The temperature dependence of water solubility in enstatite   总被引：3，自引：0，他引：3  

Katrin?Mierdel  Hans?KepplerEmail author 《Contributions to Mineralogy and Petrology》2004,148(3):305-311

The solubility of water in pure enstatite was measured on samples synthesized under water-saturated conditions at 15 kbar and temperatures ranging from 700 to 1,100°C. Polarized FTIR measurements on millimetre-sized, clear crystals showed that water solubility increases strongly with temperature, from 101 ppm by weight at 700°C to 269 ppm by weight at 1,100°C. The position and shape of the infrared bands hardly changes with temperature, with one notable exception: a band close to 3,380 cm^–1 is present in samples synthesized between 700 and 1,000°C, while this band is absent from samples synthesized at 1,100°C. This effect appears to be very reproducible and points towards a slight change in the crystal structure of enstatite between 1,000 and 1,100°C at 15 kbar. The water solubility data of this study as well as those of Rauch and Keppler (Contrib Mineral Petrol 143:525–536, 2002) can be reproduced by the equation where K is water solubility, is water fugacity, A is 0.01354 ppm/bar, V^solid=12.1 cm³/mol is the volume change of enstatite during incorporation of water, and H^{1 bar}=-4,563 J/mol is the reaction enthalpy at 1 bar. This equation predicts the following behaviour of water solubility in enstatite as a function of pressure and temperature: (1) water solubility increases with pressure up to a maximum around 80 kbar; (2) water solubility decreases with temperature at 1 bar; and (3) water solubility increases with temperature between 10 and 100 kbar. If the observed temperature dependence for enstatite were representative for other upper mantle minerals as well, it would have the following implications: (1) Lateral temperature gradients in the upper mantle could cause major variations in water contents at the same depth; in particular, hot mantle plumes may scavenge water from the surrounding shallow upper mantle. (2) The scavenging of water by hot plumes could be a major factor in increasing the mobility of plumes. (3) The predicted temperature dependence of water solubility at the base of the upper mantle may allow plumes to bypass the transition zone water filter postulated by Bercovici and Karato (Nature 425:39–44, 2003).  相似文献   

Fossa Carolina: The First Attempt to Bridge the Central European Watershed—A Review,New Findings,and Geoarchaeological Challenges     

Eva Leitholdt  Christoph Zielhofer  Stefanie Berg‐Hobohm  Katharina Schnabl  Britta Kopecky‐Hermanns  Jens Bussmann  Joachim W. Hrtling  Klaus Reicherter  Katrin Unger 《Geoarchaeology》2012,27(1):88-104

The Central European watershed passes through the southern Franconian Jura in Bavaria, Germany. This principal watershed divides the Rhine/Main catchment and the Danube catchment. In the early Middle Ages, when ships were an important means of transportation, Charlemagne decided to connect these catchments by the construction of a canal known as the Fossa Carolina. In this paper, we present for the first time ¹⁴C data from the Fossa Carolina fill and document a high‐resolution stratigraphic record of the Carolingian and post‐Carolingian trench infilling. Our results provide clear evidence for peat layers in different levels of the trench infill, suggesting a chain of ponds. However, the majority of these peat layers yield mid‐Medieval and younger ages. The period of major peat growth was during the Medieval climatic optimum. Therefore, our preliminary results do not prove the use of the trench during Carolingian times. However, first results from the reconstruction of the Carolingian trench bottom support the hypothesis that the Fossa was primarily planned as a navigable chain of ponds and not as a continuous canal. In the eastern part of the trench, a dam is located that was postulated in former studies to be part of a barrage for supplying the Carolingian canal with water. New ¹⁴C data indicate much younger ages and do not support the Carolingian barrage concept.  相似文献   

Evaluation of Two Energy Balance Closure Parametrizations   总被引：1，自引：0，他引：1  

Fabian Eder  Frederik De Roo  Katrin Kohnert  Raymond L. Desjardins  Hans Peter Schmid  Matthias Mauder 《Boundary-Layer Meteorology》2014,151(2):195-219

