Density variations of Cr-rich garnets in the upper mantle inferred from the elasticity of uvarovite garnet     

Steeve Gréaux  Akihiro Yamada 《Comptes Rendus Geoscience》2019,351(2-3):95-103

The thermoelastic parameters of Ca₃Cr₂Si₃O₁₂ uvarovite garnet were examined in situ at high pressure up to 13 GPa and high temperature up to 1100 K by synchrotron radiation energy-dispersive X-ray diffraction within a 6-6-type multi-anvil press apparatus. A least-square fitting of room T data to a third-order Birch–Murnaghan (BM3) EoS yielded K₀ = 164.2 ± 0.7 GPa, V₀ = 1735.9 ± 0.3 ų (K’₀ fixed to 4.0). P–V–T data were fitted simultaneously by a modified HT-BM3 EoS, which gave the isothermal bulk modulus K₀ = 163.6 ± 2.6 GPa, K’₀ = 4.1 ± 0.5, its temperature derivative (?K_0,T/?T)_P = –0.014 ± 0.002 GPa K^?1, and the thermal expansion coefficients a₀ = 2.32 ± 0.13 ×10^?5 K^?1 and b₀ = 2.13 ± 2.18 ×10^?9 K^?2 (K’₀ fixed to 4.0). Our results showed that the Cr³⁺ enrichment in natural systems likely increases the density of ugrandite garnets, resulting in a substantial increase of mantle garnet densities in regions where Cr-rich spinel releases chromium through a metasomatic reaction.  相似文献   

Study on the fate of petroleum-derived polycyclic aromatic hydrocarbons (PAHs) and the effect of chemical dispersant using an enclosed ecosystem,mesocosm     

Yamada M  Takada H  Toyoda K  Yoshida A  Shibata A  Nomura H  Wada M  Nishimura M  Okamoto K  Ohwada K 《Marine pollution bulletin》2003,47(1-6):105-113

Polycyclic Aromatic Hydrocarbons (PAHs) are one of the components found in oil and are of interest because some are toxic. We studied the environmental fate of PAHs and the effects of chemical dispersants using experimental 500 l mesocosm tanks that mimic natural ecosystems. The tanks were filled with seawater spiked with the water-soluble fraction of heavy residual oil. Water samples and settling particles in the tanks were collected periodically and 38 PAH compounds were analyzed by gas chromatography-mass spectrometry (GC-MS). Low molecular weight (LMW) PAHs with less than three benzene rings disappeared rapidly, mostly within 2 days. On the other hand, high molecular weight (HMW) PAHs with more than four benzene rings remained in the water column for a longer time, up to 9 days. Also, significant portions (10-94%) of HMW PAHs settled to the bottom and were caught in the sediment trap. The addition of chemical dispersant accelerated dissolution and biodegradation of PAHs, especially HMW PAHs. The dispersant amplified the amounts of PAHs found in the water column. The amplification was the greater for the more hydrophobic PAHs, with an enrichment factor of up to six times. The increased PAHs resulting from dispersant use overwhelmed the normal degradation and, as a result, higher concentrations of PAHs were observed in water column throughout the experimental period. We conclude that the addition of the dispersant could increase the concentration of water column PAHs and thus increase the exposure and potential toxicity for organisms in the natural environment. By making more hydrocarbon material available to the water column, the application of dispersant reduced the settling of PAHs. For the tank with dispersant, only 6% of chrysene initially introduced was detected in the sediment trap whereas 70% was found in the trap in the tank without dispersant.  相似文献   

Estimation of water requirement per unit carbon fixed by<Emphasis Type="Italic">Eucalyptus camaldulensis</Emphasis> in semi-arid land of Western Australia     

