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91.
92.
Understanding the effects of microbiota on mineral alteration requires the ability to recognize evidence of bacteria-promoted dissolution on mineral surfaces. Although siderophores are known to promote mineral dissolution, their effects on mineral surfaces are not well known. We have utilized atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and Mirau vertical scanning interferometry (VSI) to investigate surfaces after incubation with the siderophore desferrioxamine-B mesylate (DFAM) and under colonies of bacteria. Iron-silicate glass planchets chemically similar to hornblende were incubated in buffered growth medium with siderophore-producing bacteria (Bacillus sp.) for 46 days with parallel abiotic experiments conducted with and without 240 μM DFAM, with and without 0.01 g l− 1 of microbially produced extracellular polysaccharides (EPS, alginate or xanthan gum). Some glass planchets were protected by dialysis tubing from direct contact with the EPS. Weekly sampling and analysis of all filtered sample solutions showed negligible Fe and Al release in the control experiments and significant release of Fe and Al in the presence of DFAM, with negligible changes in pH. Concentration of Fe in the filtered solutions after incubation with bacteria was below detection, consistent with uptake of Fe by cells. Release of Fe, Al, and Si in control, xanthan-only, and alginate-only experiments was negligible. Release of these elements was enhanced in all experiments containing DFAM, and greatest in alginate + DFAM experiments.

AFM and VSI analyses reveal widespread, small etch pits and greater root mean squared roughness on siderophore-exposed surfaces and fewer, localized, larger etch pits on bacteria-exposed surfaces. This is the first documented case of etch pit development during siderophore-promoted dissolution. Roughness was not affected by the growth medium, alginate, or xanthan gum alone. The roughness trends among samples correlate with trends in Fe depletion documented by XPS. Enhanced dissolution and roughness cannot be attributed to direct contact with EPS because no significant chemical or physical differences were observed between surfaces directly exposed to EPS and those protected by dialysis tubing. Acetate released from the EPS may have enhanced the siderophore-promoted dissolution. Siderophores produced by Bacillus sp. may be responsible for some of the ‘biopits.’ The difference in size and distribution of the biopits may be related to colonization.  相似文献   

93.
Sediment from two deep boreholes (∼400 m) approximately 90 km apart in southern Bangladesh was analyzed by X-ray absorption spectroscopy (XAS), total chemical analyses, chemical extractions, and electron probe microanalysis to establish the importance of authigenic pyrite as a sink for arsenic in the Bengal Basin. Authigenic framboidal and massive pyrite (median values 1500 and 3200 ppm As, respectively), is the principal arsenic residence in sediment from both boreholes. Although pyrite is dominant, ferric oxyhydroxides and secondary iron phases contain a large fraction of the sediment-bound arsenic between approximately 20 and 100 m, which is the depth range of wells containing the greatest amount of dissolved arsenic. The lack of pyrite in this interval is attributed to rapid sediment deposition and a low sulfur flux from riverine and atmospheric sources. The ability of deeper aquifers (>150 m) to produce ground water with low dissolved arsenic in southern Bangladesh reflects adequate sulfur supplies and sufficient time to redistribute the arsenic into pyrite during diagenesis.  相似文献   
94.
Annual cycles of convectively important atmospheric parameters have been computed for a variety of from the National Center for Atmospheric Research (NCAR)/National Centers for Environmental Prediction (NCEP) global reanalysis, using 7 years of reanalysis data. Regions in the central United States show stronger seasonality in combinations of thermodynamic parameters than found elsewhere in North America or Europe. As a result, there is a period of time in spring and early summer when climatological mean conditions are supportive of severe thunderstorms.The annual cycles help in understanding the large-scale processes that lead to the combination of atmospheric ingredients necessary for strong convection. This, in turn, lays groundwork for possible changes in distribution of the environments associated with possible global climate change.  相似文献   
95.
Little is known regarding hormone export from tile‐drained agricultural fields despite the widespread presence of tile drains in the Midwestern United States. By intensively measuring water flow rates and hormone concentrations in four subsurface tile drains and three receiving ditches at a working Midwest farm, hormone fluxes and loads from the tile‐drained fields were quantified. Before and during the 17‐month study period (January 2009 – May 2010), the associated farm fields received various animal waste applications (beef, dairy, poultry, sheep, and swine). Hormones monitored included the estrogens17β‐ and 17α‐estradiol, estrone, and estriol; the natural androgens testosterone, and androstenedione; and the synthetic androgens 17β‐ and 17α‐trenbolone, and trendione. Hormone loads measured in the ditches for three drainage areas during the entire 17‐month study period were in ranges of 16–58 mg/ha for total estrogens, 6.8–19 mg/ha for natural androgens, and 4.2–44 mg/ha for synthetic androgens. Because higher hormone concentrations generally occurred during discrete periods of increased flow, high flow rates often were associated with a disproportionately high hormone flux. For example, 80% of total estrogens and natural androgens exported into the ditches occurred during only 9–26% of the study period, coinciding with the most significant storm events. In addition, hormone fluxes were highest during storm events that occurred shortly after animal waste applications. Therefore, to effectively reduce hormone loads exported to downstream aquatic ecosystems in the absence of any application reduction, the short periods during which high‐flow events occur must be targeted. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
96.
