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31.
32.
Sample data in the Earth and environmental sciences are limited in quantity and sampling location and therefore, sophisticated spatial modeling techniques are indispensable for accurate imaging of complicated structures and properties of geomaterials. This paper presents several effective methods that are grouped into two categories depending on the nature of regionalized data used. Type I data originate from plural populations and type II data satisfy the prerequisite of stationarity and have distinct spatial correlations. For the type I data, three methods are shown to be effective and demonstrated to produce plausible results: (1) a spline-based method, (2) a combination of a spline-based method with a stochastic simulation, and (3) a neural network method. Geostatistics proves to be a powerful tool for type II data. Three new approaches of geostatistics are presented with case studies: an application to directional data such as fracture, multi-scale modeling that incorporates a scaling law, and space-time joint analysis for multivariate data. Methods for improving the contribution of such spatial modeling to Earth and environmental sciences are also discussed and future important problems to be solved are summarized.   相似文献   
33.
A calculation method for determining the amount of Rn isotopes and daughter products at the start of measurement (CRAS) is proposed as a more accurate means of estimating the initial Rn concentration in soil gas. The CRAS utilizes the decay law between 222Rn and 220Rn isotopes and the daughter products 218Po and 216Po, and is applicable to α-scintillation counter measurements. As Rn is both inert and chemically stable, it is useful for fault investigation based on the soil gas geochemistry. However, the total number of α particles emitted by the decay of Rn has generally been considered to be proportional to the initial Rn concentration, without considering the gas condition with respect to radioactive equilibrium. The CRAS method is shown to be effective to derive Rn concentration for soil gases under both nonequilibrium conditions, in which the total number of decays increases with time, and equilibrium conditions, which are typical of normal soil under low gas flux. The CRAS method in conjunction with finite difference method simulation is applied to the analysis of two active fault areas in Japan, and it is demonstrated that this combination could detect the sharp rises in 222Rn concentrations associated with faults. The method also allows the determination of fault geometry near the surface based on the asymmetry variation of the Rn concentration distribution when coupled with a numerical simulation of 222Rn transport. The results for the new method as applied to the two case studies are consistent with the data collected from the geological survey. It implies that the CRAS method is suitable for investigating the fault system and interstitial gas mobility through fractures. The present analyses have also demonstrated that high Rn concentrations require the recent and repeated accumulation of 222Rn parents (230Th and 226Ra) in fault gouges through deep gas release during fault movement.  相似文献   
34.
Extinction coefficients were measured for three kind of hydrous silicate minerals, montmorillonite, chlorite and serpentine, from 7 to 140 m. The infrared extinction coefficients of these minerals show (1) a few broad bands in the mid-infrared region and (2) a less steep wavelength-dependence in the far-infrared region, in contrast to those of high-temperature magnesium silicates. In the far-infrared region, montmorillonite shows a –0.8±0.1 dependence (, the wavelength) without any band structure, chlorite has a double maxima structure around 80 m, and serpentine shows a rather steep dependence with a small peak at 77 m.The changes of mid-infrared spectra by heating were measured. Change in chlorite spectrum is the most significant. Many fine features appear by heating and then they disappear. Above 900°C one broad feature remains around 10 m. Fine features of the montmorillonite spectrum disappear by heating. For serpentine, many new peaks appear and the spectrum resembles the spectrum of olivin. In near-infrared a band around 2.72 m disappears by heating.Extinction coefficients at very low temperatures were measured in the far-infrared region. For montmorillonite and serpentine, the spectrum is the same as that at room temperature. The double peaks of chlorite around 80 m become higher.  相似文献   
35.
Mid-infrared extinction coefficients of five natural amorphous silicates and seven synthetic glasses were measured. Three bands at about 10, 12, and 20 μm were seen for all the measured samples. The quantities of these bands are found to have good correlations with the SiO2 content of the samples. The correlations are the most remarkable for the 10 μm band. As the SiO2 content decreases, the peak wavelengthλ m shifts to longer side, the peak heightK m decreases and the full width of half maximumW increases. A quantityλ m K m W is constant within 15%. Empirical formula $$\lambda_m (\mu m) = {11.10-2.30 x 10^-2} {[SiO_2 wt.\%]} \pm 0.15$$ and $$W(\mu m) = {5.14-4.68 x 10^- 2} {[SiO_2 wt.\%]} \pm 0.30$$ are obtained for the measured samples. Therefore, the correlation is present between the 10 μm peak wavelengthλ m and peak widthW for amorphous silicates. The change in peak widthW is remarkable compared the change in peak wavelengthλ m as the SiO2 content varies. For the 12 μm band the correlations with the SiO2 content are not so good. A tendency that theλ m shifts to the red and theK m lowers as the decreasing SiO2 content are found. For the samples with SiO2 content less than 50% the 12 μm band cannot recognized as the peak. For the 20 μm band, theλ m is almost independent on SiO2 content and theK m lowers with decreasing SiO2 content. The results are compared with the observed 10 μm band of the astronomical objects. A method to estimate the SiO2 content of astronomical grain materials is proposed and 48±8% SiO2 wt.% is found corresponding to the peak wavelength of 9.7 μm and the peak width of 2.5–3.0 μm of typical celestial objects.  相似文献   
36.
