Water organisation at the solid–aqueous solution interfaceOrganisation de l'eau à l'interface solide–solution aqueuse     

Laurent J. Michot  Frédéric Villiéras  Michèle François  Isabelle Bihannic  Manuel Pelletier  Jean-Maurice Cases 《Comptes Rendus Geoscience》2002,334(9):611-631

The aim of this review is to examine the present knowledge about water structure close to an interface or confined in porous spaces. First, the structure of liquid water is briefly described. Though its understanding remains incomplete, it appears that it is largely dominated by the hydrogen bond network and its dynamical evolution. The presence of any ‘foreign’ substance in water perturbs such a structure by changing at least locally the hydrogen bond network. For this reason, the presence of a solid interface significantly modifies the structure of the first adsorbed layers. Whatever the support, it is now clearly evidenced that structural perturbations are limited to distances lower than 10–15 Å from the interface. The nature, energetic heterogeneity and hydrophilicility/hydrophobicity of the solid surface influence the arrangement of water molecules. This surface organisation must definitely be considered when studying adsorption phenomena at the solid–aqueous solution interface. The relevance of such problems to geosciences is illustrated by a few situations in which water structure plays a prominent role. To cite this article: L.J. Michot et al., C. R. Geoscience 334 (2002) 611–631.  相似文献   

Locating a Community Recycling Center within a Residential Area: A Belgian Case Study     

Benoît Flahaut  Marie‐Alexandre Laurent  Isabelle Thomas 《The Professional geographer》2002,54(1):67-82

This article demonstrates the operation of a simple optimal location‐allocation technique for solving the problem of locating one or several community recycling center(s) within a residential area. The article attempts to measure both transportation and externality costs in comparable units, and to incorporate them into the model. A sensitivity analysis of the results at the level of the nuisance provides further insight into the operation of the model and the relative importance of the quantification of pollution in applied location‐allocation problems.  相似文献   

地震储层表征:在模拟储层的三维地震响应时考虑盖层、地震勘探布局和储层物性的敏感度(英文)     

Havar Gjoystda Astound Drottning Isabelle Lecomte Mike Branston 《地学前缘》2008,15(1):123-132

根据三维地震地质模型对地震数据进行模拟是从勘探到生产的周期内决策过程中的一个不可或缺的组成部分。虽然对于在储层内的动力过程和地震地质的模型表述已经取得很大进展,但如何从这些模型得到地震数据的精确模拟仍面临很多挑战。通常是在地球模型范围内根据物性用一维褶积方法来模拟地震数据。然而这个过程一般不考虑地震勘探布局和盖层对地震信号的影响。我们审视了为什么这些因素会制约三维地球模型的有效性,并考虑了为什么需要把盖层和地震勘探布局对三维覆盖和分辨率的影响加进模拟过程之中。我们提出了一种新方法,把建立物性模型和一种新的地震模拟技术结合起来,给出一个工作流程;利用这个流程,勘探工作者可以很快模拟出三维的PSDM数据,这些数据加进了盖层和地震勘探布局对覆盖及分辨率的影响。我们利用从远离挪威海岸的一个油田得到的数据,在考虑覆盖和分辨率效应的地震数据模拟之前,对岩石物性做了一些扰动,然后进行地震数据模拟,以此来说明如何可以用这种方法提高三维地球模型的精确性和增进我们对储层的了解。  相似文献   

ESC and KAIT observations of the transitional Type Ia SN 2004eo     

A. Pastorello  P. A. Mazzali  G. Pignata  S. Benetti  E. Cappellaro  A. V. Filippenko  W. Li  W. P. S. Meikle  A. A. Arkharov  G. Blanc  F. Bufano  A. Derekas  M. Dolci  N. Elias-Rosa  R. J. Foley  M. Ganeshalingam  A. Harutyunyan  L. L. Kiss  R. Kotak  V. M. Larionov  J. R. Lucey  N. Napoleone  H. Navasardyan  F. Patat  J. Rich  S. D. Ryder  M. Salvo  B. P. Schmidt  V. Stanishev  P. Székely  S. Taubenberger  S. Temporin  M. Turatto  W. Hillebrandt 《Monthly notices of the Royal Astronomical Society》2007,377(4):1531-1552

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Fault throw determination using 4 component VSP: Aigion fault (Greece) case study     

Joachim Place  Charles Naville  Isabelle Moretti   《Tectonophysics》2007,440(1-4):141-158