97.
The Musgrave Province developed at the nexus of the North,West and South Australian cratons and its Mesoproterozoic evolution incorporates a 100 Ma period of ultra-high temperature(UHT) metamorphism from ca.1220 to ca.1120 Ma.This was accompanied by high-temperature A-type granitic magmatism over an 80 Ma period,sourced in part from mantle-derived components and emplaced as a series of pulsed events that also coincide with peaks in UHT metamorphism.The tectonic setting for this thermal event(the Musgrave Orogeny) is thought to have been intracontinental and the lithospheric architecture of the region is suggested to have had a major influence on the thermal evolution.We use a series of two dimensional,fully coupled thermo-mechanical-petrological numerical models to investigate the plausibility of initiating and prolonging UHT conditions under model setup conditions appropriate to the inferred tectonic setting and lithospheric architecture of the Musgrave Province.The results support the inferred tectonic framework for the Musgrave Orogeny,predicting periods of UHT metamorphism of up to 70 Ma,accompanied by thin crust and extensive magmatism derived from both crustal and mantle sources.The results also appear to be critically dependent upon the specific location of the Musgrave Province,constrained between thicker cratonic masses.  相似文献   
98.
International examples of interactions between Indigenous peoples and the new conservation paradigm come mainly from developing countries and suggest divisions over priorities. As a Western settler society, Australia is at a critical time in conservation and Indigenous peoples' rights. Innovative approaches to conservation are promoted. The role and influence of non-governmental organisations is increasing. Indigenous peoples' rights to land are recognised and Indigenous involvement in conservation is growing. Yet, despite Australia being considered a leader in these arenas, particularly the latter, there has been little analysis of the relationship between innovative approaches to conservation and Indigenous Australians under the new paradigm. This paper describes how the spatial manifestations of approaches under the new conservation paradigm and Indigenous land in Australia are creating new geographies. We identify geographies of overlap, dichotomy and absence. The paper identifies research needs into these geographies, including: examining the influence of ‘recognition’ in engagements between conservation and Indigenous Australians; investigating the impacts of approaches under the new paradigm such as scaling-up, territorialism and differing governance structures on Indigenous Australians; and questioning the social responsibilities of the non-governmental organisations towards Indigenous Australians.  相似文献   
99.
Reservoirs provide important water resources and require careful management, through ecological monitoring, to identify and mitigate changes in water quality. Long-term data on vegetation changes and the impacts of human activities on reservoir water chemistry, however, are often limited. Setting restoration targets can therefore be problematic. Palaeoenvironmental research has made little use of reservoir sediments and there is great potential for palaeoecological data to be incorporated into management planning. Diatoms and pollen were analysed in sediment cores from Venford Reservoir, southwest England, to infer pH and land-use changes, respectively, over the last century. Diatom-inferred (DI) pH indicates that reservoir pH declined from ~pH 6.0 in the early part of the record and reached a low between AD 1920 and 1940 (~pH 5.6), which was likely associated with fossil fuel combustion and acid deposition. DI-pH then increased, but values remained relatively low, even in the most recent sediments (~pH 5.7), and the magnitude of inferred pH change over time was small. Land-use changes, such as increased grazing intensity and erosion, and establishment of pine plantations, also likely influenced reservoir water chemistry changes over time. Understanding the impacts of such factors on water chemistry has implications for future catchment land-use planning, which is essential for managing water resources. The pollen record indicates a shift from heather-dominated to grass-dominated vegetation since ~AD 1935–1950, which could be related to increased grazing intensity. The palaeoecological dataset is valuable as a long-term record against which short-term monitoring datasets and future changes can be assessed.  相似文献   
100.
Jellyfish blooms in pelagic systems appear to be increasing on a global scale because of anthropogenic impacts, but much less is known about the link between human activities and epibenthic jellyfish abundance. The aim of this study was to investigate whether the epibenthic jellyfish, Cassiopea spp., were found in greater abundance, and attained larger sizes, in coastal habitats adjacent to high human population densities compared to sites adjacent to uninhabited areas on Abaco Island, Bahamas. Cassiopea spp. were found to be significantly more dense and larger in areas with high human population densities. Ambient nutrient levels and nutrient content of seagrass were elevated in high human population density sites, and may be one mechanism driving higher abundance and size of Cassiopea spp. Cassiopea spp. may have important effects on community structure and ecosystem function in critical coastal ecosystems (e.g., seagrass beds), and their impacts warrant further study.  相似文献   
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