Environmental changes in an alpine lake (Gossenköllesee, austria) over the last two centuries – the influence of air temperature on biological parameters     

Karin A. Koinig  Christian Kamenik  Roland Schmidt  Anna Agustí-Panareda  Peter Appleby  Andrea Lami  Miroslava Prazakova  Neil Rose  Øyvind A. Schnell  Richard Tessadri  Roy Thompson  Roland Psenner 《Journal of Paleolimnology》2002,28(1):147-160

Changes in microfossils (diatoms, chrysophytes, chironomids and cladocera remains), geochemistry and deposition of atmospheric pollutants have been investigated in the sediment records of the alpine lake Gossenköllesee (Tyrol, Austria) spanning the last two centuries. The sediment records were compared with seasonal and annual air temperature trends calculated for the elevation (2417 m a.s.l.) and the geographical position (47° 1346N, 11° 0051E) of the lake, and with precipitation records available since 1866 from Innsbruck. Temperature trends followed a 20–30 year oscillation between cold and warm periods. Regarding long-term changes, temperature trends showed a U-shaped trend between 1780 and 1950, followed by a steep increase since 1975.Physical, geochemical, and organic parameters were not controlled by air temperature. Among the biological records only diatoms and chrysophytes reacted to air temperature changes: the relative abundance of planktonic diatoms increased during warm periods and changes in mean annual alpine air temperature explained 36.5% of their variation. The relation between abundance of seasonal stomatocyst types and air temperature varied on two different time scales: while summer stomatocysts were influenced by short term temperature fluctuations, the autumn stomatocysts were affected only by the long term changes. Other biological parameters exhibited a constant species composition (chironomids, pigments) or changes were small and independent of temperature (cladocera). Spheroidal carbonaceous fly-ash particles, and trends in Pb and Cr indicated increasing deposition of atmospheric pollutants but had no detectable effects on the biological parameters either. In respect to temperature variations over the last 200 years, this alpine lake is much less sensitive than expected and has thus to be regarded as a well buffered site. However, temperature alone is not sufficient to understand changes in species composition and other biogeochemical processes with unknown historical patterns might have affected species composition more strongly.  相似文献   

Gaseous and Particulate Oxidized and Reduced Nitrogen Species in the Atmospheric Boundary Layer in Scandinavia in Spring     

Asgeir Sorteberg  Øystein Hov  Sverre Solberg  Kjetil Tørseth  Hans Areskoug  Martin Ferm  Kit Granby  Heikki Lättilä  Karin Persson  David Simpson 《Journal of Atmospheric Chemistry》1998,30(2):241-271

Observations of the concentration of several nitrogen containing compounds at five rural Scandinavian sites during March–June 1993 are reported. Total nitrate (NO ₃ ^- + HNO₃) and total ammonium (NH ₄ ⁺ + NH₃) were measured by denuder and filter pack. In general the methods agree well. At all sites the particulate fraction dominated, with the largest fraction of NO ₃ ^- and the lowest of NH ₄ ⁺ at the sites which were closest to the emission sources. The fraction of NO ₃ ^- of total nitrate increased with increasing NO₂ concentrations, indicating that the nighttime conversion of NO₂ to NO ₃ ^- is an important route of formation for NO ₃ ^- . A positive correlation was found between HNO₃ and O₃ in June at all sites, while no correlation was found early in the spring. Model calculations were made with a lagrangian boundary layer photooxidant model for the whole period, and compared to the measured concentrations. The calculated ratio between mean observed and modelled daily maximum concentrations of ozone over the measurement period were within +/–10% at all sites. The models ability to describe the daily ozone maximum concentration was satisfactory with an average deviation of 19–22% from the observed concentrations. HNO₃ was underestimated by over 50% at all sites except the one closest to the emission sources. The correlation between modelled and observed concentrations was generally best for the sites with shortest transport distance from the sources of emission.  相似文献   

Hydrothermal gases offshore Milos Island, Greece   总被引：3，自引：0，他引：3  

Reiner Botz  Doris Stüben  Gisela Winckler  Reinhold Bayer  Manfred Schmitt  Eckhard Faber 《Chemical Geology》1996,130(3-4):161-173

Hydrothermal fluids emerge from the seafloor of Paleohori Bay on Milos. The gases in these fluids contain mostly CO₂ but CH₄ concentrations up to 2% are present. The stable carbon isotopic composition of the CO₂ (near 0%) indicates an inorganic carbon source (dissociation of underlying marine carbonates). The carbon and hydrogen isotopes of most CH₄ samples are enriched in the heavy species (δ¹³C = −9.4 to −17.8‰; δD = −102 to −189‰) which is believed to be characteristic for an abiogenic production of CH₄ by CO₂-reduction (Fischer-Tropsch reactions). Depletions in the deuterium content of three CH₄ samples (to −377%) are probably caused by unknown subsurface rock alteration processes. Secondary hydrogen isotope exchange processes between methane, hydrogen and water are most likely responsible for calculated unrealistic methane formation temperatures.