A general lack of energy balance closure indicates that tower-based eddy-covariance (EC) measurements underestimate turbulent heat fluxes, which calls for robust correction schemes. Two parametrization approaches that can be found in the literature were tested using data from the Canadian Twin Otter research aircraft and from tower-based measurements of the German Terrestrial Environmental Observatories (TERENO) programme. Our analysis shows that the approach of Huang et al. (Boundary-Layer Meteorol 127:273–292, 2008), based on large-eddy simulation, is not applicable to typical near-surface flux measurements because it was developed for heights above the surface layer and over homogeneous terrain. The biggest shortcoming of this parametrization is that the grid resolution of the model was too coarse so that the surface layer, where EC measurements are usually made, is not properly resolved. The empirical approach of Panin and Bernhofer (Izvestiya Atmos Oceanic Phys 44:701–716, 2008) considers landscape-level roughness heterogeneities that induce secondary circulations and at least gives a qualitative estimate of the energy balance closure. However, it does not consider any feature of landscape-scale heterogeneity other than surface roughness, such as surface temperature, surface moisture or topography. The failures of both approaches might indicate that the influence of mesoscale structures is not a sufficient explanation for the energy balance closure problem. However, our analysis of different wind-direction sectors shows that the upwind landscape-scale heterogeneity indeed influences the energy balance closure determined from tower flux data. We also analyzed the aircraft measurements with respect to the partitioning of the “missing energy” between sensible and latent heat fluxes and we could confirm the assumption of scalar similarity only for Bowen ratios $\approx $ 1.  相似文献   

Palaeoclimate inferred from δ18O and palaeobotanical indicators in freshwater tufa of Lake Äntu Sinijärv,Estonia     

Liina Laumets  Volli Kalm  Anneli Poska  Sándor Kele  Katrin Lasberg  Leeli Amon 《Journal of Paleolimnology》2014,51(1):99-111

We investigated a 3.75-m-long lacustrine sediment record from Lake Äntu Sinijärv, northern Estonia, which has a modeled basal age >12,800 cal yr BP. Our multi-proxy approach focused on the stable oxygen isotope composition (δ¹⁸O) of freshwater tufa. Our new palaeoclimate information for the Eastern Baltic region, based on high-resolution δ¹⁸O data (219 samples), is supported by pollen and plant macrofossil data. Radiocarbon dates were used to develop a core chronology and estimate sedimentation rates. Freshwater tufa precipitation started ca. 10,700 cal yr BP, ca. 2,000 years later than suggested by previous studies on the same lake. Younger Dryas cooling is documented clearly in Lake Äntu Sinijärv sediments by abrupt appearance of diagnostic pollen (Betula nana, Dryas octopetala), highest mineral matter content in sediments (up to 90 %) and low values of δ¹⁸O (less than ?12 ‰). Globally recognized 9.3- and 8.2-ka cold events are weakly defined by negative shifts in δ¹⁸O values, to ?11.3 and ?11.7 ‰, respectively, and low concentrations of herb pollen and charcoal particles. The Holocene thermal maximum (HTM) is palaeobotanically well documented by the first appearance and establishment of nemoral thermophilous taxa and presence of water lilies requiring warm conditions. Isotope values show an increasing trend during the HTM, from ?11.5 to ?10.5 ‰. Relatively stable environmental conditions, represented by only a small-scale increase in δ¹⁸O (up to 1 ‰) and high pollen concentrations between 5,000 and 3,000 cal yr BP, were followed by a decrease in δ¹⁸O, reaching the most negative value (?12.7 ‰) recorded in the freshwater tufa ca. 900 cal yr BP.  相似文献   

Review of strength models for masonry spandrels     

Katrin Beyer  Sujith Mangalathu 《Bulletin of Earthquake Engineering》2013,11(2):521-542

Many older unreinforced masonry (URM) buildings feature timber floors and solid brick masonry. Simple equivalent frame models can help predicting the expected failure mechanism and estimating the strength of a URM wall. When modelling a URM wall with an equivalent frame model rather than, for example, a more detailed simplified micro-model, the strengths of the piers and spandrels need to be estimated from mechanical or empirical models. Such models are readily available for URM piers, which have been tested in many different configurations. On the contrary, only few models for spandrel strength have been developed. This paper reviews these models, discusses their merits, faults and compares the predicted strength values to the results of recent experimental tests on masonry spandrels. Based on this assessment, the paper outlines recommendations for a new set of strength equations for masonry spandrels.  相似文献   

