The radiocarbon budget for Mono Lake: an unsolved mystery     

Wallace S. Broecker  Rik Wanninkhof  Guy Mathieu  Tsung-Hung Peng  Scott Stine  Steve Robinson  Andy Herczeg  Minze Stuiver 《Earth and Planetary Science Letters》1988,88(1-2)

Since 1957 the ¹⁴C/C ratio of the dissolved inorganic carbon in Mono Lake has risen by about 60‰. The magnitude of this increase is about four times larger than that expected from the invasion of bomb-produced¹⁴C from the atmosphere. We have eliminated the following explanations: (1) measurement error, (2) an unusually high physical exchange rate for non-reactive gases, (3) inorganic enhancement of the CO₂ exchange rate, and (4) biological enhancement of the CO₂ exchange rate. Clandestine disposal of waste radiocarbon remains a dark-horse explanation.In the course of our investigations we have uncovered evidence for at least one episodic input of radiocarbon-free carbon to the lake over the last 1000 years. We speculate that this injection was related to a hydrothermal event resulting from sublacustrine volcanic activity.  相似文献   

The transition between blueschists and lawsonite-bearing eclogites based on observations from Corsican metabasalts   总被引：2，自引：0，他引：2  

Jean-Michel Caron  Guy Pquignot 《Lithos》1986,19(3-4):205-218

Syntectonic eclogites, associated with blueschist parageneses, have recrystallized in metabasalts from eastern Corsica under very low temperatures (420°C). The evolution of these eclogites is recorded by the order of development of metamorphic minerals, as demonstrated by helicitic inclusions of lawsonite and actinolite in Fe-rich garnets, and the occurrence of fibrous Na-pyroxenes in the pressure shadows and cracks of boudinaged garnets, within a foliated matrix composed of glaucophane, Ca---Fe garnets and lawsonite.

A Schreinemakers analysis has been completed on the lawsonite-ferroglaucophane-actinolite-almandine-grossular-ferro-omphacite-chlorite system in a (T,P,μ_H2O)-space. The resulting three-dimensional relationships are applied to the studied samples. They are consistent with a prograde increase in temperature at low μ_H2O, producing eclogites from blueschists, and with a subsequent retrogressive decrease in pressure.  相似文献   

THE DETERMINATION OF FLUORINE BY PROTON INDUCED GAMMA RAY EMISSION SPECTROMETRY (PIGE) IN EIGHTEEN CHINESE STANDARD REFERENCE SAMPLES OF STREAM SEDIMENTS, SOILS AND ROCKS: GSD 9-12, GSS 1-8 AND GSR 1-6     

Iwan ROELANDTS  Guy ROBAYE  Panagiotis ALOUPOGIANNIS  Georges WEBER  Jeanne-Marie DELBROUCK-HABARU 《Geostandards and Geoanalytical Research》1987,11(1):79-80

Eighteen new Chinese standard reference samples (including stream sediments, soils and rocks) have been analysed by an automated proton induced gamma ray emission (PIGE) method for fluorine. Results of determinations are reported and are generally in good agreement with the "usable values" previously published.  相似文献   

The univariant curve liquid = forsterite + anorthite + diopside in the system CMAS at 1 bar: solid solutions and melt structure     

Guy Libourel  Pierre Boivin  Gordon M. Biggar 《Contributions to Mineralogy and Petrology》1989,102(4):406-421

One atmosphere liquid-present experiments were carried out in the CMAS system using an ordinary quench furnace apparatus. The runs, including reversal and duplicate experiments, describe the univariant curve l=fo+an+ di between the invariant points Q: l+fo+an=di+sp and F: l+fo=an+di+oen, located respectively at 1245±1° C and 1244±1° C. The thermal divide on this curve M₃: l= fo+an+di is located at 1275±1° C and plots well within the silica-saturated field, in agreement with Longhi's (1987) experiments. Along the univariant curve l=fo+an+di, liquid composition evolves away from the thermal divide either toward invariant points Q or F and pierces the silica saturation plane, i.e., the join Di-An-En, in the silica saturated field. In this compositional range, the Al solubility in clinopyroxene changes drastically from one side of the thermal divide to the other, with great increase of Al solubility in the silica-undersaturated field. Four endmembers must be used to describe the complex solid solution of anorthite: CaAl₂Si₂O₈, CaMgSi₃O₈, MgAl₂Si₂O₈ and [] Si₄O₈. The last two of these are present only within the silica-saturated field. Unlike clinopyroxene, the Mg content of anorthite is insensitive to the thermal barrier but is only sensitive to silica-saturation plane. Olivine composition can be described by a binary solid solution of forsterite and monticellite with no Ca in the M₂ site. As with anorthite, olivine compositions exhibit a marked change with crossing of the silica-saturation plane. The above features imply that the solubility of minor elements in crystalline phases (Al in clinopyroxene, Ca in olivine and Mg in anorthite) selectively respond to only one or another of these particular plane. Results have many important consequences. One is the likelihood of changes in melt speciation depending on position with respect to the thermal divide and the silica-saturation plane.  相似文献   

