The 1.4–22.4 Å range of the soft X-ray spectrum includes a multitude of emission lines which are important for the diagnosis of plasmas in the 1.5–50 million degree temperature range. In particular, the hydrogen and helium-like ions of all abundant solar elements with Z > 7 have their primary transitions in this region and these are especially useful for solar flare and active region studies. The soft X-ray polychromator (XRP) is a high resolution experiment working in this spectral region. The XRP consists of two instruments with a common control, data handling and power system. The bent crystal spectrometer is designed for high time resolution studies in lines of Fe i-Fe xxvi and Ca xix. The flat crystal scanning spectrometer provides for 7 channel polychromatic mapping of flares and active regions in the resonance lines of O viii, Ne ix, Mg xi, Si xiii, S xv, Ca xix, and Fe xxv with 14 spatial resolution. In its spectral scanning mode it covers essentially the entire 1.4–22.5 Å region.This paper summarizes the scientific objectives of the XRP experiment and describes the characteristics and capabilities of the two instruments. Sufficient technical information for experiment feasibility studies is included and the resources and procedures planned for the use of the XRP within the context of the Solar Maximum Mission is briefly discussed. 相似文献
234Th/238U disequilibria have been used extensively in studies of particle dynamics and the fate and transport of particle-reactive matter in marine environments. Similar work in low salinity, estuarine, and freshwater systems has not occurred primarily because the lower concentrations of both parent and daughter nuclides that are typical of these systems often render established methods for the analysis of 234Th inadequate. The application of this radionuclide tracer technique to these systems, however, has great potential. To this end, we present a method for measuring low activities of 234Th in relatively small samples (<200 l) using low background gas-flow proportional counters, a 229Th yield monitor, and empirical corrections for the interferences from real and apparent betas that are emitted by other thorium isotopes and their progeny. For samples with low 234Th/228Th activity ratios, we improve upon current beta counting methodologies that rely on immediate sample counting, weak beta absorption, or multiple beta counts so that, using the analytical approach outlined here, it should be possible to measure 234Th activities (i) as low as 1.5 dpm/total sample, (ii) up to 2 weeks after radiochemical purification of thorium, and (iii) with only one sample count for alpha and beta activity. 相似文献
Palaeozoic intrusive rocks of the New England Batholith from the Rockvale district in the southern New England Orogen form three distinct associations: (i) the Carboniferous Rockvale Adamellite, a member of the Hillgrove Suite of deformed S‐type granitoids; (ii) a small I‐type igneous complex on the northwestern margin of the Rockvale Adamellite: several members of this complex have similar chemical compositions to the most mafic members of the Moonbi Suite of New England Batholith I‐types; and (iii) a suite of dyke rocks ranging in composition from calc‐alkaline lamprophyre through hornblende and biotite porphyrite to aplite. Ion‐microprobe U‐Pb zircon analysis indicates intrusion of the Rockvale Adamellite at 303 ±3 Ma (weighted mean 206Pb/238U age; 95% confidence limits). Preliminary investigation of zircon inheritance within the Rockvale Adamellite is consistent with chemical and isotopic indications of derivation of New England Batholith S‐type granitoids from a relatively juvenile protolith. Deformation of the Rockvale Adamellite occurred after complete crystallization of the pluton and prior to emplacement of dykes and I‐type intrusives. K‐Ar biotite and hornblende ages show broadly synchronous intrusion of I‐type magmas and lamprophyre dykes at ca 255 Ma, indicating that mantle magmatism associated with lamprophyres was contemporaneous with the crustal production of I‐type melts. Chemical similarities between the most mafic Moonbi Suite members and calc‐alkaline lamprophyres may also indicate a direct mantle contribution to some I‐type magmas. 相似文献
The fate of arsenic in groundwater depends largely on its interaction with mineral surfaces. We investigated the kinetics of As(III) oxidation by aquifer materials collected from the USGS research site at Cape Cod, MA, USA, by conducting laboratory experiments. Five different solid samples with similar specific surface areas (0.6-0.9 m2 g−1) and reductively extractable iron contents (18-26 μmol m−2), but with varying total manganese contents (0.5-3.5 μmol m−2) were used. Both dissolved and adsorbed As(III) and As(V) concentrations were measured with time up to 250 h. The As(III) removal rate from solution increased with increasing solid manganese content, suggesting that manganese oxide is responsible for the oxidation of As(III). Under all conditions, dissolved As(V) concentrations were very low. A quantitative model was developed to simulate the extent and kinetics of arsenic transformation by aquifer materials. The model included: (1) reversible rate-limited adsorption of As(III) onto both oxidative and non-oxidative (adsorptive) sites, (2) irreversible rate-limited oxidation of As(III), and (3) equilibrium adsorption of As(V) onto adsorptive sites. Rate constants for these processes, as well as the total oxidative site densities were used as the fitting parameters. The total adsorptive site densities were estimated based on the measured specific surface area of each material. The best fit was provided by considering one fast and one slow site for each adsorptive and oxidative site. The fitting parameters were obtained using the kinetic data for the most reactive aquifer material at different initial As(III) concentrations. Using the same parameters to simulate As(III) and As(V) surface reactions, the model