Infrared spectroscopic taxonomy for carbonaceous chondrites from speciation of hydrous components     

Takahito OSAWA  Hiroyuki KAGI  Tomoki NAKAMURA  Takaaki NOGUCHI 《Meteoritics & planetary science》2005,40(1):71-86

Abstract— Mid‐infrared absorption spectra for all types of carbonaceous chondrites were obtained in this study to establish a versatile method for spectroscopic classification of carbonaceous chondrites. Infrared spectra were measured using a conventional KBr pellet method and diamond press method. Spectra of hydrous carbonaceous chondrites exhibit intense O‐H stretching vibrations. CI chondrites are identifiable by a characteristic sharp absorption band appearing at 3685 cm^?1, which is mainly attributable to serpentine. X‐ray diffraction analysis showed the presence of serpentine. However, Yamato (Y‐) 82162 (C1) does not have the band at 3685 cm^?1 because of its thermal metamorphism. CM and CR chondrites have an intense absorption band at approximately 3600 cm^?1. This absorption tends to appear in CM chondrites more strongly than CR chondrites because the intensity ratios of an OH stretching mode at 3520 cm^?1 compared to 3400 cm^?1 for CM chondrites are in the range of 0.95–1.04, which is systematically higher than those of CR chondrites (0.86–0.88). Therefore, the two types of chondrites are distinguishable by their respective infrared spectra. The spectrum feature of the Tagish Lake meteorite is attributable to neither CI nor CM chondrites. CO chondrites are characterized by weak and broad absorption at 3400 cm^?1. CV chondrites have weak or negligible absorption of water. CK chondrites also have no water‐induced absorption. CH and CB chondrites have a sharp absorption at 3692 cm^?1 indicating the presence of chrysotile, which is also supported by observations of X‐ray diffraction and TEM. The combination of spectroscopic classification and the diamond press method allows classification of carbonaceous chondrites of very valuable samples with small quantities. As one example, carbonaceous chondrite clasts in brecciated meteorites were classified using our technique. Infrared spectra for a fragment of carbonaceous clasts (<1 μg) separated from Willard (b) and Tsukuba were measured. The 3685 cm^?1 band found in CI chondrites was clearly detected in the clasts, indicating that they are CI‐like clasts.  相似文献   

Heating effects of the matrix of experimentally shocked Murchison CM chondrite: Comparison with micrometeorites     

Naotaka TOMIOKA  Kazushige TOMEOKA  Keiko NAKAMURA‐MESSENGER  Toshimori SEKINE 《Meteoritics & planetary science》2007,42(1):19-30

Abstract— Micrometeorites have been significantly altered or melted by heating, which has been mainly ascribed to aerodynamic drag during atmospheric entry. However, if a major fraction of micrometeorites are produced by impacts on porous asteroids, they may have experienced shock heating before contact with the Earth's atmosphere (Tomeoka et al. 2003). A transmission electron microscope (TEM) study of the matrix of Murchison CM chondrite experimentally shocked at pressures of 10–49 GPa shows that its mineralogy and texture change dramatically, mainly due to shock heating, with the progressive shock pressures. Tochilinite is completely decomposed to an amorphous material at 10 GPa. Fe‐Mg serpentine is partially decomposed and decreases in amount with increasing pressure from 10 to 30 GPa and is completely decomposed at 36 GPa. At 49 GPa, the matrix is extensively melted and consists mostly of aggregates of equigranular grains of Fe‐rich olivine and less abundant low‐Ca pyroxene embedded in Si‐rich glass. The mineralogy and texture of the shocked samples are similar to those of some types of micrometeorites. In particular, the samples shocked at 10 and 21 GPa are similar to the phyllosilicate (serpentine)‐rich micrometeorites, and the sample shocked at 49 GPa is similar to the olivine‐rich micrometeorites. The shock heating effects also resemble the effects of pulse‐heating experiments on the CI and CM chondrite matrices that were conducted to simulate atmospheric entry heating. We suggest that micrometeorites derived from porous asteroids are likely to go through both shock and atmospheric‐entry heating processes.  相似文献   

