The Helsinki Commission (HELCOM) Baltic Sea Action Plan, adopted by the coastal countries of the Baltic Sea and the European Community in November 2007, is a regional intergovernmental programme of measures for the protection and management of the marine environment explicitly based on the Ecosystem Approach. The Action Plan is structured around a set of Ecological Objectives used to define indicators and targets, including effect-based nutrient input ceilings, and to monitor implementation. The Action Plan strongly links Baltic marine environmental concerns to important socio-economic fields such as agriculture and fisheries and promotes cross-sectoral tools including marine spatial planning. Due to complementarities with the European Union (EU) Marine Strategy Framework Directive, the Action Plan is in essence a pilot for this process without neglecting the important role of the Russian Federation - the only Baltic coastal country not a member of the EU. 相似文献
We investigate winter Arctic Amplification (AA) on synoptic timescales and at regional scales using a daily version of the Arctic Amplification Index (AAI) and examine causes on a synoptic scale. The persistence, frequency and intensity of high AAI events show significant increases over the Arctic. Similarly, low AAI events are decreasing in frequency, persistence and intensity. In both cases, there are regional variations in these trends, in terms of significance and timing. Significant trends in increasing persistence, frequency and intensity of high AAI events in winter are concentrated in the period 2000–2009, with few significant trends before and after this. There are some decreases in sea-ice concentration in response to synoptic-scale AA events and these AA events can contribute to the decadal trends in AA found in other studies. A sectoral analysis of the Arctic indicates that in the Beaufort–Chukchi and East Siberian–Laptev Seas, synoptic scale high AAI events can be driven by tropical teleconnections while in other Arctic sectors, it is the intrusion of moisture-transporting synoptic cyclones into the Arctic that is most important in synoptic-scale AA. The presence of Rossby wave breaking during high AAI events is indicative of forcing from lower latitudes, modulated by variations in the jet stream. An important conclusion is that the increased persistence, frequency and intensity of synoptic-scale high AAI events make significant contributions to the interannual trend in AA.
The speciation of aqueous dissolved sulfur was determined in hydrothermal waters in Iceland. The waters sampled included hot springs, acid-sulfate pools and mud pots, sub-boiling well discharges and two-phase wells. The water temperatures ranged from 4 to 210 °C, the pHT was between 2.20 and 9.30 at the discharge temperature and the SO4 and Cl concentrations were 0.020-52.7 and <0.01-10.0 mmol kg−1, respectively. The analyses were carried out on-site within ∼10 min of sampling using ion chromatography (IC) for sulfate (SO42−), thiosulfate (S2O32−) and polythionates (SxO62−) and titration and/or colorimetry for total dissolved sulfide (S2−). Sulfite (SO32−) could also be determined in a few cases using IC. Alternatively, for few samples in remote locations the sulfur oxyanions were stabilized on a resin on site following elution and analysis by IC in the laboratory. Dissolved sulfate and with few exceptions also S2− were detected in all samples with concentrations of 0.02-52.7 mmol kg−1 and <1-4100 μmol kg−1, respectively. Thiosulfate was detected in 49 samples of the 73 analyzed with concentrations in the range of <1-394 μmol kg−1 (S-equivalents). Sulfite was detected in few samples with concentrations in the range of <1-3 μmol kg−1. Thiosulfate and SO32− were not detected in <100 °C well waters and S2O32− was observed only at low concentrations (<1-8 μmol kg−1) in ∼200 °C well waters. In alkaline and neutral pH hot springs, S2O32− was present in significant concentrations sometimes corresponding to up to 23% of total dissolved sulfur (STOT). In steam-heated acid-sulfate waters, S2O32− was not a significant sulfur species. The results demonstrate that S2O32− and SO32− do not occur in the deeper parts of <150 °C hydrothermal systems and only in trace concentrations in ∼200-300 °C systems. Upon ascent to the surface and mixing with oxygenated ground and surface waters and/or dissolution of atmospheric O2, S2− is degassed and oxidized to SO32− and S2O32− and eventually to SO42− at pH >8. In near-neutral hydrothermal waters the oxidation of S2− and the interaction of S2− and S0 resulting in the formation of Sx2− are considered important. At lower pH values the reactions seemed to proceed relatively rapidly to SO42− and the sulfur chemistry of acid-sulfate pools was dominated by SO42−, which corresponded to >99% of STOT. The results suggest that the aqueous speciation of sulfur in natural hydrothermal waters is dynamic and both kinetically and source-controlled and cannot be estimated from thermodynamic speciation calculations. 相似文献