T. Kojima  Y. Tanaka  S. Katoh  K. Tahara  N. Takahashi  K. Yamada 《中国科学D辑(英文版)》2002,45(1):142-147

Afforestation in arid land is a promising method for carbon fixation, but the effective utilization of water is highly important and required. Thus, the evaluation of the amount of water per unit carbon fixed with the tree growth is required to minimize the amount of water supplied to the plants. In this research, a tree is regarded as a carbon fixation reactor with inflows of water and nutrients from roots, and CO₂ as the carbon source from leaves with outflow of water vapor from leaves and accumulation in the tree itself. In the process of photosynthesis and respiration nutritional elements are dissolved in water flow in trees. They do not flow out by these reactions, but are accumulated in trees. Thus, we have treated the behaviour of nutrients as a marker to evaluate the water/carbon ratio.Assuming that nutrient concentration is constant in sap, and the differences in the ratios of nutrient to carbon in living trees and dead (i.e. litter fall, etc.) are neglected, the ratio of the used water to fixed carbon is given as the ratio of nutrient to carbon in the tree body divided by the ratio of nutrient to water in sap. However, some nutrients are translocated and concentrated within the tree and some may be discarded through litter fall. Thus it is important to examine which nutrient element is the most suitable as the tracer.In this paper, the results of the above method applied toEucalyptus camaldulensis in semiarid land of Western Australia are shown. The value of water requirement per unit carbon fixation determined from potassium balance is between 421 kg-H₂O/kg-C for mature trees and 285 kg-H₂O/kg-C for young trees, while the values from calcium balance are much larger than these. The cause of the discrepancy between these values is discussed based on the measured element concentrations in sap and trees and the plant physiology. Finally, the actual average value through the life of a tree is suggested to fall between the two values.  相似文献   

Sedimentary effects on the expansion of a Himalayan supraglacial lake     

Kazuhisa Chikita  Jageshwar Jha  Tomomi Yamada 《Global and Planetary Change》2001,28(1-4)

Supraglacial Tsho Rolpa Lake in the Nepal Himalaya has been increasing rapidly in size since the 1950s, corresponding to the mountain-glacier shrinkage after the Little Ice Age. The lake basin expansion results from the subsidence by dead-ice melt below the bottom of the lake, and the retreat of the glacier terminus. Field observations of Tsho Rolpa in 1996 revealed that the retreat of glacier terminus is connected to a wind-induced vertical circulation of surface water heated by solar radiation. In order to clarify the mechanism of the lake expansion associated with sedimentary processes, we measured bottom sedimentation rate with some sediment traps, and vertical suspended sediment concentration (SSC) and water temperature, and analyzed the grain size of suspended and trapped sediments. The sediments, mostly composed of clay-sized grains, are dominantly supplied by glacier-melt water inflow at the glacier terminus. Sedimentary processes of such fine sediment comprise: (1) suspended-sediment fallout from intrusion of horizontal currents; (2) sediment sorting by sediment-laden underflows; and (3) the debris supply from the ice collapse at the glacier terminus. The (1) and (2) processes produce the density stratification of the lake, accompanied by a pycnocline at a depth of about 27 m. The existence of the pycnocline builds up the vertical water circulation in the surface layer to enhance the glacier-melt at the terminus. With respect to the subsidence of the lake bottom, nearly molecular thermal diffusion is probably dominant near the bottom of the deepest point, which results from the kinetic-energy dissipation of sediment-laden underflows. The stable existence of the bottom turbid water throughout the year could cause continuous dead-ice melt below the lake bottom.  相似文献   

The phase boundary between wadsleyite and ringwoodite in Mg2SiO4 determined by in situ X-ray diffraction     

T. Inoue  T. Irifune  Y. Higo  T. Sanehira  Y. Sueda  A. Yamada  T. Shinmei  D. Yamazaki  J. Ando  K. Funakoshi  W. Utsumi 《Physics and Chemistry of Minerals》2006,33(2):106-114

