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An adaptively stabilized finite element scheme is proposed for a strongly coupled hydro‐mechanical problem in fluid‐infiltrating porous solids at finite strain. We first present the derivation of the poromechanics model via mixture theory in large deformation. By exploiting assumed deformation gradient techniques, we develop a numerical procedure capable of simultaneously curing the multiple‐locking phenomena related to shear failure, incompressibility imposed by pore fluid, and/or incompressible solid skeleton and produce solutions that satisfy the inf‐sup condition. The template‐based generic programming and automatic differentiation (AD) techniques used to implement the stabilized model are also highlighted. Finally, numerical examples are given to show the versatility and efficiency of this model. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
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The Greenland ice core from NorthGRIP (NGRIP) contains a proxy climate record across the Pleistocene–Holocene boundary of unprecedented clarity and resolution. Analysis of an array of physical and chemical parameters within the ice enables the base of the Holocene, as reflected in the first signs of climatic warming at the end of the Younger Dryas/Greenland Stadial 1 cold phase, to be located with a high degree of precision. This climatic event is most clearly reflected in an abrupt shift in deuterium excess values, accompanied by more gradual changes in δ18O, dust concentration, a range of chemical species, and annual layer thickness. A timescale based on multi‐parameter annual layer counting provides an age of 11 700 calendar yr b2 k (before AD 2000) for the base of the Holocene, with a maximum counting error of 99 yr. A proposal that an archived core from this unique sequence should constitute the Global Stratotype Section and Point (GSSP) for the base of the Holocene Series/Epoch (Quaternary System/Period) has been ratified by the International Union of Geological Sciences. Five auxiliary stratotypes for the Pleistocene–Holocene boundary have also been recognised. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
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This study investigates partitioning of elements between immiscible aluminosilicate and borosilicate liquids using three synthetic mixtures doped with 32 trace elements. In order to get a good spatial separation of immiscible liquids, we employed a high-temperature centrifuge. Experiments were performed at 1,050–1,150°C, 1 atm, in sealed Fe and Pt containers. Quenched products were analysed by electron microprobe and LA ICP-MS. Nernst partition coefficients (D’s) between the Fe-rich and Si-rich aluminosilicate immiscible liquids are the highest for Zn (3.3) and Fe (2.6) and the lowest for Rb and K (0.4–0.5). The plots of D values against ionic potential Z/r in all the compositions show a convex upward trend, which is typical also for element partitioning between immiscible silicate and salt melts. The results bear upon the speciation and structural position of elements in multicomponent silicate liquids. The ferrobasalt–rhyolite liquid immiscibility is observed in evolved basaltic magmas, and may play an important role in large gabbroic intrusions, such as Skaergaard, and during the generation of unusual lavas, such as ferropicrites.  相似文献   
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Infrared-stimulated luminescence (IRSL) dating of feldspars has the potential to date deposits beyond the age range of quartz optical (OSL) dating. Successful application of feldspar IRSL dating is, however, often precluded due to anomalous-fading, the tunnelling of electrons from one defect site to another. In this paper we test procedures proposed for anomalous-fading correction by comparing feldspar IRSL and quartz OSL dating results on a suite of samples from continental deposits from the southeastern Netherlands. We find that even after anomalous-fading correction IRSL ages underestimate the burial age of the deposits and argue that this may be a consequence of a dependency of anomalous fading rate on the dose rate and on the absorbed dose.  相似文献   
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At eight different areas on the shores of the lower part of Lake Zürich sphaeriids were collected at depths of 3, 6, 9, 12 and 15 m. 368 samples, each 1/16 m2 in size, contained 19,780 individuals, which belong to 14 species. The following points were examined: depth distributions of the species, associations between different species and the dependence of their abundance on environmental factors. Over the period of one year fish were kept away from test-sites in order to estimate their influence on the sphaeriid fauna.  相似文献   
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The chemical weathering of primary Fe-bearing minerals, such as biotite and chlorite, is a key step of soil formation and an important nutrient source for the establishment of plant and microbial life. The understanding of the relevant processes and the associated Fe isotope fractionation is therefore of major importance for the further development of stable Fe isotopes as a tracer of the biogeochemical Fe cycle in terrestrial environments. We investigated the Fe mineral transformations and associated Fe isotope fractionation in a soil chronosequence of the Swiss Alps covering 150 years of soil formation on granite. For this purpose, we combined for the first time stable Fe isotope analyses with synchrotron-based Fe-EXAFS spectroscopy, which allowed us to interpret changes in Fe isotopic composition of bulk soils, size fractions, and chemically separated Fe pools over time in terms of weathering processes. Bulk soils and rocks exhibited constant isotopic compositions along the chronosequence, whereas soil Fe pools in grain size fractions spanned a range of 0.4‰ in δ56Fe. The clay fractions (<2 μm), in which newly formed Fe(III)-(hydr)oxides contributed up to 50% of the total Fe, were significantly enriched in light Fe isotopes, whereas the isotopic composition of silt and sand fractions, containing most of the soil Fe, remained in the range described by biotite/chlorite samples and bulk soils. Iron pools separated by a sequential extraction procedure covered a range of 0.8‰ in δ56Fe. For all soils the lightest isotopic composition was observed in a 1 M NH2OH-HCl-25% acetic acid extract, targeting poorly-crystalline Fe(III)-(hydr)oxides, compared with easily leachable Fe in primary phyllosilicates (0.5 M HCl extract) and Fe in residual silicates. The combination of the Fe isotope measurements with the speciation data obtained by Fe-EXAFS spectroscopy permitted to quantitatively relate the different isotope pools forming in the soils to the mineral weathering reactions which have taken place at the field site. A kinetic isotope effect during the Fe detachment from the phyllosilicates was identified as the dominant fractionation mechanism in young weathering environments, controlling not only the light isotope signature of secondary Fe(III)-(hydr)oxides but also significantly contributing to the isotope signature of plants. The present study further revealed that this kinetic fractionation effect can persist over considerable reaction advance during chemical weathering in field systems and is not only an initial transient phenomenon.  相似文献   
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There is a growing interest in the rescue and reuse of data from past studies (so-called legacy data). Data loss is alarming, especially where natural archives are under threat, such as peat deposits. Here we develop a workflow for reuse of legacy radiocarbon dates in peatland studies, including a rigorous quality assessment that can be tailored to specific research questions and study regions. A penalty is assigned to each date based on criteria that consider taphonomic quality (i.e., sample provenance) and dating quality (i.e., sample material and method used). The weights of quality criteria may be adjusted based on the research focus, and resulting confidence levels may be used in further analyses to ensure robustness of conclusions. We apply the proposed approach to a case study of a (former) peat landscape in the Netherlands, aiming to reconstruct the timing of peat initiation spatially. Our search yielded 313 radiocarbon dates from the 1950s to 2019. Based on the quality assessment, the dates—of highly diverse quality—were assigned to four confidence levels. Results indicate that peat initiation for the study area first peaked in the Late Glacial (~14,000 cal years BP), dropped during the Boreal (~9,500 cal years BP) and showed a second peak in the Subboreal (~4,500 cal years BP). We tentatively conclude that the earliest peak was mostly driven by climate (Bølling–Allerød interstadial), whereas the second was probably the result of Holocene sea level rise and related groundwater level rise in combination with climatic conditions (hypsithermal). Our study highlights the potential of legacy data for palaeogeographic reconstructions, as it is cost-efficient and provides access to information no longer available in the field. However, data retrieval may be challenging, and reuse of data requires that basic information on location, elevation, stratigraphy, sample and laboratory analysis are documented irrespective of the original research aims.  相似文献   
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