Fisheries management benefits from the contribution of several academic disciplines, each with their own perspectives, concerns and solutions. In this essay we argue that the contribution of biology, economics, sociology and other relevant disciplines to fisheries would be improved if they originated from broader, more integrated analytical perspectives that are attuned to the empirical realities of fisheries management. Today, disciplinary boundaries narrow the perspectives of fisheries management, creating tunnel vision and standardized technical fixes to complex and diverse management problems. Having worked separately and together for a number of years in fisheries research and consultancy in many parts of the world we, as a group of biologists, economists and sociologists, feel that the time to rid ourselves from disciplinary dogmatism is long overdue. We claim that improvements in fisheries management will be realized not through the promotion of technical fixes but instead by embracing and responding to the complexity of the management problem. 相似文献
Mid-infrared 2-D spectroscopic measurements from 8.0 to 12.7 μm of Mercury were taken using Boston University's Mid-Infrared Spectrometer and Imager (MIRSI) mounted on the NASA Infrared Telescope Facility (IRTF) on Mauna Kea, Hawaii, 7-11 April 2006. Measurements reported here cover radar bright region C, a dark plains region west of Caloris Basin, and the interior of Caloris Basin. By use of spectral deconvolution with a large spectral library composed of many mineral compositions and grain size separates, we fitted, or “unmixed”, the Mercury spectra. We find mineral suites composed of magnesium-rich orthopyroxene and olivine, Ca-, Mg-, Na-rich clinopyroxene, potassium feldspar, and Na-bearing plagioclase feldspar. Both Ca- and Mg-rich garnet (pyrope and grossular, respectively) are apparently present in small amounts. Opaque minerals are required for spectral matching, with rutile (TiO2) repeatedly providing the “best fit”. However, in the case of the radar bright region C, perovskite also contributed to a very good fit. Caloris Basin infill is rich in both potassium feldspar and Na-rich plagioclase. There is little or no olivine in the Caloris interior smooth plains. Together with the high alkali content, this indicates that resurfacing magmas were low to intermediate in SiO2. Data suggest the dark plains exterior to Caloris are highly differentiated low-iron basaltic magmas resulting in material that might be classified as oligoclase basalts. 相似文献
The adsorption of gentisic acid (GA) by hematite nano-particles was examined under static and dynamic conditions by conducting batch and column tests. To simulate natural sediments, the iron oxide was deposited on 10 μm quartz particles. The GA adsorption was described by a surface complexation model fitted to pH-adsorption curves with GA concentrations of 0.1-1 mM in a pH range of 3-10. The surface was described with one type of site (FeOH°), while gentisic acid at the surface was described by two surface complexes (FeLH2°, log Kint = 8.9 and FeLH−, log Kint = −8.2). Modeling was conducted with PHREEQC-2 using the MINTEQ database. From a kinetic point of view, the intrinsic chemical reactions were likely to be the rate-limiting step of sorption (∼10−3 s−1) while external and internal mass transfer rates (∼102 s−1) were much faster. Under flow through conditions (column), adsorption of GA to hematite-coated sand was about 7-times lower than under turbulent mixing (batch). This difference could not be explained by chemical adsorption kinetics as shown by test calculations run with HYDRUS-1D software. Surface complexation model simulations however successfully described the data when the surface area was adjusted, suggesting that under flow conditions the accessibility to the reactive surface sites was reduced. The exact mechanism responsible for the increased mobility of GA could not be determined but some parameters suggested that decreased external mass transfer between solution and surface may play a significant role under flow through conditions. 相似文献
The permittivity measured at a frequency of 10 GHz normalized to constant density is the same within the experimental error for talc, baryte and dolomite. In the case of clay and kaolin, it is about 10% higher. This is attributed to the high content of Al2O3 (30–40%) in them, which interpretation is proved by experiment. 相似文献