Adaptive numerical simulation of the remediation of soil contamination by in‐situ gas venting     

S.V. Pennington  P.K. Jimack  K. McFarlane 《Computational Geosciences》1999,3(2):135-160

This paper describes a mathematical model and adaptive numerical simulation of the time‐dependent multiphase, multicomponent flow which occurs when a gas venting process is used to remove a volatile contaminant from a porous medium. The numerical simulation is adaptive in both space and time and involves the use of a finite element spatial discretization and the SPRINT2D software [6] for time integration. Results are presented which demonstrate the high quality of the simulation, both in terms of the length scales of the features that are resolved and the efficiency of the solutions relative to those obtained on fixed grids. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Introduction: A symposium on Global Shadows: Africa in the Neoliberal World Order     

Alex Jeffrey  Colin McFarlane  Alexander Vasudevan 《Singapore journal of tropical geography》2008,29(3):251-253

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A significant middle Pleistocene tephra deposit preserved in the caves of Mulu,Borneo     

Joyce Lundberg  Donald A. McFarlane 《Quaternary Research》2012,77(3):335-343

A distinctive white sediment in the caves of Mulu, Sarawak, Borneo is a well-preserved tephra, representing a fluvially transported surface air-fall deposit, re-deposited inside the caves. We show that the tephra is not the Younger Toba Tephra, formerly considered as most likely. The shards are rod-shaped with elongate tubular vesicles; the largest grains ~ 170 μm in length; of rhyolitic composition; and ⁸⁷Sr/⁸⁶Sr ratio of 0.70426 ± 0.00001. U–Th dating of associated calcites suggest that the tephra was deposited before 125 ± 4 ka, and probably before 156 ± 2 ka. Grain size and distance from closest potential source suggests an eruption of VEI 7. Prevailing winds, grain size, thickness of deposit, location of potential sources, and Sr isotopic ratio limit the source to the Philippines. Comparisons with the literature give the best match geochemically with layer 1822 from Ku et al. (2009a), dated by ocean core stratigraphy to 189 ka. This tephra represents a rare terrestrial repository indicating a very substantial Plinian/Ultra-Plinian eruption that covered the Mulu region of Borneo with ash, a region that rarely receives tephra from even the largest known eruptions in the vicinity. It likely will be a valuable chronostratigraphic marker for sedimentary, palaeontological and archaeological studies.  相似文献   

Model determination of non‐point source phosphorus transport pathways in a fertilized grassland catchment     

Todd M. Scanlon  Ger Kiely  Roberto Amboldi 《水文研究》2005,19(14):2801-2814

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Hydraulic redistribution by deeply rooted grasses and its ecohydrologic implications in the southern Great Plains of North America     

Erik Oerter  Eric Slessarev  Ate Visser  Kyungjin Min  Megan Kan  Karis J. McFarlane  Malay C. Saha  Asmeret Asefaw Berhe  Jennifer Pett-Ridge  Erin Nuccio 《水文研究》2021,35(9):e14366

Perennial bioenergy crops with deep (>1 m) rooting systems, such as switchgrass (Panicum virgatum L.), are hypothesized to increase carbon storage in deep soil. Deeply rooted plants may also affect soil hydrology by accessing deep soil water for transpiration, which can affect soil water content and infiltration in deep soil layers, thereby affecting groundwater recharge. Using stable H and O isotope (δ²H and δ¹⁸O) and ³H values, we studied the soil water conditions at 20–30 cm intervals to depths of 2.4–3.6 m in paired fields of switchgrass and shallow rooted crops at three sites in the southern Great Plains of North America. We found that soil under switchgrass had consistently higher soil water content than nearby soil under shallow-rooted annual crops by a margin of 15%–100%. Soil water content and isotopic depth profiles indicated that hydraulic redistribution of deep soil water by switchgrass roots explained these observed soil water differences. To our knowledge, these are the first observations of hydraulic redistribution in deeply rooted grasses, and complement earlier observations of dynamic soil water fluxes under shallow-rooted grasses. Hydraulic redistribution by switchgrass may be a strategy for drought avoidance, wherein the plant may actively prevent water limitation. This raises the possibility that deeply rooted grasses may be used to passively subsidize soil water to more shallow-rooted species in inter-cropping arrangements.  相似文献   

Land cover change and soil organic carbon stocks in the Republic of Ireland 1851–2000     

James M. Eaton  Nicola M. McGoff  Kenneth A. Byrne  Paul Leahy  Ger Kiely 《Climatic change》2008,91(3-4):317-334

