Medium-scale maps after survey from space—The “Metric-Camera”—Experiment     

Fezer Fritz Prof. Dr.  Reichenbach Bernhard  Witschel Christian MA  Hell Günter Prof. Dr.-Ing.  Duster Manfred Dipl.-Ing  Heidrich Brigitte 《GeoJournal》1987,14(4):467-478

Airphotos have been used for topographic survey since the Twenties. The “European Space Agency” (ESA), the “Deutsche Forschungs- und Versuchsanstalt für Luft- und Raumfahrt” (DFVLR) and “Carl Zeiss” have modified this successful technique for spacecraft and recently have tested the system over four continents. Each of these satellite photos covers a region of 189×189 km to the scale of 1∶800000 and may be enlarged to 1∶250000 or 1∶100000. Between the altitudes of 200 and 300 km, mapmaking or-revision seems to be economic in zones or in countries, where existing maps are of minor quality or outdated. In this paper, examples from deserts and semideserts in the Sudan are presented.  相似文献   

Strontium isotopic composition of some brines from the Precambrian Shield of Canada     

Robert H. McNutt  Shaun K. Frape  Peter Fritz 《Chemical Geology》1984,46(3):205-215

Twenty-four groundwater samples from seven operating mines at Sudbury, Yellow-knife and Thompson (Ontario, North West Territories and Manitoba, resp.), all from depths greater than 1 km and ranging in total dissolved solids (TDS) from 1900 to 250,000 mg l^?1, were measured for their ${}^{87}\text{Sr}{}^{86}\text{Ar}$ values. Each geographic location gives a limited range in values and each location is distinct from the others. This is interpreted as the result of extensive water-rock interaction on a local scale. For most of the time, these brines were isolated and only recently have been exposed to surface water as a result of the mining operations. The extent of the isolation is shown by the contrasting isotopic values of two “pockets” of water (0.711 vs. 0.716) located on opposite sides of the same fault system on the North Range at Sudbury. The exchange at all sites probably has continued until the present, as indicated by the close agreement between water and present-day${}^{87}\text{Sr}{}^{86}\text{Sr}$ whole-rock values. If so, it suggests that there is no single age for such brines, but it may be possible to date stages in the water's evolution by determining the age of secondary minerals that equilibrated with the water.  相似文献   

Water-rock interaction and chemistry of groundwaters from the Canadian Shield     

S.K. Frape  P. Fritz  R.H. McNutt 《Geochimica et cosmochimica acta》1984,48(8):1617-1627

The chemical and isotopic compositions of groundwaters in the crystalline rocks of the Canadian Shield reflect different degrees of rock-water interactions. The chemistry of the shallow, geochemically immature groundwaters and especially of the major cations is controlled by local rock compositions, whereby dissolution reactions dominate. Conservative constituents, such as chloride and bromide, however, are not entirely a result of such reactions but appear to be readily added from leachable salts during the initial stages of the geochemical evolution of these waters. Their concentration changes little as major cations increase, until concentrations of Total Dissolved Solids (TDS) reach 3000 to 5000 mg 1^?1. The isotopic composition of these shallow waters reflects local, present day precipitations.In contrast to the shallow groundwaters, the isotopic and chemical compositions of the deep, saline waters and brines are determined by extensive, low-temperature rock-water interactions. This is documented in major ion chemistries, ¹⁸O contents and strontium isotopic compositions. These data indicate that the deep brines have been contained in hydrologically isolated “pockets”. The almost total loss of primary compositions make discussions on the origin of these brines very speculative. However, all brines from across the Canadian Shield have a very similar chemical composition, which probably reflects a common geochemical history. The concentrations of some major and most minor elements in these fluids appear to be governed by reactions with secondary mineral assemblages.  相似文献   

Use of biological traits for interpreting functional relationships in large rivers     

Arne Haybach  Franz Schll  Bernd Knig  Fritz Kohmann 《Limnologica》2004,34(4):451-459

Altogether 64 predominantly biological traits were coded for more than 600 macroinvertebrate species from European rivers. The main question was: Are biological traits able to reflect “biological functionality” in large rivers and if so, is it possible to deduce an assessment system based on functionality? Analysis of the raw trait structure of all species indicates that these traits are not completely independent from their higher systematic units. To avoid mis-interpretations when judging from mixtures of habitats (β-biocoenosis) we used for our investigations only sample series from -biocoenosis, pre-tested by a mathematical criterion of homogeneity. Within -biocoenosis, traits are shown to be able to compensate for drastic changes with respect to species number and species composition along a river continuum, demonstrating their functional quality. Long-term changes in the trait and species structures of German waterways were studied using multivariate methods, based on an analysis of 142 sampling series. A shift from traits typical for K-strategists to traits typical for r-strategists was detected to be the main background variable. The rK-strategy is regarded as a true functional character of species. We calculated the relative positions of all trait-coded species on this rK-scale, and plotted the functional diversity of our samples against the structural diversity of the species from several river systems. Rivers extremely dominated by r-strategists show a deficit in functional diversity. Rivers dominated by K-strategists also show deficits, possibly in concordance with modern ecological theories such as the intermediate disturbance theory. The quantitative proportions of extreme r- to K-Strategists in -biocoenosis can be used as a general disturbance measure.  相似文献   

Arsenic — a Review. Part II: Oxidation of Arsenic and its Removal in Water Treatment     

