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71.
We consider the scenario in which the presence of ammonia in the bulk composition of Enceladus plays a pivotal role in its thermochemical evolution. Because ammonia reduces the melting temperature of the ice shell by 100 K below that of pure water ice, small amounts of tidal dissipation can power an “ammonia feedback” mechanism that leads to secondary differentiation of Enceladus within the ice shell. This leads to compositionally distinct zones at the base of the ice shell arranged such that a layer of lower density (and compositionally buoyant) pure water ice underlies the undifferentiated ammonia-dihydrate ice layer above. We then consider a large scale instability arising from the pure water ice layer, and use a numerical model to explore the dynamics of compositional convection within the ice shell of Enceladus. The instability of the layer can easily account for a diapir that is hemispherical in scale. As it rises to the surface, it co-advects the warm internal temperatures towards the outer layers of the satellite. This advected heat facilitates the generation of a subsurface ocean within the ice shell of Enceladus. This scenario can simultaneously account for the origin of asymmetry in surface deformation observed on Enceladus as well as two global features inferred to exist: a large density anomaly within the interior and a subsurface ocean underneath the south polar region.  相似文献   
72.
Abstract— Nine howardites and two diogenites were recovered from the Pecora Escarpment Icefield (PCA) in 2002. Cosmogenic radionuclide abundances indicate that the samples are paired and that they constituted an approximately 1 m (diameter) meteoroid prior to atmospheric entry. At about 1 m in diameter, the PCA 02 HED group represents one of the largest single pre‐atmospheric pieces of the Vestan surface yet described. Mineral and textural variations were measured in six of the PCA 02 howardites to investigate meter‐scale diversity of the Vestan surface. Mineral compositions span the range of known eucrite and diogenite compositions. Additional non‐diogenitic groups of Mg‐ and Fe‐rich olivine are observed, and are interpreted to have been formed by exogenic contamination and impact melting, respectively. These howardites contain olivine‐rich impact melts that likely formed from dunite‐ and harzburgite‐rich target rocks. Containing the first recognized olivine‐rich HED impact melts, these samples provide meteoritic evidence that olivine‐rich lithologies have been exposed on the surface of Vesta. Finally, we present a new method for mapping distributions of lithologies in howardites using 8 elemental X‐ray maps. Proportions of diogenite and eucrite vary considerably among the PCA 02 howardites, suggesting they originated from a heterogeneous portion of the Vestan surface. While whole sample modes are dominated by diogenite, the finer grain size fractions are consistently more eucritic. This discrepancy has implications for near‐infrared spectral observations of portions of Vesta’s surface that are similar to the PCA 02 howardites, as the finer grained eucritic material will disproportionately dominate the spectra.  相似文献   
73.
Abstract— The Kaidun meteorite contains carbonaceous chondrite (CM1) clasts that have been highly altered by reactions with hydrothermal fluids. Pyrrhotite in these clasts occurs as unusual needles wrapped by sheaths of phyllosilicate, and pentlandite forms veins that crosscut aggregates of phyllosilicate and garnet but not pyrrhotite. The isotopic compositions of S (δ34SCDT) in individual sulfide grains, measured by ion micro-probe, are fractionated compared to troilite in ordinary chondrites. The S in Kaidun sulfides is isotopically light (as much as ?4.2% for pyrrhotite and ?5.7%0 for pentlandite), unlike sulfides in other carbonaceous chondrites, which are enriched in 34S. The unusual S-isotopic composition of these texturally unique sulfides supports the hypothesis that Kaidun CM1 clasts were pervasively altered under extreme thermal conditions, possibly by fluids that had lost isotopically heavy SO2.  相似文献   
74.
