Photochemical degradation of phenanthrene as a function of natural water variables modeling freshwater to marine environments   总被引：1，自引：0，他引：1  

de Bruyn WJ  Clark CD  Ottelle K  Aiona P 《Marine pollution bulletin》2012,64(3):532-538

Photolysis rates of phenanthrene as a function of ionic strength (salinity), oxygen levels and humic acid concentrations were measured in aqueous solution over the range of conditions found in fresh to marine waters. Photolysis followed first order kinetics, with an estimated photodegradation half-life in sunlight in pure water of 10.3±0.7h, in the mid-range of published results. Photolysis rate constants decreased by a factor of 5 in solutions with humic acid concentrations from 0 to 10 mg C L(-1). This decrease could be modeled entirely based on competitive light absorption effects due to the added humics. No significant ionic strength or oxygen effects were observed, consistent with a direct photolysis mechanism. In the absence of significant solution medium effects, the photodegradation lifetime of phenanthrene will depend only on solar fluxes (i.e. temporal and seasonal changes in sunlight) and not vary with a freshwater to marine environment.  相似文献   

Bacterial communities are sensitive indicators of contaminant stress     

Sun MY  Dafforn KA  Brown MV  Johnston EL 《Marine pollution bulletin》2012,64(5):1029-1038

With many environments worldwide experiencing at least some degree of anthropogenic modification, there is great urgency to identify sensitive indicators of ecosystem stress. Estuarine organisms are particularly vulnerable to anthropogenic contaminants. This study presents bacterial communities as sensitive indicators of contaminant stress. Sediments were collected from multiple sites within inner and outer zones of three heavily modified and three relatively unmodified estuaries. Bacterial communities were censused using Automated Ribosomal Intergenic Spacer Analysis and analysed for a suite of metal and PAH contaminants. Shifts in both bacterial community composition and diversity showed strong associations with sediment contaminant concentrations, particularly with metals. Importantly, these changes are discernable from environmental variation inherent to highly complex estuarine environments. Moreover, variation in bacterial communities within sites was limited. This allowed for differences between sites, zones and estuaries to be explained by variables of interest such as contaminants that vary between, but not within individual sites.  相似文献   

Effect of zinc sacrificial anode degradation on the defence system of the Pacific oyster, Crassostrea gigas: Chronic and acute exposures     

E Mottin  C Caplat  T Latire  A Mottier  ML Mahaut  K Costil  D Barillier  JM Lebel  A Serpentini 《Marine pollution bulletin》2012,64(9):1911-1920

Two types of exposures were performed to assess the effects of zinc released from sacrificial anode degradation: a chronic exposure, in which oysters were exposed to 0.53±0.04mgZnL(-1) for 10weeks, and an acute exposure, where oysters were exposed to 10.2±1.2mgZnL(-1) for 1week. At the end of the acute exposure experiment, 81.8% mortality was recorded. In contrast, no mortality was detected after 10weeks exposure. Moreover, all of the immune system biomarkers studied, except the number of circulating haemocytes, were stimulated by a moderate level of zinc and inhibited by a high level. Our exposure conditions did not induce SOD or MXR mRNA expression in gills and digestive gland. However, an increase of MT mRNA is observed in these tissues. The results indicate that oysters are sensitive to acute zinc toxicity but are only moderately affected by a mild zinc concentration.  相似文献   

Impacts of a bottom trawling exclusion zone on Snow Crab abundance and fish harvester behavior in the Labrador Sea, Canada     

Darrell R.J. Mullowney  Corey J. MorrisEarl G. Dawe  Katherine R. Skanes 《Marine Policy》2012,36(3):567-575

The Hawke Box trawling exclusion zone off southern Labrador is a 8610 km² closed area implemented in 2003 to protect soft-shelled pre-recruit Snow Crab and juvenile cod from mortality imposed by shrimp trawling and other bottom-impact fisheries. This study utilizes survey, logbook, and observer data from the Snow Crab and Northern Shrimp fisheries to assess the effectiveness of the Hawke Box in protecting and possibly enhancing the Snow Crab resource off southern Labrador. The results indicate that the exclusion zone has failed to protect pre-recruit crabs largely due to a redistribution and intensification of directed Snow Crab effort inside the Box in the years following closure. This unexpected outcome resulted in a high level of fishery-induced mortality to pre-recruit crabs and masked any potential positive outcomes from the cessation of trawling. The shortcomings that contributed to the failure of this exclusion area are discussed in relation to the current state of knowledge on the effectiveness of marine protected areas in general as management tools for conserving aquatic resources.  相似文献   

Chesapeake Bay Plume Morphology and the Effects on Nutrient Dynamics and Primary Productivity in the Coastal Zone     

