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Rate constants for the gas-phase reactions of OH radicals, NO3 radicals and O3 with the C7-carbonyl compounds 4-methylenehex-5-enal [CH2=CHC(=CH2)CH2CH2CHO], (3Z)- and (3E)-4-methylhexa-3,5-dienal [CH2=CHC(CH3)=CHCH2CHO] and 4-methylcyclohex-3-en-1-one, which are products of the atmospheric degradations of myrcene, Z- and E-ocimene and terpinolene, respectively, have been measured at 296 ± 2 K and atmospheric pressure of air using relative rate methods. The rate constants obtained (in cm3 molecule–1 s–1 units) were: for 4-methylenehex-5-enal, (1.55 ± 0.15) × 10–10, (4.75 ± 0.35) × 10–13 and (1.46 ± 0.12) × 10–17 for the OH radical, NO3 radical and O3 reactions, respectively; for (3Z)-4-methylhexa-3,5-dienal: (1.61 ± 0.35) × 10–10, (2.17 ± 0.30) × 10–12, and (4.13 ± 0.81) × 10–17 for the OH radical, NO3 radical and O3 reactions, respectively; for (3E)-4-methylhexa-3,5-dienal: (2.52 ± 0.65) × 10–10, (1.75 ± 0.27) × 10–12, and (5.36 ± 0.28) × 10–17 for the OH radical, NO3 radical and O3 reactions, respectively; and for 4-methylcyclohex-3-en-1-one: (1.10 ± 0.19) × 10–10, (1.81 ± 0.35) × 10–12, and (6.98 ± 0.40) × 10–17 for the OH radical, NO3 radical and O3 reactions, respectively. These carbonyl compounds are all reactive in the troposphere, with daytime reaction with the OH radical and nighttime reaction with the NO3 radical being predicted to dominate as loss processes and with estimated lifetimes of about an hour or less.  相似文献   
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Lithology, pollen, macrofossils, and stable carbon isotopes from an intermontane basin bog site in southern New Zealand provide a detailed late-glacial and early Holocene vegetation and climate record. Glacial retreat occurred before 17,000 cal yr B.P., and tundra-like grassland–shrubland occupied the basin shortly after. Between 16,500 and 14,600 cal yr B.P., a minor regional expansion of forest patches occurred in response to warming, but the basin remained in shrubland. Forest retreated between 14,600 and 13,600 cal yr B.P., at about the time of the Antarctic Cold Reversal. At 13,600 cal yr B.P., a steady progression from shrubland to tall podocarp forest began as the climate ameliorated. Tall, temperate podocarp trees replaced stress-tolerant shrubs and trees between 12,800 and 11,300 cal yr B.P., indicating sustained warming during the Younger Dryas Chronozone (YDC). Stable isotopes suggest increasing atmospheric humidity from 11,800 to 9300 cal yr B.P. Mild (annual temperatures at least 1°C higher than present), and moist conditions prevailed from 11,000 to 10,350 cal yr B.P. Cooler, more variable conditions followed, and podocarp forest was completely replaced by montane Nothofagus forest at around 7500 cal yr B.P. with the onset of the modern climate regime. The Cass Basin late-glacial climate record closely matches the Antarctic ice core records and is in approximate antiphase with the North Atlantic.  相似文献   
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A model to simulate channel changes in ephemeral river channels and to test the effects of hydrological changes due to climate change and[sol ]or land use change was developed under the auspices of the EU funded MEDALUS programme (Mediterranean Desertification and Land Use). The model, CHANGISM (Channel Change GIS Simulation Model), is designed to simulate the effect of channel flow events and of climate conditions on morphology, sediment and vegetation, through sequences of events and conditions, over periods of up to several decades. The modelling is based on cellular automata but with calculations for water and sediment continuity. Process rules have both deterministic and stochastic elements. An important feature of the model is that it incorporates feedback elements between each event. The main aim of the model is to indicate the likely outcomes of events and combinations of conditions. It is linked to GIS for both input and output. The modelling is based on a channel reach and state is input as GIS layers of morphology (DEM), sediment and vegetation cover and state. Other