ABSTRACT

The increasing popularity of Location-Based Social Networks (LBSNs) and the semantic enrichment of mobility data in several contexts in the last years has led to the generation of large volumes of trajectory data. In contrast to GPS-based trajectories, LBSN and context-aware trajectories are more complex data, having several semantic textual dimensions besides space and time, which may reveal interesting mobility patterns. For instance, people may visit different places or perform different activities depending on the weather conditions. These new semantically rich data, known as multiple-aspect trajectories, pose new challenges in trajectory classification, which is the problem that we address in this paper. Existing methods for trajectory classification cannot deal with the complexity of heterogeneous data dimensions or the sequential aspect that characterizes movement. In this paper we propose MARC, an approach based on attribute embedding and Recurrent Neural Networks (RNNs) for classifying multiple-aspect trajectories, that tackles all trajectory properties: space, time, semantics, and sequence. We highlight that MARC exhibits good performance especially when trajectories are described by several textual/categorical attributes. Experiments performed over four publicly available datasets considering the Trajectory-User Linking (TUL) problem show that MARC outperformed all competitors, with respect to accuracy, precision, recall, and F1-score.  相似文献   
75.
The rise of Geographic Information Systems (GIS) technologies has been producing powerful tools for spatial data processing, management, analysis, modeling, and visualization. While supporting many tasks, GIS technologies have evoked new thinking and advanced intellectual inquiries in geography. Technological advances in other fields often stimulate new research questions and lead to revolutionary discoveries. The Hubble telescope revolutionizes our understanding of the universe, and 3D digital microscopes transform our knowledge of the coordination among biological, neurological, and physiological systems in living organisms. Can GIS claim similar revolutionary effects on geography? The answer is much up for debate. With GIS technologies, geographic studies can explore a broader extent across multiple scales in space and time and tackle problems through increasingly complex spatial statistics, visual analytics, computation, simulation, machine learning, and artificial intelligence. Both the Hubble telescope and 3D digital microscope were built based on scientific research that subserves the technological advances for inquiries into space and life systems. Likewise, GIScience research innovates GIS methods that enable novel geographic investigations and therefore contribute to geographic knowledge production. For the sake of simplicity, the term GIS used here represents both GIScience and GIS technologies. This essay attempts to clarify the intellectual contributions of GIS to geography on the following two questions: (1) What novel geographic thinking is driven by GIS? (2) How may GIS provoke new geographic inquiries and knowledge? Building on Nystuen's notion of four tensions that trigger geographic questions, the essay discusses how GIS innovations mediate historical tension, space‐time tension, dimensional tension and scale tensions.  相似文献   
76.
Additional studies of the ion composition results obtained from the OGO-6 satellite support earlier observations of irregularities in the distribution of H+ and He+ within the light ion trough near L = 4, which has been associated with the plasmapause. These irregularities are in the form of sub-troughs superimposed upon the major mid latitude decrease of the light ions. In the sub-troughs, ionization depletions and recoveries of as much as an order of magnitude are observed within a few degrees of latitude, usually exhibited in a pattern which changes significantly with longitude as the Earth rotates beneath the relatively fixed satellite orbit. The location and properties exhibited by these sub-troughs appear to be consistent with the concept of a plasmasphere distortion in the form of “plasmatails” resulting from the combined effects of magnetospheric convection plus corotation. Like the light ion trough, the “plasmatail” irregularity in H+ may be obscured on the day side by the dominant topside distribution of O+. Consequently, these light ion irregularities are seen as an important factor for studies of plasmapause-trough relationships.  相似文献   
77.
Zusammenfassung Bei der im Folgenden beschriebenen Methode zur Berechnung der Stromellipsenelemente werden die Summen und Differenzen der Hauptachsen bzw. ihrer Richtungen und Phasen als Beträge bzw. Richtungen zweier Vektoren bestimmt. Die Komponenten dieser Vektoren sind wieder Summen und Differenzen von vier Konstanten, die man bei der harmonischen Analyse der Stromkomponenten bezüglich der betreffenden Tide gewinnt. Eine andere Berechnungsmethode geht von den harmonischen Konstanten der Stromkomponenten aus und benutzt trigonometrische Funktionen komplexen Arguments. Zum Schluß werden Beziehungen zwischen den Elementen der Stromellipse und denen der Gefällsellipse aufgestellt unter der Voraussetzung, daß der Zusammenhang zwischen horizontalen und vertikalen Gezeiten sich durch die linearisierten hydrodynamischen Grundgleichungen darstellen läßt.
