Sulfur geochemistry of hydrothermal waters in Yellowstone National Park: IV Acid–sulfate waters     

D. Kirk Nordstrom  R. Blaine McCleskeyJames W. Ball 《Applied Geochemistry》2009

Many waters sampled in Yellowstone National Park, both high-temperature (30–94 °C) and low-temperature (0–30 °C), are acid–sulfate type with pH values of 1–5. Sulfuric acid is the dominant component, especially as pH values decrease below 3, and it forms from the oxidation of elemental S whose origin is H₂S in hot gases derived from boiling of hydrothermal waters at depth. Four determinations of pH were obtained: (1) field pH at field temperature, (2) laboratory pH at laboratory temperature, (3) pH based on acidity titration, and (4) pH based on charge imbalance (at both laboratory and field temperatures). Laboratory pH, charge imbalance pH (at laboratory temperature), and acidity pH were in close agreement for pH < 2.7. Field pH measurements were predominantly used because the charge imbalance was <±10%. When the charge imbalance was generally >±10%, a selection process was used to compare acidity, laboratory, and charge balance pH to arrive at the best estimate. Differences between laboratory and field pH can be explained based on Fe oxidation, H₂S or S₂O₃ oxidation, CO₂ degassing, and the temperature-dependence of pK₂ for H₂SO₄. Charge imbalances are shown to be dependent on a speciation model for pH values <3. The highest SO₄ concentrations, in the thousands of mg/L, result from evaporative concentration at elevated temperatures as shown by the consistently high δ¹⁸O values (−10‰ to −3‰) and a δD vs. δ¹⁸O slope of 3, reflecting kinetic fractionation. Low SO₄ concentrations (<100 mg/L) for thermal waters (>350 mg/L Cl) decrease as the Cl⁻ concentration increases from boiling which appears inconsistent with the hypothesis of H₂S oxidation as a source of hydrothermal SO₄. This trend is consistent with the alternate hypothesis of anhydrite solubility equilibrium. Acid–sulfate water analyses are occasionally high in As, Hg, and NH₃ concentrations but in contrast to acid mine waters they are low to below detection in Cu, Zn, Cd, and Pb concentrations. Even concentrations of SO₄, Fe, and Al are much lower in thermal waters than acid mine waters of the same pH. This difference in water chemistry may explain why certain species of fly larvae live comfortably in Yellowstone’s acid waters but have not been observed in acid rock drainage of the same pH.  相似文献   

Naturally acidic surface and ground waters draining porphyry-related mineralized areas of the Southern Rocky Mountains,Colorado and New Mexico     

Philip L. Verplanck  D. Kirk Nordstrom  Dana J. Bove  Geoffrey S. Plumlee  Robert L. Runkel 《Applied Geochemistry》2009

Acidic, metal-rich waters produced by the oxidative weathering and resulting leaching of major and trace elements from pyritic rocks can adversely affect water quality in receiving streams and riparian ecosystems. Five study areas in the southern Rocky Mountains with naturally acidic waters associated with porphyry mineralization were studied to document variations in water chemistry and processes that control the chemical variations. Study areas include the Upper Animas River watershed, East Alpine Gulch, Mount Emmons, and Handcart Gulch in Colorado and the Red River in New Mexico. Although host-rock lithologies in all these areas range from Precambrian gneisses to Cretaceous sedimentary units to Tertiary volcanic complexes, the mineralization is Tertiary in age and associated with intermediate to felsic composition, porphyritic plutons. Pyrite is ubiquitous, ranging from ∼1 to >5 vol.%. Springs and headwater streams have pH values as low as 2.6, SO₄ up to 3700 mg/L and high dissolved metal concentrations (for example: Fe up to 400 mg/L; Cu up to 3.5 mg/L; and Zn up to 14.4 mg/L). Intensity of hydrothermal alteration and presence of sulfides are the primary controls of water chemistry of these naturally acidic waters. Subbasins underlain by intensely hydrothermally altered lithologies are poorly vegetated and quite susceptible to storm-induced surface runoff. Within the Red River study area, results from a storm runoff study documented downstream changes in river chemistry: pH decreased from 7.80 to 4.83, alkalinity decreased from 49.4 to <1 mg/L, SO₄ increased from 162 to 314 mg/L, dissolved Fe increased from to 0.011 to 0.596 mg/L, and dissolved Zn increased from 0.056 to 0.607 mg/L. Compared to mine drainage in the same study areas, the chemistry of naturally acidic waters tends to overlap but not reach the extreme concentrations of metals and acidity as some mine waters. The chemistry of waters draining these mineralized but unmined areas can be used to estimate premining conditions at sites with similar geologic and hydrologic conditions. For example, the US Geological Survey was asked to estimate premining ground-water chemistry at the Questa Mo mine, and the proximal analog approach was used because a mineralized but unmined area was located adjacent to the mine property. By comparing and contrasting water chemistry from different porphyry mineralized areas, this study not only documents the range in concentrations of constituents of interest but also provides insight into the primary controls of water chemistry.  相似文献   

