Rare earth elements as tracers of sediment contamination by phosphogypsum in the Santos estuary,southern Brazil     

Sonia Maria Barros de Oliveira  Paulo Sergio Cardoso da Silva  Barbara Paci Mazzilli  Deborah Ines Teixeira Favaro  Catia Heloisa Saueia 《Applied Geochemistry》2007

In the Cubatão region, southern Brazil, sediments are transported by several rivers from the Serra do Mar Ridge into the Santos estuary. Fertilizer plants have been operating along the margins of one of these rivers (Mogi River) producing a large volume of phosphogypsum, which is stockpiled in nearby areas. Surface sediments of the Mogi River were sampled upstream and downstream in relation to the point where the effluents of the phosphogypsum piles flow into the drainage system. In the vicinity of this point one sediment core was collected. Results show that REE, Ba, Zr and Th concentrations in the non-contaminated sediments are of the same order as those present in the upper continental crust. The contaminated samples present a composition affected by that of the phosphogypsum, marked by a higher concentration of these elements and a stronger degree of REE fractionation. These phosphogypsum characteristics are inherited from the Catalão igneous phosphate ore and were moderately modified by the industrial process of phosphoric acid production. The phosphogypsum signal decreases rapidly downstream, pointing to a limited area of influence of the stacks. The deepest sediments of the core are also free of contamination, representing a time interval prior to the deposition of phosphogypsum wastes on the banks of the estuary.  相似文献   

Hydrologic response of upland catchments to wildfires     

Maria Cristina Rulli  Renzo Rosso 《Advances in water resources》2007

To which extent do wildfires affect runoff production, soil erosion and sediment transport in upland catchments? This transient effect is investigated here by combining data of long term precipitation, sediment yield and wildfire records with a fine resolution spatially distributed modeling approach to flow generation and surface erosion. The model accounts for changes in the structure and properties of soil and vegetation cover by combining the tube-flux approach to topographic watershed partition with a parsimonious parametrization of hydrologic processes. This model is used to predict hydrologic and sediment fluxes for nine small catchments in Saint Gabriel mountains of southern California under control (pre-fire) and altered (post-fire) conditions. Simulation runs using a 45 years record of hourly precipitation show the passage of fire to significantly modify catchment response to storms with a major effect on erosion and flood flows. The probability of occurrence of major floods in the post-fire season is shown to increase up to an order of magnitude under same precipitation conditions. Also, the expected anomaly of sediment yield can increase dramatically the desertification hazard in upland wildfire prone areas. One should further consider the role of firefloods produced by the combined occurrence of wildfires and storms as a fundamental source of non-stationarity in the assessment of hydrologic hazard.  相似文献   

The KS-transformation in hypercomplex form     

Maria Dina Vivarelli 《Celestial Mechanics and Dynamical Astronomy》1983,29(1):45-50

In this note the KS-transformation introduced by Kustaanheimo and Stiefel into Celestial Mechanics is formulated in terms of hypercomplex numbers as the product of a quaternion and its antiinvolute. Therefore it represents a particular morphism of the real algebra of quaternions-having for image a three-dimensional real linear subspace-and also anatural generalization of the Levi-Civita transformation. The quaternion matrix of the product leads to the KS-matrix; the bilinear relation and the two identities which play a central role in the KS-theory are easily derived. A suitable quaternion gauge-transformation is given which leads to the well-known fibration of the four-dimensional space. In addition several geometrical interpretations are brought out.  相似文献   

Secular effects of tidal friction on the planet-satellite systems of the solar system     

Anna Maria Nobili 《Earth, Moon, and Planets》1978,18(2):203-216

We separate the tidal evolution of a planet-satellite system with zero eccentricity in two phases:phase 1—from the formation of the system to satellite's corotation (satellite's corotation means that its spin angular velocity equals the orbital angular velocity);phase 2—after satellite's corotation.We study the planet-satellite system during phase 1 with Darwin's graphical method and obtain an upper limit to satellite'sQ which discloses whether or not it is corotating. Moreover we obtain some qualitative information about the future evolution of the corotating satellites.The present work does not give any new result for the Earth-Moon case and for the Neptune-Triton case.  相似文献   

Polarization and Total Energy Spectra of the Eigenvibrations of the Earth Recorded at Trieste     

Maria Bozzi Zadro  Antonio Marussi 《Geophysical Journal International》1967,12(4):425-436

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Experimentally Determined P-Wave Velocity Anisotropy for Rocks Related to the Western Bohemia Seismoactive Region     

Martínková  Marta  Pros  Zdeněk  Klíma  Karel  Lokajíček  Tomáš  Kotková  Jana 《Studia Geophysica et Geodaetica》2000,44(4):581-589

The elastic properties of granites from Western Bohemia which we measured and published earlier have been supplemented with measurements of olivine nephelinite from the same region and with data on lherzolitic xenolith from the vicinity of elezný Brod. The set of velocities measured under laboratory conditions has been compared with depth profiles suggested for the purpose of locating seismic swarm events which occur in this region. P-wave velocities were measured under pressures of up to 400 MPa. This pressure corresponds to depths of about 15 km for this region. The data were extrapolated for larger depths. Comparing laboratory measurements and seismic profiles, we can conclude that the rocks under study may be constituents of crust structures.  相似文献   

Arsenic incorporation into FeS₂ pyrite and its influence on dissolution: A DFT study   总被引：3，自引：0，他引：3  

Marc Blanchard  Maria Alfredsson  Kate Wright 《Geochimica et cosmochimica acta》2007,71(3):624-630

