Contrasting sulphide contents of the Bushveld and Sudbury Igneous Complexes     

R. Grant Cawthorn 《Mineralium Deposita》2005,40(1):1-12

The Sudbury Igneous Complex (SIC) contains abundant sulphides, especially near the base, and hosts one of the worlds largest nickel and copper deposits. The Bushveld Complex (BC) contains relatively little sulphide, but hosts the worlds largest platinum-group element deposits. The most recent calculations of the sulphur solubility in magmas that produced the BC are based on the sulphur solubility of mid-ocean ridge basalts that have less SiO₂ than Bushveld magmas. Such a difference may lead to an overestimation of sulphur solubility by as much as 25%. The revised sulphur solubility curve presented here for Bushveld magmas may also have relevance to the SIC in view of its siliceous nature. Sulphur solubility curves can be used to determine the proportion of sulphide expected in cumulate rocks once sulphur saturation is attained. These models are tested using observed sulphide contents in both intrusions. The observed decreasing sulphur contents (>0.3–0.05% S) from the base of the SIC upward are broadly consistent with these sulphur solubility curves, and are consistent with sulphide saturation through the entire mafic portion. In contrast, the lower half of the BC contains extremely little sulphur (generally <0.02% S), except for two thin layers, which is not consistent with sustained sulphide saturation at any level. Previous interpretations of the sulphur content of Bushveld rocks have suggested that the Lower and Critical Zones were sulphide saturated, but that they had then lost some of the sulphide due to various processes. The present sulphide content of the cumulates of the BC is so low that, if they had once been saturated, over 90% of all the sulphide must have been removed. Mass balance calculations indicate that these large amounts of displaced sulphur remain unaccounted for in such models. Instead, the observed sulphur contents are in reasonable agreement with that expected in a cumulate sequence forming from a sulphur-undersaturated magma. Whereas the Merensky Reef and Bastard pyroxenite contain minor sulphides, the compositions of the immediate hanging wall rocks indicate sulphide undersaturation. Such an abrupt return to sulphide undersaturation is not consistent with models involving sulphide formation from large volumes of magma. One possible explanation for these two observations is that intermittent sulphur degassing occurred through a fractured roof of the BC, so that the magma was never continuously sulphur-saturated with respect to an immiscible sulphide liquid.  相似文献   

Environmental geochemistry of the derelict Webbs Consols mine,New South Wales,Australia   总被引：3，自引：3，他引：0  

P.?M.?AshleyEmail author  B.?G.?Lottermoser  A.?J.?Collins  C.?D.?Grant 《Environmental Geology》2004,46(5):591-604

Small-scale mining and mineral processing at the Webbs Consols polymetallic PbZnAg deposit in northern New South Wales, Australia has caused a significant environmental impact on streams, soils and vegetation. Unconfined waste rock dumps and tailings dams are the source of the problems. The partly oxidised sulphidic mine wastes contain abundant sulphides (arsenopyrite, sphalerite, galena) and oxidation products (scorodite, anglesite, smectite, Fe-oxyhydroxides), and possess extreme As and Pb (wt% levels) and elevated Ag, Cd, Cu, Sb and Zn values. Contemporary sulphide oxidation, hardpan formation, crystallisation of mineral efflorescences and acid mine drainage generation occur within the waste repositories. Acid seepages (pH 1.9–6.0) from waste dumps, tailings dams and mine workings display extreme As, Pb and Zn and elevated Cd, Cu and Sb contents. Drainage from the area is by the strongly contaminated Webbs Consols Creek and although this stream joins and is diluted by the much larger Severn River, contamination of water and stream sediments in the latter is evident for 1–5 km, and 12 km respectively, downstream of the mine site. The pronounced contamination of local and regional soils and sediments, despite the relatively small scale of the former operation, is due to the high metal tenor of abandoned waste material and the scarcity of neutralising minerals. Any rehabilitation plan of the site should include the relocation of waste materials to higher ground and capping, with only partial neutralisation of the waste to pH 4–5 in order to limit potential dissolution of scorodite and mobilisation of As into seepages and stream waters.  相似文献   

