumental data of earthquakes.  相似文献   

Inferring lake depth using diatom assemblages in the shallow,seasonally variable lakes of the Nebraska Sand Hills (USA): calibration,validation, and application of a 69-lake training set     

Avery L. C. Shinneman  Danuta M. Bennett  Sherilyn C. Fritz  Jens Schmieder  Daniel R. Engstrom  Aris Efting  John Holz 《Journal of Paleolimnology》2010,44(2):443-464

The Nebraska Sand Hills are a distinctive eco-region in the semi-arid Great Plains of the western United States. The water table underlying the Sand Hills is part of the High Plains/Ogallala aquifer, an important water resource for the central Great Plains. Lake levels are affected directly by fluctuations in the water table, which is recharged primarily by local precipitation and responds quickly to climatically induced changes in regional water balance. Instrumental records are available for only 50–100 years, and paleolimnological data provide important insights into the extremes and variability in moisture balance over longer time scales. A set of 69 lakes from across Nebraska was used to establish a statistical relationship between diatom community composition and water depth. This relationship was then used to develop a diatom-based inference model for water depth using weighted averaging regression and calibration techniques. Development of the inference model was complicated by strong intra-seasonal variability in water depth and the linkages between depth and other limnologic characteristics, including alkalinity, water clarity and nutrient concentrations. Analysis of historical diatom communities from eight lakes allowed for the reconstruction of lake-level fluctuations over the past several thousand years. Comparisons of the more recent portion of these reconstructions with the instrumental Palmer Drought Severity Index (PDSI) showed that sediment records may not faithfully reflect short-term fluctuations in water level, except where sedimentation rates are very high. However, large and persistent changes in moisture availability were discernible even in longer, low-resolution records. Thus, diatoms are a useful addition to the tools available for understanding past drought in the central Great Plains, especially when trajectories of change are constrained by data from multiple sites or other proxies.  相似文献