Thermodynamic characterization of boltwoodite and uranophane: Enthalpy of formation and aqueous solubility     

Tatiana Y. Shvareva  Drew Gorman-Lewis  Peter C. Burns  Jeremy B. Fein 《Geochimica et cosmochimica acta》2011,75(18):5269-5282

Boltwoodite and uranophane are uranyl silicates common in oxidized zones of uranium ore deposits. An understanding of processes that impact uranium transport in the environment, especially pertaining to the distribution of uranium between solid phases and aqueous solutions, ultimately requires determination of thermodynamic parameters for such crystalline materials. We measured formation enthalpies of synthetic boltwoodites, K(UO₂)(HSiO₄)·H₂O and Na(UO₂)(HSiO₄)·H₂O, and uranophane, Ca(UO₂)₂(HSiO₄)₂·5H₂O, by high temperature oxide melt solution calorimetry. We also studied the aqueous solubility of these phases from both saturated and undersaturated conditions at a variety of pH. The combined data permit the determination of standard enthalpies, entropies and Gibbs free energies of formation for each phase and analysis of its potential geological impact from a thermodynamic point of view.  相似文献   

The domestic divide: Access to the Internet in New Zealand     

Jeremy Greenbrook‐Held  Philip S. Morrison 《New Zealand geographer》2011,67(1):25-38

We use unit records of the 2006 census to show that access to the Internet in the home varies geographically in New Zealand primarily as a result of demographic and socio‐economic differences among individuals. Of particular significance is the much lower rates of domestic access experienced by Māori and Pacific Island individuals even after controlling for differences in their age, gender, education, income, occupation and settlement type. While differences in Internet access by ethnicity has been noted before, it is the magnitude and persistence of this difference in New Zealand after controlling for correlated factors that renders this study unique. Our results have important implications in an education environment increasingly reliant on Web access, but they also raise questions about the extent of access to the Internet outside the home.  相似文献   

An empirical model of subcritical bedform migration     

Chan‐Yi Martin Lin  Jeremy G. Venditti 《Sedimentology》2013,60(7):1786-1799

The ability to predict bedform migration in rivers is critical for estimating bed material load, yet there is no relation for predicting bedform migration (downstream translation) that covers the full range of conditions under which subcritical bedforms develop. Here, the relation between bedform migration rates and transport stage is explored using a field and several flume data sets. Transport stage is defined as the non‐dimensional Shields stress divided by its value at the threshold for sediment entrainment. Statistically significant positive correlations between both ripple and dune migration rates and transport stage are found. Stratification of the data by the flow depth to grain‐size ratio improved the amount of variability in migration rates that was explained by transport stage to ca 70%. As transport stage increases for a given depth to grain‐size ratio, migration rates increase. For a given transport stage, the migration rate increases as the flow depth to grain‐size ratio gets smaller. In coarser sediment, bedforms move faster than in finer sediment at the same transport stage. Normalization of dune migration rates by the settling velocity of bed sediment partially collapses the data. Given the large amount of variability that arises from combining data sets from different sources, using different equipment, the partial collapse is remarkable and warrants further testing in the laboratory and field.  相似文献   

It starts at home? Climate policies targeting household consumption and behavioral decisions are key to low-carbon futures     

Ghislain Dubois  Benjamin Sovacool  Carlo Aall  Maria Nilsson  Carine Barbier  Alina Herrmann  Sébastien Bruyère  Camilla Andersson  Bore Skold  Franck Nadaud  Florian Dorner  Karen Richardsen Moberg  Jean Paul Ceron  Helen Fischer  Dorothee Amelung  Marta Baltruszewicz  Jeremy Fischer  Françoise Benevise  Rainer Sauerborn 《Chemie der Erde / Geochemistry》2013

