Chemical evidence for advection of hydrothermal solutions in the sediments of the Galapagos Mounds Hydrothermal Field     

Cynthia R.P. Maris  Michael L. Bender  Philip N. Froelich  Ross Barnes  Nile A. Luedtke 《Geochimica et cosmochimica acta》1984,48(11):2331-2346

Pore water profiles of Ca, Mg, F, PO₄^?3 and Mn in the Galapagos Mounds Hydrothermal Field are believed to reflect, in part, upwelling of hydrothermal solutions through the sediments. Concentration-depth profiles in a low heat flow area just north of the Mounds Field display diagenetic changes typical of those found in pore waters underlying highly productive surface waters, consistent with the inference of no water flow or very slow downwelling ($\text{w < 5}\text{cm/yr}$) of bottom water through these sediments. Rates of upward advection calculated from Mounds Field pore water profiles of Ca, Mg, and F profiles agree well with each other, averaging about 1 cm/yr in the pelagic sediments near the mounds and 15–30 cm/yr within the hydrothermal mounds themselves. The upward advection also modifies the shape of PO₄^?3 and Mn profiles.Advection rates inferred from the pore water data are generally in reasonable agreement with those made from heat flow data.The higher Ca and lower Mg, F, PO₄^?3 and Mn concentrations in Mounds Field pore waters (compared with those of the low heat flow area) suggest chemical exchange between the solution and basalt prior to upwelling. Li⁺, K⁺, Rb⁺, Sr⁺⁺ and SO₄^? concentrations are indistinguishable from bottom water. This suggests very high effective water/rock ratios during the reactions which produced the upwelling solutions, perhaps due to extensive prior alteration of basalt adjacent to the flow path of water through the crust Inferred reaction temperatures are between 70–150°C.  相似文献   

The effect of trapped liquid crystallization on cumulus mineral compositions in layered intrusions   总被引：24，自引：2，他引：24  

Stephen J. Barnes 《Contributions to Mineralogy and Petrology》1986,93(4):524-531

A series of calculations have been carried out to evaluate the effect on cumulus mineral compositions of solidification of trapped intercumulus liquid in orthocumulates. The calculation assumes local equilibrium between phases, and that the system remains chemically closed during crystallization of the trapped liquid. The latter assumption is held to be valid on a scale of tens to hundreds of centimeters. It is not necessary to know the composition of the trapped liquid, as the calculation only requires an estimate of FeO content and trapping temperature.The change in composition of a mineral from that of the initially precipitated cumulus crystals to the final composition after complete solidification is termed the trapped liquid shift. Its magnitude depends on the modal proportions of cumulus phases and the initial porosity, and is only weakly dependent on initial phase compositions. Trapped liquid shifts are significant when compared with mineral composition changes occurring during fractional crystallization. Crystallization of 30% trapped liquid gives rise to shifts of up to 10 mol. percent in Mg number of olivine or pyroxene. The size of the shift becomes greater when the initial cumulus assemblage has a lower total FeO+MgO content, and vice versa.As a result of the relationship between trapped liquid shift and cumulus mode, mineral composition variations and trends may be generated in sequences of cumulates which originally had constant compositions of cumulus minerals. For example, in a cyclic unit grading from a pyroxenitic base to an anorthositic top, crystallization of a uniform proportion of trapped liquid will result in an apparent iron enrichment trend from bottom to top of the cycle, as has been observed in the Upper Critical Zone of the Bushveld Complex.  相似文献   

The role of fluids in the metamorphism of komatiites,Agnew nickel deposit,western Australia     

Martin J. Gole  Stephen J. Barnes  Robin E. T. Hill 《Contributions to Mineralogy and Petrology》1987,96(2):151-162