initial conditions of soil moisture, groundwater level, and overall gradient are input. Parameters for processes are read from tables and can be easily changed for successive runs of the model. The bases for decisions on process specifications are discussed in this paper. Initial tests of the operation and sensitivity of the model were made on idealized reaches. The model was then tested using data from monitored sites in SE Spain. Simulations using clearwater flow worked well but initial simulations using events with sediment loads showed some tendency for excess deposition. Further tests and modifications are taking place. Overall, the model is one of the most sophisticated that simulates the interaction of flows with sediment and vegetation and the outcomes in terms of erosion, deposition, morphology, sediment cover, vegetation cover and plant survival over periods of up to 30 years for the scale of a channel reach. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
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The articles that comprise this critical review serve to draw attention to research papers published in specific fields of interest during 2003, provide critical comment on the relevance and importance of individual publications in these fields, and offer an overview of the comparative importance of advances in particular areas. In this way, these articles aim to assist experts in the field by keeping them informed of relevant recent publications, as well as providing an important resource for students or early career researchers who are embarking on studies in an area new to them. This year, five papers provide summaries of developments in bulk sample determinations employing (1) ICP-AES and ICP-MS (trace elements), (2) XRF and atomic absorption spectrometry and INAA, (3) isotope ratio measurements (TIMS, MC-ICP-MS, ICP-MS, ToF), as well as in situ measurements conducted using (4) secondary ion mass spectrometry and (5) laser ablation ICP-MS (trace element and isotope ratio determinations).  相似文献   
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非洲中东部地区的经济主要依靠自给农业支撑,该地区农业经济对降水的变化尤为敏感.本文以卢旺达为例,观测分析指出卢旺达的次季节降雨主要集中在10-25天;根据次季节尺度降水变率的单点相关方法,发现卢旺达的次季节降水变率和周围区域变化一致;进一步合成结果显示该地区次季节降水变率与异常西风有关,这可追溯到赤道地区西传的赤道Rossby波.最后,本文评估了当前动力模式ECMWF对 卢旺达地区(即非洲中东部)次季节降水变率的预报能力,发现EC模式在对该区域降水和相关风场指数的预报技巧都在18天左右,且预报技巧表现出一定的年际差异,这可能与热带太平洋的背景海温信号有关.该工作增进了当 前对非洲中东部地区的次季节降水变率和预测水平的认知,并且对该地区国家粮食安全和防灾减灾具有启示性意义.  相似文献   
20.
A new digital map of glacial geomorphic features and interpreted glacial landsystems was produced for an area covering ~415 000 km2 in the Keewatin Sector of the Laurentide Ice Sheet (LIS) in Nunavut. The map integrates information from previous surficial geology maps and >14 000 field stations, and is significantly improved by the detailed inventory of ~152 000 glacigenic features using high-resolution ArcticDEM data and Landsat 8 imagery. From this, we identify and map coherent patterns of landform development (landsystems) between the Manitoba border and the Arctic coast, many of which are entirely new and others that are significantly modified or updated. In particular, we recognize six separate ice streams, including one probable remnant ice stream, and we delineate numerous palimpsest streamlined landscapes with associated ice-flow trends and relative ages. A continuum of relict terrains with varying basal ice thermal conditions is mapped for the first time in the ice divide migration zone between Baker Lake and Wager Bay. In addition, deglacial cold-based retreat terrains and preserved warm-based landscapes unaffected by younger glacial events have been identified. These new georeferenced, multi-scale data sets and interpreted glacial landsystems provide a comprehensive framework to strengthen reconstructions of the glacial history and dynamics of one of the largest ice domes of the LIS, identify distinct glacial sediment transport paths for applications to mineral exploration, and test numerical modelling of the LIS in support of climate change studies and long-term evolution of modern ice sheets.  相似文献   
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