The postglacial history of three Picea species in New England, USA     

Matts Lindbladh  George L Jacobson Jr.Molly Schauffler 《Quaternary Research》2003,59(1):61-69

Given the difficulty of separating the three Picea species—P. glauca, P. mariana, and P. rubens (white, black, and red spruce)—in the pollen record, little is known about their unique histories in eastern North America following deglaciation. Here we report the first use of a classification tree analysis (CART) to distinguish pollen grains of these species. It was successfully applied to fossil pollen from eight sites in Maine and one in Massachusetts. We focused on the late glacial/early Holocene (14,000 to 8000 cal yr B.P.) and the late Holocene (1400 cal yr B.P. to present)—the two key periods since deglaciation when Picea has been abundant in the region. The result shows a shift from a Picea forest of P. glauca and P. mariana in the late glacial to a forest of P. rubens and P. mariana in the late Holocene. The small number of P. rubens grains identified from the late glacial/early Holocene samples (<5%) suggests that that species was either absent or rare at most of the sites. The occurrence and distribution of the three species do not reveal any geographic or temporal trend during late glacial time, but the data suggest that they were distributed in local patches on the landscape. The results of this study indicate that the recent population expansion of Picea (1000 to 500 cal yr B.P.) was likely the first time since deglaciation that P. rubens was abundant in the region.  相似文献   

Kinetics and Mechanism of Trithionate and Tetrathionate Oxidation at Low pH by Hydroxyl Radicals     

Gregory K. Druschel  Robert J. Hamers  George W. Luther III  Jillian F. Banfield 《Aquatic Geochemistry》2003,9(2):145-164

The oxidation kinetics of trithionate (S₃O₆^2- ) and tetrathionate (S₄O ₆ ^2- ) with hydroxyl radicals (OH^*) have been investigated in systems analogous to acid mine drainage (AMD) environments. The discovery of hydroxyl radical (OH^*) formation on pyrite surfaces (Borda et al., 2003) suggests hydroxyl radicals may affect the oxidation kinetics of intermediate sulfur species such as tetrathionate. Cyclic voltammetry experiments in acidic solutions indicate that the reaction of S₄O ₆ ^2- with OH^* goes through an unknown intermediate, tentatively assigned as S₃O ₄ ^n- . An outer-sphere electron transfer mechanism for the reaction of S₄O ₆ ^2- with OH^* to form S₃O ₄ ^n- is proposed based on experimental results. Oxidation rates for trithionate and tetrathionate in the presence of Fenton's reagent (which forms hydroxyl radicals) are too fast to be directly measured using UV-Vis spectrophotometry, electrochemical, or stop-flow spectrophotometry methods. Competitive reaction kinetics within the context of the Haber—Weiss mechanism suggests that the rate constant for the oxidation of trithionate and tetrathionate with OH^* is in excess of 10⁸ M^-1 sec^-1.  相似文献   

Shear-wave anisotropy: spatial and temporal variations in time delays at Parkfield, Central California   总被引：4，自引：0，他引：4  

Yun Liu  Stuart Crampin  Ian Main 《Geophysical Journal International》1997,130(3):771-785

Shear-wave splitting is analysed on data recorded by the High Resolution Seismic Network (HRSN) at Parkfield on the San Andreas fault, Central California, during the three-year period 1988-1990. Shear-wave polarizations either side of the fault are generally aligned in directions consistent with the regional horizontal maximum compressive stress, at some 70° to the fault strike, whereas at station MM in the immediate fault zone, shear-wave polarizations are aligned approximately parallel to the fault. Normalized time delays at this station are found to be about twice as large as those in the rock mass either side. This suggests that fluid-filled cracks and fractures within the fault zone are elastically or seismically different from those in the surrounding rocks, and that the alignment of fault-parallel shear-wave polarizations are associated with some fault-specific phenomenon.
Temporal variations in time delays between the two split shear-waves before and after a M_L = 4 earthquake can be identified at two stations with sufficient data: MM within the fault zone and VC outside the immediate fault zone. Time delays between faster and slower split shear waves increase before the M_L = 4 earthquake and decrease near the time of the event. The temporal variations are statistically significant at 68 per cent confidence levels. Earthquake doublets and multiplets also show similar temporal variations, consistent with those predicted by anisotropic poroelasticity theory for stress modifications to the microcrack geometry pervading the rock mass. This study is broadly consistent with the behaviour observed before three other earthquakes, suggesting that the build-up of stress before earthquakes may be monitored and interpreted by the analysis of shear-wave splitting.  相似文献   

Inelastic models of lithospheric stress-I. Theory and application to outer-rise plate deformation     

Steve Mueller  George L. Choy  William Spence 《Geophysical Journal International》1996,125(1):39-53