Monique Bissen  Fritz H. Frimmel 《洁净——土壤、空气、水》2003,31(2):97-107

In natural waters arsenic normally occurs in the oxidation states +III (arsenite) and +V (arsenate). The removal of As(III) is more difficult than the removal of As(V). Therefore, As(III) has to be oxidized to As(V) prior to its removal. The oxidation in the presence of air or pure oxygen is slow. The oxidation rate can be increased by ozone, chlorine, hypochlorite, chlorine dioxide, or H₂O₂. The oxidation of As(III) is also possible in the presence of manganese oxide coated sands or by advanced oxidation processes. Arsenic can be removed from waters by coprecipitation with Fe(OH)₃, MnO₂ or during water softening. Fixed‐bed filters have successfully been applied for the removal of arsenic.The effectiveness of arsenic removal was tested in the presence of adsorbents such as FeOOH, activated alumina, ferruginous manganese ore, granular activated carbon, or natural zeolites. Other removal technologies are anion exchange, electrocoagulation, and membrane filtration by ultrafiltration, nanofiltration or reverse osmosis.  相似文献   

Alkaline Degradation of Dissolved Organic Matter     

Thomas Brinkmann  Gudrun Abbt‐Braun  Fritz H. Frimmel 《洁净——土壤、空气、水》2003,31(3):213-224

The degradation of dissolved organic matter (DOM) was studied in alkaline solution. The products were characterised using UV/vis spectroscopy, size‐exclusion chromatography (SEC), and by the analysis of low‐molecular‐weight organic acids (LMWOA). The degradation experiments were performed with water from a brown water lake or its isolated fulvic acid fraction and sodium hydroxide at different reaction times and temperatures. Depending on the wavelength and the reaction time, the UV/vis absorbance between 230 nm and 600 nm increased or decreased. The behaviour of model compounds during reactions in alkaline media was compared to the UV/vis spectroscopic behaviour of DOM. The release of LMWOA was described by kinetic data and compared to the data of model reactions. Evidence was given for the carboxylic esters playing a significant role in the release of LMWOA only during the beginning of the alkaline degradation. The results gained by SEC with on‐line UV and DOC detection showed that the average size of DOM was decreasing, and that a major part of the degradation products consisted of low‐molecular‐weight mono‐ and dicarboxylic acids.  相似文献   

Arsenic — a Review. Part I: Occurrence,Toxicity, Speciation,Mobility     

Monique Bissen  Fritz H. Frimmel 《洁净——土壤、空气、水》2003,31(1):9-18

In natural waters arsenic concentrations up to a few milligrams per litre were measured. The natural content of arsenic found in soils varies between 0.01 mg/kg and a few hundred milligrams per kilogram. Anthropogenic sources of arsenic in the environment are the smelting of ores, the burning of coal, and the use of arsenic compounds in many products and production processes in the past. A lot of arsenic compounds are toxic and cause acute and chronic poisoning. In aqueous environment the inorganic arsenic species arsenite (As(III)) and arsenate (As(V)) are the most abundant species. The mobility of these species is influenced by the pH value, the redox potential, and the presence of adsorbents such as oxides and hydroxides of Fe(III), Al(III), Mn(III/IV), humic substances, and clay minerals.  相似文献   

Short Static GPS Sessions: Robust Estimation Results   总被引：4，自引：0，他引：4  

Andreas Wieser  Fritz K. Brunner 《GPS Solutions》2002,5(3):70-79

Least-squares estimation (LS) yields results of low accuracy in the presentce of GPS phase-corrupting environmental conditions. We present a robust estimator that clearly identifies outlying observations caused by obstacles like diagonal cables, branches, or leaves. It performs significantly better than standard LS and signal-to-noise ratio dependent weighting if unfavorable signal distortion occurs, and is equal to LS otherwise. The estimator is realized by an iterated LS algorithm using an equivalent weight matrix. It is a generalization of the Danish Method to heterogeneous and correlated observations. The excellent peformance of the estimator for processing short static sessions is demonstrated using data obtained from an investigation of GPS signal obstruction. ? 2002 Wiley Periodicals, Inc.  相似文献   

Étude expérimentale des transformations de phase dans un gradient thermique : application au granite de Soultz-sous-Forêts,France     

Armelle Baldeyrou  Olivier Vidal  Bertrand Fritz 《Comptes Rendus Geoscience》2003,335(4):371-380

The circulation of an injected fluid in the deep granite of the Soultz-sous-Forêts HDR (‘Hot Dry Rock’) site causes important textural and mineralogical modifications. In order to determine the potential crystallization sequences along the fluid pathway, several experiments under thermal gradient were conducted at 600 bar (between 300 and 200 °C). After 40 days, the observed sequences of the newly formed products along the thermal gradient are always as follows, from high to low temperatures: quartz, feldspars, and finally interstratified clays, this implying a significant mobility of aluminium in the solution. To cite this article: A. Baldeyrou et al., C. R. Geoscience 335 (2003).  相似文献   

Argiles et zéolites dans l'altération d'un volcan bouclier en milieu tropical (Le Piton des Neiges,La Réunion)     

Laurent Bret  Jean-Lambert Join  Xavier Legal  Jean Coudray  Bertrand Fritz 《Comptes Rendus Geoscience》2003,335(14):1031-1038

The drilling of a gallery through the Roche-Écrite massif (Reunion Island) allowed to sample the old formations of the ‘Piton des Neiges’ volcano. The mineralogical study of the alteration products of the formations showed significant variations of the zeolites/clay minerals ratio depending on the location of the rocks in the volcano. The abundance of zeolites in the formation near the surface hydrographic network or the underground water drainage system seems to be due to the physicochemical processes favouring zeolites in more open systems in their competition with secondary clays. To cite this article: L. Bret et al., C. R. Geoscience 335 (2003).  相似文献