High-resolution X-Band radar measurements of currents,bathymetry and sea state in highly inhomogeneous coastal areas   总被引：1，自引：1，他引：0  

Katrin Hessner  Konstanze Reichert  Jose Carlos Nieto Borge  Craig L. Stevens  Murray J. Smith 《Ocean Dynamics》2014,64(7):989-998

In this paper, high-resolution wave, current and water depth fields derived by marine X-Band radar are presented for a coastal region of extreme tidal currents in the presence of inhomogeneous bathymetry at the south coast of New Zealand’s North Island. The current and water depth information for the presented location covers an area of approximately 13 km² with a spatial resolution of 225 m and an update rate of 3 min. The sea state data provides a spatial representation of coastal effects like wave shoaling and refraction forced by bathymetry and current interaction. The near-surface current measurements about 3 km off the coast show expected tidal current pattern with maximum northwest/southeast current of 1.5–2 m/s alongshore. This is in agreement with currents from the RiCOM hydrodynamic model. The spatial resolution of the observed current field exhibits in addition small-scale current features caused by the influence of the local bathymetry. These data demonstrate the insight to be gained in complex, high-energy coastal situations through the use of high-resolution remote sensing techniques.  相似文献   

Economic costs of ocean acidification: a look into the impacts on global shellfish production     

Daiju Narita  Katrin Rehdanz  Richard S. J. Tol 《Climatic change》2012,113(3-4):1049-1063

Ocean acidification is increasingly recognized as a major global problem. Yet economic assessments of its effects are currently almost absent. Unlike most other marine organisms, mollusks, which have significant commercial value worldwide, have relatively solid scientific evidence of biological impact of acidification and allow us to make such an economic evaluation. By performing a partial-equilibrium analysis, we estimate global and regional economic costs of production loss of mollusks due to ocean acidification. Our results show that the costs for the world as a whole could be over 100 billion USD with an assumption of increasing demand of mollusks with expected income growths combined with a business-as-usual emission trend towards the year 2100. The major determinants of cost levels are the impacts on the Chinese production, which is dominant in the world, and the expected demand increase of mollusks in today’s developing countries, which include China, in accordance with their future income rise. Our results have direct implications for climate policy. Because the ocean acidifies faster than the atmosphere warms, the acidification effects on mollusks would raise the social cost of carbon more strongly than the estimated damage adds to the damage costs of climate change.  相似文献   

New Sediment Cores Reveal Environmental Changes Driven by Tectonic Processes at Ancient Helike,Greece     

Max Engel  Kirstin Jacobson  Katrin Boldt  Peter Frenzel  Dora Katsonopoulou  Steven Soter  Carlos A. Alvarez Zarikian  Helmut Brückner 《Geoarchaeology》2016,31(2):140-155

According to various historical sources an earthquake and an associated tsunami wiped out the Greek city of Helike on the Gulf of Corinth in 373 B.C. This study combines stratigraphical data from a new series of sediment cores with archaeological findings of the Helike Project to better assess the fate of Helike. Abrupt lithological changes, for example, from coarse‐grained littoral facies at the base to fine‐grained lagoonal deposits, in three of the new cores suggest sudden formation of lagoonal or lacustrine conditions in the central delta during tectonic events of subsidence due to fault‐slip. These events date before c. 2550 B.C., before 348 cal. B.C.–64 cal. A.D. (probably 373 B.C.), and before 1437–1634 cal. A.D. (probably A.D. 1402). Vertically displaced isochronic surfaces between two neighboring cores may be related to active faulting of the fan‐delta north of the Western Helike Fault Zone in 373 B.C. and A.D. 1402. Although the Helike Project reported possible tsunami evidence in earlier cores and trenches, no unequivocal sedimentary traces of a tsunami were identified in the Classical horizons of the new cores.  相似文献   