Katherine C. Filippino  Peter W. Bernhardt  Margaret R. Mulholland 《Estuaries and Coasts》2009,32(3):410-424

To determine the effects of the Chesapeake Bay outflow plume on the coastal ocean, nutrient concentrations and climatology were evaluated in conjunction with nitrogen (N) and carbon (C) uptake rates during a 3-year field study. Sixteen cruises included all seasons and captured high- and low-flow freshwater input scenarios. Event-scale disturbances in freshwater flow and wind speed and direction strongly influenced the location and type of plume present and thus the biological uptake of N and C. As expected, volumetric primary productivity rates did not always correlate with chlorophyll a concentrations, suggesting that high freshwater flow does not translate into high productivity in the coastal zone; rather, high productivity was observed during periods where recycling processes may have dominated. Results suggest that timing of meteorological events, with respect to upwelling or downwelling favorable conditions, plays a crucial role in determining the impact of the estuarine plume on the coastal ocean.  相似文献   

Geodynamic evolution of a forearc rift in the southernmost Mariana Arc     

Julia M. Ribeiro  Robert J. Stern  Fernando Martinez  Osamu Ishizuka  Susan G. Merle  Katherine Kelley  Elizabeth Y. Anthony  Minghua Ren  Yasuhiko Ohara  Mark Reagan  Guillaume Girard  Sherman Bloomer 《Island Arc》2013,22(4):453-476

The southernmost Mariana forearc stretched to accommodate opening of the Mariana Trough backarc basin in late Neogene time, erupting basalts at 3.7–2.7 Ma that are now exposed in the Southeast Mariana Forearc Rift (SEMFR). Today, SEMFR is a broad zone of extension that formed on hydrated, forearc lithosphere and overlies the shallow subducting slab (slab depth ≤ 30–50 km). It comprises NW–SE trending subparallel deeps, 3–16 km wide, that can be traced ≥ ∼30 km from the trench almost to the backarc spreading center, the Malaguana‐Gadao Ridge (MGR). While forearcs are usually underlain by serpentinized harzburgites too cold to melt, SEMFR crust is mostly composed of Pliocene, low‐K basaltic to basaltic andesite lavas that are compositionally similar to arc lavas and backarc basin (BAB) lavas, and thus defines a forearc region that recently witnessed abundant igneous activity in the form of seafloor spreading. SEMFR igneous rocks have low Na₈, Ti₈, and Fe₈, consistent with extensive melting, at ∼23 ± 6.6 km depth and 1239 ± 40°C, by adiabatic decompression of depleted asthenospheric mantle metasomatized by slab‐derived fluids. Stretching of pre‐existing forearc lithosphere allowed BAB‐like mantle to flow along the SEMFR and melt, forming new oceanic crust. Melts interacted with pre‐existing forearc lithosphere during ascent. The SEMFR is no longer magmatically active and post‐magmatic tectonic activity dominates the rift.  相似文献   

TEMPORAL SENSITIVITY OF REGIONAL CLIMATE TO LAND-SURFACE HETEROGENEITY     

Katherine Klink 《自然地理学》2013,34(4):289-314

Increased interest in climate change at local and regional scales has prompted climate simulations for regional areas, but tests of climate models have not specifically examined the impacts of regional heterogeneity, and they have largely overlooked possible temporal sensitivity. In this study I used a coupled surface-atmosphere mesoscale model to evaluate the effects of regional heterogeneity in five land-surface parameters that have the strongest impacts on the surface energy balance: albedo, roughness, canopy resistance, rooting profile, and soil water content. I included temporal variability in climate sensitivity by completing a series of mid-month simulations representative of the June-September growing season. I modeled land surfaces of maize contrasted with bare soil, grass, or coniferous trees. Roughness discontinuities were important factors in determining regional energy balance and surface temperature for all three surface contrasts. The effects varied over the growing season as a function of maize height. Canopy resistance was equally important, especially during the middle of the season when the maize canopy was at its fullest extent. Albedo effects appeared to be secondary, but often were more important in September. Changes in soil water content had little impact because vegetation in these simulations was not stressed by low soil moisture. The importance of roots in these simulations was primarily a function of their presence or absence, rather than of the specific profile assigned to each vegetation type. Roughness and canopy resistance discontinuities appeared to play the largest role in determining the regional average energy balance and surface temperature for growing season dates. [Key words: land-surface heterogeneity, energy balance, climatology.]  相似文献   

The Handling of Hazard Data on a National Scale: A Case Study from the British Geological Survey     

