The influence of crystal field stabilization energy on Fe2+ partitioning in paragenetic minerals     

Klaus Langer  Vladimir M. Khomenko 《Contributions to Mineralogy and Petrology》1999,137(3):220-231

In order to explore possible quantitative relations between crystal field stabilization energy, CFSE, and partitioning behaviour of the 3d ⁶-configured Fe²⁺ ion, a suite of 29 paragenetic rock-forming minerals from 12 high-grade metamorphic rock samples of the Ukrainian shield, including the parageneses garnet/orthopyroxene/clinopyroxene (2x), orthopyroxene/clinopyroxene, garnet/clinopyroxene, garnet/orthopyroxene/biotite, garnet/biotite, garnet/cordierite, garnet/cordierite/biotite, garnet/orthopyroxene/clinopyroxene/Ca-amphibole, Ca-amphibole/biotite (retrograde), was studied by electron microprobe analysis to obtain the respective K _D Fe^{2+ (Ph1/Ph2)} values and by polarized single crystal electronic absorption spectroscopy to evaluate the respective CFSE_Fe2+ values. Other than in the case of Cr³⁺, a clear quantitative relation between K _D ^(Ph1/Ph2) and the ΔCFSE^(Ph1/Ph2) was only observed when geometrical factors, mainly the volume of crystallographic sites and ionic radii of ions competing in the partitioning process, are similar in the respective two paragenetic phases to within 15–20%. In such cases, the ΔCFSE_Fe2+ contribution to K _D ^(Ph1/Ph2) amounts to 0.1 to 0.2 log K _D per 100 cm⁻¹ΔCFSE. The conclusion is that ΔCFSE_Fe2+ plays only a secondary role after geometrical factors, in the partitioning behaviour of Fe²⁺. The reason for this is seen in the facts that, compared to the 3d ³-configured Cr³⁺ ion, CFSE of the 3d ⁶-configured Fe²⁺ amounts only to 20–25%, and that the former ion enters only octahedral sites with similar geometrical properties in the paragenetic mineral phases. Received: 17 November 1998 / Accepted: 28 June 1999  相似文献   

Barium partitioning in coccoliths of Emiliania huxleyi     

Gerald Langer  Gernot Nehrke  Heather Stoll 《Geochimica et cosmochimica acta》2009,73(10):2899-443

The coccolithophore Emiliania huxleyi was grown in seawater under different Ba concentrations. The relationship of coccolith Ba/Ca ratio and seawater Ba/Ca ratio was found to be linear. The linear regression yields the apparent Ba exchange coefficient of 0.10. Our data support a recently proposed generic model (Langer G., Gussone N., Nehrke G., Riebesell U., Eisenhauer A., Kuhnert H., Rost B., Trimborn S., and Thoms S. (2006) Coccolith strontium to calcium ratios in Emiliania huxleyi: the dependence on seawater strontium and calcium concentrations. Limnol. Oceanogr.51, 310-320.) developed for explaining apparent exchange coefficients of metabolically inert divalent trace metals, such as Sr, in E. huxleyi. This model represents the first approach combining cell physiological processes and data from inorganic precipitation experiments, which quantitatively explains coccolith apparent Sr and Ba exchange coefficients.  相似文献   

The dispersion of fibrous amphiboles by glacial processes in the area surrounding Libby,Montana, USA     

William H. Langer  Bradley S. Van Gosen  Gregory P. Meeker  David T. Adams  Todd M. Hoefen 《Environmental Earth Sciences》2011,64(1):157-168