A hydrofluoric acid solution calorimetric investigation of glasses in the systems NaAlSi₃O₈-KAlSi₃O₈ and NaAlSi₃O₈-Si₄O₈     

Guy L. Hovis 《Geochimica et cosmochimica acta》1984,48(3):523-525

Glasses in the systems NaAlSi₃O₈-KAlSi₃O₈ and NaAlSi₃O₈-Si₄O₈ have been studied by means of hydrofluoric acid solution calorimetry at 50°C. Results indicate small negative enthalpies of mixing in the former system and small positive departures from ideality in the latter.  相似文献   

The evolution of icy satellite interiors and surfaces     

Guy J. Consolmagno  John S. Lewis 《Icarus》1978,34(2):280-293

The satellites of the outer solar system planets are thought to be mixtures of ices and rocky material, in which decay of radioactive nuclides can lead to internal melting and solid-state convection. Time-dependent models indicate that melting will reach its maximum extent approximately 2.0 GYr after formation; bodies of radius <500 km will never melt, and those <750 km in radius will be totally refrozen by present. Surface water flows are not expected for bodies of <1500-km radius. However, even small (100 km) bodies may be unstable against solid-state convection, and their surfaces may show signs of tectonism. Other processes altering the surfaces include sublimation and photolysis of ices. Sublimation likely explains the absence of CH₄ ices on any Saturnian satellite except Titan; photolysis explains the absence of NH₃ ices on these bodies, and possibly the absence of water ice on the surface of Callisto. The photolysis rate of CH₄ also implies a crustal reservoir of CH₄ on Titan.  相似文献   

Spatial variability of palaeosols across Cretaceous interfluves in the Dunvegan Formation, NE British Columbia, Canada: palaeohydrological, palaeogeomorphological and stratigraphic implications     

Paul J. McCarthy  A. Guy Plint† 《Sedimentology》2003,50(6):1187-1220

A basic sedimentological and palaeopedological framework is now in place for non-marine sequence models. The variability of interfluve palaeosols has not, however, been systematically documented, nor have the stratigraphic implications of that variability been incorporated into sequence models. Interfluve palaeosol variability in the deltaic Dunvegan Formation, NE British Columbia, Canada, is investigated, for which a detailed allostratigraphic and palaeogeographic framework has been developed, based on abundant well (> 2300 logs) and outcrop (> 60 sections) control. Regionally extensive valley fills and interfluves have been mapped in coastal plain deposits over an area of about 50 000 km². This palaeogeographic framework permits interfluve surfaces exposed in outcrop to be located in terms of distance from the margins of coeval valleys. The micromorphological, geochemical and mineralogical characteristics of five representative sequence-bounding palaeosols located from 250 m to more than 15 km from coeval valley margins are described. These interfluve palaeosols are similar to modern Alfisols and all record (i) aggradation on an alluvial/coastal plain; (ii) a subsequent static and/or degradational phase related to valley incision, non-deposition and soil thickening; and (iii) a final aggradational phase related to valley filling and renewed sedimentation across the coastal plain. Within this overall template, however, variations in palaeosol thickness, redoximorphic features, illuvial clay content and geochemistry suggest developmental control by hydrological characteristics that were influenced by both the nature of the underlying alluvial sediments and distance from the valley margin. The presence of mature interfluve palaeosols with complex developmental histories suggests that landscape dissection may have been related to terrace development associated with valley incision. Palaeosols closer to valley margins are thicker, contain more illuvial clay and display characteristics suggesting better drained conditions relative to those palaeosols that developed further from valley margins. Subsequent deposition on interfluves also reflects distance from valleys, with those sites close to valleys accumulating cumulic soils with evidence of brackish groundwater, whereas far from valleys (> 10–15 km), groundwater was fresh and clastic supply minimal, encouraging peat formation. Variations in drainage and palaeotopography during landscape dissection resulted in different palaeosol development styles on interfluve surfaces that can be shown, on the basis of physical correlation, to have the same geomorphic age. These observations support the concept of the soil-forming interval as a basis for pedostratigraphic correlation in ancient terrestrial deposits. Palaeosol variability on interfluves is to be expected, and recognition and documentation of this variability is an important prerequisite to palaeogeomorphological, palaeoclimatic and sequence stratigraphic interpretations.  相似文献   

