Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans in sediments from Hong Kong   总被引：4，自引：0，他引：4  

Müller JF  Gaus C  Prange JA  Päpke O  Poon KF  Lam MH  Lam PK 《Marine pollution bulletin》2002,45(1-12):372-378

Concentrations of 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were determined in 14 sediment samples collected from four sites in the Mai Po Marshes Nature Reserve (within a RAMSAR Site) and from another six sites in Victoria Harbour and along the Hong Kong coastline. Elevated levels of PCDDs, and particularly OCDD, were detectable in all samples collected from the Mai Po Marshes and five of the six sites. In contrast to PCDDs, PCDFs were mainly found in sediment samples collected from industrial areas (Kwun Tong and To Kwa Wan) in Victoria Harbour. PCDD/F levels and congener profiles in the samples from the Mai Po Marshes Nature Reserve in particular show strong similarities to those reported in studies which have attributed similar elevated PCDD concentrations to nonanthropogenic PCDD sources.  相似文献   

Efficient satellite orbit modelling using pseudo-stochastic parameters     

G. Beutler  A. Jäggi  U. Hugentobler  L. Mervart 《Journal of Geodesy》2006,80(7):353-372

If the force field acting on an artificial Earth satellite is not known a priori with sufficient accuracy to represent its observations on their accuracy level, one may introduce so-called pseudo-stochastic parameters into an orbit determination process, e.g. instantaneous velocity changes at user-defined epochs or piecewise constant accelerations in user-defined adjacent time subintervals or piecewise linear and continuous accelerations in adjacent time subintervals. The procedures, based on standard least-squares, associated with such parameterizations are well established, but they become inefficient (slow) if the number of pseudo-stochastic parameters becomes large. We develop two efficient methods to solve the orbit determination problem in the presence of pseudo-stochastic parameters. The results of the methods are identical to those obtained with conventional least-squares algorithms. The first efficient algorithm also provides the full variance–covariance matrix; the second, even more efficient algorithm, only parts of it.  相似文献   

Parameterization of Ozone Photolysis Frequency in the Lower Troposphere Using Data from Photodiode Array Detector Spectrometers     

Evelyn Jäkel  Manfred Wendisch  Barry L. Lefer 《Journal of Atmospheric Chemistry》2006,54(1):67-87

Spectroradiometers using photodiode array detectors (PDAs) are increasingly applied for airborne and ground-based atmospheric measurements of spectral actinic flux densities due to their high time resolution (less than one second). However they have limited sensitivity of ultraviolet (UV) radiation for wavelengths less than about 305 nm. This results in uncertainties of ozone photolysis frequencies derived from spectral actinic flux density measurements using PDA spectrometers. To overcome this limitation a parameterization method is introduced which extrapolates the data towards the wavelength range of limited sensitivity of the PDA spectrometers (less than about 305 nm). The parameterization is based on radiative transfer simulations and is valid for measurements in the lower troposphere. The components of the suggested parameterization are the lower threshold wavelength of the PDA spectrometer, the slant ozone column (ratio of the total ozone column and the cosine of the solar zenith angle), and the ambient temperature. Tests of the parameterization with simulated actinic flux density spectra have revealed an uncertainty of the derived ozone photolysis frequency of ±5%. Field comparisons of the parameterization results with independent measurements of the ozone photolysis frequency were within ±10% for solar zenith angles less than 70^∘. Finally the parameterization was applied to airborne measurements to emphasize the advantage of high time resolution of PDA spectrometers to study ozone photolysis frequency fields in inhomogeneous cloud condtitions.  相似文献   

Towards urbanisation of the non-hydrostatic numerical weather prediction model Lokalmodell (LM)     

Lina Neunhäuserer  Barbara Fay  Matthias Raschendorfer 《Boundary-Layer Meteorology》2007,124(1):81-97

Numerical weather prediction models are increasingly employed for providing meteorological data for urban air quality applications. Model resolution, physiographic parameters and surface-layer parameterisations need to be adapted to the requirements of the urban boundary layer. The Lokalmodell of the German Weather Service was triple-nested down to a horizontal grid resolution of 1.1 km, urbanised physiographic parameters were implemented, and an additional anthropogenic heat source was introduced. Results of a sensitivity study for a spring dust episode in Helsinki show a clear urbanisation effect of these measures on temperature, humidity and the partitioning of surface fluxes, leading to an increased Bowen ratio and heat storage and an urban heat island effect.  相似文献   

Comparing field and laboratory breakdown rates of coarse particulate organic matter: Sediment dynamics mask the impacts of dissolved nutrients on CPOM mass loss in streams     

Bernd Spänhoff  Clemens Augspurger  Kirsten Küsel 《Aquatic Sciences - Research Across Boundaries》2007,69(4):495-502

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Micrometeorological Observations of a Microburst in Southern Finland     

Leena Järvi  Ari-Juhani Punkka  David M. Schultz  Tuukka Petäjä  Harri Hohti  Janne Rinne  Toivo Pohja  Markku Kulmala  Pertti Hari  Timo Vesala 《Boundary-Layer Meteorology》2007,125(2):343-359