FeS₂ pyrite can incorporate large amounts of arsenic (up to ca. 10 wt%) and hence has a strong impact on the mobility of this toxic metalloid. Focussing on the lowest arsenic concentrations for which the incorporation occurs in solid solution, the substitution mechanisms involved have been investigated by assuming simple incorporation reactions in both oxidising and reducing conditions. The solution energies were calculated by Density Functional Theory (DFT) calculations and we predict that the formation of AsS dianion groups is the most energetically favourable mechanism. The results also suggest that the presence of arsenic will accelerate the dissolution and thus the generation of acid drainage, when the crystal dissolves in oxidising conditions.  相似文献   

Oxygen isotope ratios of cellulose-derived phenylglucosazone: An improved paleoclimate indicator of environmental water and relative humidity     

Leonel da S.L. Sternberg  Maria C. Pinzon  William T. Anderson  Kristina Beuning 《Geochimica et cosmochimica acta》2007,71(10):2463-2473

Oxygen atoms within fossil wood provide high-resolution records of climate change, particularly for the Quaternary. However, current analysis methods of fossil cellulose do not differentiate between different positions of the oxygen atoms. Here, we propose a refinement to tree-cellulose paleoclimatology modeling, using the cellulose-derived compound phenylglucosazone as the isotopic substrate. Stem samples from trees were collected at northern latitudes as low as 24°37′N and as high as 69°00′N. We extracted stem water and cellulose from each stem sample and analyzed them for their ¹⁸O content. In addition, we derived the cellulose to phenylglucosazone, a compound which lacks the oxygen attached to the second carbon of the cellulose-glucose moieties. Oxygen isotope analysis of phenylglucosazone allowed us to calculate the ¹⁸O content of the oxygen attached to the second carbon of the cellulose-glucose moieties. By way of these analyses, we tested two hypotheses: first, that the ¹⁸O content of the oxygen attached to second carbon will more closely reflect the ¹⁸O content of the stem water, and will not resemble the ¹⁸O content of either cellulose or its derivative phenylglucosazone. Second, tree-ring models that incorporate the variable oxygen isotope fractionation shown here and elsewhere are more accurate than those that do not. Our first hypothesis was rejected on the basis that the oxygen isotope ratios of the oxygen attached to the second carbon of the glucose moieties had a noisy isotopic signal with a large standard deviation and gave the poorest correlation with the oxygen isotope ratios of stem water. Related to this isotopic noise, we observed that the correlation between oxygen isotope ratios of phenylglucosazone with both stem water and relative humidity were higher than those observed for cellulose. Our hypothesis about tree-ring models which account for changes in the oxygen isotopic fractionation during cellulose synthesis was consistent only for the ¹⁸O content of phenylglucosazone. We showed that the tree-ring model based on the ¹⁸O content of phenylglucosazone was an improvement over existing models that are based on whole cellulose. Additionally, this approach may be used in other cellulose based archives such as peat deposits and lacustrine sediments.  相似文献   

The surface energy balance and the mixing height in urban areas—activities and recommendations of COST-Action 715     

Martin Piringer  Sylvain Joffre  Alexander Baklanov  Andreas Christen  Marco Deserti  Koen De Ridder  Stefan Emeis  Patrice Mestayer  Maria Tombrou  Douglas Middleton  Kathrin Baumann-Stanzer  Aggeliki Dandou  Ari Karppinen  Jerzy Burzynski 《Boundary-Layer Meteorology》2007,124(1):3-24

The specific problems of determining and simulating the surface energy balance (SEB) and the mixing height (MH) over urban areas are examined. The SEB and MH are critical components of algorithms and numerical models for the urban boundary layer, though the constituent parts of the SEB and the MH are not routinely measured by national weather services. Parameterisations are thus needed in applications. In this investigation, several recently developed algorithms and models for estimating the SEB and MH were applied to new datasets and assessed. Results are discussed in terms of the need for spatial resolution and the parameters needed to describe the urban atmosphere. Limitations of models are identified and recommendations for further development and observations are given. Having identified gaps in knowledge, key findings from new urban experiments and numerical modelling for the SEB and MH are given. The diurnal cycle for the SEB is significantly different from rural conditions—urban heat storage is needed in urban parameterisations. The urban MH is increased over the rural MH, as shown by several numerical schemes and careful sodar analyses. This work has been carried out within the COST-715 Action “Meteorology applied to urban air pollution problems (1998–2004). COST 715 reached a consensus proposing representatively sited measurements of meteorological parameters and turbulent fluxes above roof-tops, and recognised that such data are needed to improve numerical models of the urban surface processes.  相似文献   

Coastal risk forecast system     

André Sabino  Pedro Poseiro  Armanda Rodrigues  Maria Teresa Reis  Conceição J. Fortes  Rui Reis  João Araújo 《Journal of Geographical Systems》2018,20(2):159-184

The run-up and overtopping by sea waves are two of the main processes that threaten coastal structures, leading to flooding, destruction of both property and the environment, and harm to people. To build early warning systems, the consequences and associated risks in the affected areas must be evaluated. It is also important to understand how these two types of spatial information integrate with sensor data sources and the risk assessment methodology. This paper describes the relationship between consequences and risk maps, their role in risk management and how the HIDRALERTA system integrates both aspects in its risk methodology. It describes a case study for Praia da Vitória Port, Terceira Island, Azores, Portugal, showing that the main innovations in this system are twofold: it represents the overtopping flow and consequent flooding, which are critical for coastal and port areas protected by maritime structures, and it works also as a risk assessment tool, extremely important for long-term planning and decision-making. Moreover, the implementation of the system considers possible known variability issues, enabling changes in its behaviour as needs arise. This system has the potential to become a useful tool for the management of coastal and port areas, due to its capacity to effectively issue warnings and assess risks.  相似文献