The geochemistry of volatile species in melt inclusions and sulfide minerals from Izu-Oshima volcano, Japan     

Kei Ikehata  Atsushi Yasuda  Kenji Notsu 《Mineralogy and Petrology》2010,99(1-2):143-152

Olivine-hosted melt inclusions in the O95 pyroclastic layer of Izu-Oshima volcano, Japan are basaltic to basaltic-andesitic in composition. The negative correlation between SiO₂ and H₂O in melt inclusions and reverse compositional zoning observed in olivine and other mineral phenocrysts is inferred to arise from mixing between a highly evolved and a less evolved magma. The latter is characterized by the highest S (0.15 wt.%) and H₂O (3.4 wt.%) concentrations among those described in reports of previous studies. The S⁶⁺/S_total ratios in melt inclusions were 0.64?–?0.73, suggesting a relatively high oxidation state (NNO + 0.87 at 1150°C). The presence of pyrrhotites, which are found only in titanomagnetite microlites, suggests that sulfide saturation occurred during microlite growth under at a sulfur fugacity (log fS₂) value of around + 0.5 for T = 1060°C. The groundmass glass compositions are more evolved (andesitic composition) than any melt inclusions containing high amounts of Cl (0.13 wt.%) but negligible H₂O (0.20 wt.%) and S (< 70 ppm), suggesting that Cl was retained in the magma, in contrast to S and H₂O, which degassed strongly during magma effusion.  相似文献   

Effect of the variation in the lower tropospheric temperature on the wind onset of the Indian summer monsoon     

Kenji Taniguchi  Devraj Rajan  Toshio Koike 《Meteorology and Atmospheric Physics》2010,106(1-2):75-94

There is a large thermal contrast between the Arabian Peninsula and India (Δθ _AI) at the mature stage of the Indian summer monsoon (ISM). The forming process of Δθ _AI is investigated analyzing various datasets. It forms earlier in the lower troposphere than in the middle and upper layers. The potential temperature in the lower troposphere over the west coast of India (θ _IW) abruptly decreases in advance of the rapid enhancement of the westerly wind over the Arabian Sea corresponding to the ISM onset. Such a process was observed for all the target years and the rapid decrease in θ _IW could trigger the ISM onset. The decrease in θ _IW had two patterns. In one case, cooler air is brought by the strong winds around a cyclone over the Arabian Sea. In another case, θ _IW decreases gradually by a synergy of a southwesterly wind over the Arabian Sea and the enlargement of Δθ _AI.  相似文献   

Isotopic evidence for trapped fissiogenic REE and nucleogenic Pu in apatite and Pb evolution at the Oklo natural reactor     

Kenji Horie  François Gauthier-Lafaye 《Geochimica et cosmochimica acta》2004,68(1):115-125

A part of the boundary layer of reactor zone 10 at the Oklo natural reactor shows a unique petrologic texture, which contains high-grade uraninite and massive apatite concretions. In order to study distribution behavior of fission products around the boundary between the reactor zone and the wall rock and to clarify the relation of migration mechanisms of fission products with geochemical factors, in-situ isotopic analyses of Nd, Sm, Gd, Pb and U in uraninite and apatite from the sample were performed by Sensitive High Resolution Ion Microprobe (SHRIMP). Sm and Gd isotopic ratios of uraninite and apatite show evidence of neutron irradiation with fluence between 4.4-6.8×10¹⁹ n/cm². Judging from the isotopic anomalies of Nd and U, the apatite coexisting with the uraninite plays an important role in trapping fissiogenic LREE and nucleogenic ²³⁹Pu into the structure. Systematic Pb isotopic data from apatite, uraninite, galena and minium suggest the following chronological interpretations.

1.

The apatite formed 1.92±0.01 Ga ago and trapped fissiogenic light REE and nucleogenic ²³⁹Pu that migrated from the reactor during the criticality.

2.

