The formation and alteration of the Renazzo-like carbonaceous chondrites I: Implications of bulk-oxygen isotopic composition     

Devin L. Schrader  Ian A. Franchi  Richard C. Greenwood  Jenny M. Gibson 《Geochimica et cosmochimica acta》2011,75(1):308-325

To better understand the role of aqueous alteration on the CR chondrite parent asteroid, a whole-rock oxygen isotopic study of 20 meteorites classified as Renazzo-like carbonaceous chondrites (CR) was conducted. The CR chondrites analyzed for their oxygen isotopes were Dhofar 1432, Elephant Moraine (EET) 87770, EET 92042, EET 96259, Gao-Guenie (b), Graves Nunataks (GRA) 95229, GRA 06100, Grosvenor Mountains (GRO) 95577, GRO 03116, LaPaz Ice Field (LAP) 02342, LAP 04720, Meteorite Hills (MET) 00426, North West Africa (NWA) 801, Pecora Escarpment (PCA) 91082, Queen Alexandra Range (QUE) 94603, QUE 99177, and Yamato-793495 (Y-793495). Three of the meteorites, Asuka-881595 (A-881595), GRA 98025, and MET 01017, were found not to be CR chondrites. The remaining samples concur petrographically and with the well-established oxygen-isotope mixing line for the CR chondrites. Their position along this mixing line is controlled both by the primary oxygen-isotopic composition of their individual components and their relative degree of aqueous alteration. Combined with literature data and that of this study, we recommend the slope for the CR-mixing line to be 0.70 ± 0.04 (2σ), with a δ¹⁷O-intercept of −2.23 ± 0.14 (2σ).Thin sections of Al Rais, Shi?r 033, Renazzo, and all but 3 samples analyzed for oxygen isotopes were studied petrographically. The abundance of individual components is heterogeneous among the CR chondrites, but FeO-poor chondrules and matrix are the most abundant constituents and therefore, dominate the whole-rock isotopic composition. The potential accreted ice abundance, physico-chemical conditions of aqueous alteration (e.g. temperature and composition of the fluid) and its duration control the degree of alteration of individual CR chondrites. Combined with literature data, we suggest that LAP 02342 was exposed to lower temperature fluid during alteration than GRA 95229. With only two falls, terrestrial alteration of the CR chondrites complicates the interpretation of their whole rock isotopic composition, particularly in the most aqueously altered samples, and those with relatively higher matrix abundances. We report that QUE 99177 is the isotopically lightest whole rock CR chondrite known (δ¹⁸O = −2.29‰, δ¹⁷O = −4.08‰), possibly due to isotopically light unaltered matrix; which shows that the anhydrous component of the CR chondrites is isotopically lighter than previously thought. Although it experienced aqueous alteration, QUE 99177 provides the best approximation of the pristine CR-chondrite parent body’s oxygen-isotopic composition, before aqueous alteration took place. Using this value as a new upper limit on the anhydrous component of the CR chondrites, water/rock ratios were recalculated and found to be higher than previously thought; ratios now range from 0.281 to 1.157. We also find that, according to their oxygen isotopes, a large number of CR chondrites appear to be minimally aqueously altered; although sample heterogeneity complicates this interpretation.  相似文献   

Chironomid assemblages in cores from multiple water depths reflect oxygen-driven changes in a deep French lake over the last 150 years     

Victor Frossard  Laurent Millet  Valérie Verneaux  Jean-Philippe Jenny  Fabien Arnaud  Michel Magny  Jérôme Poulenard  Marie-Elodie Perga 《Journal of Paleolimnology》2013,50(3):257-273

