The early proterozoic Mississippi Valley-type Pb-Zn-F deposits of the Campbellrand and Malmani Subgroups,South Africa     

J. E. J. Martini  P. G. Eriksson  C. P. Snyman 《Mineralium Deposita》1995,30(2):135-145

Pb-Zn-F deposits occur in the very late Archaean (2.55 Ga) shallow marine dolostone of the relatively undeformed Campbellrand and Malmani Sub-groups, which are overlain unconformably by the lower Proterozoic Postmasburg and Pretoria Group siliciclastics. They consist of stratiform deposits formed by replacement and porosity-filling, as well as pipes, ring-shaped and irregular bodies associated with collapse breccia. In the Transvaal basin the latter were generated during the karst denudation period between the deposition of the Chuniespoort Group (ending at 2.4 Ga) and of the Pretoria Group (starting at 2.35 Ga). A part of these mineralisations were overprinted by the metamorphism of the Bushveld Complex intrusion at 2.06 Ga. In the Transvaal basin, the age of the mineralisation is constrained between the start of the Pretoria Group deposition and the Bushveld intrusion. It is concluded that, although most of the mineralisations are characteristic of the Mississippi Valley-type, some of the northernmost occurrences, rich in siderite, are less typical. A classic genetic model is proposed. In an environment characterised by tensional tectonics and basin development, brines of basinal origin were heated by circulation into pre-Chuniespoort rocks, leached metals from the rocks they permeated, and rose as hydrothermal plumes. At relatively shallow depth they deposited minerals after mixing with water of surficial origin.  相似文献   

Light hydrocarbons in hydrothermal and magmatic fumaroles: hints of catalytic and thermal reactions     

B. Capaccioni  M. Martini  F. Mangani 《Bulletin of Volcanology》1995,56(8):593-600

Volcanic gaseous mixtures emitted from active volcanoes frequently show variable amounts of saturated (alkanes), unsaturated (alkenes) and aromatic volatile hydrocarbons. Three major patterns of distributions can be recognized, apparently related to the chemical-physical environment of formation of the gas exhalations: alkane-rich, low-temperature gas emissions from recently active volcanic areas; aromatic-rich hydrothermal manifestations; and alkene-rich, magmatic fumaroles on active volcanoes. Thermodynamic data, together with theoretical and practical findings from the petroleum industry, point to two main types of reactions occurring in these volcanic environments: cracking and reforming. Cracking processes, mainly caused by thermal effects, occur when hydrocarbon-bearing hydrothermal fluids enter and mix with a hot and dry, rapidly rising magmatic gas phase. The most probable products are light alkenes with carbon numbers decreasing with increasing reaction temperatures. The presence of aromatic species in hydrothermal fluids can be linked to reforming processes, catalysed by several possible agents, such as smectites and zeolites, generally present in the hydrothermally altered volcanic terranes, and facilitated by long residence times in a hydrothermal envelope.  相似文献   

Cement stratigraphy: image probes of cathodoluminescent facies     

Aurèle Vuillemin  Mapathe Ndiaye  Rossana Martini  Eric Davaud 《Swiss Journal of Geoscience》2011,104(1):55-66

Cement stratigraphy of carbonates aims to establish the chronology of processes involved in the rock diagenesis. Regional cement stratigraphy allows correlations and understanding of the petrological heterogeneities in reservoirs and aquifers, but is a long and rigorous approach. This article exposes a methodology of image analysis that facilitates the spatial correlation of diagenetic events in carbonate rocks. Based on the statistical comparison of signals extracted from the red spectrum emission of cathodoluminescence digital images, it gives via crosscorrelation a measure of similarity (values scaled from minimum −1 to maximum 1) between two cathodoluminescence facies. Cementation events and diagenetic chronologies can thus be quickly correlated without the support of a full chronology, the model normally established on cement morphologies, petrological analyses and cathodoluminescence zonation sequences. A case study from two Upper Kimmeridgian Mount Salève outcrops (France) illustrates this methodology. Their diagenetic sequences recorded in cathodoluminescent cements are presented and being compared. The final statistical similarity between the two outcrops reaches an index of R = 0.78. This result is sustained by petrological and geochemical analyses such as alizarine–ferricyanure stained thin sections, X microfluorescence mapping of elements, and microthermometry of fluid inclusions.  相似文献   