predictions were compared to observations for aquifer materials with different manganese contents. The model simulated the experimental data very well for all materials at all initial As(III) concentrations. The As(V) production rate was related to the concentrations of the free oxidative surface sites and dissolved As(III), as with apparent second-order rate constants of and for the fast and the slow oxidative sites, respectively. The As(III) removal rate decreased approximately by half for a pH increase from 4 to 7. The pH dependence was explained using the acid-base behavior of the surface oxidative sites by considering a surface pKa = 6.2 (I = 0). In the presence of excess surface adsorptive and oxidative sites, phosphate diminished the rate of As(III) removal and As(V) production only slightly due to its interaction with the oxidative sites. The observed As(III) oxidation rate here is consistent with previous observations of As(III) oxidation over short transport distances during field-scale transport experiments. The model developed here may be incorporated into groundwater transport models to predict arsenic speciation and transport in chemically heterogeneous systems. 相似文献
The Solar System Odyssey mission uses modern-day high-precision experimental techniques to test the laws of fundamental physics
which determine dynamics in the solar system. It could lead to major discoveries by using demonstrated technologies and could
be flown within the Cosmic Vision time frame. The mission proposes to perform a set of precision gravitation experiments from
the vicinity of Earth to the outer Solar System. Its scientific objectives can be summarized as follows: (1) test of the gravity
force law in the Solar System up to and beyond the orbit of Saturn; (2) precise investigation of navigation anomalies at the
fly-bys; (3) measurement of Eddington’s parameter at occultations; (4) mapping of gravity field in the outer solar system
and study of the Kuiper belt. To this aim, the Odyssey mission is built up on a main spacecraft, designed to fly up to 13
AU, with the following components: (a) a high-precision accelerometer, with bias-rejection system, measuring the deviation
of the trajectory from the geodesics, that is also giving gravitational forces; (b) Ka-band transponders, as for Cassini,
for a precise range and Doppler measurement up to 13 AU, with additional VLBI equipment; (c) optional laser equipment, which
would allow one to improve the range and Doppler measurement, resulting in particular in an improved measurement (with respect
to Cassini) of the Eddington’s parameter. In this baseline concept, the main spacecraft is designed to operate beyond the
Saturn orbit, up to 13 AU. It experiences multiple planetary fly-bys at Earth, Mars or Venus, and Jupiter. The cruise and
fly-by phases allow the mission to achieve its baseline scientific objectives [(1) to (3) in the above list]. In addition
to this baseline concept, the Odyssey mission proposes the release of the Enigma radio-beacon at Saturn, allowing one to extend
the deep space gravity test up to at least 50 AU, while achieving the scientific objective of a mapping of gravity field in
the outer Solar System [(4) in the above list].
相似文献
Broadly the science of geology has passed through a number of distinct phases. In the early days attention was focussed on establishing a stratigraphic framework, concentrating on fossils and lithologies—the days of mapping and systematizing of sedimentary successions and the uncovering of the succession of life. Later, in the early twentieth century, geologists became much more interested in igneous rocks. By the 1960s attention turned to the ocean basins, culminating in the acceptance of the paradigm of plate tectonics. At the end of the 1960s, one area of geology that remained relatively little understood was the huge span of time represented by the Precambrian, about 80 per cent of Earth's history. By the 1960s this was changing. Radiometric dating was beginning to show the relative ages of such terranes and new methods of mapping were beginning to be used. 相似文献
The Hillgrove mineral field, in the southern part of the New England Orogen of northeastern New South Wales, Australia, contains numerous mesothermal Au---Sb vein systems. Calc-alkaline (shoshonitic) lamprophyre (CAL) dykes are also associated with mineralisation with dilational lode structures acting as conduits for dyke intrusion, which has occurred before and after major quartz-stibnite veining. Dykes include minette and vogesite compositions and were emplaced in the late Permian (247–255 Ma), at the same time as regionally extensive I-type magmatism in the New England Orogen. Least-altered dykes are enriched in Mg, K, Ba, Rb, Sr, Zr, Th, Cr and Ni relative to I-type intrusives although chemical affinities are evident between lamprophyres and the more mafic members of the high-K Moonbi Plutonic Suite.
Hillgrove lamprophyres are commonly enriched in Sb, As, Hg, Au, W and Bi with respect to average CAL compositions. Evidence indicates this is most likely due to contamination of magma during intrusion through mineralised structures, rather than a primary magmatic feature. Partially resorbed xenocrystic stibnite occurs in dykes which have intruded lode structures, probably facilitated by the low melting point of stibnite (550°C) and its incorporation into the magma. Carbon and oxygen isotopic data from carbonates in least-altered, post-lode lamprophyres are indistinguishable from carbonate in altered dykes and veins, implying that hydrothermal interaction continued after dyke intrusion. Although it is unlikely that lamprophyre dykes have been a direct source for mineralisation at Hillgrove, the close temporal and spatial relation of dykes, mesothermal Au---Sb veins and I-type intrusions are interpreted to be manifestations of the post-collisional setting and influx of mantle-derived heat and partial melts into the New England Orogen during the late Permian. 相似文献