Mining operations began at a world-class vermiculite deposit at Vermiculite Mountain near Libby, Montana, circa 1920 and ended in 1990. Fibrous and asbestiform amphiboles intergrown with vermiculite ore are suspected to be a causative factor in an abnormally high number of cases of respiratory diseases in former mine and mill workers, and in residents of Libby. The question addressed in this report is whether some of the amphibole from Vermiculite Mountain could have been dispersed by Pleistocene glacial processes rather than by human activity after vermiculite mining began. The history of Pinedale glaciation in the Libby area provides a framework for estimating the presence and distribution of asbestiform amphiboles derived from Vermiculite Mountain and found in naturally occurring sediments of Glacial Lake Kootenai that underlie the Libby Valley area. There were two situations where sediments derived from Vermiculite Mountain were deposited into Glacial Lake Kootenai: (1) as lake-bottom sediments derived from meltwater flowing down Rainy Creek when the valley south of Vermiculite Mountain was free of ice but active ice still covered Vermiculite Mountain; and (2) as lake-bottom sediments eroded from the Rainy Creek outwash and re-deposited during a re-advance of the Purcell Trench Glacier lobe near Moyie Springs, Idaho.  相似文献   

Model parameter optimization for site-dependent simulation of ground motion by simulated annealing: Re-evaluation of the Ashigara Valley prediction experiment     

F. Scherbaum  C. Palme  H. Langer 《Natural Hazards》1994,10(3):275-296

More than 40 groups from 10 different countries participated in a weak- and strong-motion prediction experiment at Ashigara Valley which required the blind prediction of time series, spectra and spectral ratios for selected and instrumented sedimentary sites with well-known geotechnical properties. The wide scatter of the results of this experiment have raised a number of questions as to how to model high-frequency ground motion in the presence of available geotechnical and geophysical data. Using a simulated annealing waveform inversion method, we have tried to optimize and automate the model construction for ID site-dependent ground-motion simulation. We found a whole set of successfull models which provide good waveform fit (r > 0.8) for the observed displacement records at site KS2 but also yield sufficiently accurate response spectra and peak value predictions for both surface and downhole site. This shows that ID models are fully adequate to model the site conditions at least for the weak motion data. The resulting successful layer models consistently show a slower, less dense, and slightly thicker low velocity coverage with stronger damping than the official geotechnical model. Furthermore, their statistical properties directly measure the sensitivity of the individual parameters for the simulations. The critical re-evaluation of our own prediction which was based on stochastic simulation shows that although this approach has its greatest merits in situations where little information is available, it can also be successfully applied to model individual records if sufficient care is taken to determine the source parameters. Simulated annealing waveform inversion has shown to be a powerful tool to optimize that process.  相似文献   

Pressure- and temperature-effects on exchange-coupled-pair bands in electronic spectra of some oxygen-based iron-bearing minerals     

M. N. Taran  K. Langer  A. N. Platonov 《Physics and Chemistry of Minerals》1996,23(4-5):230-236

The special properties of spin-allowed transitions of Fe²⁺, exchanged-coupled in pairs with Fe³⁺, (ECP-effect) are studied in single crystals of vivianite, phlogopite, biotite, elbaite and schörl under changing temperature and pressure in the ranges 79≤T[K]≤597 and 10^-4≤P[GPa]≤8. The two Fe²⁺ dd-transitions, known to be subject to ECP-effects, occur at 11000 to 14000 (II) and 8400 to 9150 cm^-1 (III), depending on the structural matrix. With pressure, band energies shift to higher values, while temperature has the opposite effect. Δv is nearly the same in all cases, decrease on temperature, and increase with pressure. Δα/ΔT or Δα/ΔP have similar values for bands II and III in all minerals studied. These observations are interpreted in terms of geometrical and vibrational changes of the octahedra, involved in the pair effects, on changing P and T. They clearly separate the ECP-bands from ordinary dd-transitions and also from IVCT-bands. A unique pressure effect in the spectral range of 17000 to 26000 cm^-1 was found in schörl: a band system that immensly gains intensity on pressure. Two explanations are suggested: (a) traces of Ti³⁺, exchange-coupled to Fe²⁺ show the above pressure effect typical of ECP, (b) there occurs pressureinduced reduction of Ti⁴⁺ in Y-positions, induced by Fe²⁺ in connected Y-octahedra, whereby OH in trans-configuration of Y-octahedra promote this process.  相似文献   

Temperature dependent polarized single crystal absorption spectra of kaemmererite     