The latest Ursus spelaeus in Italy,a new contribution to the extinction chronology of the cave bear     

Ivan Martini  Mauro Coltorti  Paul P.A. Mazza  Marco Rustioni  Fabio Sandrelli 《Quaternary Research》2014

The skeleton of a young prime adult cave bear, Ursus spelaeus, was found in Chiostraccio Cave (Siena, Tuscany, central Italy), only slightly buried under rock falls. The specimen was dated yielding a conventional age of 24,030 ± 100 ¹⁴C yr BP (29,200–28,550 cal yr BP), which makes it the latest known representative of the species in Italy. The skeleton was accompanied by the remains of wolf (Canis lupus), wild boar (Sus scrofa), aurochs (Bos primigenius), red deer (Cervus elaphus), roe deer (Capreolus capreolus), bat (Vespertinus murinus), and crow (Corvus monedula). The site seems confirming that the latest Italian U. spelaeus populations shared the risk of intrusion. The association of the cave bear with other animals suggests that the assemblage is an attritional palimpsest of remains of different species not originally associated in life. Cave bears were probably more vegetarian than brown bears and possibly became extinct when plant productivity dropped at the onset of MIS 2. Central and southern Italy may have offered isolated and sheltered refugia for cave bears.  相似文献   

Evolution and architecture of a West Mediterranean Upper Pleistocene to Holocene coastal apron‐fan system     

Stefano Andreucci  Laura Panzeri  I. Peter Martini  Francesco Maspero  Marco Martini  Vincenzo Pascucci 《Sedimentology》2014,61(2):333-361

The Quaternary deposits of tectonically stable areas are a powerful tool to investigate high‐frequency climate variations (<10 ka) and to distinguish allogenic and autogenic factors controlling deposition. Therefore, an Upper Pleistocene–Holocene coastal apron‐fan system in north–western Sardinia (Porto Palmas, Italy) was studied to investigate the relations between climate changes, sea‐level fluctuations and sediment source‐supply that controlled its development. The sedimentary sequence records the strong influence of local (wet/dry) and worldwide (sea‐level) environmental variations in the sedimentation and preservation of the deposits. A multi‐disciplinary approach allowed subdivision of the succession into four major, unconformity‐bounded stratigraphic units: U1 U2, U3 and U4. Unit U1, tentatively dated to the warm and humid Marine Isotopic Stage (MIS) 5, consists of sandy, gravelly coastal/beach deposits developed during high sea‐level in low‐lying areas. Unit U2 consists of debris‐flow dominated fan‐deposits (ca 74 ka; MIS 4), preserved as partial fills of small valleys and coves. Unit U2 is mainly composed of reddish silty conglomerate to pebbly siltstones sourced from the Palaeozoic metamorphic inland hills (bedrock), superficially disintegrated during the preceding warm, vegetation‐rich MIS 5. The cold and semi‐arid climate strongly reduced vegetation cover along the valley flanks. Therefore, sediment gravity‐flow processes, possibly activated by rainstorms, led to deposition of debris‐flow dominated fans. Unit U3 consists of water‐flow dominated alluvial‐fan deposits (ca 47 to 23 ka; MIS 3), developed on a slightly inclined coastal plain. Unit U3 is composed of sandstone and sandy conglomerate fed from two main sediment sources: metamorphic inland bedrock and Quaternary bioclastic‐rich shelf‐derived sands. During this cold phase, sea‐level dropped sufficiently to expose bioclastic sands accumulated on the shelf. Frequent climate fluctuations favoured inland aeolian transport of sand during dry phases, followed by reworking of the aeolian bodies by flash floods during wet phases. Bedrock‐derived fragments mixed with water‐reworked, wind‐blown sands led to the development of water‐flow dominated fans. The Dansgaard–Oeschger events possibly associated with sand landward deflation and main fan formations are Dansgaard–Oeschger 13 (ca 47 ka), Dansgaard–Oeschger 8 (ca 39 ka) and Dansgaard–Oeschger 2 (ca 23 ka). No record of sedimentation during MIS 2 was observed. Finally, bioclastic‐rich aeolianites (Unit U4, ca 10 to 5 ka; MIS 1), preserved on a coastal slope, were developed during the Holocene transgression (ca 10 to 5 ka; MIS 1). The studied sequence shows strong similarities with those of other Mediterranean sites; it is, however, one of the few where the main MIS 4 and MIS 3 climatic fluctuations are registered in the sedimentary record.  相似文献   