The Agnew nickel sulfide deposit is spatially associated with a lenticular body of ultramafic rocks which shows a concentric zonation in metamorphic mineralogy. Olivine + tremolite + chlorite + cummingtonite ±enstatite assemblages occur at the margin of the ultramafic lens, giving way to olivine + anthophyllite, olivine + talc and olivine + antigorite assemblages successively inwards. These rocks are interpreted as having crystallized from komatiitic lavas, and exhibit a spectrum of compositions from those of original flow tops to pure olivine adcumulates. The relative modal abundances of metamorphic olivine, tremolite and chlorite reflect original proportions of cumulus olivine and komatiite liquid in the protolith. Peak metamorphic conditions are estimated at 550° C, based on garnet-biotite thermometry, at a maximum pressure of 3 kb. This temperature falls within the narrow range over which metamorphic olivine may co-exist with enstatite, anthophyllite, talc or antigorite depending upon the fugacity of water in the metamorphic fluid. The observed mineralogical zonation is therefore attributed to infiltration by CO₂-rich fluids, generated by decarbonation of talc-carbonate rocks formed during pre-metamorphic marginal alteration of the ultramafic lens. Metamorphic fluids were essentially binary mixtures of water and CO₂, with minor H₂S having a maximum partial pressure less than 1 percent of total pressure. Enstatite-bearing assemblages formed in the presence of CO₂-rich fluids at fluid: rock volume ratios close to one, while anthophyllite, talc and antigorite bearing assemblages formed in the presence of progressively more water-rich fluids at progressively lower fluid-rock ratios.  相似文献   

A comparative study of olivine and clinopyroxene spinifex flows from Alexo,abitibi greenstone Belt,Ontario, Canada     

Sarah-Jane Barnes  M. P. Gorton  A. J. Naldrett 《Contributions to Mineralogy and Petrology》1983,83(3-4):293-308

A petrological and geochemical study of an olivine and of a clinipyroxene spinifex textured flow, from Alexo, indicates that the initial liquid in both flows probably came from the same mantle melting event and that the source was incompatible element depleted. The starting liquid of the clinopyroxene flow had experienced more olivine fractionation (10%) prior to its emplacement at Alexo, than the initial liquid of the olivine spinifex flow. The development of each of the textural and compositional zones in the flows can be modelled by means of crystal fractionation. In the case of the clinopyroxene flow the B-zone is formed by the fractionation of olivine, low-Ca pyroxene and chromite. An unusual feature of the Alexo clinopyroxene flow is presence of a peridotitic komatiite above the pyroxene cumulate layer, where a basaltic komatiite would usually be present. The presence of the peridotitic komatiite suggests an influx of new magma and hence a dynamic model for the flow. The composition of the clinopyroxene spinifex zone represents a mixture of clinopyroxene plus liquid, rather than simply a frozen liquid. This could happen if the clinopyroxene needles grew stalactitelike from the chilled upper surface of the flow into a flowing basaltic liquid. In the olivine spinifex flow the zones can be modelled as frozen liquids in the A₂-zone, as initial liquid which has fractionated 30% olivine in the A₃-zone and as liquid plus 50% olivine in the B-zone. But, if the clinopyroxene spinifex developed by stalactite growth of clinopyroxene needles into the a flowing liquid, the possibility that the olivine spinifex represent fractionated liquid plus stalactite olivines arises.  相似文献   

Atmospheric and glow images from the Shuttle     

E. J. Llewellyn  I. C. McDade  M. R. Gale  D. J. W. Kendall  R. L. Gattinger  S. B. Mende  G. R. Swenson  W. S. C. Brooks 《Surveys in Geophysics》1987,9(2):149-168

The use of simple photographic cameras on early Shuttle missions allowed spacecraft glow to be clearly identified, and its potential for the contamination of weak atmospheric emissions to be estimated. Since those early flights the equipment has been extensively modified so that it is now possible to obtain images with a spectral resolution of 0.1 nm. The early Shuttle glow observations are reviewed and the use of spatially scanned filters to obtain spectral results is described. These glow measurements are discussed in terms of some current ideas for vehicle induced glows and it is suggested that the glow intensity may be controlled by the temperature of the glowing surface. An example of an atmospheric image obtained with the interference filter camera is presented and the limitations in the use of such images are discussed.  相似文献   

Metamorphic assemblages and the direction of flow of metamorphic fluids in four instances of serpentinization   总被引：3，自引：0，他引：3  

Ivan Barnes  John B. Rapp  James R. O'Neil  Richard A. Sheppard  Arthur J. Gude III 《Contributions to Mineralogy and Petrology》1972,35(3):263-276

