Total nitrogen content of deep sea basalts     

Thomas L. Norris  Oliver A. Schaeffer 《Geochimica et cosmochimica acta》1982,46(3):371-379

Various models have been suggested concerning the origin and evolution of the earth's atmosphere. An estimate of the nitrogen content of the mantle could further constrain atmospheric models. Total nitrogen content was determined by thermal neutron activation analysis via ¹⁴N(n,p)¹⁴C. The ¹⁴C was converted to carbon dioxide and counted in miniature low level proportional counters. The total nitrogen content of U.S.G.S. standards BCR-1 and G-2 as determined by different laboratories is variable, probably due to atmospheric adsorption by the finely ground samples. Total nitrogen content was determined in deep sea basalt glasses from three regions: East Pacific Rise ($\text{15 ± 4, 18 ± 4}$, and $\text{7 ±}\text{ppm}\text{2 N}$), Mid-Atlantic Rift (FAMOUS Region:$\text{22 ± 5, 18 ± 3}$, and $\text{10 ± 2}\text{ppm}\text{N}$) and the Juan de Fuca Ridge ($\text{17 ± 4}\text{ppm}\text{N}$). Matrix material from the same samples as the glasses was available from the East Pacific Rise ($\text{37 ± 6, 26 ± 4}$, and $\text{34 ± 6}\text{ppm}\text{N}$) and the Mid-Atlantic Rift ($\text{39 ± 4}\text{ppm}\text{N}$) which are about 50 to 100% greater than the associated glasses. The increased matrix abundance may be due to incorporation of chemically bound nitrogen from sea water rather than dissolved molecular nitrogen. The nitrogen content of the FAMOUS samples are inconsistent with the model of Langmuir et al. (1977) for petrogenesis based on trace element data. Factors which can affect the observed nitrogen content in the basalts and the interpretation in terms of the mantle nitrogen abundance are discussed (e.g. partial melting and degassing of the basalts). A lower limit of about 2 ppm N in the mantle can be estimated.  相似文献   

Spectra of the earthquake sequence February-March, 1981, in south-central Sweden     

Ota Kulhnek  Torild Van Eck  Norris John  Klaus Meyer  Rutger Wahlstrm 《Tectonophysics》1983,93(3-4)

On February 13, 1981 a relatively strong earthquake occurred in the Lake Vänern region in south-central Sweden. The shock had a magnitude ofM_L = 3.3 and was followed within three weeks by three aftershocks, with magnitudes 0.5 ≤ M_L ≤ 1.0. The focal mechanism solution of the main shock indicates reverse faulting with a strike in the N-S or NE-SW direction and a nearly horizontal compressional stress. The aftershocks were too small to yield data for a full mechanism solution, but first motions of P-waves, recorded at two stations, are consistent for the aftershocks. Dynamic source parameters, derived from Pg- and Sg-wave spectra, show similar stress drops for the main shock (2 bar) and the aftershocks (1 bar), while the differences in seismic moment (1.5·10²⁰ resp. 4·10¹⁸dyne cm), fault length (0.7 resp. 0.2 km) and relative displacement (0.15 resp. 0.03 cm) are significant.  相似文献   

Sources, distribution and storage of heavy metals in the Río Pilcomayo, Bolivia     

Karen A. Hudson-Edwards  Mark G. Macklin  Jerry R. Miller  Paul J. Lechler 《Journal of Geochemical Exploration》2001,72(3)