  相似文献   

Inelastic models of lithospheric stress-11. Implications for outer-rise seismicity and dynamics     

Steve Mueller  William Spence  George L. Choy 《Geophysical Journal International》1996,125(1):54-72

  相似文献   

410 km discontinuity sharpness and the form of the olivine α-β phase diagram: resolution of apparent seismic contradictions     

George R. Helffrich  Bernard J. Wood 《Geophysical Journal International》1996,126(2):F7-F12

  相似文献   

Geomorphological studies in Southern Africa: G.F. Dardis and B.P. Moon (Editors). A.A. Balkema, Rotterdam, 1988, x + 509 pp., 222 figures (including 105 half-tone photos) and 31 tables. Price: US$60.00 hardback. ISBN 90-6191-831-6     

George A. Brook 《Geomorphology》1996,16(4):349-350

  相似文献   

Dynamic stochastic estimation of physical variables   总被引：1，自引：0，他引：1  

George Christakos  Vijayanivas R. Raghu 《Mathematical Geology》1996,28(3):341-365

A fundamental problem facing the physical sciences today is analysis of natural variations and mapping of spatiotemporal processes. Detailed maps describing the space/time distribution of groundwater contaminants, atmospheric pollutant deposition processes, rainfall intensity variables, external intermittency functions, etc. are tools whose importance in practical applications cannot be overestimated. Such maps are valuable inputs for numerous applications including, for example, solute transport, storm modeling, turbulent-nonturbulent flow characterization, weather prediction, and human exposure to hazardous substances. The approach considered here uses the spatiotemporal random field theory to study natural space/time variations and derive dynamic stochastic estimates of physical variables. The random field model is constructed in a space/time continuum that explicitly involves both spatial and temporal aspects and provides a rigorous representation of spatiotemporal variabilities and uncertainties. This has considerable advantages as regards analytical investigations of natural processes. The model is used to study natural space/time variations of springwater calcium ion data from the Dyle River catchment area, Belgium. This dataset is characterized by a spatially nonhomogeneous and temporally nonstationary variability that is quantified by random field parameters, such as orders of space/time continuity and random field increments. A rich class of covariance models is determined from the properties of the random field increments. The analysis leads to maps of continuity orders and covariances reflecting space/time calcium ion correlations and trends. Calcium ion estimates and the associated statistical errors are calculated at unmeasured locations/instants over the Dyle region using a space/time kriging algorithm. In practice, the interpretation of the results of the dynamic stochastic analysis should take into consideration the scale effects.  相似文献   

Porewater pressure increases in soil and rock from underground chemical and nuclear explosions   总被引：3，自引：0，他引：3  

Wayne A. Charlie  George E. Veyera  Deanna S. Durnford  Donald O. Doehring 《Engineering Geology》1996,43(4):225-236

A review and analysis of chemical and nuclear explosive-induced porewater pressure increases and induced rise in groundwater table elevations (groundwater mounding) is presented. Our analysis indicates that residual pore pressure increases and groundwater mounding can be induced by underground chemical and nuclear explosions to scaled distances of 879 m/(kt)^1/3. This relationship is linear over seven orders of magnitude of explosive energy ranging from a 0.01 kg chemical explosion to a 100 kt nuclear explosion and is valid for a wide variety of saturated geological profiles. Underground chemical explosions, and probably underground nuclear explosions have the potential to induce liquefaction of water-saturated soils to scaled distances of about 260 m/(kt)^1/3.  相似文献   

Lake Koronia, Greece: Shift from autotrophy to heterotrophy with cultural eutrophication and progressive water-level reduction     

Chrysoula Mitraki  Thomas L. Crisman  George Zalidis 《Limnologica》2004,34(1-2):110

Lake Koronia, a Ramsar site, is shallow, polymictic, hypertrophic and until recently was aerially the fourth largest lake in Greece. Although exceeding 5 m in the past, lake depth has declined progressively from 3.8 m in 1980 to < 1 m in 1997, reducing surface area and water volume by 50% and 80%, respectively. Specific conductivityincreased from 1300 μS cm⁻¹ in 1977 to >6000 μS cm⁻¹ in 1991. Increased phosphate concentrations from the late 1970's (8–45 μg L⁻¹) to the late 1990's (100–1000 μg L⁻¹) document that the previously eutrophic system with a limited littoral zone switched to hypertrophy dominated by massive cyanobacteria blooms. Oxygen saturation of the water column increased progressively from about 80% in 1983 to full saturation about 1993, after which it decreased progressively to only 20% saturation in 1997. In spite of cyanobacteria dominance, community metabolism of the lake switched from progressively increasing autotrophy to rapidly advancing heterotrophy associated with progressive water-level reduction leading to fish extirpation in the lake.  相似文献