A method of calculating tidal stream and gradient ellipses
Summary In the following paper a method of calculating the elements of tidal stream ellipses is described by which the sums and differences of the major axes or their directions and phases are determined as the scalar quantities or directions of two vectors. The components of these vectors, on their turn, are sums and differences of four constants obtained by the harmonic analysis of the stream components with regard to the respective tide. Another calculating method proceeds from the harmonic constants of the stream components and employs trigonometric functions of complex arguments. Finally, on the supposition that the relation between horizontal and vertical tides may be represented by the linearized fundamental hydrodynamic equations, relations are established between the elements of the tidal stream ellipse and those of the gradient ellipse.

Mode de calcul des ellipses du courant de marée et du gradient
Résumé Le mode de calcul des éléments des ellipses du courant expliqué ci-dessous demande que les sommes et les différences des grandaxes ou leurs directions et leurs phases soient déterminées comme grandeurs scalaires ou comme directions de deux vecteurs. Les composantes de ces vecteurs sont, de leur part, les sommes ou les différences de quatre constantes qui résultent de l'analyse harmonique des composantes de courant de la marée en question. Une autre méthode de calcul part des constantes harmoniques des composantes de courant et emploie des fonctions trigonométriques à l'argument complexe. Enfin, pourvu que la relation entre les composantes horizontales et verticales puisse être représentée à l'aide des équations hydrodynamiques fondamentales linéarisées, des relations entre les éléments de l'ellipse du courant et ceux de l'ellipse du gradient sont établies.
  相似文献   
78.
As sea level is projected to rise throughout the twenty-first century due to climate change, there is a need to ensure that sea level rise (SLR) models accurately and defensibly represent future flood inundation levels to allow for effective coastal zone management. Digital elevation models (DEMs) are integral to SLR modelling, but are subject to error, including in their vertical resolution. Error in DEMs leads to uncertainty in the output of SLR inundation models, which if not considered, may result in poor coastal management decisions. However, DEM error is not usually described in detail by DEM suppliers; commonly only the RMSE is reported. This research explores the impact of stated vertical error in delineating zones of inundation in two locations along the Devon, United Kingdom, coastline (Exe and Otter Estuaries). We explore the consequences of needing to make assumptions about the distribution of error in the absence of detailed error data using a 1 m, publically available composite DEM with a maximum RMSE of 0.15 m, typical of recent LiDAR-derived DEMs. We compare uncertainty using two methods (i) the NOAA inundation uncertainty mapping method which assumes a normal distribution of error and (ii) a hydrologically correct bathtub method where the DEM is uniformly perturbed between the upper and lower bounds of a 95% linear error in 500 Monte Carlo Simulations (HBM+MCS). The NOAA method produced a broader zone of uncertainty (an increase of 134.9% on the HBM+MCS method), which is particularly evident in the flatter topography of the upper estuaries. The HBM+MCS method generates a narrower band of uncertainty for these flatter areas, but very similar extents where shorelines are steeper. The differences in inundation extents produced by the methods relate to a number of underpinning assumptions, and particularly, how the stated RMSE is interpreted and used to represent error in a practical sense. Unlike the NOAA method, the HBM+MCS model is computationally intensive, depending on the areas under consideration and the number of iterations. We therefore used the HBM+ MCS method to derive a regression relationship between elevation and inundation probability for the Exe Estuary. We then apply this to the adjacent Otter Estuary and show that it can defensibly reproduce zones of inundation uncertainty, avoiding the computationally intensive step of the HBM+MCS. The equation-derived zone of uncertainty was 112.1% larger than the HBM+MCS method, compared to the NOAA method which produced an uncertain area 423.9% larger. Each approach has advantages and disadvantages and requires value judgements to be made. Their use underscores the need for transparency in assumptions and communications of outputs. We urge DEM publishers to move beyond provision of a generalised RMSE and provide more detailed estimates of spatial error and complete metadata, including locations of ground control points and associated land cover.  相似文献   
79.