Révision stratigraphique de l’Ile de Timor (Indonésie orientale)     

Michel Villeneuve  Jean-Jacques Cornée  Agus Harsolumakso  Rossana Martini et Louisette Zaninetti 《Eclogae Geologicae Helvetiae》2005,98(2):297-310

Resume. De nombreuses échelles stratigraphiques de l’?le de Timor ont vu le jour car les corrélations stratigraphiques étaient rendues difficiles par la complexité tectonique de l’?le et par la variété des faciès. Dès les premiers travaux, plusieurs séries ont été distinguées, regroupées en trois unités litho-structurales principales: unité allochtone, sub-autochtone et autochtone. Les données stratigraphiques et géodynamiques récentes montrent que l’?le de Timor est en fait constituée par six unités litho-structurales, chacune témoignant d’un épisode majeur de l’histoire géologique de l’Ile. Cette histoire consiste d’abord à la séparation, au Jurassique, d’un bloc issu du continent de Gondwana (unité para-allochtone) qui est entré en collision avec l’arc volcanique asiatique à l’Oligo-Miocène (unités allochtone et sub-allochtone). Cet ensemble a ensuite été séparé de l’Asie lors de l’ouverture de la mer de Banda sud, au Miocène supérieur (unité sub-autochtone) pour finalement entrer en collision avec la marge nord australienne au cours du Pliocène moyen (plateforme australienne et groupe de Kolbano). Timor est depuis incorporée à la marge nord australienne (unité autochtone). Ce travail présente les différentes échelles stratigraphiques de chaque nouvelle unité, des propositions de corrélations et une comparaison avec les ?les voisines de Sumba et de Sulawesi pour aboutir à une proposition d’évolution géodynamique. Manuscrit re?u le 13 février 2004 Révision acceptée le 14 février 2005  相似文献   

Geodetic and seismologic evidence for slip variability along a blind normal fault in the Umbria-Marche 1997–1998 earthquakes (central Italy)     

Paolo Marco De Martini  Nicola Alessandro Pino  Gianluca Valensise  Salvatore Mazza 《Geophysical Journal International》2003,155(3):819-829

  相似文献   

Pleistocene recharge to midcontinent basins: effects on salinity structure and microbial gas generation   总被引：2，自引：0，他引：2  

J.C. McIntosh  L.M. WalterA.M. Martini 《Geochimica et cosmochimica acta》2002,66(10):1681-1700