The uraninite around the boundary between reactor and sandstone dissolved once 1.1∼1.2 Ga ago.

3.

Galena grains were formed by U-Pb mobilization in association with the intrusion of dolerite dyke 0.45∼0.83 Ga ago.

4.

Minium was derived from recent dissolution of galena under locally oxidizing conditions.

  相似文献   

Impacts by heavy-oil spill from the Russian tanker Nakhodka on intertidal ecosystems: recovery of animal community     

Yamamoto T  Nakaoka M  Komatsu T  Kawai H;Marine Life Research Group of Takeno  Ohwada K 《Marine pollution bulletin》2003,47(1-6):91-98

The impact of a heavy-oil spill from the Nakhodka on an intertidal animal community, and the recovery process of animals from the damage were surveyed from the autumn of 1997 to the spring of 2001. The field study was carried out in the rocky coast of Imago-Ura Cove, located along the Sea of Japan, where clean-up operations for oil pollution had been conducted less intensely than in other polluted areas. We have examined individual number of each animal taxon by continuously placing a quadrat of 5 m width along the entire intertidal zone of the cove. A total of 76 invertebrate taxa including 57 species of mollusks, 10 species of crustaceans were observed during the survey. The number of taxa increased from 1998 to 1999 in areas where the initial oil pollution was intense. Total individual number of benthic animals continued to increase from 1998 to 2000 in the polluted areas. The impact of oil on benthic animals was different from species to species. Some species such as Cellana toreuma and Monodonta labio confusa increased rapidly after the oil spill, whereas other species such as Patelloida saccharina lanx and Septifer virgatus did not show any apparent temporal tendencies. Population size structure of P. saccharina lanx varied greatly among years, however that of M. labio confusa did not. For P. saccharina lanx, recruitment was unsuccessful in 1997, possibly due to the effect of oil pollution. These differences in responses to oil pollution among benthic animals are considered to be caused by the differences in habitat use, susceptibility to heavy-oil, life history and migration ability. The findings suggest that it took at least 2-3 years for the intertidal animal community to recover to its original level after the oil spill.  相似文献   

Integrated description of deformation modes in a sedimentary basin: A case study around a shallow drilling site in the Mizunami area, eastern part of southwest Japan     

Yasuto  Itoh  Kenji  Amano Naoki  Kumazaki 《Island Arc》2006,15(1):165-177

Abstract   Tectonic episodes in a sedimentary basin are described on the basis of an integrated study combining reflection seismic interpretation, drilling survey and paleomagnetism. A shallow inclined borehole penetrated a fault shown by reflection seismic and geological surveys in the Mizunami area, in the eastern part of southwest Japan. Paleomagnetic measurements were carried out on core samples successfully oriented using side-wall image logging of structural attitude. At six horizons, stable characteristic remanent magnetization (ChRM) was confirmed through thermal and alternating field demagnetization tests, which were carried by magnetite with minor amounts of high coercivity minerals, as revealed by experiments of stepwise acquisition of isothermal remanent magnetization. After correction of multiphase deformation inferred from borehole structural analysis, ChRM directions were combined with previous data and confirmed an easterly deflection reflecting the coherent clockwise rotation of the arc before the Middle Miocene. Compilation of reliable paleomagnetic data described differential rotation of the eastern part of southwest Japan raised by collision of the Izu–Bonin Arc since the Middle Miocene. The present study suggests that (i) the Mizunami area is adjacent to a highly deformed zone bounded by the Akaishi Tectonic Line (ATL), and (ii) forearc deformation of southwest Japan is localized around the ATL, which is quite different from gradual bending on the back-arc side without remarkable crustal break related to the collision event.  相似文献   

热液合成板状高结晶度三八面体蒙脱石     

Hirohisa YAMADA  Kenji TAMURA  Shingo YOKOYAMA  Yujiro WATANABE 《地质学报》2006,80(4):616