Through their consumption behavior, households are responsible for 72% of global greenhouse gas emissions. Thus, they are key actors in reaching the 1.5 °C goal under the Paris Agreement. However, the possible contribution and position of households in climate policies is neither well understood, nor do households receive sufficiently high priority in current climate policy strategies. This paper investigates how behavioral change can achieve a substantial reduction in greenhouse gas emissions in European high-income countries. It uses theoretical thinking and some core results from the HOPE research project, which investigated household preferences for reducing emissions in four European cities in France, Germany, Norway and Sweden. The paper makes five major points: First, car and plane mobility, meat and dairy consumption, as well as heating are the most dominant components of household footprints. Second, household living situations (demographics, size of home) greatly influence the household potential to reduce their footprint, even more than country or city location. Third, household decisions can be sequential and temporally dynamic, shifting through different phases such as childhood, adulthood, and illness. Fourth, short term voluntary efforts will not be sufficient by themselves to reach the drastic reductions needed to achieve the 1.5 °C goal; instead, households need a regulatory framework supporting their behavioral changes. Fifth, there is a mismatch between the roles and responsibilities conveyed by current climate policies and household perceptions of responsibility. We then conclude with further recommendations for research and policy.  相似文献   

Age and tectonomagmatic setting of the Eocene Çöpler–Kabataş magmatic complex and porphyry-epithermal Au deposit, East Central Anatolia, Turkey     

Ali İmer  Jeremy P. Richards  Robert A. Creaser 《Mineralium Deposita》2013,48(5):557-583

The Çöpler epithermal Au deposit and related subeconomic porphyry Cu–Au deposit is hosted by the middle Eocene Çöpler–Kabata? magmatic complex in central eastern Anatolia. The intrusive rocks of the complex were emplaced into Late Paleozoic–Mesozoic metamorphosed sedimentary basement rocks near the northeastern margin of the Tauride-Anatolide Block. Igneous biotite from two samples of the magmatic complex yielded ⁴⁰Ar/³⁹Ar plateau ages of 43.75?±?0.26 Ma and 44.19?±?0.23, whereas igneous hornblende from a third sample yielded a plateau age of 44.13?±?0.38. These ages closely overlap with ⁴⁰Ar/³⁹Ar ages of hydrothermal sericite (44.44?±?0.28 Ma) and biotite (43.84?±?0.26 Ma), and Re–Os ages from two molybdenite samples (44.6?±?0.2 and 43.9?±?0.2 Ma) suggesting a short-lived (<1 my) magmatic and hydrothermal history at Çöpler. No suitable minerals were found that could be used to date the epithermal system, but it is inferred to be close in age to the precursor porphyry system. The Çöpler–Kabata? intrusive rocks show I-type calc-alkaline affinities. Their normalized trace element patterns show enrichments in large ion lithophile and light rare earth elements and relative depletions in middle and heavy rare earth elements, resembling magmas generated in convergent margins. However, given its distance from the coeval Eocene Maden–Helete volcanic arc, the complex is interpreted to be formed in a back-arc setting, in response to Paleocene slab roll-back and upper-plate extension. The tectonomagmatic environment of porphyry-epithermal mineralization at Çöpler is comparable to some other isolated back-arc porphyry systems such as Bajo de la Alumbrera (Argentina) or Bingham Canyon (USA).  相似文献   

Linear and non-linear theory of a parametric instability of hydrodynamic warps in Keplerian discs     

Charles F. Gammie  Jeremy Goodman  Gordon I. Ogilvie 《Monthly notices of the Royal Astronomical Society》2000,318(4):1005-1016

We consider the stability of warping modes in Keplerian discs. We find them to be parametrically unstable using two lines of attack, one based on three-mode couplings and the other on Floquet theory. We confirm the existence of the instability and investigate its non-linear development in three dimensions, via numerical experiment. The most rapidly growing non-axisymmetric disturbances are the most nearly axisymmetric (low- m ) ones. Finally, we offer a simple, somewhat speculative model for the interaction of the parametric instability with the warp. We apply this model to the masing disc in NGC 4258 and show that, provided the warp is not forced too strongly, parametric instability can fix the amplitude of the warp.  相似文献   

Gravitational radiation from strongly magnetized white dwarfs     

Jeremy S. Heyl 《Monthly notices of the Royal Astronomical Society》2000,317(2):310-314

The magnetic fields of white dwarfs distort their shape generating an anisotropic moment of inertia. A magnetized white dwarf that rotates obliquely relative to the symmetry axis has a mass quadrupole moment that varies in time, so it will emit gravitational radiation. The Laser Interferometer Space Antenna ( LISA ) mission may be able to detect the gravitational waves from two nearby, rapidly rotating white dwarfs.  相似文献   

Burial and exhumation of the Hoh Xil Basin,northern Tibetan Plateau: Constraints from detrital (U-Th)/He ages     