Polyculture of scallopChlamys farreri and kelpLaminaria japonica in Sungo Bay     

Fang Jian-guang  Sun Hui-ling  Yan Jing-ping  Kuang Shi-huan  Li Feng  Gary F. Newkirk  Jon Grant 《中国海洋湖沼学报》1996,14(4):322-329

Several polyculture models of scallopChlamys farreri and kelpLaminaria japonica currently employed in Sungo Bay and other parts of northern China are described in this paper. Economic benefits of different polyculture models are analysed based on the growth rate, culture density and market price. In addition, site selection, critical environmental conditions and polyculture problems are discussed in detail. This project was funded by the International Development and Research Centre (IDRC), Canada, and the National Committee of Science and Technology of China.  相似文献   

Regional fish stock management: A model for North-West Africa     

John P. Warren  Wade L. Griffin  William E. Grant 《Marine Policy》1982,6(2):121-130

Development of a bio-economic model for applications in managing an important north African fishery is reported in this article. The model is applied through identification of baseline conditions and analysis of two alternative fishery management plans; limiting the number of vessels and instituting a closed season. Several key assumptions relative to biological and fleet variables are necessarily made, since in some areas historical data are limited. However, results strongly suggest that rents to resource owners (African coastal countries) can be substantially increased by either method of limiting access to the fishery and by licensing vessels and fishermen.  相似文献   

TAXATION AND THE CONSUMPTION THEORY OF LAND RENT*     

Grant Ian Thrall 《The Professional geographer》1981,33(2):197-207

Assume an ideal two-sector city composed of households and a local government. Following an increase in property, sales, or income taxes, the magnitude and direction of the change in welfare, total population and density, rent, and urban radius depend upon the type of tax levied and the ability of households to migrate out of the city. The graphical consumption theory of land rent is used as the medium to explain the change in the geography of the city following an increase in taxation within open and closed settings.  相似文献   

Millennial‐scale variability in the oceans: an ocean modelling view     

Grant R. Bigg  Martin R. Wadley 《第四纪科学杂志》2001,16(4):309-319

Climate and ocean‐only models have shown that the ocean will respond abruptly to significant perturbations in surface forcing. Centennial‐scale oscillation is a characteristic of circulation in large semi‐enclosed ocean basins such as the Arctic, whereas millennial‐scale adjustment to changes in surface forcing has been found in the global ocean component of climate models. We show that the millennial time‐scale in climate models is likely to be intrinsic to the ocean through its presence in an ocean‐only model. The strength of the thermohaline circulation is shown to be very sensitive to the magnitude of ice albedo and, to a lesser extent, perturbation in the surface freshwater flux. Modelled glacial ocean circulation, in contrast to present‐day simulations, requires an enhanced freshwater flux over the northern Atlantic, even in its non‐Heinrich state, to obtain realistic overturning in the North Atlantic. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

Characterization of colloidal and particulate matter transported by the magela creek system,Northern Australia     

Barry T. Hart  Grant B. Douglas  Ronald Beckett  Annick Van Put  Rene E. Van Grieken 《水文研究》1993,7(1):105-118

The composition and amount of colloidal and suspended participate matter transported during a small flood event in Magela Creek in tropical northern Australia was investigated. The flood studied constituted approximately 3 % of the total annual flow, most (90%) of which occurred between mid-January and mid-February of the study year. Three fractions were separated from water samples using a sequential method involving a continuous flow centrifuge to separate suspended particulate matter (SPM; nominally > 1 μm) followed by hollow fibre filtration, first using a 0.1 μm filter to separate course colloidal matter (CCM; nominal size 1–0.1 μm) and then a 0–015 μm filter to separate fine colloidal matter (FCM; nominal size 0.1–0.015 μm). The SPM was predominantly inorganic (organic matter 21 %), whereas the colloidal fractions were dominantly organic matter (CCM 60%; FCM 83%). Analysis of individual particles using electron microprobe and automated image analysis indicated that the mineral fractions in both the SPM and CCM were dominated by iron-enriched aluminosilicates (including kaolinite) (72–82%) and quartz (9–10%), indicative of a highly weathered and extensively laterized catchment. Surprisingly there was very little difference in the composition of the SPM or CCM fractions during the flood event studied, which may indicate either that sediment availability was restricted following the major run-off events in January and February, or that all the sediment sources within the catchment are geochemically similar. Approximately the same amounts of particulate (20 tonne), colloidal (21 tonne) and dissolved material (17 tonne) were transported during the 25 hour period of the main flood peak; over 90% of the colloidal matter was 0.1–1.0 μm in size. These data suggest that previous estimates of the amounts of particulate (and colloidal) matter transported by Magela Creek, which were based on suspended solids measurements, may have underestimated the particulate matter load by as much as 50%. It is possible that the relatively high proportion of colloidal matter is unique to Magela Creek because coagulation and aggregation of colloidal matter to particulate matter is slow due to the very low concentations of calcium and magnesium in these waters. However, if the result is more widespread, there are important implications for the global estimates of fluvially transported particulate and dissolved materials as many of the previous studies may have underestimated the particulate load and overestimated the dissolved load.  相似文献   