SEQUENTIAL STIFFNESS DESIGN FOR SEISMIC DRIFT RANGES OF A SHEAR BUILDING–PILE–SOIL SYSTEM     

T. NAKAMURA  I. TAKEWAKI  Y. ASAOKA 《地震工程与结构动力学》1996,25(12):1405-1420

A shear building supported by a prescribed pile–soil system is subjected to bedrock earthquake input. A new design procedure is presented for generating a sequence of stiffness designs satisfying the constraints on interstorey drifts. The mean peak interstorey drifts of the shear building subjected to a set of spectrum-compatible ground motions at the bedrock are evaluated by a modal combination rule. Tuning of the fundamental natural period of a shear building with a fixed base with that of a shear beam ground results in a non-monotonic sequence of stiffness designs with respect to a ground stiffness parameter and previous approaches cannot be applied to such a problem. This difficulty in finding such a non-monotonic sequence is overcome by utilizing the ground stiffness parameter and the superstructure stiffness parameter alternately in multiple design phases and by developing a new multi-phase perturbation technique. Fundamental characteristics of this sequence of stiffness designs and the effect of ground stiffnesses on the design of the shear building are disclosed. It is further shown that the stiffness contour method is also useful for the design procedure such that a scattering effect in the estimates of ground stiffnesses is taken into account. The usefulness of the proposed procedure of sequential stiffness design and contour line method is demonstrated through several sequential design examples.  相似文献   

Validation of Jason-1 Nadir Ionosphere TEC Using GEONET     

JINSONG PING  KOJI MATSUMOTO  KOSUKE HEKI  AKINORI SAITO  PHILIP CALLAHAN  LARAMIE POTTS 《Marine Geodesy》2013,36(3-4):741-752

The Jason-1 dual-frequency nadir ionosphere Total Electron Content (TEC) for 10-day cycles 1–67 is validated using absolute TEC measured by Japan's GPS Earth Observation Network (GEONET), or the GEONET Regional Ionosphere Map (RIM). The bias estimates (Jason–RIM) are small and statistically insignificant: 1.62 ± 9 TECu (TEC unit or 10¹⁶ electrons/m², 1 TECu = 2.2 mm delay at Ku-band) and 0.73 ± 0.05 TECu, using the along-track difference and Gaussian distribution method, respectively. The bias estimates are –3.05 ± 10.44 TECu during daytime passes, and 0.02 ± 8.05 TECu during nighttime passes, respectively. When global Jason-1 TEC is compared with the Global Ionosphere Map (GIM) from the Center for Orbit Determination in Europe (or CODE) TEC, the bias (Jason–GIM) estimate is 0.68 ± 1.00 TECu, indicating Jason-1 ionosphere delay at Ku-band is longer than GIM by 3.1 mm, which is at present statistically insignificant. Significant zonal distributions of biases are found when the differences are projected into a sun-fixed geomagnetic reference frame. The observed biases range from –7 TECu (GIM larger by 15.4 mm) in the equatorial region, to +2 TECu in the Arctic region, and to +7 TECu in the Antarctica region, indicating significant geographical variations. This phenomena is primarily attributed to the uneven and poorly distributed global GPS stations particularly over ocean and near polar regions. Finally, when the Jason-1 and TOPEX/Poseidon (T/P) TECs were compared during Jason-1 cycles 1–67 (where cycles 1–21 represent the formation flight with T/P, cycles 22–67 represent the interleave orbits), the estimated bias is 1.42 ± 0.04 TECu. It is concluded that the offset between Jason/TOPEX and GPS (RIM or GIM) TECs is < 4 mm at Ku-band, which at present is negligible.  相似文献   

Customary Management System of Irrigation Ponds in Japan-a Case Study in a Globally Important Agricultural Heritage Systems (GIAHS) Site of Noto Island,Ishikawa Prefecture     