Coupled North Atlantic slope water forcing on Gulf of Maine temperatures over the past millennium     

Alan D. Wanamaker Jr  Karl J. Kreutz  Bernd R. Schöne  Neal Pettigrew  Harold W. Borns  Douglas S. Introne  Daniel Belknap  Kirk A. Maasch  Scott Feindel 《Climate Dynamics》2008,31(2-3):183-194

To investigate ocean variability during the last millennium in the Western Gulf of Maine (GOM), we collected a 142-year-old living bivalve (Arctica islandica L.) in 2004, and three fossil A. islandica shells (calibrated ¹⁴C_AMS = 1030 ± 78 ad; 1320 ± 45 ad; 1357 ± 40 ad) for stable isotope and growth increment analysis. A statistically significant relationship exists between modern GOM temperature records [shell isotope-derived (30 m) (r = ?0.79; P < 0.007), Prince 5 (50 m) (r = ?0.72; P < 0.019), Boothbay Harbor SST (r = ?0.76; P < 0.011)], and Labrador Current (LC) transport data from the Eastern Newfoundland Slope during 1993–2003. In all cases, as LC transport increased, GOM water temperatures decreased the following year. Decadal trends in the North Atlantic Oscillation (NAO) and the Atlantic Multidecadal Oscillation (AMO) influence GOM water temperatures in the most recent period, with water temperatures decreasing during NAO and AMO negative modes most likely linked to LC transport and Gulf Stream interaction. Mean shell-derived isotopic changes (δ¹⁸O_c) during the last 1,000 years were +0.47‰ and likely reflect a 1–2°C cooling from 1000 ad to present. Based on these results, we suggest that observed cooling in the GOM during the last millennium was due to increased transport and/or cooling of the LC, and decreased Gulf Stream influence on the GOM.  相似文献   

Titan's diverse landscapes as evidenced by Cassini RADAR's third and fourth looks at Titan     

J.I. Lunine  C. Elachi  S.D. Wall  M.D. Allison  R. Boehmer  P. Encrenaz  G. Franceschetti  G. Hamilton  W.T.K. Johnson  R.L. Kirk  R. Lorenz  D.O. Muhleman  S.J. Ostro  P. Paillou  F. Posa  L.E. Roth  S. Shaffer  B. Stiles  S. Vetrella  C.A. Wood  H. Zebker  E. Karkoschka  E. McFarlane  B. Kazeminejad 《Icarus》2008,195(1):415-433

Cassini's third and fourth radar flybys, T7 and T8, covered diverse terrains in the high southern and equatorial latitudes, respectively. The T7 synthetic aperture radar (SAR) swath is somewhat more straightforward to understand in terms of a progressive poleward descent from a high, dissected, and partly hilly terrain down to a low flat plain with embayments and deposits suggestive of the past or even current presence of hydrocarbon liquids. The T8 swath is dominated by dunes likely made of organic solids, but also contain somewhat enigmatic, probably tectonic, features that may be partly buried or degraded by erosion or relaxation in a thin crust. The dark areas in T7 show no dune morphology, unlike the dark areas in T8, but are radiometrically warm like the dunes. The Huygens landing site lies on the edge of the T8 swath; correlation of the radar and Huygens DISR images allows accurate determination of its coordinates, and indicates that to the north of the landing site sit two large longitudinal dunes. Indeed, had the Huygens probe trajectory been just 10 km north of where it actually was, images of large sand dunes would have been returned in place of the fluvially dissected terrain actually seen—illustrating the strong diversity of Titan's landscapes even at local scales.  相似文献   

Electrical conductivity method for natural waters     

R. Blaine McCleskey  D. Kirk Nordstrom  Joe N. Ryan 《Applied Geochemistry》2011

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Chronostratigraphic and Paleoenvironmental Evidence for Marsh Habitats during the Early Pueblo I (A.D. 700–900) Occupation of Ridges Basin,Southwest Colorado,USA     

Kirk C. Anderson  James M. Potter 《Geoarchaeology》2015,30(2):100-119

Ridges Basin was home to one of the largest early village communities in the American Southwest. The short‐lived occupation grew rapidly around A.D. 750, construction peaked in the A.D. 780s, but Ridges Basin was depopulated by A.D. 810. Chronostratigraphic, paleoenvironmental, and archaeological investigations indicate that abundant food resources related to intermittent marsh habitats attracted migrants into the basin and aided the growing population. Extreme droughts between A.D. 795 and 809 led to decreased crop yields and marsh desiccation. We attribute the abrupt depopulation of Ridges Basin to declining environmental conditions and societal stresses. We describe the impact of marsh formation on the inhabitants, and explore the wider implications of marshes and reservoirs on the Puebloan landscape. We suggest that early Puebloans positioned their settlements in proximity to natural marshes to take advantage of the abundant plant and animal resources, which later Puebloans achieved through the construction of reservoirs.  相似文献   