We sampled modern chironomids at multiple water depths in Lake Annecy, France, before reconstructing changes in chironomid assemblages at sub-decadal resolution in sediment cores spanning the last 150 years. The lake is a large, deep (z_max = 65 m), subalpine waterbody that has recently returned to an oligotrophic state. Comparison between the water-depth distributions of living chironomid larvae and subfossil head capsules (HC) along three surface-sediment transects indicated spatial differences in the influence of external forcings on HC deposition (e.g. tributary effects). The transect with the lowest littoral influence and the best-preserved, depth-specific chironomid community characteristics was used for paleolimnological reconstructions at various water depths. At the beginning of the twentieth century, oxygen-rich conditions prevailed in the lake, as inferred from M. contracta-type and Procladius sp. at deep-water sites (i.e. cores from 56 to 65 m) and Paracladius sp. and H. grimshawi-type in the core from 30 m depth. Over time, chironomid assemblages in cores from all three water depths converged toward the dominance of S. coracina-type, indicating enhanced hypoxia. The initial change in chironomid assemblages from the deep-water cores occurred in the 1930s, at the same time that an increase in lake trophic state is inferred from an increase in total organic carbon (TOC) concentration in the sediment. In the 1950s, an assemblage change in the core from 30 m water depth reflects the rapid expansion of the hypoxic layer into the shallower region of the lake. Lake Annecy recovered its oligotrophic state in the 1990s. Chironomid assemblages, however, still indicate hypoxic conditions, suggesting that modern chironomid assemblages in Lake Annecy are decoupled from the lake trophic state. Recent increases in both TOC and the hydrogen index indicate that changes in pelagic functioning have had a strong indirect influence on the composition of the chironomid assemblage. Finally, the dramatic decrease in HC accumulation rate over time suggests that hypoxic conditions are maintained through a feedback loop, wherein the accumulation of (un-consumed) organic matter and subsequent bacterial respiration prevent chironomid re-colonization. We recommend study of sediment cores from multiple water depths, as opposed to investigation of only a single core from the deepest part of the lake, to assess the details of past ecological changes in large deep lakes.  相似文献   

Graphical design of world map projections     

Bernhard Jenny  Tom Patterson  Lorenz Hurni 《International journal of geographical information science》2013,27(11):1687-1702

The design of new map projections has up until now required mathematical and cartographic expertise that has limited this activity to a small group of specialists. This article introduces the background mathematics for a software-based method that enables cartographers to easily design new small-scale world map projections. The software is usable even by those without mathematical expertise. A new projection is designed interactively in an iterative process that allows the designer to graphically and numerically assess the graticule, the representation of the continents, and the distortion properties of the new projection. The method has been implemented in Flex Projector, a free and open-source application enabling users to quickly create new map projections and modify existing projections. We also introduce new tools that help evaluate the distortion properties of projections, namely a configurable acceptance index to assess areal and angular distortion, a derived acceptance visualization, and interactive profiles through the distortion space of a projection. To illustrate the proposed method, a new projection, the Cropped Ginzburg VIII projection, is presented.  相似文献   

The Southern Westerlies in Central Chile: Holocene precipitation estimates based on a water balance model for Laguna Aculeo (33°50′S)     

B. Jenny  D. Wilhelm  B. Valero-Garcés 《Climate Dynamics》2003,20(2-3):269-280

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United Kingdom ports policy: Changing government attitudes     

S.J. Pettit   《Marine Policy》2008,32(4):719-727

The United Kingdom ports industry has been at the forefront of international trade and, therefore, cargo movement since the industrial revolution. Its contribution to the wider economy is still pivotal, handling the majority of the UK's trade. At this point in time, particularly with the government in the process of reviewing the future of its policy for the ports industry through it Ports Policy Review, it is pertinent to assess the forces, which are both driving port development and seeking to restrain unfettered growth. This paper, therefore considers the role of government and how it has shaped, and is continuing to shape, the UK ports industry.  相似文献   

Value of information analysis in rock engineering: a case study of a tunnel project in Äspö Hard Rock Laboratory     

Miriam S. Zetterlund  Tommy Norberg  Lars O. Ericsson  Jenny Norrman  Lars Rosén 《Georisk: Assessment and Management of Risk for Engineered Systems and Geohazards》2015,9(1):9-24

Geoengineering prognoses are often based on data from a limited number of investigations of soil and rock mass. There is generally a desire to reduce the uncertainty in the prognoses while minimising the investigation costs. Value of Information Analysis (VOIA) is a support for decisions regarding investigation strategies and the aim of this paper is to present methodology for VOIA that takes into account four decision alternatives where the input data could be provided by experts. The methodology will be applied in a case study where the value of information related to an investigation borehole will be calculated. The results indicate that the value of information of the borehole is low compared with the realisation costs of the investigation. It was found that models for VOIA in underground construction projects are complex but that the analysis can be simplified with extensive use of expert knowledge and calculations of the value of perfect information as a benchmark for investigation strategies.  相似文献   

A Model-Averaging Method for Assessing Groundwater Conceptual Model Uncertainty     

Ming Ye  Karl F. Pohlmann  Jenny B. Chapman  Greg M. Pohll  Donald M. Reeves 《Ground water》2010,48(5):716-728