Fluids related to Serpentinization are of at least three types. The first reported (Barnes and O'Neil, 1969) is a fluid of local meteoric origin, the chemical and thermodynamic properties of which are entirely controlled by olivine, orthopyroxene, brucite, and serpentine reactions. It is a Ca⁺²-OH^–1 type and is shown experimentally to be capable of reacting with albite to yield calcium hydroxy silicates. Rodingites may form where the Ca⁺²-OH^–1 type waters flow across the ultramafic contact and react with siliceous country rock.The second type of fluid has its chemical composition largely controlled before it enters the ultramafic rocks, but reactions within the ultramafic rocks fix the thermodynamic properties by reactions of orthopyroxene, olivine, calcite, brucite, and serpentine. The precipitation of brucite from this fluid clearly shows that fluid flow allows reaction products to be deposited at a distance from the point of solution. Thus, textural evidence for volume relations during Serpentinization may not be valid.The third type of fluid has its chemical properties fixed in part before the reactions with ultramafic rocks, in part by the reactions of orthopyroxene, olivine, and serpentine and in part by reactions with siliceous country rock at the contact. The reactions of the ultramafic rock and country rock with the fluid must be contemporaneous and require flow to be along the contact. This third type of fluid is grossly supersaturated with talc and tremolite, both found along the contact. The occurrence of magadiite, kenyaite, mountainite, and rhodesite along the contact is probably due to a late stage low-temperature reaction of fluids of the same thermodynamic properties as those that formed the talc and tremolite at higher temperatures. Oxygen isotope analyses of some of these minerals supports this conclusion.Rodingites form from Ca⁺²-rich fluids flowing across the contact; talc and tremolite form from silica-rich fluids flowing along the contact.Isotopic analyses of the fluids indicate varied origins including unaltered local meteoric water and connate water. Complexion Spring water may be a sample of only slightly altered Jurassic or Cretaceous sea water.Publication authorized by the Director, U.S. Geological Survey.  相似文献   

A composite geologic and seismic profile beneath the southern Rio Grande rift, New Mexico, based on xenolith mineralogy, temperature, and pressure     

J.M. Hamblock  C.L. Andronicos  K.C. Miller  C.G. Barnes  M-H. Ren  M.G. Averill  E.Y. Anthony 《Tectonophysics》2007,442(1-4):14-48

A complete understanding of the processes of crustal growth and recycling in the earth remains elusive, in part because data on rock composition at depth is scarce. Seismic velocities can provide additional information about lithospheric composition and structure, however, the relationship between velocity and rock type is not unique. The diverse xenolith suite from the Potrillo volcanic field in the southern Rio Grande rift, together with velocity models derived from reflection and refraction data in the area, offers an opportunity to place constraints on the composition of the crust and upper mantle from the surface to depths of  60 km. In this work, we calculate seismic velocities of crustal and mantle xenoliths using modal mineralogy, mineral compositions, pressure and temperature estimates, and elasticity data. The pressure, temperature, and velocity estimates from xenoliths are then combined with sonic logs and stratigraphy estimated from drill cores and surface geology to produce a geologic and velocity profile through the crust and upper mantle. Lower crustal xenoliths include garnet ± sillimanite granulite, two-pyroxene granulite, charnokite, and anorthosite. Metagabbro and amphibolite account for only a small fraction of the lower crustal xenoliths, suggesting that a basaltic underplate at the crust–mantle boundary is not present beneath the southern Rio Grande rift. Abundant mid-crustal felsic to mafic igneous xenoliths, however, suggest that plutonic rocks are common in the middle crust and were intraplated rather than underplated during the Cenozoic. Calculated velocities for garnet granulite are between  6.9 and 8.0 km/s, depending on garnet content. Granulites are strongly foliated and lineated and should be seismically anisotropic. These results suggest that velocities > 7.0 km/s and a layered structure, which are often attributed to underplated mafic rocks, can also be characteristic of alternating garnet-rich and garnet-poor metasedimentary rocks. Because the lower crust appears to be composed largely of metasedimentary granulite, which requires deep burial of upper crustal materials, we suggest the initial construction of the continental crust beneath the Potrillo volcanic field occurred by thickening of supracrustal material in the absence of large scale magmatic accretion. Mantle xenoliths include spinel lherzolite and harzburgite, dunite, and clinopyroxenite. Calculated P-wave velocities for peridotites range from 7.75 km/s to 7.89 km/s, with an average of 7.82 km/s. This velocity is in good agreement with refraction and reflection studies that report P_n velocities of 7.6–7.8 km/s throughout most of the Rio Grande rift. These calculations suggest that the low P_n velocities compared to average uppermost mantle are the result of relatively high temperatures and low pressures due to thin crust, as well as a fertile, Fe-rich, bulk upper mantle composition. Partial melt or metasomatic hydration of the mantle lithosphere are not needed to produce the observed P_n velocities.  相似文献   