Unlike the majority of the water in the flooded mine complex of Butte Montana, which includes the highly acidic Berkeley pit lake, groundwater in the flooded West Camp underground mine workings has a circum-neutral pH and contains at least 8 μM aqueous sulfide. This article examines the geochemistry and stable isotope composition of this unusual H2S-rich mine water, and also discusses problems related to the colorimetric analysis of sulfide in waters that contain FeS(aq) cluster compounds. The West Camp mine pool is maintained at a constant elevation by continuous pumping, with discharge water that contains elevated Mn (90 μM), Fe (16 μM), and As (1.3 μM) but otherwise low metal concentrations. Dissolved inorganic carbon in the mine water is in chemical and isotopic equilibrium with rhodochrosite in the mineralized veins. The mine water is under-saturated with mackinawite and amorphous FeS, but is supersaturated with Cu- and Zn-sulfides. However, voltammetry studies show that much of the dissolved sulfide and ferrous iron are present as FeS(aq) cluster molecules: as a result, the free concentration of the West Camp water is poorly constrained. Concentrations of dissolved sulfide determined by colorimetry were lower than gravimetric assays obtained by AgNO3 addition, implying that the FeS(aq) clusters are not completely extracted by the Methylene Blue reagent. In contrast, the clusters are quantitatively extracted as Ag2S after addition of AgNO3. Isotopic analysis of co-existing aqueous sulfide and sulfate confirms that the sulfide was produced by sulfate-reducing bacteria (SRB). The H2S-rich mine water is not confined to the immediate vicinity of the extraction well, but is also present in flooded mine shafts up to 3 km away, and in samples bailed from mine shafts at depths up to 300 m below static water level. This illustrates that SRB are well established throughout the southwestern portion of the extensive (>15 km3) Butte flooded mine complex.  相似文献   
80.
Hydrous high-pressure veins formed during dehydration of eclogites in two paleo-subduction zones (Trescolmen locality in the Adula nappe, central Alps and Münchberg Gneiss Massif, Variscan fold belt, Germany) constrain the major and trace element composition of solutes in fluids liberated during dehydration of eclogites. Similar initial isotopic compositions of veins and host eclogites at the time of metamorphism indicate that the fluids were derived predominantly from the host rocks. Quartz, kyanite, paragonite, phengite, zoisite and omphacite are the dominant minerals in the veins. The major element compositions of the veins are in agreement with experimental evidence indicating that the composition of solutes in such fluids is dominated by SiO2 and Al2O3. Relative to N-MORB, the veins show enrichments of Cs, Rb, Ba, Pb, and K, comparable or slightly lower abundances of Sr, U, and Th, and very low abundances of Nd, Sm, Zr, Nb, Ti and Y. The differential fractionation of highly incompatible elements such as K, U and Th in the veins, as well as the presence of hydrous minerals in the eclogites rule out partial melting as a cause for vein formation. These results confirm previous suggestions that fluids derived from subducted basalt may have low abundances of high field strength elements, rare earth elements and Y. Variable vein-eclogite enrichment factors of incompatible alkalis and to a lesser extent Pb appear to reflect mineralogical controls (phengite, epidote-group minerals) on partitioning of these elements during dehydration of eclogite in subduction zones. However, abundance variations of incompatible elements in minerals from eclogites suggest that the composition of fluids released from eclogites at temperatures <700°C may not reflect true equilibrium partitioning during dehydration. Simple models for the trace elements U and Th indicate the relative importance of the basaltic and sedimentary portions of subducted oceanic crust in producing the characteristic chemical signatures of these elements in convergent plate margin volcanism.  相似文献   
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