Katherine R. Royse 《Surveys in Geophysics》2011,32(6):753-776

This paper reviews how hazard data and geological map data have been combined by the British Geological Survey (BGS) to produce a set of GIS-based national-scale hazard susceptibility maps for the UK. This work has been carried out over the last 9 years and as such reflects the combined outputs of a large number of researchers at BGS. The paper details the inception of these datasets from the development of the seamless digital geological map in 2001 through to the deterministic 2D hazard models produced today. These datasets currently include landslides, shrink-swell, soluble rocks, compressible and collapsible deposits, groundwater flooding, geological indicators of flooding, radon potential and potentially harmful elements in soil. These models have been created using a combination of expert knowledge (from both within BGS and from outside bodies such as the Health Protection Agency), national databases (which contain data collected over the past 175 years), multi-criteria analysis within geographical information systems and a flexible rule-based approach for each individual geohazard. By using GIS in this way, it has been possible to model the distribution and degree of geohazards across the whole of Britain.  相似文献   

Hydrogen isotope ratios of leaf wax n-alkanes in grasses are insensitive to transpiration     

Francesca A. McInerney  Brent R. Helliker  Katherine H. Freeman 《Geochimica et cosmochimica acta》2011,75(2):541-554

We analyzed hydrogen isotope ratios of high-molecular weight n-alkanes (δD_l) and oxygen isotope ratios of α-cellulose (δ¹⁸O_C) for C₃ and C₄ grasses grown in the field and in controlled-environment growth chambers. The relatively firm understanding of ¹⁸O-enrichment in leaf water and α-cellulose was used to elucidate fractionation patterns of δD_l signatures. In the different relative humidity environments of the growth chambers, we observed clear and predictable effects of leaf-water enrichment on δ¹⁸O_C values. Using a Craig-Gordon model, we demonstrate that leaf water in the growth chamber grasses should have experienced significant D-enriched due to transpiration. Nonetheless, we found no effect of transpirational D-enrichment on the δD_l values. In field samples, we saw clear evidence of enrichment (correlating with relative humidity of the field sites) in both δ¹⁸O_C and δD_l. These seemingly contrasting results could be explained if leaf waxes are synthesized in an environment that is isotopically similar to water entering plant roots due to either temporal or spatial isolation from evaporatively enriched leaf waters. For grasses in the controlled environment, there was no enrichment of source water, whereas enrichment of grass source water via evaporation from soils and/or stems was likely for grass samples grown in the field.Based on these results, evaporation from soils and/or stems appears to affect δD_l, but transpiration from leaves does not. Further evidence for this conclusion is found in modeling expected net evapotranspirational enrichment. A Craig-Gordon model applied to each of the field sites yields leaf water oxygen isotope ratios that can be used to accurately predict the observed δ¹⁸O_C values. In contrast, the calculated leaf water hydrogen isotope ratios are more enriched than what is required to predict observed δD_l values. These calculations lend support to the conclusion that while δ¹⁸O_C reflects both soil evaporation and transpiration, δD_l appears to only record evaporation from soils and/or stems. Therefore, the δD of n-alkanes can likely be used to reconstruct the δD of water entering a leaf, supporting the soil-enrichment model of Smith and Freeman (2006). In both the field and controlled studies, we found significant photosynthetic pathway effects on n-alkane δD suggesting that biochemical pathways or plant phylogeny have a greater effect on leaf wax δD than leaf-water enrichment in grasses.  相似文献   

Nitrogen uptake and primary productivity rates in the Mid-Atlantic Bight (MAB)     

Katherine C. Filippino  Margaret R. MulhollandPeter W. Bernhardt 《Estuarine, Coastal and Shelf Science》2011

Nutrient concentrations, primary productivity, and nitrogen uptake rates were measured in coastal waters of the Mid-Atlantic Bight over a two-year period that included measurements from all four seasons. In order to assess carbon productivity and nitrogen demand within the context of the physical environment, the region was divided into three distinct hydrographic regimes: the Chesapeake and Delaware Bay outflow plumes (PL), the southern Mid-Atlantic shelf influenced by the Gulf Stream (SS), and the mid-shelf area to the north of the Chesapeake Bay mouth (MS). Annual areal rates of total nitrogen (N) uptake were similar across all regions (10.9 ± 2.1 mol N m⁻² y⁻¹). However, annual areal rates of net primary productivity were higher in the outflow plume region (43 mol C m⁻² y⁻¹), than along the Mid-Atlantic shelf and in areas influenced by the Gulf Stream (41 and 34 mol C m⁻² y⁻¹, respectively). Rates of net primary productivity were not well correlated with Chl a concentrations and were uncoupled with net N uptake rates. Seasonally averaged annual areal rates of net primary productivity for the Mid-Atlantic Bight measured in this study were higher than those calculated in previous decades and provide important validation information for biogeochemical models and satellite remote sensing algorithms developed for the region.  相似文献