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31.
We established the relationships between water chemistry changes in a pool fed by a permanent spring and seasonal variations in trace-element contents (Sr & Mg) in the shells of the ostracod species Herpetocypris intermedia, based on monthly collections of ostracod and water samples. The water chemistry of the investigated pool (Maïques, Valëncia, Spain) was dominated by calcium and bicarbonate, and showed marked seasonal variation in alkalinity, Ca2+ content, Sr/Ca and Mg/Ca ratios. Although the variability in the water chemistry was relatively low (~10% relative standard deviation over the entire period), the trace-element contents in the ostracod shells tracked the seasonal change in the water chemistry of Maïques pool. Moreover, due to the rapid renewal of H. intermedia population, this species is able torecord in its shells the evolution of the water chemistry at a monthly time scale. Our results also showed that, in the Maïques pool system, ostracod Sr/Ca and Mg/Ca ratios increased with the decrease in water salinity.To our knowledge, this is the first geochemical study of ostracods dwelling in spring environments. The results of this study may be applied to paleohydrological reconstruction using ostracods preserved in sediments deposited around springs (i.e. travertine and tufa deposits).  相似文献   
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By combining AVHRR data from the NOAA satellites with information from a database of in situ measurements, large-scale maps can be generated of the microphysical parameters most immediately significant for the modelling of global circulation and climate. From the satellite data, the clouds can be classified into cumuliform, stratiform and cirrus classes and then into further sub-classes by cloud top temperature. At the same time a database of in situ measurements made by research aircraft is classified into the same sub-classes and a statistical analysis is used to derive relationships between the sub-classes and the cloud microphysical properties. These two analyses are then linked to give estimates of the microphysical properties of the satellite observed clouds. Examples are given of the application of this technique to derive maps of the probability of occurrence of precipitating clouds and of precipitating water content derived from a case study within the International Cirrus Experiment (ICE) held in 1989 over the North Sea.  相似文献   
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The significance and validity of integrating data obtained from a variety of analytical techniques to understand, elucidate and model kerogen's complex chemical structure is reported here using degradative (open and closed system pyrolysis, chemical oxidation), non-degradative (13C CP/MAS NMR) and optical (incident white light and blue light) methods. Seven Cambrian Alum Shale samples, ranging in maturity from immature to post-mature with respect to petroleum generation, were studied and were chosen for their simple geological history, uniform organic matter type and high organic carbon content. The Alum Shale kerogens, which primarily consist of algal organic matter, liberate low molecular weight gaseous and aromatic compounds on pyrolysis and give mostly branched dicarboxylic acids on chemical oxidation. 13C NMR spectroscopy shows that the Alum Shale kerogens are anomalously rich in oxygen-bearing functional groups (such as C = O, ArCO, CHO, CHxO), most of which apparently remain intact within the kerogen macro-molecule (KMM) through the diagenetic and catagenetic stages. Fragments released by different degradative techniques are quantified and the aromaticity (fa), O/C and relative proportions of various carbon types estimated by 13C NMR. A synthesis of these data has allowed us to better understand the chemistry of the Alum Shale kerogen.  相似文献   
37.
Summary. Rotational remanent magnetization, RRM, is the magnetization acquired when a sample is rotated during alternating field demagnetization. Although the existence of RRM has been well documented in different laboratories, until now no physical mechanism explaining its origin has been given. We propose that the RRM originates from thermal fluctuations biased by a precessional torque associated with the alternating field. Our theory is consistent with the observation that no directional preference exists in the experimental situation until the sample is rotated relative to the alternating field. Moreover, our theory predicts that the combined sample rotation and precession will produce a RRM that switches direction when the frequency of sample rotation increases from any value below the frequency of the alternating field to any value above that frequency as observed in experiments. Although no precise theory is given for the intensity of RRM, the model presented here can qualitatively explain previous intensity observations.  相似文献   
38.
The completeness and the accuracy of the Brest sea level time series dating from 1807 make it suitable for long-term sea level trend studies. New data sets were recently discovered in the form of handwritten tabulations, including several decades of the eighteenth century. Sea level observations have been made in Brest since 1679. This paper presents the historical data sets which have been assembled so far. These data sets span approximately 300 years and together constitute the longest, near-continuous set of sea level information in France. However, an important question arises: Can we relate the past and the present-day records? We partially provide an answer to this question by analysing the documents of several historical libraries with the tidal data using a ‘data archaeology’ approach advocated by Woodworth (Geophys Res Lett 26:1589–1592, 1999b). A second question arises concerning the accuracy of such records. Careful editing was undertaken by examining the residuals between tidal predictions and observations. It proved useful to remove the worst effects of timing errors, in particular the sundial correction to be applied prior to August 1, 1714. A refined correction based on sundial literature [Savoie, La gnomique, Editions Les Belles Lettres, Paris, 2001] is proposed, which eliminates the systematic offsets seen in the discrepancies in timing of the sea level measurements. The tidal analysis has also shown that shallow-water tidal harmonics at Brest causes a systematic difference of 0.023 m between mean sea level (MSL) and mean tide level (MTL). Thus, MTL should not be mixed with the time series of MSL because of this systematic offset. The study of the trends in MTL and MSL however indicates that MTL can be used as a proxy for MSL. Three linear trend periods are distinguished in the Brest MTL time series over the period 1807–2004. Our results support the recent findings of Holgate and Woodworth (Geophys Res Lett) of an enhanced coastal sea level rise during the last decade compared to the global estimations of about 1.8 mm/year over longer periods (Douglas, J Geophys Res 96:6981–6992, 1991). The onset of the relatively large global sea level trends observed in the twentieth century is an important question in the science of climate change. Our findings point out to an ‘inflexion point’ at around 1890, which is remarkably close to that in 1880 found in the Liverpool record by Woodworth (Geophys Res Lett 26:1589–1592, 1999b).  相似文献   
39.
Modern subaerial sand beds deposited by major tsunamis and hurricanes were compared at trench, transect, and sub-regional spatial scales to evaluate which attributes are most useful for distinguishing the two types of deposits. Physical criteria that may be diagnostic include: sediment composition, textures and grading, types and organization of stratification, thickness, geometry, and landscape conformity.