The initial conditions of isolated star formation – VI. SCUBA mapping of pre-stellar cores     

J. M. Kirk  D. Ward-Thompson  P. André 《Monthly notices of the Royal Astronomical Society》2005,360(4):1506-1526

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Titan's surface from Cassini RADAR SAR and high resolution radiometry data of the first five flybys     

F. Paganelli  M.A. Janssen  R. West  J.I. Lunine  S.D. Wall  R.M. Lopes  R.L. Kirk  L. Roth  the Radar Team 《Icarus》2007,191(1):211-222

The first five Titan flybys with Cassini's Synthetic Aperture RADAR (SAR) and radiometer are examined with emphasis on the calibration and interpretation of the high-resolution radiometry data acquired during the SAR mode (SAR-radiometry). Maps of the 2-cm wavelength brightness temperature are obtained coincident with the SAR swath imaging, with spatial resolution approaching 6 km. A preliminary calibration shows that brightness temperature in these maps varies from 64 to 89 K. Surface features and physical properties derived from the SAR-radiometry maps and SAR imaging are strongly correlated; in general, we find that surface features with high radar reflectivity are associated with radiometrically cold regions, while surface features with low radar reflectivity correlate with radiometrically warm regions. We examined scatterplots of the normalized radar cross-section σ⁰ versus brightness temperature, finding differing signatures that characterize various terrains and surface features. Implications for the physical and compositional properties of these features are discussed. The results indicate that volume scattering is important in many areas of Titan's surface, particularly Xanadu, while other areas exhibit complex brightness temperature variations consistent with variable slopes or surface material and compositional properties.  相似文献   

Subglacial clast behaviour and its implication for till fabric development: new results derived from wireless subglacial probe experiments     

Jane K. Hart  Kathryn C. Rose  Kirk Martinez  Royan Ong 《Quaternary Science Reviews》2009,28(7-8):597-607

This study has investigated the three-dimensional movement of clasts within deformation till, using embedded wireless probes. These probes were part of an environmental sensor network, which measured subglacial properties (temperature, water pressure, resistivity, case strain and tilt) six times a day, and relayed that data via radio to the glacier surface, where they were forwarded and broadcast on-line. The system was installed at Briksdalsbreen, Norway and operated from August 2004 until August 2006. Approximately 2000 probe days worth of data were collected, with an increase in performance (41% more readings) during the second year. The probes showed similar patterns of water pressure rises throughout the two years, but with slightly different magnitudes and timings. These changes in water pressure could be related to clast behaviour. The probes decreased their dip over the year, and the rate of change was related to an increase in glacier velocity. After initial changes in dip, the probes experienced changes in orientation, followed by rotation about the a-axis. This continuous rotation was similar to the motion suggested by Jeffery [1922. The motion of ellipsoidal particles immersed in a viscous fluid. Proceedings of the Royal Society of London, Series A 102, 161–179] for the behaviour of clasts within a viscous material. In addition, some probes also showed short, frequent dip oscillations in spring and autumn, which were interpreted to reflect stick-slip events, similar to lodging; and demonstrated how local conditions can interrupt the predicted rotation pattern.Overall, it is demonstrated that when water pressures were high, decoupling occurred associated with basal sliding and dip oscillations; and when water pressures fell, the ice and sediment were coupled and till deformation occurred. These events happened during summer and autumn. It is this combination of “lodgement” and deformation that builds up both a complex (but predictable) fabric and a resultant composite till sedimentology.  相似文献   

Random porosity fields and their influence on the stability of granular media     

Jos E. Andrade  Jack W. Baker  Kirk C. Ellison 《国际地质力学数值与分析法杂志》2008,32(10):1147-1172

It is well established that the mechanical behavior of granular media is strongly influenced by the media's microstructure. In this work, the influence of the microstructure is studied by integrating advances in the areas of geostatistics and computational plasticity, by spatially varying the porosity on samples of sand. In particular, geostatistical tools are used to characterize and simulate random porosity fields that are then fed into a nonlinear finite element model. The underlying effective mechanical response of the granular medium is governed by a newly developed elastoplastic model for sands, which readily incorporates spatial variability in the porosity field at the meso‐scale. The objective of this study is to assess the influence of heterogeneities in the porosity field on the stability of sand samples. One hundred and fifty isotropic and anisotropic samples of dense sand are failed under plane‐strain compression tests using Monte Carlo techniques. Results from parametric studies indicate that the axial strength of a specimen is affected by both the degree and orientation of anisotropy in heterogeneous porosity values with anisotropy orientation having a dominant effect, especially when the bands of high porosity are aligned with the natural orientation of shear banding in the specimen. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献