The Río Pilcomayo rises on the Cerro Rico de Potosí precious metal-polymetallic tin deposits of Bolivia, and flows in a southeasterly direction for ca. 600 km to Bolivia's southern border with Argentina. Mining of the Potosí deposits has occurred continuously since 1545, generating large quantities of waste materials in the headwater of the basin. In addition, a tailings dam breach at the Porco mine in 1996 released an estimated 235 000 m³ of tailings and fluid into the upper reaches of the Río Pilaya, the largest tributary to the Pilcomayo.Concentrations of As, Sb, Cd, Cu, Pb, Hg, Ag, Tl and Zn in contemporary channel sediments upstream of the Pilaya confluence are significantly elevated above background values. Elevated levels appear to be associated with pyrite- and other sulphide mineral-bearing tailings materials transported more than 200 km downstream of the Potosí mines. Significant downstream declines in elemental concentrations occur within 15 km, and again between 150 and 200 km, from the mines. The initial decrease in concentrations is due to the rapid dilution of nearly pure tailings effluent released to the river from milling facilities near Potosí. The latter decrease results from a combination of geomorphic processes including the storage of sediment-borne metals within the channel bed and the influx of ‘clean’ sediment from several large tributaries. Downstream of the Pilaya confluence, concentrations of Cu, Pb, Hg and Zn are only slightly elevated above background values, and Ag, Cd, Sb and Tl cannot be distinguished from background levels. These data suggest that while the Porco tailings spill may have had a significant short-term impact on sediment and water quality along the lower reaches of the Río Pilcomayo, its longer-term impacts were limited. Metals stored and eroded from alluvial deposits of historical age in upstream reaches appear to be an important source of metals to the river today. An additional, and perhaps more significant source, is the release of tailings effluent to the river from modern milling operations. The transport of these contaminants downstream of Icla (203 km from Potosí) appears to be restricted by aggradational processes occurring in the vicinity of Puente Sucre. In addition, downstream of the confluence of the Río Pilaya, inputs of large amounts of ‘clean’ sediment have caused dilution of the metal contaminants. Data from other studies where similar geomorphic processes have occurred suggest that the metals in the upper Pilcomayo may eventually be moved downvalley as the aggradational processes are reversed and channel stabilisation occurs. Thus, the most significant impacts of metal contamination may not be realised in downstream areas for decades.  相似文献   

Monitoring Networks in Fractured Rocks: A Decision Analysis Approach   总被引：1，自引：0，他引：1  

Karen Jardine  Leslie Smith  Tom Clemo 《Ground water》1996,34(3):504-518

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Teaching GIS in Geography*   总被引：2，自引：0，他引：2  

Karen K. Kemp  Michael F. Goodchild  Rustin F. Dodson 《The Professional geographer》1992,44(2):181-191

Although numerous courses in geographic information systems (GIS) have been introduced into the geography curriculum over the past few years, there has been remarkably little debate over the issues involved. This paper first discusses the arguments for geography as an appropriate disciplinary setting for GIS teaching at the undergraduate level. This is followed by a discussion of the nature of GIS courses and their appropriate place in the undergraduate geography curriculum. The final section of the paper describes the NCGIA Core Curriculum project and examines its significance in this broader context.  相似文献   

Major and trace elements in igneous rocks from apollo 15     

Philip A. Helmke  Douglas P. Blanchard  Larry A. Haskin  Karen Telander  Charles Weiss  Jeffrey W. Jacobs 《Earth, Moon, and Planets》1973,8(1-2):129-148

The concentrations of major and trace elements have been determined in igneous rocks from Apollo 15. All materials analyzed have typical depletions of Eu except for minerals separated from sample 15085. Four samples have concentrations of trace elements that are similar to those of KREEP. The samples of mare basalt from Apollo 15 have higher concentrations of FeO, MgO, Mn, and Cr and lower concentrations of CaO, Na₂O, K₂O, and rare-earth elements (REE) as compared to the samples of mare basalt from Apollos 11, 12, and 14. The samples can be divided into two groups on the basis of their normative compositions. One group is quartz normative and has low concentrations of FeO while the other is olivine normative and has high concentrations of FeO. The trace element data indicate that the samples of olivine normative basalt could be from different portions of a single lava flow. At least two and possible three parent magmas can be identified from the samples of the quartz normative group on the basis of their concentration ratios of Sm to Eu. Within each group, the compositions of the samples appear to be related by crystallization of olivine or pyroxene. Significant variations of the ratio of concentration of Sm to Eu cannot be produced without plagioclase-liquid equilibrium. The source material of mare basalt may be depleted in Eu. Alternatively, the magmas may have assimilated a small volume of material similar to KREEP.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.  相似文献   

Quantifying Organization of Atmospheric Turbulent Eddy Motion Using Nonlinear Time Series Analysis   总被引：3，自引：0，他引：3  

Karen H. Wesson  Gabriel G. Katul  Mario Siqueira 《Boundary-Layer Meteorology》2003,106(3):507-525

Using three methods from nonlinear dynamics, we contrast the level of organization inthe vertical wind velocity (w) time series collected in the atmospheric surface layer(ASL) and the canopy sublayer (CSL) for a wide range of atmospheric stability ()conditions. The nonlinear methods applied include a modified Shannon entropy, waveletthresholding, and mutual information content. Time series measurements collected overa pine forest, a hardwood forest, a grass-covered forest clearing, and a bare soil, desertsurface were used for this purpose. The results from applying all three nonlinear timeseries measures suggest that w in the CSL is more organized than that in the ASL, and that as the flows in both layers evolve from near-neutral to near-convective conditions, the level of organization increases. Furthermore, we found that the degree of organization in w associated with changes in is more significant than the transition from CSL to ASL.  相似文献   