在热液条件下合成了板状的和高度结晶的三八面体蒙脱石。用淬冷玻璃与脱水的钠基蒙脱石分别在(a)500°C,100MPa下1天和11天;(b)300°C,100MPa下7天的条件下进行反应。产物的结晶度和颗粒大小取决于初始玻璃的化学组成,合成温度和热液改性的时间。XRD尖锐的峰和一定相对湿度下水合作用证明了产物结构的高度有序和大尺寸。透射电镜也被用来表征产物颗粒尺寸。通过改变初始材料的化学成分,产物的颗粒大小可以在10nm到几个微米之间变化。有序度最高和尺寸最大的产物是在500°C,100MPa的条件下用Na0.33(Mg1.83Al0.67)Si4O11成分的玻璃反应…  相似文献   

Ion Chromatographic Determination of Fluorine and Chlorine in Silicate Rocks Following Alkaline Fusion     

Kenji Shimizu  Takaaki Itai  Minoru Kusakabe 《Geostandards and Geoanalytical Research》2006,30(2):121-129

A simple and accurate method to determine fluorine and chlorine contents in small amounts (∼ 30 mg) in rock has been developed using ion chromatography after extraction by alkaline fusion. Powdered sample was mixed with sodium carbonate and zinc oxide at a mass ratio of 1:3:1, and was fused in an electric furnace at 900 °C for 30-40 minutes. An aqueous solution obtained by dissolving the fused silicate rock was diluted to the appropriate concentration of sodium carbonate (< ∼ 24 mmol l^-1) to minimise the tailing effect on F^- during ion chromatography caused by the large amount of carbonate species originating from the flux. Fluorine and chlorine contents were then determined by a standard additions method. Based on the relative standard deviation of the backgrounds, detection limits of both fluorine and chlorine were ∼ 4 μg g^-1, when 30 mg test portions were fused and diluted by a factor of 1200. We also report new fluorine and chlorine contents in nine GSJ (Geological Survey of Japan) reference materials, including peridotite (JP-1), granite (JG-1a), basalts (JB-1b, 2 and 3), andesites (JA-1 and 2) and rhyolites (JR-1 and 2). Fluorine and chlorine contents in the reference materials in this study were consistent with previously reported values. Reproducibilities were < 10 % for samples with F and Cl concentrations of > 20 μg g-1 and < 20 % with F and Cl < 20 μg g^-1.  相似文献   

Magma mixing recorded in intermediate rocks associated with high-Mg andesites from the Setouchi volcanic belt, Japan: implications for Archean TTG formation   总被引：6，自引：0，他引：6  

Hiroshi Kawabata  Kenji Shuto 《Journal of Volcanology and Geothermal Research》2005,140(4):241-271

Calc-alkaline intermediate rocks are spatially and temporally associated with high-Mg andesites (HMAs, Mg#>60) in Middle Miocene Setouchi volcanic belt. The calc-alkaline rocks are characterized by higher Mg# (strongly calc-alkaline trend) than ordinary calc-alkaline rocks at equivalent silica contents. Phenocrysts in the intermediate rocks have petrographical features such as: (1) coexisting reversely and normally zoned orthopyroxene phenocrysts in single rock; (2) sieve type plagioclase in which cores are mantled by higher An%, melt inclusion-rich zone; and (3) reversely zoned amphibole phenocrysts with opacite cores. In addition, mingling textures and magmatic inclusions were observed in some rocks. These petrographic features and the mineral chemistry indicate that magma mixing was the most important process in producing the strongly calc-alkaline rocks. The core composition of normally zoned orthopyroxene phenocrysts and the mantle composition of reversely zoned orthopyroxene phenocrysts have relatively high Mg# (85–90) in maximum. Although basaltic and high-Mg andesitic magmas are candidate as possible mafic end-member magmas, basaltic magma is excluded in terms of phenocryst assemblage and bulk composition. HMA magmas are suitable mafic end-member magmas that precipitated high Mg# (90) orthopyroxene, whereas andesitic to dacitic magma are suitable felsic end-members. In contrast, it is difficult to produce the strongly calc-alkaline trend through fractional crystallization from a HMA magma, because it would require removal of plagioclase together with mafic minerals from the early stage of crystallization, whereas the precipitation of plagiolase is suppressed due to the high water content of HMA magmas. These results imply that Archean Mg#-rich TTGs (>45–55), which are an analog of the strongly calc-alkaline rocks in terms of chemistry and magma genesis, can be derived from magma mixing in which a HMA magma is the mafic end-member magma, rather than by fractional crystallization from a HMA magma.  相似文献   