The hydrogeochemistry of saline-meteoric water interface zones in sedimentary basins is important in constraining the fluid migration history, chemical evolution of basinal brines, and physical stability of saline formation waters during episodes of freshwater recharge. This is especially germane for interior cratonic basins, such as the Michigan and Illinois basins. Although there are large differences in formation water salinity and hydrostratigraphy in these basins, both are relatively quiescent tectonically and have experienced repeated cycles of glaciation during the Pleistocene. Exploration for unconventional microbial gas deposits, which began in the upper Devonian-age Antrim Shale at the northern margin of the Michigan Basin, has recently extended into the age-equivalent New Albany Shale of the neighboring Illinois Basin, providing access to heretofore unavailable fluid samples. These reveal an extensive regional recharge system that has profoundly changed the salinity structure and induced significant biogeochemical modification of formation water elemental and isotope geochemistry.New-formation water and gas samples were obtained from Devonian-Mississippian strata in the Illinois Basin. These included exploration wells in the New Albany Shale, an organic-rich black shale of upper Devonian age, and formation waters from over- and underlying regional aquifer systems (Siluro-Devonian and Mississippian age). The hydrostratigraphic relations of major aquifers and aquitards along the eastern margin of the Illinois Basin critically influenced fluid migration into the New Albany Shale. The New Albany Shale formation water chemistry indicates significant invasion of meteoric water, with δD values as low as −46.05‰, into the shale. The carbon stable isotope system (δ¹³C values as high as 29.4‰), coupled with δ¹⁸O, δD, and alkalinity of formation waters (alkalinity ≤24.08 meq/kg), identifies the presence of microbial gas associated with meteoric recharge. Regional geochemical patterns identify the underlying Siluro-Devonian carbonate aquifer system as the major conduit for freshwater recharge into the fractured New Albany Shale reservoirs. Recharge from overlying Mississippian carbonates is only significant in the southernmost portion of the basin margin where carbonates directly overlie the New Albany Shale.Recharge of dilute waters (Cl⁻ <1000 mM) into the Siluro-Devonian section has suppressed formation water salinity to depths as great as 1 km across the entire eastern Illinois Basin margin. Taken together with salinity and stable isotope patterns in age-equivalent Michigan Basin formation waters, they suggest a regional impact of recharge of δ¹⁸O- and δD-depleted fluids related to Pleistocene glaciation. Devonian black shales at both basin margins have been affected by recharge and produced significant volumes of microbial methane. This recharge is also manifested in different salinity gradients in the two basins because of their large differences in original formation water salinity. Given the relatively quiet tectonic history and subdued current topography in the midcontinent region, it is likely that repeated cycles of glacial meltwater invasion across this region have induced a strong disequilibrium pattern in fluid salinity and produced a unique class of unconventional shale-hosted gas deposits.  相似文献   

The application of GPR to barrier—lagoon sedimentation study in Boao of Hainan Island     

Yin Yong Ph.D.  Zhu Dakui  Tang Wenwu  Martini I. Peter 《地理学报(英文版)》2002,12(3):313-320

Sedimentary successions and internal structure of the coastal barrier-lagoon system of Boao, eastern Hainan Island were studied through utilizing data from test holes and trenches and ground-penetrating-radar (GPR) profiles. During late Pleistocene, fluvial and delta plains developed over an unevenly eroded bedrock during low sea level stand, followed by the formation of littoral and lagoon facies and defined coastal barrier-lagoon-estuary system during the post-glacial uppermost Pleistocene-lower Holocene eustatic rise of the sea level, and the upper Holocene high stand. GPR results show that Yudaitan, a sandy coastal bar backed by a low-laying land (shoal) just east of the active lagoon, is a continuous, parallel and slightly-wavy reflectors indicating homogeneous sandy or sandy gravel sediments, and inclined reflectors partly caused by progradation and accumulation of beach sand and gravel. Quasi-continuous, hummocky and chaotic reflectors from the shoal of Nangang village correspond to mixed accumulation of sands and clay. This research indicates the GPR is a non-intrusive, rapid, and economical method for high-resolution profiling of subsurface sediments in sandy gravelly coast.  相似文献   

Triassic stratigraphy,facies and evolution of the Arabian shelf in the northern United Arab Emirates     

Florian Maurer  Roberto Rettori  Rossana Martini 《International Journal of Earth Sciences》2008,97(4):765-784

This study provides a reconstruction of the Late Permian and Triassic depositional history of the Arabian shelf in the northern United Arab Emirates based on facies analysis and foraminiferal biostratigraphy. The presented data show that sedimentation occurred in three major sequences. From the Late Permian to Olenekian carbonates and evaporites were deposited in restricted lagoons and tidal flats. After a hiatus, sedimentation resumed and continued until the Late Ladinian/Carnian, leading to the deposition of a carbonate platform dominated by peritidal dolostones. A period of shelf exposure and erosion, spanning from the Carnian to Norian, was followed by the third major sequence with sedimentation into the Early Jurassic. During this third depositional sequence sedimentation changed from pure carbonate into mixed carbonate–siliciclastic deposits. This transition reflects the global regression of the sea in the Late Triassic (Triasina hantkeni Zone) and the increased erosion of large parts of the Arabian hinterland. A comparison of the evolution of the Arabian shelf in the study area with chronostratigraphic reference schemes for the Arabian Plate reveals remarkable differences in the distribution of Middle and Upper Triassic sequences. These are most likely the result of poor biostratigraphic control on previously studied formations in the region.  相似文献