On the afternoon of 3 July 2004 in Hyytiälä (Juupajoki, Finland), convective cells produced a strong downburst causing forest damage. The SMEAR II field station, situated near the damage site, enabled a unique micrometeorological analysis of a microburst with differences above and inside the canopy. At the time of the event, a squall line associated with a cold front was crossing Hyytiälä with a reflectivity maximum in the middle of the squall line. A bow echo, rear-inflow notch, and probable mesovortex were observed in radar data. The bow echo moved west-north-west, and its apex travelled just north of Hyytiälä. The turbulence data were analysed at two locations above the forest canopy and at one location at sub-canopy. At 1412 EET (Eastern European Time, UTC+2), the horizontal and vertical wind speed increased and the wind veered, reflecting the arrival of a gust front. At the same time, the carbon dioxide concentration increased due to turbulent mixing, the temperature decreased due to cold air flow from aloft and aerosol particle concentration decreased due to rain scavenging. An increase in the number concentration of ultra-fine particles (< 10 nm) was detected, supporting the new particle formation either from cloud outflow or due to rain. Five minutes after the gust front (1417 EET), strong horizontal and downward vertical wind speed gusts occurred with maxima of 22 and 15 m s^?1, respectively, reflecting the microburst. The turbulence spectra before, during and after the event were consistent with traditional turbulence spectral theory.  相似文献   

Determination of post-glacial land uplift from the three precise levellings in Finland     

J. Mäkinen  V. Saaranen 《Journal of Geodesy》1998,72(9):516-529

We have calculated vertical velocities and their change in time from three precise levellings in Finland, with central epochs 1902, 1946, and 1986. Models with and without simultaneous determination of heights give the same results for velocities. Evidence for velocity change in time appears at first sight strong but on closer examination turns out to be inconclusive. We offer an alternative explanation in terms of levelling errors and estimate them. A new uplift map closely reproduces main features of earlier maps from partial data, but does not support some details in them. Received: 27 January 1997/ Accepted: 20 April 1998  相似文献   

The exceptional Oder flood in summer 1997 — distribution patterns of the oder discharge in the Pomeranian Bight     

Herbert Siegel  Wolfgang Matthäus  Regina Bruhn  Monika Gerth  Günther Nausch  Thomas Neumann  Christa Pohl 《Ocean Dynamics》1998,50(2-3):145-167

The exceptional Oder flood in summer 1997 was a unique event in order to investigate the impacts on and the consequences for the ecosystem of the Baltic Sea of about 6.5 km³ additional water loaded with nutrients and contaminants and discharged within only 5 weeks. About 15 institutions participated in this investigation in both the Szczecin Lagoon and the Pomeranian Bight. The Baltic Sea Research Institute Warnemünde studied the water and nutrient inflow, the spreading of the Oder discharge, and the impact of the discharge on the ecosystem. The main topic of the presented investigations is a detailed study of the spatial and temporal spreading of the extreme river discharge in the Pomeranian Bight and the southern Baltic Sea by satellite data, ship observations and continuous buoy measurements as well as numerical modelling. The meteorological conditions were characterized by mainly easterly winds which guided the outflowing riverine water along the German coast into the Arkona Sea. The spatial and temporal development of the distribution patterns of the Oder discharge was monitored by about 80 Sea Surface Temperature (SST) images of NOAA satellites. Shipborne measurements showed that the vertical extent of the Oder plume ranged between 5 and 7 metres. The concentrations of inorganic nutrients, except higher silicate, were comparable to typical winter/early spring values (seasonal maximum) in this region. The high dilution effect of the flood water reduced the concentration of contaminants and thus, prevented a direct negative impact of trace metals and chlorinated organic compounds on the marine environment. Coupled physical-biochemical modelling in combination with SST-images demonstrated the temporal development and satellite data in the visible spectral range delivered the maximum extent of discharged river water into the southern Arkona Sea where a further western transport was limited by the upwelling region off Hiddensee. Thus, all detected effects of the Oder flood were confined to the Pomeranian Bight and the southern Arkona Sea, without long-term consequences for the ecosystem.  相似文献   

The baltic sea in 1997-impacts of the extremely warm summer and of the exceptional oder flood     

Wolfgang Matthäus  Günther Nausch  Hans Ulrich Lass  Klaus Nagel  Herbert Siegel 《Ocean Dynamics》1998,50(1):47-69

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Recombination rates of small ions and their attachment to aerosol particles     

W. Gringel  K. H. Käselau  R. Mühleisen 《Pure and Applied Geophysics》1978,116(6):1101-1113

It could be shown by measurements of the air conductivity and using a mean profile for the ionization rate that experimental and theoretical values of the recombination rate of small ions based on a three body recombination process (Thomson) are in very good agreement up to 20 km altitude. The divergency of the experimental and theoretical curves above 20 km can be interpreted by assuming that there exists in this altitude region a crossover from the three body recombination to a two body recombination process. The value of the recombination coefficient is about 4·10^–7 cm³ s^–1 in 25 km altitude, compared with 1.4·10^–6 cm³ s^–1 at ground level. Furtheron it was possible for the first time to get some experimental data of attachment coefficients up to 13 km from simultaneous measurements of the air conductivity and Aitken nuclei concentration. These values are in good agreement with those obtained by theoretical considerations.  相似文献