Mapping of Ozone and Water in the Atmosphere of Mars near the 1997 Aphelion     

Robert E. NovakMichael J. Mumma  Michael A. DiSanti  Neil Dello Russo  Karen Magee-Sauer 《Icarus》2002,158(1):14-23

We present absolute abundances and latitudinal variations of ozone and water in the atmosphere of Mars during its late northern spring (L_s=67.3°) shortly before aphelion. Long-slit maps of the a¹Δ_g state of molecular oxygen (O₂) and HDO, an isotopic form of water, were acquired on UT January 21.6 1997 using a high-resolution infrared spectrometer (CSHELL) at the NASA Infrared Telescope Facility. O₂(a¹Δ_g) is produced by ozone photolysis, and the ensuing dayglow emission at 1.27 μm is used as a tracer for ozone. Retrieved vertical column densities for ozone above ∼20 km ranged between 1.5 and 2.8 μm-atm at mid- to low latitudes (30°S-60°N) and decreased outside that region. A significant decrease in ozone density is seen near 30°N (close to the subsolar latitude of 23.5°N). The rotational temperatures retrieved from O₂(a-X) emissions show a mean of 172±2.5 K, confirming that the sensed ozone lies in the middle atmosphere (∼24 km). The ν₁ fundamental band of HDO near 3.67 μm was used as a proxy for H₂O. The retrieved vertical column abundance of water varies from 3 precipitable microns (pr-μm) at ∼30°S to 24 pr-μm at ∼60°N. We compare these results with current photochemical models and with measurements obtained by other methods.  相似文献   

Atmospheric Electrification in the Solar System     

Karen L. Aplin 《Surveys in Geophysics》2006,27(1):63-108

Atmospheric electrification is not a purely terrestrial phenomenon: all Solar System planetary atmospheres become slightly electrified by cosmic ray ionisation. There is evidence for lightning on Jupiter, Saturn, Uranus and Neptune, and it is possible on Mars, Venus and Titan. Controversy surrounds the role of atmospheric electricity in physical climate processes on Earth; here, a comparative approach is employed to review the role of electrification in the atmospheres of other planets and their moons. This paper reviews the theory, and, where available, measurements, of planetary atmospheric electricity which is taken to include ion production and ion–aerosol interactions. The conditions necessary for a planetary atmospheric electric circuit similar to Earth’s, and the likelihood of meeting these conditions in other planetary atmospheres, are briefly discussed. Atmospheric electrification could be important throughout the solar system, particularly at the outer planets which receive little solar radiation, increasing the relative significance of electrical forces. Nucleation onto atmospheric ions has been predicted to affect the evolution and lifetime of haze layers on Titan, Neptune and Triton. Atmospheric electrical processes on Titan, before the arrival of the Huygens probe, are summarised. For planets closer to Earth, heating from solar radiation dominates atmospheric circulations. However, Mars may have a global circuit analogous to the terrestrial model, but based on electrical discharges from dust storms. There is an increasing need for direct measurements of planetary atmospheric electrification, in particular on Mars, to assess the risk for future unmanned and manned missions. Theoretical understanding could be increased by cross-disciplinary work to modify and update models and parameterisations initially developed for a specific atmosphere, to make them more broadly applicable to other planetary atmospheres.  相似文献   

The clean development mechanism’s contribution to sustainable development: a review of the literature     

Karen Holm Olsen 《Climatic change》2007,84(1):59-73

The challenges of how to respond to climate change and ensure sustainable development are currently high on the political agenda among the world’s leading nations. The Clean Development Mechanism (CDM) is part of the global carbon market developing rapidly as part of the Kyoto response towards the mitigation of global warming. One of the aims of the CDM is to achieve sustainable development in developing countries, but uncertainty prevails as to whether the CDM is doing what it promises to do. Close to 200 studies on the CDM have been carried out since its birth in 1997 including peer-reviewed articles and reports from the grey literature. This review of the literature serves to assess the state of knowledge on how the CDM contributes to sustainable development (SD) including poverty alleviation. The main finding of the review is that, left to market forces, the CDM does not significantly contribute to sustainable development.  相似文献