Evaluation of tsunami impacts on shallow marine sediments: An example from the tsunami caused by the 2003 Tokachi-oki earthquake, northern Japan     

Atsushi Noda  Hajime Katayama  Tsumoru Sagayama  Kazuya Suga  Yasuhito Uchida  Kenji Satake  Kohei Abe  Yukinobu Okamura 《Sedimentary Geology》2007,200(3-4):314-327

A combined approach of field geology and numerical simulation was conducted for evaluating the tsunami impacts on the shelf sediments. The 2003 Tokachi-oki earthquake, M 8.0, that occurred on 25 September 2003 off southeastern Hokkaido, northern Japan, generated a locally destructive tsunami. Maximum run-up height of the tsunami waves reached 4 m above sea level. In order to estimate the tsunami impacts on shallow marine sediments, we compared pre- and post-tsunami marine sediments in water depths of 38–112 m in terms of grain size, sedimentary structure, and microfossil content. Decreases of fine fractions, especially finer than very fine sand, which led to coarsen the mean grain size, were detected in the inner shelf of the northern part of the study area. Foraminiferal assemblages also changed in the coarsened sediments. On the other hand, the other shelf sediments largely unchanged or slightly fined. We also simulated the tsunami wave velocity and direction, and grain size entrained by the modeled tsunami. The numerical simulation resulted in that the 2003 tsunami could transport very fine sand in water depths shallower than 45–95 m at the northern part of the study area. This is comparable with the actual grain-size changes after the tsunami had passed. However, some storms and tidal currents might also be possible to stir the surface sediments after the pre-tsunami survey, so we could not conclude that the grain-size changes had been caused only by the tsunami. Nevertheless, a combined approach of sampling and modeling was powerful for estimating the tsunami impacts under the sea.  相似文献   

Influence of climate fluctuation on clay formation in the Baikal drainage basin     

Takayuki?SakaiEmail author  Koji?Minoura  Mitsuyuki?Soma  Yukinori?Tani  Atsushi?Tanaka  Fumiko?Nara  Nobuyasu?Itoh  Takayoshi?Kawai 《Journal of Paleolimnology》2005,33(1):105-121

Sedimentary cores BDP 96 and 98 and VER 96-2 St. 3 from Academician Ridge in Lake Baikal were investigated to investigate the effect of climatic fluctuations on rock weathering and clay formation in the Baikal drainage basin. Illite, smectite, vermiculite, and kaolinite were identified as the major clay minerals in the sediments by X-ray diffraction analysis. Biotite in gravels in alluvial soils of the Baikal drainage area weathers through illite to vermiculite, smectite, and finally to kaolinite. To investigate the relationship between weathering and climate, we measured the clay content and the concentration of biogenic silica in the sediments. High surface productivity (increased biogenic silica) and high chemical weathering (decreased clay content) occurred simultaneously, showing that crustal weathering and soil formation were enhanced under warm climatic conditions.Clay formation was enhanced in the watershed from the Late Miocene to the Middle Pliocene, and mechanical weathering of rocks increased during glacial intervals after the climate began to cool in Late Pliocene time. This change in the weathering mode in the watershed reduced the nutrient flux and aquatic productivity of Lake Baikal.  相似文献