Using both historic records and CORINE land cover maps, we assessed the impact of land cover change on the stock of soil organic carbon (SOC) in the Republic of Ireland from 1851 to 2000. We identified ten principal land cover classes: arable land, forest, grassland, heterogeneous agricultural areas/other, nonvegetated semi-natural areas, peatland, suburban, urban, water bodies, and wetland. For each land cover class, the SOC stock was estimated as the product of SOC density and land cover area. These were summed to calculate a national SOC budget for the Republic of Ireland. The Republic of Ireland’s 6.94 million hectares of land have undergone considerable change over the past 150 years. The most striking feature is the decrease in arable land from 1.44 million ha in 1851 to 0.55 million ha in 2000. Over the same time period, forested land increased by 0.53 million ha. As of 2000, agricultural lands including arable land (7.85%), grassland (54.33%), and the heterogeneous agricultural areas/other class (7.91%) account for 70.09% of Irish land cover. We estimate that the SOC stock in the Republic of Ireland, to 1 m depth, has increased from 1,391 Tg in 1851 to 1,469 Tg in 2000 despite soil loss due to urbanization. This increase is largely due to the increase of forested land with its higher SOC stocks when compared to agricultural lands. Peatlands contain a disproportionate quantity of the SOC stock. Although peatlands only occupy 17.36% of the land area, as of 2000, they represented 36% of the SOC stock (to 1 m depth).  相似文献   

Contrasting response of monazite and zircon to a high-T thermal overprint     

Christopher R.M. McFarlane  James N. Connelly  William D. Carlson 《Lithos》2006,88(1-4):135-149

Contact metamorphism in the aureole of the 1322 Ma Makhavinekh Lake Pluton, northern Labrador, affected monazite and zircon in the adjacent 1850 Ma metapelitic gneisses. Transformation of regional garnet and sillimanite to lower-pressure symplectitic intergrowths of cordierite, orthopyroxene, and spinel was accompanied by resorption of inherited monazite inclusions in garnet coupled with the appearance of coronitic high-Y monazite rims. In situ ion-microprobe dating is used to show that high-Y rims formed during contact metamorphism. Liberation of Y and HREE from garnet also gave rise to new xenotime growth. The coronitic nature of monazite overgrowths reflects the diffusion-controlled nature of net-transfer reactions whereas its higher Y composition reflects equilibration with xenotime at peak T (> 800 °C) conditions in the inner aureole. Very thin overgrowths on inherited zircon were also encountered, but only where zircon is surrounded by the symplectitic assemblage, reflecting liberation of Zr from garnet. Although these overgrowths are too thin to date using conventional ion-microprobe techniques, well-developed triple junctions between zircon and orthopyroxene suggests that they grew in textural equilibrium with the contact metamorphic assemblage.

In contrast to monazite, inherited zircon remained intact during contact metamorphism, exhibiting no change in morphology (other than the growth of thin rims) or internal zoning throughout the aureole. However, inherited sector-zoned zircons of anatectic origin display evidence for intracrystalline Pb redistribution in the inner aureole. In these samples, ion-microprobe analyses encountered heterogeneous Pb signals and a dispersion of ²⁰⁷Pb / ²⁰⁶Pb dates away from the well constrained 1850 Ma age of regional metamorphism. Whereas analyses from the outer aureole faithfully record the age of regional metamorphism, those from the inner aureole are normally and reversely discordant and distributed along a line collinear with a 1850 to 1322 Ma discordia. This disturbance is correlated with proximity to the pluton implying that Pb was mobile in the zircon lattice during contact metamorphism. Most grains are characterized by apparent Pb loss from low-U domains and apparent Pb gain in higher-U domains. These data are interpreted to reflect recovery of strained crystalline domains leading to expulsion of Pb* that was able to efficiently diffuse into higher-U domains that were partly amorphous prior to rapid reheating in the inner aureole.  相似文献   