Spatial discordance in fish,coral, and sponge assemblages across a Caribbean atoll reef gradient          下载免费PDF全文

Charles Acosta  Robin Barnes  Rebecca McClatchey 《Marine Ecology》2015,36(2):167-177

Certain biodiversity patterns on coral reefs are generally consistent but we still lack fundamental insight into how assemblages vary across spatially heterogeneous reef systems. We compared fish, coral, and sponge assemblages across a symmetrical physiographical gradient (windward forereef, lagoon patch reef, leeward forereef) of the Glover's Reef atoll, Belize. Species richness of fishes and corals was highest in the deep habitat (15 m) on the windward forereef. Sponges were diverse and abundant on both deep windward and leeward forereefs but not on the exposed shallow (5 m) windward forereef. Fish and benthic assemblages were relatively distinct in each reef zone, with the lagoon patch reef communities consisting of a combination of leeward and windward species. Nevertheless, there were no clear patterns in community similarity matrices of fish and benthic assemblages, suggesting that overall coral and sponge assemblages had weak or no direct association with patterns in fish assemblages. A closer examination of fish trophic groups indicated that planktivores and predators were predictably associated with depth, whereas herbivores were associated with shallow protected reefs. None was specifically associated with spatial location along the atoll gradient. These patterns of diversity distribution are important for identifying spatial conservation priorities. A Marine Protected Area (MPA) at Glover's Reef encompasses substantial windward forereef and patch reef habitats. A much lesser extent of protection is afforded the leeward forereef that supports faunal assemblages that are unique and productive, if not as diverse as the windward forereef. Isolated coral atolls can serve as ideal systems to study spatial heterogeneity and biodiversity patterns, but more experimental studies are needed to reveal the mechanistic processes underlying these patterns.  相似文献   

The Helioseismic and Magnetic Imager (HMI) Vector Magnetic Field Pipeline: Optimization of the Spectral Line Inversion Code     

R. Centeno  J. Schou  K. Hayashi  A. Norton  J. T. Hoeksema  Y. Liu  K. D. Leka  G. Barnes 《Solar physics》2014,289(9):3531-3547

The Very Fast Inversion of the Stokes Vector (VFISV) is a Milne–Eddington spectral line inversion code used to determine the magnetic and thermodynamic parameters of the solar photosphere from observations of the Stokes vector in the 6173 Å Fe i line by the Helioseismic and Magnetic Imager (HMI) onboard the Solar Dynamics Observatory (SDO). We report on the modifications made to the original VFISV inversion code in order to optimize its operation within the HMI data pipeline and provide the smoothest solution in active regions. The changes either sped up the computation or reduced the frequency with which the algorithm failed to converge to a satisfactory solution. Additionally, coding bugs which were detected and fixed in the original VFISV release are reported here.  相似文献   

Emerging transitions in organic waste infrastructure in Aotearoa New Zealand     

Gradon Diprose  Kelly Dombroski  Emma Sharp  Amanda Yates  Bailey Peryman  Martine Barnes 《New Zealand geographer》2023,79(1):15-26

Aotearoa New Zealand is at a critical juncture in reducing and managing organic waste. Research has highlighted the significant proportion of organic waste sent to landfills and associated adverse effects such as greenhouse gas emissions and loss of valuable organic matter. There is current debate about what practices and infrastructure to invest in to better manage and use organic waste. We highlight the diversity of existing organic waste practices and infrastructures, focusing on Auckland, Wellington and Christchurch. We show how debates about organic waste practices and infrastructure connect across three themes: waste subjectivities, collective action in place and language.  相似文献