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101.
Samples of the deep crust and upper mantle in the Northern Andes occur as abundant xenoliths in the Granatífera Tuff, a late Cenozoic vent in the Mercaderes area of SW Colombia. The lower crustal assemblage includes granulites, hornblendites, pyribolites, pyroxenites and gneisses; mafic rocks predominate, but felsic material is also common. PT conditions for the pyribolite assemblages (i.e. Hbl+Fs/Scp+Grt+Cpx+Qtz±Bt), which are the best constrained, are 720–850 °C and 10–14 kbar, consistent with a deep-to-lower crustal origin. A notable feature of this xenolith suite is that it is dominated by hornblende. However, mineral reactions within the suite show that there is a transition from amphibolite to granulite facies, and there is a probable restite–melt relationship represented within the suite. However, the latter appears to be dominated by hornblende and garnet.The mafic rocks mostly lack the high Cr and Ni that would be expected of cumulates. Neither do they possess the positive Sr and Eu anomalies that would be consistent with resite or cumulate models for the lower crust. They bear greatest similarity to oceanic basalts (s.l.). The Rb contents of the xenoliths, whether mafic or silicic, are very low, and the more silicic members of the suite tend to have small positive Sr and Eu anomalies, which are transitional to adakitic compositions. The Sr isotopic compositions of the xenoliths lie between 0.704 and 0.705; however, the Nd isotopic compositions are much more variable, indicating considerable long-term heterogeneity. Few of the xenoliths can be compositionally recognised as metasedimentary; however, a sedimentary component is evident in the Pb isotopic compositions. Within these constraints, our favoured model is a deep crust formed by basaltic components (subduction–accretion?), and minor sediment, which is subject to an increase in thermal gradient to produce the granulites, any melting being dominated by hornblende-out reactions involving garnet. However, there is no evidence of any pervasive crustal melting, leading to the conclusion that the voluminous Andean magmatism arises from the mantle wedge.  相似文献   
102.
During the summer of 1989 surface sediment samples were collected in Lake Coeur d'Alene, the Coeur d'Alene River and the St Joe River, Idaho, at a density of approximately one sample per square kilometre. Additional samples were collected from the banks of the South Fork of the Coeur d'Alene and the Coeur d'Alene Rivers in 1991. All the samples were collected to determine trace element concentrations, partitioning and distribution patterns, and to relate them to mining, mining related and discharge operations that have occurred in the Coeur d'Alene district since the 1880s, some of which are ongoing. Most of the surface sediments in Lake Coeur d'Alene north of Conkling Point and Carey Bay are substantially enriched in Ag, As, Cu, Cd, Hg, Pb, Sb and Zn relative to unaffected sediments in the southern portion of the lake near the St Joe River. All the trace element enriched sediments are extremely fine grained (mean grain sizes « 63 μm). Most of the enriched trace elements, based on both the chemical analyses of separated heavy and light mineral fractions and a two step sequential extraction procedure, are associated with an operationally defined Fe oxide phase; much smaller percentages are associated either with operationally defined organics/sulphides or refractory phases. The presence, concentration and distribution of the Fe oxides and heavy minerals indicates that a substantial portion of the enriched trace elements are probably coming from the Coeur d'Alene River, which is serving as a point source. Within the lake, this relatively simple point source pattern is complicated by a combination of (1) the formation of trace element rich authigenic Fe oxides that appear to have reprecipitated from material solubilized from anoxic bed sediments and (2) physical remobilization by currents and wind driven waves. The processes that have caused the trace element enrichment in the surface sediments of Lake Coeur d'Alene are likely to continue for the foreseeable future.  相似文献   
103.
104.
Along the lower reaches of the Waipaoa River, New Zealand, cross‐section survey data indicate there was a 23 per cent decrease in bankfull width and a 22 per cent reduction in channel cross‐section area between 1948 and 2000, as the channel responded to increased inputs of fine (suspended) sediment following deforestation of the headwaters in late C19 and early C20. We determined the bankfull discharge within a ~39 km long reach by routing known discharges through the one‐dimensional MIKE 11 flow model. The model runs suggest that the bankfull discharge varies between ~800 and ~2300 m3 s?1 and that the average recurrence interval is 4 ± 2 years on the annual maximum series; by contrast, the effective flow (360 m3 s?1) is equaled or exceeded three times a year. The variability in bankfull discharge arises because the banks tend to be lower in places where flood flows are constricted than in reaches where overbank flow is dispersed over a wide area, and because scour has counteracted aggradation in some locations. There is no downstream variation in Shields stress, or in relative shear stress, within the study reach. Bankfull shear stress is, on average, five times greater than the shear stress required to initiate motion. At the effective discharge it is more than twice the threshold value. The effective discharge probably has more relevance than the bankfull discharge to the overall picture of sediment movement in the lower reaches of the Waipaoa River but, because width is constrained by the stability and resistance of the bank material to erosion during high flows that also scour the bed, the overall channel geometry is likely determined by discharges at or near bankfull. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
105.
106.