This study evaluates alternative groundwater models with different recharge and geologic components at the northern Yucca Flat area of the Death Valley Regional Flow System (DVRFS), USA. Recharge over the DVRFS has been estimated using five methods, and five geological interpretations are available at the northern Yucca Flat area. Combining the recharge and geological components together with additional modeling components that represent other hydrogeological conditions yields a total of 25 groundwater flow models. As all the models are plausible given available data and information, evaluating model uncertainty becomes inevitable. On the other hand, hydraulic parameters (e.g., hydraulic conductivity) are uncertain in each model, giving rise to parametric uncertainty. Propagation of the uncertainty in the models and model parameters through groundwater modeling causes predictive uncertainty in model predictions (e.g., hydraulic head and flow). Parametric uncertainty within each model is assessed using Monte Carlo simulation, and model uncertainty is evaluated using the model averaging method. Two model-averaging techniques (on the basis of information criteria and GLUE) are discussed. This study shows that contribution of model uncertainty to predictive uncertainty is significantly larger than that of parametric uncertainty. For the recharge and geological components, uncertainty in the geological interpretations has more significant effect on model predictions than uncertainty in the recharge estimates. In addition, weighted residuals vary more for the different geological models than for different recharge models. Most of the calibrated observations are not important for discriminating between the alternative models, because their weighted residuals vary only slightly from one model to another.  相似文献   

Shifting challenges for British maritime policy: A post-war review     

B.M. Gardner  S.J. Pettit  H.A. Thanopoulou 《Marine Policy》1996,20(6):517-524

Although Britain may no longer “rule the waves” in terms of national fleet presence, London still maintains its supremacy as the world's leading maritime centre. However, with the decline of the fleet there has been an inevitable decline in the maritime skills-base and a loss of shipping expertise. The authors review half a century of government maritime policy measures and of recurrent challenges confronted with varying degrees of success, and identify the current period as critical for the future of London as a maritime centre and as a crossroads in British maritime policy.  相似文献   

Groundwater monitoring for cement kiln dust disposal units in karst aquifers     

Wanfang Zhou  Barry F. Beck  Jie Wang  Arthur J. Pettit 《Environmental Geology》2007,52(4):761-777

Well-developed karst aquifers tend to be heterogeneous and consist of variable porosities. Groundwater monitoring and the associated data interpretations in such aquifers are often more complicated than porous medium aquifers. Collection of representative data in karst aquifers often requires monitoring at appropriately located wells and/or springs that are proven to connect to the groundwater system. Water samples are to be collected under different flow conditions, including base flow, high-flow, and low-flow. The sampling frequencies may vary from several months for base flows to minutes in response to recharge events. The groundwater monitoring program presented in this paper is for a cement kiln dust mono-fill site in a karst area of southern Indiana. Following dye tracing and extensive geophysical investigations, one spring was selected as a monitoring location. A second spring should be used as a monitoring location when the last cell of the mono-fill begins receiving the wastes. The paper discusses results from the first spring, at which nine background sampling events were completed to evaluate the natural variations of the water quality. Based on the background data, a statistical evaluation plan was developed for 12 water-quality parameters to determine the integrity of the landfill. The statistical power of the statistical analyses was evaluated by Monte Carlo simulations.  相似文献   

The last 7500 cal yr B.P. of westerly rainfall in Central Chile inferred from a high-resolution pollen record from Laguna Aculeo (34°S)     

Rodrigo Villa-Martínez  Carolina Villagrn  Bettina Jenny 《Quaternary Research》2003,60(3):284-293

We report multiproxy analyses of a sediment core obtained from Laguna Aculeo that spans the past 7500 years. Laguna Aculeo (33°50′S, 70°55′W) is one of the few natural inland lakes located in the Mediterranean zone of Central Chile, near the northern margin of the influence of the southern westerlies. The record shows elevated pollen counts of halophytes and seasonally drying of the lake basin prior to 5700 cal yr B.P., indicating severe aridity and warmer-than-present conditions. This was followed by the establishment of a fresh-water lake, along with an increase in arboreal and herbaceous plant diversity between 5700 and 3200 cal yr B.P. An intensification of this trend started at 3200 cal yr B.P., along with the abrupt decrease of halophytes until 100 cal yr B.P. Within this humid period, pollen accumulation rates show large-amplitude fluctuations, coeval with numerous turbidite layers, suggesting a highly variable and torrential rainfall pattern. This intense and variable precipitation regime is probably associated with the El Niño–Southern Oscillation (ENSO) phenomenon. We suggest that the modern Mediterranean climate of Central Chile was established at 3200 cal yr B.P. Paleovegetation and paleolimnological changes starting at 100 cal yr B.P. correlate with documented human activity surrounding the lake.  相似文献