The present paper presents the results of a technique based on Vertical Seismic Profiling (VSP) to quantify the offset of a fault in a context where seismic reflection profiles do not image any reflectors. The case study is located in Greece, in the Aigion area, on the south border of the Corinth Gulf. The Aigion fault, oriented East–West, and dipping at 60°N, has been intersected by the scientific well Aig-10 at 760 m in depth, but some uncertainty remained concerning its exact offset since the depth of the pre-rift sequence is open to debate due to the lack of subsurface data. The pre-rift consists of a Mesozoic low-porosity series (carbonates and radiolarite), while the syn-rift consists of poorly compacted conglomerates and turbidites.

Seismic diffractions on fault edges are expected to be present along the fault surface. We find that a few diffracted events are effectively recorded in P and S wave mode by the 4 components of the VSP survey, and critically refracted arrivals along the Aigion fault plane. These singular events have been used in order to refine the fault geometry and to determine its throw. Additionally, results from a 2D finite difference elastic seismic model of a single fault step geometry have been closely examined in order to illustrate the generation of the singular seismic events observed on the field data, such as P-wave and S-wave refracted and diffracted events, and support their interpretation with higher confidence. As a result, the seismic arrival patterns from full waveform seismic modelling confirm the characterisation of the main fault geometry (mainly its throw: about 200 m) in the well vicinity derived from the actual analysis of the 4 Component Aigion VSP data.  相似文献   

Preservation potential of highstand coastal sedimentary bodies in a macrotidal basin: Example from the Bay of Mont-Saint-Michel, NW France     

Isabelle Billeaud  Bernadette Tessier  Bruno Caline 《Sedimentary Geology》2007,202(4):754-775

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Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part I: Isotopic (C,O) study of the Khushaym Matruk natural analogue (central Jordan)     

Serge Fourcade  Laurent Trotignon  Philippe Boulvais  Isabelle Techer  Marcel Elie  Didier Vandamme  Elias Salameh  Hani Khoury 《Applied Geochemistry》2007

The Khushaym Matruk site in central Jordan may represent a natural analogue depicting the interaction of alkaline solutions with a clayey sedimentary formation or with clay-rich confining barriers at the interface with concrete structures in waste disposal sites. In this locality, past spontaneous combustion of organic matter in a clayey biomicritic formation produced a ca. 60 m-thick layer of cement-marble containing some of the high-temperature phases usually found in industrial cements (e.g., spurrite, brucite, and Ca-aluminate). A vertical cross-section of the underlying sediments was used in order to study the interaction between cement-marbles and neighbouring clayey limestones under weathering conditions. A thermodynamic approach of the alteration parageneses (calcite–jennite–afwillite–brucite and CSH phases) in the cement-marbles constrains the interacting solutions to have had pH-values between 10.5 and 12. Over 3 m, the sediments located beneath the metamorphic unit were compacted and underwent carbonation. They display large C and O isotopic variations with respect to “pristine” sediments from the bottom of the section. Low δ¹³C-values down to −31.4‰/PDB show the contribution of CO₂ derived from the oxidization of organic matter and from the atmosphere to the intense carbonation process affecting that particular sedimentary level. The size of the C isotopic anomalies, their geometrical extent and their coincidence with the variations of other markers like the Zn content, the structure of organic matter, the mineralogical composition, all argue that the carbonation process was induced by the percolation of high pH solutions which derived from the alteration of cement-marbles. The temperature of the carbonation process remains conjectural and some post-formation O isotopic reequilibration likely affected the newly-formed carbonate. Carbonation induced a considerable porosity reduction, both in fractures and matrixes. The Khushaym Matruk site may have some bearing to the early life of a repository site, when water saturation of the geological formations hosting the concrete structures is incomplete, enabling simultaneous diffusion of alkaline waters and gaseous CO₂ in the near field.  相似文献   

Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part II: Organic matter evolution,magnetic susceptibility and metals (Ti,Cr, Fe) at the Khushaym Matruk natural analogue (Central Jordan)     

Marcel Elie  Isabelle Techer  Laurent Trotignon  Hani Khoury  Elias Salameh  Didier Vandamme  Philippe Boulvais  Serge Fourcade 《Applied Geochemistry》2007