QIU Zhenmian  CHEN Bixia  NAKAMURA Koji 《资源与生态学报(英文版)》2016,7(3):205-210

Recent research has showed increasing interest at the vital role of irrigation ponds that plays at biodiversity conservation, and provides ecological functions at a wide range. However, many irrigation ponds were abolished due to the economic and societal transformation in the rural. In particular, small-scale ponds were abolished and rebuilt to other public uses based on the consensus building process among the community. At the same time, civil organizations also launched initiatives to conserve irrigation ponds for its ecological significance or landscape scenery. However, study pertinent to the small scale ponds in the rural setting is largely neglected. This research aims at revealing the current situation of the utilization and management of small irrigation ponds using a case study of Noto Island in Ishikawa Prefecture. It was found that irrigation ponds are still under the traditional co-management of rural community. The most important finding in this study is that the traditional management of pond water use largely contributes to mitigate the harvest loss from natural disasters such as drought in the face of extreme climate. However, irrigation ponds are facing the threat of degradation due to the sharp decrease of farm population and the existing large number of part time farmers. Therefore, the small scale irrigation ponds and pertinent management and water use allotment should be revalued for its functions at a wide range from the biological and ecological functions and human knowledge system to mitigate disaster threats.  相似文献   

Motion of iron sulfide inclusions inside a shock‐melted chondrule     

Masayuki UESUGI  Takeshi AKAKI  Minoru SEKIYA  Tomoki NAKAMURA 《Meteoritics & planetary science》2005,40(7):1103-1114

Abstract— We calculated the trajectories of molten spheres of iron sulfide inclusions inside a melted chondrule during the nebular shock wave heating. Our calculations included the effects of high‐velocity internal flow in the melted chondrule and apparent gravitational force caused by the drag force of nebular gas flow. The calculated results show that large iron sulfide inclusions, which have radii 0.23 times larger than those of the parent chondrules, must reach the surface of the melted chondrule within a short period of time (<<1 s). This effect will provide us with very important information about chondrule formation by nebular shock wave heating.  相似文献   

Origin of manganese carbonates in Jurassic red shale, central Japan     

KOJI MINOURA  SHU NAKAYA  ATSUSHI TAKEMURA 《Sedimentology》1991,38(1):137-152

Manganese carbonate deposits in Japanese Jurassic sedimentary rocks were studied petrogeochemically. The deposits are characteristically composed of spheroidal micronodules, up to 1 mm in diameter, and always contain well-preserved radiolarian shells. Chemical elemental composition and mineralogical characteristics indicate that the micronodules contain rhodochrosite in a mixed carbonate phase composition (Mn_86.7?92.2Ca_2.2?2.9Mg_2.6?6.7Fe_2.6?5.6)CO₃ Carbon and oxygen isotope values, which range from ?7.99 to ?4.78‰ and ?4.05 to 0.28‰ relative to PDB, respectively, suggest that the manganese carbonate was precipitated in a suboxic zone. The micronodules closely resemble agglutinated benthic foraminifera in shape. We suggest that agglutinated foraminiferal tests composed of radiolarian shells accumulated selectively on the sediment surface during redeposition of bottom sediments and were replaced by manganese carbonate in suboxic diagenetic conditions of manganese reduction.  相似文献   

Rapid contamination during storage of carbonaceous chondrites prepared for micro FTIR measurements     

Yoko KEBUKAWA  Satoru NAKASHIMA  Takahiro OTSUKA  Keiko NAKAMURA‐MESSENGER  Michael E. ZOLENSKY 《Meteoritics & planetary science》2009,44(4):545-557