We found high potential activities of alkaline phosphatase associated with particles (0.2 μm or greater size fraction) in deep waters (1000–4000 m) of the central Pacific Ocean. The potential enzyme activity at depth (0.03 – 0.3 nM h−1) was up to 50% of that at the surface (0–125 m). In contrast, activities of α- and β-d-glucosidase in the deep layer were low (generally less than 1 % of those in the upper layer), yielding up to two orders of magnitude difference in the ratio of alkaline phosphatase and α- and β-d-glucosidase activities with depth. It is unlikely that the phosphatase is actively produced by microorganisms inhabiting the deep-sea environment, where labile organic carbon supply is limited and phosphate concentration is high (2.4 – 3.0 AM). Instead, deep-water phosphatase is probably supplied by rapidly sinking particles and their subsequent fragmentation and dissolution. Different distributions of phosphatase and glucosidase indicate that sinking particles of phytoplankton origin are an important source of alkaline phosphatase enzymes in the deep sea.  相似文献   
37.
Fine scale distribution of nitrous oxide in marine sediments   总被引:1,自引:0,他引:1  
Vertical profiles of nitrous oxide and other inorganic nitrogen compounds in the sediments in Tokyo Bay and its vicinity were measured using the whole core squeezing method. Within the bay area, vertical profiles of nitrous oxide in the interstitial waters showed one or two distinctive peaks around the depth of 2–4 cm, which corresponded to the peaks of nitrite and nitrate. In situ formation of nitrous oxide through nitrification was suggested in those sediments, which was possibly activated by the presence of benthic animals. On the other hand, at the deep sediment off Tokyo Bay the profiles of nitrous oxide, nitrite and nitrate gave a monotonous single peak, indicating less bioturbated condition. Denitrification or dissimilatory nitrate reduction might be important for the formation of nitrous oxide peaks in the latter type of sediment.  相似文献   
38.
Consumption of silicate and nitrate (Si:N molar ratio) in the upper layer of the pelagic subarctic Pacific in summer was evaluated by a regression analysis of silicate vs. nitrate concentrations at the upper 100 m depth. Based on data of three cruises, the pelagic subarctic Pacific can be classified into two groups. First group is characterized by roughly 1:1 consumption of silicate and nitrate, and occupies rather larger area of subarcfic Pacific, i.e., the Gulf of Alaska and the Western Subarctic gyre (averaged slope of Si:N linear regression: 1.21, n = 10 and 1.45, n = 9, respectively). Second group is the regions of the Bering Sea basin and the Oyashio region, and showed higher silicate consumption compared to that of nitrate (averaged slope of Si:N linear regression: 2.14, n = 9 and 2.36, n = 3, respectively). The Si:N difference observed is possibly attributed to relative contribution of diatoms production among the phytoplankton assemblages in the regions, i.e., dominance of diatoms production in the regions of the second group. Higher accumulation of ammonium at the bottom of euphotic layer in the summer Bering Sea basin would also contribute to increase consumption ratio of Si:N amounts.  相似文献   
39.
Pumping rate of a mud shrimp,Callianassa japonica, in its burrow was measured by continuous monitoring of dye concentration in the burrow water. Measurement of dilution in two directions from stained overlying seawater to normal burrow water andvice versa, gave no significant difference in results. The rate of exchange (v) of burrow water was estimated from,v=(u tu 0)V/(mu t−1)t, whereV is volume of burrow water,u 0,u t−1 andu tis dye concentration of burrow water at time 0,t−1 andt, respectively, andm is dye concentration of overlying water. The pumping rate ranged from 0.63 to 5.46 ml min−1, which corresponded to a turnover time for the burrow water of 7–51 min. Short term changes in the pumping rate were correlated to intermittent behaviour of the shrimp in the burrow.  相似文献   
40.
A Geographic Information System (GIS)-aided flow-tracking technique was adopted to investigate nutrient exchange rates between specific benthic communities and overlying seawater in a fringing reef of Ishigaki Island, subtropical Northwestern Pacific. Net exchange rates of NO3 , NO2 , NH4 +, PO4 3−, Total-N and Total-P were estimated from concentration changes along the drogue trajectories, each of which was tracked by the Global Positioning System and plotted on a benthic map to determine the types of benthic habitat over which the drogue had passed. The observed nutrient exchange rates were compared between 5 typical benthic zones (branched-coral (B) and Heliopora communities (H), seaweed-reefrock zone (W), bare sand area (S), and seagrass meadow (G)). The dependence of nutrient exchange rates on nutrient concentrations, physical conditions and benthic characteristics was analyzed by multiple regression analysis with the aid of GIS. The spatial correlation between nutrient exchange rates and benthic characteristics was confirmed, especially for NO3 and PO4 3−, which were usually absorbed in hydrographically upstream zones B and W and regenerated in downstream zones H and G. NO3 uptake in zones B and W was concentration-dependent, and the uptake rate coefficient was estimated to be 0.58 and 0.67 m h−1, respectively. Both nutrient uptake in zone W and regeneration in zone H were enhanced in summer. The net regeneration ratio of NO3 /PO4 3− in zone H in summer ranged 5.2 to 34 (mean, 17.4), which was somewhat higher than previously measured NO3 /PO4 3− for sediment pore waters around this zone (1.1–8.5). Nutrient exchanges in zone S were relatively small, indicating semi-closed nutrient cycling at the sediment-water interface of this zone. NH4 + efflux from sediments was suggested in zone G. The data suggest that the spatial pattern of nutrient dynamics over the reef flat community was constrained by zonation of benthic biota, and that abiotic factors such as nutrient concentrations and flow rates, influenced nutrient exchange rates only in absorption-dominated communities such as zones B and W.  相似文献   
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