The phase boundary between wadsleyite and ringwoodite in Mg₂SiO₄ has been determined in situ using a multi-anvil apparatus and synchrotron X-rays radiation at SPring-8. In spite of the similar X-ray diffraction profiles of these high-pressure phases with closely related structures, we were able to identify the occurrence of the mutual phase transformations based on the change in the difference profile by utilizing a newly introduced press-oscillation system. The boundary was located at ~18.9 GPa and 1,400°C when we used Shim’s gold pressure scale (Shim et al. in Earth Planet Sci Lett 203:729–739, 2002), which was slightly (~0.8 GPa) lower than the pressure as determined from the quench experiments of Katsura and Ito (J Geophys Res 94:15663–15670, 1989). Although it was difficult to constrain the Clapeyron slope based solely on the present data due to the kinetic problem, the phase boundary [P (GPa)=13.1+4.11×10⁻³×T (K)] calculated by a combination of a P–T position well constrained by the present experiment and the calorimetric data of Akaogi et al. (J Geophys Res 94:15671–15685, 1989) reasonably explains all the present data within the experimental error. When we used Anderson’s gold pressure scale (Anderson et al. in J Appl Phys 65:1535–1543, 1989), our phase boundary was located in ~18.1 GPa and 1,400°C, and the extrapolation boundary was consistent with that of Kuroda et al. (Phys Chem Miner 27:523–532, 2000), which was determined at high temperature (1,800–2,000°C) using a calibration based on the same pressure scale. Our new phase boundary is marginally consistent with that of Suzuki et al. (Geophys Res Lett 27:803–806, 2000) based on in situ X-ray experiments at lower temperatures (<1,000°C) using Brown’s and Decker’s NaCl pressure scales.  相似文献   

Seasonal variation of land–atmosphere coupling strength over the West African monsoon region in an atmospheric general circulation model     

Tomohito J. Yamada  Shinjiro Kanae  Taikan Oki  Randal D. Koster 《水文科学杂志》2013,58(6):1276-1286

Abstract

The seasonal variation of land–atmosphere coupling strength has been examined using an extended series of atmospheric general circulation model (AGCM) simulations. In the Western Sahel of Africa, strong coupling strength for precipitation is found in April and May, just prior to and at the beginning of the monsoon season. At this time, heat and water fluxes from the surface are strongly controlled by land conditions, and the unstable conditions in the lower level of the troposphere, as induced by local land state, allow the surface fluxes to influence the variability of convective precipitation—and thus the timing of monsoon onset.

Editor Z. W. Kundzewicz

Citation Yamada, T.J., Kanae, S., Oki, T., and Koster, R.D., 2013. Seasonal variation of land–atmosphere coupling strength over the West African monsoon region in an atmospheric general circulation model. Hydrological Sciences Journal, 58 (6), 1276–1286.  相似文献   

Anaerobic generation and emission of nitrous oxide in waste landfills     

Tomonori Ishigaki  Mikako Nakagawa  Masanao Nagamori  Masato Yamada 《Environmental Earth Sciences》2016,75(9):750

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Experimental evidence on formation of imminent and short-term hydrochemical precursors for earthquakes     

Jianguo Du  Kazuhiro Amita  Shinji Ohsawa  Youlian Zhang  Chunli Kang  Makoto Yamada 《Applied Geochemistry》2010

The formation of imminent hydrochemical precursors of earthquakes is investigated by the simulation for water–rock reaction in a brittle aquifer. Sixty-one soaking experiments were carried out with granodiorite and trachyandesite grains of different sizes and three chemically-distinct waters for 6 to 168 h. The experimental data demonstrate that water–rock reaction can result in both measurable increases and decreases of ion concentrations in short times and that the extents of hydrochemical variations are controlled by the grain size, dissolution and secondary mineral precipitation, as well as the chemistry of the rock and groundwater. The results indicate that water–rock reactions in brittle aquifers and aquitards may be an important genetic mechanism of hydrochemical seismic precursors when the aquifers and aquitards are fractured in response to tectonic stress.  相似文献