This paper considers the ground trace of an artificial earth satellite. It determines the effects of the trace caused by perturbations due to atmospheric drag, the oblateness of the earth, and the moon and the sun as a third body.The necessary mathematical relations giving these perturbations which are available in literature are utilized (Betz, 1967; Brouwer and Clemence, 1961; Brouwer and Hori, 1961; Danby, 1962; Escobal, 1965; Kentet al., 1963; Kozai, 1962). Those relations unavailable elsewhere are derived.The computation was done by programming in FORTRAN language and utilizing an IBM 360/65.Captain, USAF  相似文献   
107.
Benthic exchange of nutrients in Galveston Bay, Texas   总被引:4,自引:0,他引:4  
Nutrient regeneration rates were determined at three sites increasing in distance from the Trinity River, the main freshwater input source, to Galveston Bay, Texas, from 1994 through 1996. Diffusive fluxes generally agreed in direction with directly measured benthic fluxes but underestimated the exchange of nutrients across the sediment-water interface. While the fluxes of ammonium and phosphate were directed from the sediment into the overlying waters, the fluxes of silicate and chloride changed in both magnitude and direction in response to changing Trinity River flow conditions. Oxygen fluxes showed benthic production during both summer 1995 and winter 1996, while light-dark deployments showed production-consumption, respectively. Benthic inputs of nutrients were higher at either the middle or outer Trinity Bay regions, most likely due to a higher quality and quantity of the autochthonous organic matter deposited. This feature is consistent with and gives evidence for previously observed non-conservative mixing behaviors reported for nutrients in this region of Galveston Bay. Calculated turnover times, between 7 to 135 d for phosphate, 4 to 56 d for silicate, and 0.3 to 10 d for ammonium were significantly shorter than the average Trinity Bay water residence time of 1.5 yr for the period September 1995 through October 1996. During periods of decreased Trinity River flow and increased residence times, benthic inputs of ammonium and phosphate were 1 to 2 orders of magnitude greater than Trinity River inputs and were the dominant input source of these nutrients to Trinity Bay. The sediments, a sink for silicate when overlying water column concentrations of silicate were elevated, became a source of silicate to the overlying waters of Trinity Bay under reduced flow, high salinity conditions.  相似文献   
108.
A fluorescence-based chemistry has been developed for the detection of nitrite and nitrate (as excess nitrite following reduction of nitrate to nitrite). Detection limits are 4.6 and 6.9 nM, respectively. The technique capitalizes on the triple bond between the two nitrogen atoms within the diazonium ion formed via the well-known reaction between an acidified nitrite sample and an aromatic primary amine. Fluorescence of π-electrons within this bond allows this reaction to be probed with standard fluorescence spectroscopy. Reverse Flow Injection Analysis (rFIA) is used to correct for background fluorescence from leachates and naturally occurring dissolved organic matter (DOM). Comparisons of samples analyzed for nitrite with this technique and with a highly-sensitive chemiluminescent method [Braman, R.S., Hendrix, S.A., 1989. Nanogram nitrite and nitrate determination in environmental and biological materials by vanadium (III) reduction with chemiluminescence detection. Analytical Chemistry, 61 (24) 2716–2718] showed excellent agreement between the two methods (slope=0.9996 and r2=0.9956). These fluorescent nitrite and nitrate + nitrite chemistries were coupled in a sensor package with a modified version of a fluorescent ammonia chemistry [Jones, R.D., 1991. An improved fluorescence method for the determination of nanomolar concentrations of ammonia in natural waters, Limnology and Oceanography. 36(4) 814–819], which also has a nanomolar detection limit. The throughput rate of the fully automated three-channel instrumentation is 18 samples per hour. A field experiment demonstrated the capability of the nutrient sensor package to determine horizontal gradients in nitrate, nitrite, and ammonia in oligotrophic surface waters.  相似文献   
109.
110.
Based upon our characterization of three separate stones by electron and X‐ray beam analyses, computed X‐ray microtomography, Raman microspectrometry, and visible‐IR spectrometry, Sutter's Mill is a unique regolith breccia consisting mainly of various CM lithologies. Most samples resemble existing available CM2 chondrites, consisting of chondrules and calcium‐aluminum‐rich inclusion (CAI) set within phyllosilicate‐dominated matrix (mainly serpentine), pyrrhotite, pentlandite, tochilinite, and variable amounts of Ca‐Mg‐Fe carbonates. Some lithologies have witnessed sufficient thermal metamorphism to transform phyllosilicates into fine‐grained olivine, tochilinite into troilite, and destroy carbonates. One finely comminuted lithology contains xenolithic materials (enstatite, Fe‐Cr phosphides) suggesting impact of a reduced asteroid (E or M class) onto the main Sutter's Mill parent asteroid, which was probably a C class asteroid. One can use Sutter's Mill to help predict what will be found on the surfaces of C class asteroids such as Ceres and the target asteroids of the OSIRIS‐REx and Hayabusa 2 sample return missions (which will visit predominantly primitive asteroids). C class asteroid regolith may well contain a mixture of hydrated and thermally dehydrated indigenous materials as well as a significant admixture of exogenous material would be essential to the successful interpretation of mineralogical and bulk compositional data.  相似文献   
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