Effects of metallic system components on marine electromagnetic loop data     

Konstantin Reeck  Hendrik Müller  Sebastian Hölz  Amir Haroon  Katrin Schwalenberg  Marion Jegen 《Geophysical Prospecting》2020,68(7):2254-2270

Electromagnetic loop systems rely on the use of non-conductive materials near the sensor to minimize bias effects superimposed on measured data. For marine sensors, rigidity, compactness and ease of platform handling are essential. Thus, commonly a compromise between rigid, cost-effective and non-conductive materials (e.g. stainless steel versus fibreglass composites) needs to be found. For systems dedicated to controlled-source electromagnetic measurements, a spatial separation between critical system components and sensors may be feasible, whereas compact multi-sensor platforms, remotely operated vehicles and autonomous unmanned vehicles require the use of electrically conductive components near the sensor. While data analysis and geological interpretations benefit vastly from each added instrument and multidisciplinary approaches, this introduces a systematic and platform-immanent bias in the measured electromagnetic data. In this scope, we present two comparable case studies targeting loop-source electromagnetic applications in both time and frequency domains: the time-domain system trades the compact design for a clear separation of 15 m between an upper fibreglass frame, holding most critical titanium system components, and a lower frame with its coil and receivers. In case of the frequency-domain profiler, the compact and rigid design is achieved by a circular fibreglass platform, carrying the transmitting and receiving coils, as well as several titanium housings and instruments. In this study, we analyse and quantify the quasi-static influence of conductive objects on time- and frequency-domain coil systems by applying an analytically and experimentally verified 3D finite element model. Moreover, we present calibration and optimization procedures to minimize bias inherent in the measured data. The numerical experiments do not only show the significance of the bias on the inversion results, but also the efficiency of a system calibration against the analytically calculated response of a known environment. The remaining bias after calibration is a time/frequency-dependent function of seafloor conductivity, which doubles the commonly estimated noise floor from 1% to 2%, decreasing the sensitivity and resolution of the devices. By optimizing size and position of critical conductive system components (e.g. titanium housings) and/or modifying the transmitter/receiver geometry, we significantly reduce the effect of this residual bias on the inversion results as demonstrated by 3D modelling. These procedures motivate the opportunity to design dedicated, compact, low-bias platforms and provide a solution for autonomous and remotely steered designs by minimizing their effect on the sensitivity of the controlled-source electromagnetic sensor.  相似文献   

Effects of grain-size distribution and shape on sediment bed stability,near-bed flow and bed microstructure     

Franziska Staudt  Julia C. Mullarney  Conrad A. Pilditch  Katrin Huhn 《地球表面变化过程与地形》2019,44(5):1100-1116

Different studies investigating the stability of mixed sediment have found that the fine fraction can either stabilize or mobilize the bed. This study aims to find where the transition between these two modes occurs for sandy sediment and to identify the underlying (grain-scale) processes. Flume experiments with bimodal sediment were used to investigate near-bed processes of a non-cohesive sediment bed, and in particular how the grain shape and the ratio of different grain sizes influence bed mobility. Medium sand (D_50,c ≈ 400 μm) was mixed with 40 % fine material of different diameters (D_50,f = 53; 111; 193 μm) and subjected to increasing flow velocities (U = 1.3–22.2 cm s^-1). The bed mobility (i.e. the change of the bed level over time), turbidity and near-bed hydrodynamics were analysed. Selected results were compared with similar previous experiments with spherical glass beads. The findings indicate that, due to the complex grain shapes of natural sediment, a sand bed is more stable than a bed composed of glass beads. The grain-size ratio RD = D_c /D_f between the coarse and fine grain diameters controls whether the mixed bed is stabilized or mobilized by the presence of fines, with the transition between the modes occurring at RD = 4–5.5. Mixed beds with a very low RD < 2 behave like a unimodal bed. The results suggest that RD and grain shape influence bed roughness, near-bed flow, bed microstructure and the flow into and through the upper bed layers, which subsequently governs bed mobility. The interplay between all these processes can explain the transition between the stabilizing effect (high RD, small pore space) and the mobilizing effect (low RD, large pore space) of a fine fraction in a grain-size mixture. © 2018 John Wiley & Sons, Ltd.  相似文献