Spontaneous combustion, less than 1 Ma ago, affected a 60-m thick sediment pile of biomicrite at the Khushaym Matruck site (Jordan). The present study shows that three retrograde alteration stages occurred: weathering, thermal stress and oxidative alkaline perturbation. μ-FT-i.r. spectra of isolated kerogens and oxygen index of whole rocks indicate that oxidation of organic matter occurred down to ∼10 m beneath the metamorphosed zone at Khushaym Matruck. The occurrence of the oxidative weathering bacterially mediated, as suggested by the mass chromatograms of saturated hydrocarbons, can explain high Rock-Eval T_max values and low petroliferous potential measured along the sedimentary pile. On the other hand, the thermal extent of combustion events was limited to the first 2 m from the contact. The mean reflectance of 0.20–0.24% and porosity of ca. 50% of the grey clayey biomicrites indicate that organic matter was very immature and sediments were unconsolidated at the time of the combustion event. Using mineralogy, microscopic analyses of vegetable debris and magnetic susceptibility, a suite of characteristic points corresponding to the thermal imprint can be assessed: (i) x = 0m, T ∼ 1000 °C, (ii) x = 1 m, T ∼ 350 °C, (iii) x = 2 m, T ∼ 150 °C and (iv) x > ∼ 8 m, T ∼ 30 °C. Paleocirculation of meteoric groundwater in the ‘cement-marbles’ generated high-pH fluids that have circulated via fractures and through the matrix porosity of the underlying biomicrites but have also induced alkaline hydrolysis and oxidative attack of the organic matter. The polysaccharide/lignin ratio derived from μ-FT-i.r. analyses shows that the delignification of vegetable debris and degradation of polysaccharides progressively decline in the indurated zone, which indicates a decrease in the pH of migrating solutions. The latter also severely oxidized organic matter at 2.10 and 3.05 m as revealed by the oxygen index and induced the generation of bitumen. The spatial correlation between the oxidation levels of organic matter and the metal contents (Fe, Ti and Cr) suggests that redox reactions were responsible for the immobilization of metals in the indurated biomicrites. The intensity of these reactions is attributed to changes in the fluid flow regime within the sedimentary column.  相似文献   

Reconstitution des apports en éléments traces métalliques et bilan de leur migration dans un Luvisol sableux soumis à 100 ans d'irrigation massive par des eaux usées brutes     

Christelle Dère  Isabelle Lamy  Folkert van Oort  Denis Baize  Sophie Cornu 《Comptes Rendus Geoscience》2006,338(8):565-573

Raw wastewaters were massively spread on sandy luvisols near Paris from 1899 to 2002, leading to high trace metals (TM) pollution of soils. Mass balance calculations were performed on a soil profile to assess vertical migration of TM. The contamination was estimated by subtracting the natural pedo-geochemical background of the horizons. TM inputs were estimated using Cr as an invariant. It is shown that Pb and Cr remained in the surface horizon, while Ni, Cd, Cu and Zn migrated downward, being more or less trapped depending on the physicochemical properties of the horizons. To cite this article: C. Dère et al., C. R. Geoscience 338 (2006).  相似文献   

From the green color of eskolaite to the red color of ruby: an X-ray absorption spectroscopy study     

Émilie Gaudry  Philippe Sainctavit  Farid Juillot  Federica Bondioli  Philippe Ohresser  Isabelle Letard 《Physics and Chemistry of Minerals》2006,32(10):710-720

The best known cause for colors in insulating minerals is due to transition metal ions as impurities. As an example, Cr³⁺ is responsible for the red color of ruby (α-Al₂O₃:Cr³⁺) and the green color of eskolaite (α-Cr₂O₃). Using X-ray absorption measurements, we connect the colors of the Cr _x Al_2−x O₃ series with the structural and electronic local environment around Cr. UV–VIS electronic parameters, such as the crystal field and the Racah parameter B, are related to those deduced from the analysis of the isotropic and XMCD spectra at the Cr L_2,3-edges in Cr_0.07Al_1.93O₃ and eskolaite. The Cr–O bond lengths are extracted by EXAFS at the Cr K-edge in the whole Cr _x Al_2−x O₃ (0.07≤x< 2) solid solution series. The variation of the mean Cr–O distance between Cr_0.07Al_1.93O₃ and α-Cr₂O₃ is evaluated to be 0.01₅ Å (≈1%). The variation of the crystal field in the Cr _x Al_2−x O₃ series is discussed in relation with the variation of the averaged Cr–O distances.  相似文献