We show that excess helium, slightly enriched in ³He, is present in the hydrothermal fluids emerging the seafloor of Paleohori Bay. When the isotopic ratio of the excess component is calculated a ³He/⁴He_excess of 3.6 · 10⁻⁶ is obtained: This indicates that the excess component consists of about one third of mantle helium and two thirds of radiogenic helium. We infer that the mantle-derived component has been strongly diluted by radiogenic helium during the ascent of the fluids to the surface.  相似文献   

Modelling of uranium and neptunium chemistry in a deep rock environment     

Iréne Lundén  Karin Andersson  Gunnar Skarnemark 《Aquatic Geochemistry》1996,2(4):345-358

According to the present concept for final storage of spent nuclear fuel in Sweden, the spent fuel, encapsulated in copper or copper/steel canisters, will be placed in tunnels in a deep rock formation. The canisters will be surrounded by compacted bentonite clay acting as a buffer material. In connection with a safety analysis of such a storage facility, the total solubility of certain elements (e.g., uranium) as well as the transport properties (e.g., retardation due to sorption on mineral surfaces) of the long-lived radionuclides released from the canister have to be predicted or measured. The chemical conditions, governing the solubility and speciation of trace elements encountered in and around the repository depend on interactions between the ground water and the engineering materials in the repository and a production of oxidants due to radiolysis in the spent fuel. In the present study the speciation and solubility of uranium and neptunium in a bentonite-ground water system and in ground waters with compositions measured at a site at äspö, SE Sweden, have been calculated. The calculations have been carried out using a recent version of the geochemical computer code PHREEQE and the database HATCHES 5.0. Predictions of the uranium and neptunium concentrations in the ground water in the vicinity of a damaged high level waste repository have also been performed. The uranium concentration in the water in the bentonite barrier is predicted to be of the same order of magnitude or lower than that found in some granitic ground waters. For neptunium the calculations are uncertain due to the small amount of experimentally determined thermodynamic data and few verifications under the conditions (pH - Eh - carbonate concentration) considered. The predicted concentrations (ca 10^–12 m, corresponds to ca 0.006 Bq/l) may be regarded as high, considering the high toxicity of neptunium and its long half-life.  相似文献   

Warming at 18,000 yr B.P. in the Tropical Andes     

Karin F. Helmens  Peter Kuhry  Nathaniel W. Rutter  Klaas Van Der Borg  Arie F. M. De Jong 《Quaternary Research》1996,45(3):289-299

Palynological, paleopedological, and glacial geomorphological evidence from the area of the high plain of Bogotá in the Colombian Eastern Cordillera indicates a significant climatic warming around 18,000¹⁴C yr B.P. Comparison of dated vegetation changes, pedogenic episodes, and glacier fluctuations provides the basis for defining the so-called “La Laguna Interstadial” that lasted from 19,500 to 17,000 yr B.P. During this interstadial period, mean annual temperatures in the tropical Andes were up to 4°C higher than during the preceding and following stadial periods, when full-glacial conditions prevailed and temperatures were up to 8°C colder than at present.  相似文献   

Growth and mortality rates of larval American shad,Alosa sapidissima,at different salinities     

Karin E. Limburg  Robert M. Ross 《Estuaries and Coasts》1995,18(2):335-340

The tolerance of post yolk-sac American shad Alosa sapidissima larvae to salinities typically seen in estuaries was assessed experimentally. Sixteen-day-old Hudson River (experiment I) and 35-d-old Delaware River (experiment II) larvae were held for 8 d and 9 d respectively in low (0–1‰), medium (9–11‰), and highly (19–20‰) brackish water, and mortality and growth rates were measured. Growth rates did not vary significantly among salinity treatments. Mortality in experiment I did not vary significantly among salinity treatments however, in experiment II, mortality was zero at 10‰ but higher and statistically indistinguishable between 0‰ and 20‰ In experiment II relative condition increased with salinity. These results imply that estuarine salinities neither depress growth rates nor elevate mortality rates of larval American shad when compared with freshwater conditions. We conclude that ecological factors other than the physiological effects of salinity have played more important roles in the evolution of the upriver spawning and nursery preference shown by this species.  相似文献   

Assessing streams in Germany with benthic invertebrates: development of a practical standardised protocol for macroinvertebrate sampling and sorting   总被引：4，自引：0，他引：4  

Peter Haase  Susanne Lohse  Steffen Pauls  Karin Schindehütte  Andrea Sundermann  Peter Rolauffs  Daniel Hering 《Limnologica》2004,34(4):349-365

In the past, no single standardised method for sampling and sorting benthic macroinvertebrates has been implemented in Germany. Therefore, we tested the suitability of two common sorting protocols, RIVPACS and AQEM/STAR, by taking samples with each protocol at 44 sampling sites. Our results reveal that different methods deliver slightly different assessment results. Moreover these two methods differ in costs. Although the AQEM/STAR protocol takes longer than the RIVPACS protocol, we favoured the AQEM/STAR protocol because of its higher level of standardisation. In order to limit costs to an acceptable level, a modification of the AQEM/STAR protocol (MAS method) is developed. This method is highly standardised, gives stable assessment results and is relatively inexpensive (€ 224.00 for processing of an average sample). A detailed protocol of the newly developed method is given.  相似文献   