Published reports of Pacific Ocean tsunami impacts and our field observations suggest that sandy tsunami deposits are generally < 25 cm thick, extend hundreds of meters inland from the beach, and fill microtopography but generally conform to the antecedent landscape. They commonly are a single homogeneous bed that is normally graded overall, or that consists of only a few thin layers. Mud intraclasts and mud laminae within the deposit are strong evidence of tsunami deposition. Twig orientation or other indicators of return flow during bed aggradation are also diagnostic of tsunami deposits. Sandy storm deposits tend to be > 30 cm thick, generally extend < 300 m from the beach, and will not advance beyond the antecedent macrotopography they are able to fill. They typically are composed of numerous subhorizontal planar laminae organized into multiple laminasets that are normally or inversely graded, they do not contain internal mud laminae and rarely contain mud intraclasts. Application of these distinguishing characteristics depends on their preservation potential and any deposit modifications that accompany burial.

The distinctions between tsunami and storm deposits are related to differences in the hydrodynamics and sediment-sorting processes during transport. Tsunami deposition results from a few high-velocity, long-period waves that entrain sediment from the shoreface, beach, and landward erosion zone. Tsunamis can have flow depths greater than 10 m, transport sediment primarily in suspension, and distribute the load over a broad region where sediment falls out of suspension when flow decelerates. In contrast, storm inundation generally is gradual and prolonged, consisting of many waves that erode beaches and dunes with no significant overland return flow until after the main flooding. Storm flow depths are commonly < 3 m, sediment is transported primarily as bed load by traction, and the load is deposited within a zone relatively close to the beach.  相似文献   

40.
A new complex earth system model consisting of an atmospheric general circulation model, an ocean general circulation model, a three-dimensional ice sheet model, a marine biogeochemistry model, and a dynamic vegetation model was used to study the long-term response to anthropogenic carbon emissions. The prescribed emissions follow estimates of past emissions for the period 1751–2000 and standard IPCC emission scenarios up to the year 2100. After 2100, an exponential decrease of the emissions was assumed. For each of the scenarios, a small ensemble of simulations was carried out. The North Atlantic overturning collapsed in the high emission scenario (A2) simulations. In the low emission scenario (B1), only a temporary weakening of the deep water formation in the North Atlantic is predicted. The moderate emission scenario (A1B) brings the system close to its bifurcation point, with three out of five runs leading to a collapsed North Atlantic overturning circulation. The atmospheric moisture transport predominantly contributes to the collapse of the deep water formation. In the simulations with collapsed deep water formation in the North Atlantic a substantial cooling over parts of the North Atlantic is simulated. Anthropogenic climate change substantially reduces the ability of land and ocean to sequester anthropogenic carbon. The simulated effect of a collapse of the deep water formation in the North Atlantic on the atmospheric CO2 concentration turned out to be relatively small. The volume of the Greenland ice sheet is reduced, but its contribution to global mean sea level is almost counterbalanced by the growth of the Antarctic ice sheet due to enhanced snowfall. The modifications of the high latitude freshwater input due to the simulated changes in mass balance of the ice sheet are one order of magnitude smaller than the changes due to atmospheric moisture transport. After the year 3000, the global mean surface temperature is predicted to be almost constant due to the compensating effects of decreasing atmospheric CO2 concentrations due to oceanic uptake and delayed response to increasing atmospheric CO2 concentrations before.  相似文献   
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