Abstract— Organic contamination (?2965 and ?1260 cm^?1peaks) was found on Tagish Lake (C2) and Murchison (CM2) carbonaceous chondrites containing abundant hydrous minerals by Fourier transform infrared (FTIR) microspectroscopy on the samples pressed on Al plates. On the other hand, anhydrous chondrite (Moss, CO3) was not contaminated. This contamination occurred within one day of storage, when the samples pressed on Al were stored within containers including silicone rubber mats. Volatile molecules having similar peaks to the contaminants were detected by long‐path gas cell FTIR measurements for the silicone rubber mat. Rapid adsorption of the volatile contaminants also occurred when silica gel and hydrous minerals such as serpentine were stored in containers including silicone rubber, silicone grease, or adhesive tape. However, they did not show any contamination when stored in glass and polystyrene containers without these compounds. Therefore, precious astronomical samples such as meteorites, interplanetary dust particles (IDPs), and mission‐returned samples from comets, asteroids, and Mars, should be measured by micro FTIR within one day of storage in glass containers without silicone rubber, silicone grease, or adhesive tape.  相似文献   

Noble gases in enstatite chondrites released by stepped crushing and heating     

Ryuji OKAZAKI  Nobuo TAKAOKA  Keisuke NAGAO  Tomoki NAKAMURA 《Meteoritics & planetary science》2010,45(3):339-360

Abstract– Enstatite chondrites (ECs) were subjected to noble gas analyses using stepped crushing and pyrolysis extraction methods. ECs can be classified into subsolar gas‐carrying and subsolar gas‐free ECs based on the ³⁶Ar/⁸⁴Kr/¹³²Xe ratios. For subsolar gas‐free ECs, elemental ratios, and Xe isotopic compositions indicate that Q gas is the dominant trapped component, the Q gas concentration can be correlated with the petrologic type, reasonably explained by gas release from a common EC parental material during subsequent heating. Atmospheric Xe with sub‐Q elemental ratios is found in Antarctic E3s at 600–800 °C and through crushing. The ¹³²Xe released in these fractions accounts for 30–60% of the bulk concentrations. Hence, the sub‐Q signature is generally due to contamination of elementally fractionated atmosphere. Subsolar gas is mainly released (up to 78% of the bulk ³⁶Ar) at 1300–1600 °C and through crushing, suggesting that enstatite and friable phases are the host phases. Subsolar gas is isotopically identical to solar gas, but elementally fractionated. These observations are consistent with a previous study, which suggested that subsolar gas could be fractionated solar wind having been implanted into chondrule precursors ( Okazaki et al. 2001 ). Unlike subsolar gas‐free ECs, the primordial gas concentrations of subsolar gas‐carrying ECs are not simply correlated with the petrologic type. It is inferred that subsolar gas‐rich chondrules were heterogeneously distributed in the solar nebula and accreted to form subsolar gas‐carrying ECs. Subsequent metamorphic and impact‐shock heating events have affected noble gas compositions to various degrees.  相似文献   

Petrogenesis of Mafic Inclusions in Rhyolitic Lavas from Narugo Volcano, Northeastern Japan   总被引：1，自引：0，他引：1  

BAN  MASAO; TAKAHASHI  KOJI; HORIE  TAKEHIRO; TOYA  NARUHISA 《Journal of Petrology》2005,46(8):1543-1563

Mafic inclusions present in the rhyolitic lavas of Narugo volcano,Japan, are vesiculated andesites with diktytaxitic texturesmainly composed of quenched acicular plagioclase, pyroxenes,and interstitial glass. When the mafic magma was incorporatedinto the silica-rich host magma, the cores of pyroxenes andplagioclase began to crystallize (>1000°C) in a boundarylayer between the mafic and felsic magmas. Phenocryst rim compositionsand interstitial glass compositions (average 78 wt % SiO₂) inthe mafic inclusions are the same as those of the phenocrystsand groundmass glass in the host rhyolite. This suggests thatthe host felsic melt infiltrated into the incompletely solidifiedmafic inclusion, and that the interstitial melt compositionin the inclusions became close to that of the host melt (c.850°C). Infiltration was enhanced by the vesiculation ofthe mafic magma. Finally, hybridized and density-reduced portionsof the mafic magma floated up from the boundary layer into thehost rhyolite. We conclude that the ascent of mafic magma triggeredthe eruption of the host rhyolitic magma. KEY WORDS: mafic inclusion; stratified magma chamber; magma mixing; mingling; Narugo volcano; Japan  相似文献