Jin-Gen Dai  Matthew Fox  David L. Shuster  Jeremy Hourigan  Xu Han  Ya-Lin Li  Cheng-Shan Wang 《Basin Research》2020,32(5):894-915

The uplift and associated exhumation of the Tibetan Plateau has been widely considered a key control of Cenozoic global cooling. The south-central parts of this plateau experienced rapid exhumation during the Cretaceous–Palaeocene periods. When and how the northern part was exhumed, however, remains controversial. The Hoh Xil Basin (HXB) is the largest late Cretaceous–Cenozoic sedimentary basin in the northern part, and it preserves the archives of the exhumation history. We present detrital apatite and zircon (U-Th)/He data from late Cretaceous–Cenozoic sedimentary rocks of the western and eastern HXB. These data, combined with regional geological constraints and interpreted with inverse and forward model of sediment deposition and burial reheating, suggest that the occurrence of ca. 4–2.7 km and ca. 4–2.3 km of vertical exhumation initiated at ca. 30–25 Ma and 40–35 Ma in the eastern and western HXB respectively. The initial differential exhumation of the eastern HXB and the western HXB might be controlled by the oblique subduction of the Qaidam block beneath the HXB. The initial exhumation timing in the northern Tibetan Plateau is younger than that in the south-central parts. This reveals an episodic exhumation of the Tibetan Plateau compared to models of synchronous Miocene exhumation of the entire plateau and the early Eocene exhumation of the northern Tibetan Plateau shortly after the India–Asia collision. One possible mechanism to account for outward growth is crustal shortening. A simple model of uplift and exhumation would predict a maximum of 0.8 km of surface uplift after upper crustal shortening during 30–27 Ma, which is insufficient to explain the high elevations currently observed. One way to increase elevation without changing exhumation rates and to decouple uplift from upper crustal shortening is through the combined effects of continental subduction, mantle lithosphere removal and magmatic inflation.  相似文献   

The Symbolic Wolf: A Construal Level Theory Analysis of the Perceptions of Wolves in the United States     

Kristina M. Slagle  Robyn S. Wilson  Jeremy T. Bruskotter  Eric Toman 《社会与自然资源》2019,32(3):322-337

Charismatic wildlife can be difficult to manage due to the controversies they generate among stakeholders, which may be rooted in their symbolic meaning. Using construal-level theory, we coded the images of gray wolves mentioned by respondents to a national survey (n?=?621) and an issue public survey (n?=?447) as symbolic (abstract) or corporeal (concrete). We analyzed the relationship between these representations of wolves and several perceptions that may perpetuate social conflict. Most people thought of wolves abstractly, and abstract thoughts were associated with positive feelings toward wolves and agreement with existence beliefs regarding wolves. Concrete representations were associated with identifying as a gun or property rights advocate, hunter, or farmer/rancher. Given these disparate views of wolves, engaging stakeholders through collaborative processes designed to foster a shared understanding of this species, while addressing the concerns of those groups, could be useful in reducing conflict concerning wolf management.  相似文献   

Mineralogy and petrogenesis of lunar magnesian granulitic meteorite Northwest Africa 5744          下载免费PDF全文

Jeremy J. Kent  Alan D. Brandon  Katherine H. Joy  Anne H. Peslier  Thomas J. Lapen  Anthony J. Irving  Daniel M. Coleff 《Meteoritics & planetary science》2017,52(9):1916-1940

Lunar meteorite Northwest Africa (NWA) 5744 is a granulitic breccia with an anorthositic troctolite composition that may represent a distinct crustal lithology not previously described. This meteorite is the namesake and first‐discovered stone of its pairing group. Bulk rock major element abundances show the greatest affinity to Mg‐suite rocks, yet trace element abundances are more consistent with those of ferroan anorthosites. The relatively low abundances of incompatible trace elements (including K, P, Th, U, and rare earth elements) in NWA 5744 could indicate derivation from a highlands crustal lithology or mixture of lithologies that are distinct from the Procellarum KREEP terrane on the lunar nearside. Impact‐related thermal and shock metamorphism of NWA 5744 was intense enough to recrystallize mafic minerals in the matrix, but not intense enough to chemically equilibrate the constituent minerals. Thus, we infer that NWA 5744 was likely metamorphosed near the lunar surface, either as a lithic component within an impact melt sheet or from impact‐induced shock.  相似文献