Metal speciation in rivers affected by enhanced soil erosion and acidity     

Miriam I. Nystrand  Peter Österholm  Maria E. Nyberg  Jon Petter Gustafsson 《Applied Geochemistry》2012

Dissolved (<1 kDa), colloidal (1 kDa–0.45 μm) and particulate (>0.45 μm) size fractions of 30 elements were determined for four rivers (Sirppujoki, Laajoki, Mynäjoki and Paimionjoki), including 12 low-order inflow streams, largely affected by soil erosion and acidity in SW Finland. In addition, geochemical modelling was used to predict the formation of free ions and complexes in these rivers. Total metal concentrations were relatively high but most of the elements occurred mainly in a colloidal or particulate form and even elements expected to be very soluble occurred to a large extent in colloidal form. According to geochemical modelling these patterns could be explained by in-stream metal complexation/adsorption only to a limited extent. Instead there were strong indications that the high metal concentrations and dominant solid fractions were largely caused by erosion of metal bearing phyllosilicates. A strong influence of acid sulphate (AS) soils, known to exist in the catchment, could be clearly distinguished in Sirppujoki river as it had very high concentrations of dissolved metals, while in the two nearby rivers (Laajoki and Mynäjoki) the influence of AS soils was largely masked by eroded phyllosilicates. In Paimionjoki river the colloidal and particulate fractions dominated very strongly, indicating that total metal concentrations are almost solely controlled by erosion of phyllosilicates. Consequently, rivers draining clay plains sensitive to erosion, like those in SW Finland, have generally high “background” metal concentrations due to erosion of relatively non-toxic colloidal/particulate phyllosilicates. Thus, relying on only semi-dissolved (<0.45 μm) concentrations obtained in routine monitoring and/or speciation modelling can lead to a great overestimation of the water toxicity in this environment.  相似文献   

Lack of relationship between Al ages of chondrules and their mineralogical and chemical compositions     

Johan Villeneuve  Marc Chaussidon  Guy Libourel 《Comptes Rendus Geoscience》2012,344(9):423-431

Previous studies have suggested the existence of a correlation between ²⁶Al relative crystallisation ages and mineralogical and bulk chemical compositions of ferromagnesian chondrules from the Bishunpur and Semarkona unequilibrated ordinary (0120 and 0150). However, because the precision in ²⁶Al ages was moderate, these correlations are questionable. Here, we report mineralogical and chemical compositions of 14 ferromagnesian chondrules from Semarkona for which precise ²⁶Al ages were previously obtained (Villeneuve et al., 2009). We find global correlation of ²⁶Al ages neither with bulk chemical composition of chondrules, nor with the different types of ferromagnesian chondrules, i.e. PO, POP and PP. This indicates that if some kind of correlations between chemical compositions of chondrules and their ages of formation exists, they do not exist at timescales that can be measured with the ²⁶Al-²⁶Mg systematics but presumably at much shorter timescales.  相似文献   

The Dwarskersbos,South Africa local tsunami of August 27, 1969: field survey and simulation as a meteorological event   总被引：1，自引：1，他引：0  

Emile A. Okal  Johan N. J. Visser  Coenraad H. de Beer 《Natural Hazards》2014,74(1):251-268

We investigate the hitherto unexplained wave which inundated the village of Dwarskersbos, South Africa, in the early hours of August 27, 1969, in the absence of any seismic disturbance or major meteorological storm. A field survey, based on the interview of nine elderly witnesses still residing in the community, documented maximum run-up of 2.9 m, concentrated on an extremely short segment of coastline, less than 2 km in length. These characteristics are incompatible with generation by a seismic source (which, at any rate, should have been felt by the population). A landslide source, located at the only canyon featuring a steep enough ocean floor, is also ruled out since a numerical simulation fails to reproduce the concentration of the wave at Dwarskersbos. By contrast, the wave can be explained as a “meteo-tsunami” resulting from resonance between a meteorological squall propagating at 18 m/s in the azimuth \(\hbox {N101}^{\circ }\hbox {E}\) and a gravity wave propagating in the shallow waters off the eastern shore of St. Helena Bay. This is confirmed by numerical simulation under the formalism of Proudman (Dynamical oceanography. Methuen, London, 1953), which provides a satisfactory model of the distribution of run-up along the beach.  相似文献   

Geodynamic and climate controls in the formation of Mio–Pliocene world-class oxidized cobalt and manganese ores in the Katanga province, DR Congo     

Sophie Decrée  Étienne Deloule  Gilles Ruffet  Stijn Dewaele  Florias Mees  Christian Marignac  Johan Yans  Thierry De Putter 《Mineralium Deposita》2010,45(7):621-629

The Katanga province, Democratic Republic of Congo, hosts world-class cobalt deposits accounting for ~50% of the world reserves. They originated from sediment-hosted stratiform copper and cobalt sulfide deposits within Neoproterozoic metasedimentary rocks. Heterogenite, the main oxidized cobalt mineral, is concentrated as “cobalt caps” along the top of silicified dolomite inselbergs. The supergene cobalt enrichment process is part of a regional process of residual ore formation that also forms world-class “manganese cap” deposits in western Katanga, i.e., the “black earths” that are exploited by both industrial and artisanal mining. Here, we provide constraints on the genesis and the timing of these deposits. Ar–Ar analyses of oxidized Mn ore and in situ U–Pb SIMS measurements of heterogenite yield Mio–Pliocene ages. The Ar–Ar ages suggest a multi-phase process, starting in the Late Miocene (10–5 Ma), when the metal-rich substratum was exposed to the action of meteoric fluids, due to major regional uplift. Further oxidation took place in the Pliocene (3.7–2.3 Ma) and formed most of the observed deposits under humid conditions: Co- and Mn-caps on metal-rich substrata, and coeval Fe laterites on barren areas. These deposits formed prior to the regional shift toward more arid conditions in Central Africa. Arid conditions still prevailed during the Quaternary and resulted in erosion and valley incision, which dismantled the metal-bearing caps and led to ore accumulation in valleys and along foot slopes.  相似文献