Caractérisation minéralogique et microtexturale du vieillissement anthropique du minerai de fer lorrainMineralogical and microtextural characterisation of the anthropic-origin ageing of iron ore in Lorraine (France)     

Guy Dagallier  Dragan Grgic  Françoise Homand 《Comptes Rendus Geoscience》2002,334(7):455-462

The abandoned pillars in iron mines in Lorraine show that the oolitic ore underwent several chemical-mineralogical transformations. The first one is a rapid alteration of the diagenetic siderite and berthierine cement promoted by a bacterial flora. The oolites of goethite pack down and get loaded by deviatory-type stresses; they desquamate, get deformed and become powdery; the ore looses its cohesion. A second step, featuring recrystallisation–neoformation of berthierine in the previously formed micro-cavities, then the formation of a cavernous goethite–hematite crust, leads to a low cohesion to the crumbled ore; this anthropic-origin ageing may be one cause of mine collapsing. To cite this article: G. Dagallier et al., C. R. Geoscience 334 (2002) 455–462.  相似文献   

Réflexions sur la formation des bandes de Forbes : l'instabilité de la fusion de la glace saleReflections on the formation of Forbes ogives: the instability of fusion of dirty ice     

Bernard Guy  Martin Daigneault  Gérard Thomas 《Comptes Rendus Geoscience》2002,334(15):1061-1070

Forbes ogives show alternations of dark (ice + mineral dust) and light bands at the surface of certain glaciers. We propose to understand their origin by the influence of the content of mineral matter on the lowering of the temperature and pressure of ice fusion and upon the increase of fusion velocity. We are then in an unstable situation: a local increase in the mineral content being induced by the fusion process, which in turn increases; this creates a dark band. The movement of the glacier cannot keep up with the fusion: pressure is lowered again below the fusion point, and a white band is formed. To cite this article: B. Guy et al., C. R. Geoscience 334 (2002) 1061–1070.  相似文献   

Three distinct regimes of volcanic tremor associated with the eruption of Shishaldin Volcano, Alaska 1999     

Glenn Thompson  Stephen R. McNutt  Guy Tytgat 《Bulletin of Volcanology》2002,64(8):535-547

Tremor signals associated with the eruption of Shishaldin Volcano on 19 and 23 April 1999 were the strongest recorded anywhere in the Aleutian Arc by the Alaska Volcano Observatory (AVO) in its 10-year history. Reduced displacements (D_R) reached 23 cm² on 19 April and 43 cm² on 23 April. During the activity, D_R and spectral data with a frequency resolution of 0.1 Hz were computed and put on the World Wide Web every 10 min. These data are analyzed here. The general temporal patterns of seismicity of these eruption events were similar, but the eruptions and their effects quite different. The 19 April event is known to have culminated in a sub-Plinian phase, which ejected ash to an altitude of 16 km. Despite higher amplitudes and the largest hotspot from satellite data, the 23 April event produced little ash reaching only 6 km altitude. For several hours prior to the sub-Plinian phase on 19 April, tremor with a peak frequency of 1.3 Hz intensified. During the sub-Plinian phase the peak frequency increased to 4-8 Hz. However, in 15 h after the eruption, three episodes of stronger tremor occurred with a lower 1.0-Hz peak, alternating with weaker tremor with a 1.3-Hz peak. These transitions correspond to D_R=~8 cm². Although these strong tremor episodes produced higher D_R levels than the sub-Plinian phase, data from a pressure sensor show that only strong Strombolian explosions occurred. The suite of observations suggests three distinct tremor regimes that may correspond to slug flow, bubbly flow, and sustained strong eruptions, or a cyclic change in source parameters (e.g., geometry, sound speed, or ascent rate). This behavior occurred at Shishaldin only during the April 1999 sequence, and we are not aware of similar behavior at other volcanoes.  相似文献