Vertical mixing at the head of the Laurentian Channel     

R.Grant Ingram 《Estuarine, Coastal and Shelf Science》1983,16(3):333-338

Temperature, salinity and velocity profiles taken over a 5-day period in the St. Lawrence Estuary at the head of the Laurentian Channel are used to describe the semidiurnal tidal period isopycnal oscillations occurring in this region. The observed variation in the degree of vertical mixing over the tidal cycle is used to support the concept of nutrification of the estuarine surface waters and suggests an explanation for the quarter-diurnal variability of primary production in this region.  相似文献   

Emission cores in H and K lines     

R. Grant Athay  A. Skumanich 《Solar physics》1968,4(2):176-184

Calculations are made for the center-limb variations of the K₂ and K₃ components of the solar Ca ii K line using an optically thick model of the chromosphere. The center-limb variations are shown to require an increase of Doppler width with height in the chromosphere and to depend critically upon the location of the point where _D has increased by a factor e. Good agreement with observations is found when, and only when, the increase in _D occurs nearly simultaneously with the increase in chromospheric temperature.  相似文献   

Stress transfer in earthquakes, hazard estimation and ensemble forecasting: Inferences from numerical simulations     

John B. Rundle  Paul B. Rundle  Andrea Donnellan  P. Li  W. Klein  Gleb Morein  D.L. Turcotte  Lisa Grant   《Tectonophysics》2006,413(1-2):109

Observations indicate that earthquake faults occur in topologically complex, multi-scale networks driven by plate tectonic forces. We present realistic numerical simulations, involving data-mining, pattern recognition, theoretical analyses and ensemble forecasting techniques, to understand how the observable space–time earthquake patterns are related to the fundamentally inaccessible and unobservable dynamics. Numerical simulations can also help us to understand how the different scales involved in earthquake physics interact and influence the resulting dynamics. Our simulations indicate that elastic interactions (stress transfer) combined with the nonlinearity in the frictional failure threshold law lead to the self-organization of the statistical dynamics, producing 1) statistical distributions for magnitudes and frequencies of earthquakes that have characteristics similar to those possessed by the Gutenberg–Richter magnitude–frequency distributions observed in nature; and 2) clear examples of stress transfer among fault activity described by stress shadows, in which an earthquake on one group of faults reduces the Coulomb failure stress on other faults, thereby delaying activity on those faults. In this paper, we describe the current state of modeling and simulation efforts for Virtual California, a model for all the major active strike slip faults in California. Noting that the Working Group on California Earthquake Probabilities (WGCEP) uses statistical distributions to produce earthquake forecast probabilities, we demonstrate that Virtual California provides a powerful tool for testing the applicability and reliability of the WGCEP statistical methods. Furthermore, we show how the simulations can be used to develop statistical earthquake forecasting techniques that are complementary to the methods used by the WGCEP, but improve upon those methods in a number of important ways. In doing so, we distinguish between the “official” forecasts of the WGCEP, and the “research-quality” forecasts that we discuss here. Finally, we provide a brief discussion of future problems and issues related to the development of ensemble earthquake hazard estimation and forecasting techniques.  相似文献