Re–Os and Pb–Pb geochronology of the Archean Salobo iron oxide copper–gold deposit, Carajás mineral province, northern Brazil     

Karin Requia  Holly Stein  Lluís Fontboté  Massimo Chiaradia 《Mineralium Deposita》2003,38(6):727-738

Rhenium–osmium ages were determined for two molybdenite samples and a Pb–Pb age was derived from bornite–chalcopyrite–magnetite at the Salobo iron oxide copper–gold deposit to determine the timing of mineralization and its relation to the nearby Old Salobo Granite. Rhenium–osmium dating of molybdenite spatially associated with copper sulfide minerals yields ages with weighted means of 2576±8 and 2562±8 Ma. Removing the error multiplier introduced by the decay constant uncertainty, appropriate for comparing ages from the same isotopic system, these data convincingly argue for two temporally separated pulses of molybdenite deposition at 2576.1±1.4 Ma (n=2) and 2561.7±3.1 Ma (n=3). The 2576±8 Ma age coincides with a previously published U–Pb age of 2573±2 Ma for the Old Salobo Granite, suggesting that main stage ore formation may have been contemporaneous with granite magmatism. The slightly younger 2562 Ma age most likely represents new molybdenite precipitation associated with the development or reactivation of local shear zones. Lead–lead stepwise leaching of copper sulfide minerals yields a less precise isochron age of 2579±71 Ma, and supports an Archean age for the Salobo ores. This is the first documentation of an Archean iron oxide copper–gold deposit, and the Re–Os and Pb–Pb geochronology herein support 2580–2550 Ma estimates for basement reactivation and regional granite magmatism associated with the development of brittle–ductile shear zones.  相似文献   

A probabilistic seismic hazard assessment for the Turkish territory—part I: the area source model     

Karin Sesetyan  Mine B. Demircioglu  Tamer Y. Duman  Tolga Çan  Senem Tekin  Tuba Eroğlu Azak  Özge Zülfikar Fercan 《Bulletin of Earthquake Engineering》2018,16(8):3367-3397

The seismic zoning map of Turkey that is used in connection with the national seismic design code (versions issued both in 1997 and 2007) is based on a probabilistic seismic hazard assessment study conducted more than 20 years ago (Gülkan et al. in En son verilere göre haz?rlanan Türkiye deprem bölgeleri haritas?, Report No: METU/EERC 93-1, 1993). In line with the efforts for the update of the seismic design code, the need aroused for an updated seismic hazard map, incorporating recent data and state-of-the-art methodologies and providing ground motion parameters required for the construction of the design spectra stipulated by the new Turkish Earthquake Design Code. Supported by AFAD (Disaster and Emergency Management Authority of Turkey), a project has been conducted for the country scale assessment of the seismic hazard by probabilistic methods. The present paper describes the probabilistic seismic hazard assessment study conducted in connection with this project, incorporating in an area source model, all recently compiled data on seismicity and active faulting, and using a set of recently developed ground motion prediction equations, for both active shallow crustal and subduction regimes, evaluated as adequately representing the ground motion characteristics in the region. The area sources delineated in the model are fully parameterized in terms of maximum magnitude, depth distribution, predominant strike and dip angles and mechanism of possible ruptures. Resulting ground motion distributions are quantified and presented for PGA and 5 % damped spectral accelerations at T = 0.2 and 1.0 s, associated with return periods of 475 and 2475 years. The full set of seismic hazard curves was also made available for the hazard computation sites. The second part of the study, which is based on a fault source and smoothed seismicity model is covered in Demircioglu et al. in Bull Earthq Eng, (2016).  相似文献   

Understanding heterogeneity in metropolitan India: The added value of remote sensing data for analyzing sub-standard residential areas     

Isa Baud  Monika Kuffer  Karin Pfeffer  Richard Sliuzas  Sadasivam Karuppannan 《International Journal of Applied Earth Observation and Geoinformation》2010

Analyzing the heterogeneity in metropolitan areas of India utilizing remote sensing data can help to identify more precise patterns of sub-standard residential areas. Earlier work analyzing inequalities in Indian cities employed a constructed index of multiple deprivations (IMDs) utilizing data from the Census of India 2001 (http://censusindia.gov.in). While that index, described in an earlier paper, provided a first approach to identify heterogeneity at the citywide scale, it neither provided information on spatial variations within the geographical boundaries of the Census database, nor about physical characteristics, such as green spaces and the variation in housing density and quality. In this article, we analyze whether different types of sub-standard residential areas can be identified through remote sensing data, combined, where relevant, with ground-truthing and local knowledge. The specific questions address: (1) the extent to which types of residential sub-standard areas can be drawn from remote sensing data, based on patterns of green space, structure of layout, density of built-up areas, size of buildings and other site characteristics; (2) the spatial diversity of these residential types for selected electoral wards; and (3) the correlation between different types of sub-standard residential areas and the results of the index of multiple deprivations utilized at electoral ward level found previously.  相似文献