On the causes of glacial inception at 116 kaBP     

M. Yoshimori  M. Reader  A. Weaver  N. McFarlane 《Climate Dynamics》2002,18(5):383-402

To explore processes involved in glacial inception at 116 kaBP, the response of an atmospheric general circulation model (AGCM) to changes in lower boundary conditions is investigated. Two 116 kaBP experiments are conducted to examine the importance of sea surface conditions (sea surface temperature and sea ice distribution): one with the present-day sea surface conditions, and the other with 116 kaBP sea surface conditions. These two different sea surface conditions are obtained from simulations using an earth system climate model of intermediate complexity. Perennial snow cover occurred over the Canadian Archipelago under 116 kaBP orbital and CO₂ forcing with present-day "warm" sea surface conditions, and further expanded over northeastern Canada when 116 kaBP "cool" sea surface conditions were applied. The net positive accumulation in northeastern Canada, with little in Alaska, is in good agreement with geological records. Two additional 116 kaBP experiments are conducted to examine the combined importance of sea surface conditions and land surface conditions (vegetation): one with the present-day sea surface and modified land surface conditions, and the other with 116 kaBP sea surface and modified land surface conditions. Modifying vegetation, based on cooling during summer induced by 116 kaBP sea surface conditions, leads to much larger areas of perennial snow cover. Only when 116 kaBP sea surface conditions are applied, is a realistic global net snow accumulation rate obtained. Contrary to the earlier ice age hypothesis, our results suggest that the capturing of glacial inception at 116 kaBP requires the use of "cooler" sea surface conditions than those of the present climate. Also, the large impact of vegetation change on climate suggests that the inclusion of the vegetation feedback is important for model validation, at least, in this particular period of Earth history.  相似文献   

Convective scaling of the average dissipation rate of temperature variance in the atmospheric surface layer     

Gerard Kiely  John D. Albertson  Marc B. Parlance  William E. Eichinger 《Boundary-Layer Meteorology》1996,77(3-4):267-284

The flux of sensible heat from the land surface is related to the average rate of dissipation of temperature fluctuations in the atmospheric surface layer through the temperature variance budget equation. In many cases it is desirable to estimate the heat flux from measurement or inference of the dissipation rate. Here we study how the dissipation rate scales with atmospheric stability, using three inertial range methods to calculate the dissipation rate: power spectra, second order structure functions, and third order structure functions. Experimental data are analyzed from a pair of field experiments, during which turbulent fluctuations of velocity and temperature were measured over a broad range of neutral and unstable atmospheric flows. It is shown that the temperature dissipation rate scales with a single convective power law continuously from near-neutral to strongly unstable stratification. The dissipation scaling is found to nearly match production in the near-neutral region, but to be consistently lower than production in the more convective regimes. The convective scaling is shown to offer a simplified means of computing sensible heat flux from the dissipation rate of temperature variance.Also at Johns Hopkins University, Baltimore, MarylandAlso at Los Alamos National Laboratory, Los Alamos, New Mexico.  相似文献   

Modelling subsurface flow conditions in a salinized catchment in south‐western Australia,with a view to improving management practices     

W. J. Stolte  R. J. George  D. J. McFarlane 《水文研究》1999,13(17):2689-2703

Finite element modelling of the saturated–unsaturated surface–subsurface flow mechanisms operative in a small salinized catchment in south‐western Australia was used to help define the flow system and explain the causes of waterlogging and salinization there. Data available at the site from a previous study were used to obtain a first approximation to the flow system. Altering the properties of some of the strata gave a closer calibration. It was found that the modelled saturated hydraulic conductivity of the B horizon in the duplex soil zone needed to be at least an order of magnitude lower than that measured in order to reproduce the perching conditions observed in the field. Also, the model indicated the influence of a doleritic dyke, whose presence was confirmed by field measurement. Our analysis showed that there were two main flow systems operating in the hillslope. The first, and most dominant, was the recharge occurring through the upslope gradational soil zone and percolating down to both the deeply weathered regolith and the basal aquifer. The second flow system is an unsaturated flow system operating in the high permeability A horizon in the downslope duplex soil zone. The first system is primarily responsible for the saline seepage zone in the valley bottom. The second contributes to the waterlogging and perching occurring upslope of the seepage zone. Vertical flow through the higher permeability B horizon in the gradational soil zone in the upper slopes is a major contributor of recharge. Recharge by flow through macropores occurs where, but only where, perched aquifers develop and allow the macropores to be activated. Areas with perched aquifers occurred in downslope locations and near a doleritic dyke located upslope. Thus, the area where macropore recharge occurred was not large. The recharge rate required to maintain the piezometric levels at present values is only about 30 mm/yr (about 5% of the annual rainfall). The piezometric levels under the upper part of the catchment varied greatly with only small changes in recharge rate. A 50% reduction in recharge rate had the effect of reducing the length of the seepage zone at the end of winter by 40%. Changes in recharge rate had little effect on the extent of the perched aquifer at the end of winter. Deep‐rooted perennial forages, shrubs or trees on the gradational soil zone in the upper part of the catchment and on the zones upslope of geological barriers to flow would be required to reduce the recharge and to allow for rehabilitation of the saline valley floor. Waterlogging associated with the perched water table in the bottom part of the catchment would be best addressed by tree plantations located just upslope of the salinized zone in the valley floor. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献