M. Andrut  M. Wildner  M. Taran  K. Langer  R. Schulz 《Physics and Chemistry of Minerals》1996,23(4-5):242-243

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Dynamic response of single-span beam bridges to a series of moving loads     

Marian Klasztorny  Jan Langer 《地震工程与结构动力学》1990,19(8):1107-1124

The paper makes a contribution to the problem of a stream of loads crossing a single-span beam bridge. There are considered the basic load models, in the form of a stream of fixed amplitude forces, unsprung masses and viscoelastic oscillators. The matrix equations of motion of the system are formulated and discussed. The problem of dynamic stability and steady-state response of a bridge carrying a periodic stream of inertial loads is formulated and solved. The paper also includes a vibration study of a beam bridge subjected to a uniform stream of moving loads, of a limited or unlimited number of load cycles.  相似文献   

Polarized electronic absorption spectra of synthetic (Mg,Fe)-orthopyroxenes,ferrosilite and Fe3+-bearing ferrosilite     

G. Steffen  K. Langer  F. Seifert 《Physics and Chemistry of Minerals》1988,16(2):120-129

The assignment of spin-allowed Fe²⁺-bands in orthopyroxene electronic absorption spectra is revised by studying synthetic bronzite (Mg_0.8 Fe_0.2)₂Si₂O₆, hypersthene (Mg_0.5 Fe_0.5)₂Si₂O₆ and ferrosilite (Fe₂Si₂O₆). Reheating of bronzite and hypersthene single crystals causes a redistribution of the Fe²⁺-ions over the M1 and M2 octahedra, which was determined by Mössbauer spectroscopy and correlated to the intensity change of the spin-allowed Fe²⁺ d-d bands in the polarized absorption spectra. The 11000 cm^-1 band is caused by Fe²⁺ in M1 (⁵B_2g→⁵A_1g) and Fe²⁺ in M2 (⁵A₁→⁵A₁), the 8500 cm^-1 band by Fe²⁺ in M1 (⁵B_2g→⁵B_1g) and the 5000 cm^-1 band by Fe²⁺ in M2 octahedra (⁵A₁→⁵B₁). The Fe²⁺-Fe³⁺ charge transfer band is identified at 12500cm^-1 in the spectra of synthetic Fe³⁺ -Al bearing ferrosilite. This band shows a strong γ-polarization and therefore is caused by Fe²⁺ -Fe³⁺-ions in edge-sharing octahedra.  相似文献   

High Angular Resolution Study of the Ion and Neutral Spectra as a Probe of the Magnetic Field Structure     

Shih-Ping Lai  T. Velusamy  W.D. Langer 《Astrophysics and Space Science》2004,292(1-4):247-254

We present the observations and analysis of the spectral linewidths of neutral and ion species across the DR21(OH) core to investigate the cyclotron interaction as a probe of magnetic fields. It has been suggested that under average interstellar field strengths the cyclotron interaction between ions and magnetic fields is strong enough to narrow the linewidth and suppress the line wings in the ion spectra. We have obtained high spatial resolution spectral line images of H¹³CN and H¹³CO⁺ at 3 mm in DR21(OH) with the Millimeter Array of the Owens Valley Radio Observatory. Our results show that in the eastern parts of the DR21(OH) core the spectral linewidth of the ions is narrower than that of the neutrals. We use our results, along with the existing Zeeman and dust/CO polarization data on small scales, to derive the 3D magnetic field structure. We obtain a field strength of 0.44 ± 0.12 mG with inclination of 36° to the line of sight, directed toward the observer, and a position angle of ?75° in the plane of the sky.  相似文献   

Exploratory seismic site response surveys in a complex geologic area: a case study from Mt. Etna volcano (southern Italy)     

Panzera  F.  Lombardo  G.  Longo  E.  Langer  H.  Branca  S.  Azzaro  R.  Cicala  V.  Trimarchi  F. 《Natural Hazards》2016,86(2):385-399

A preliminary study targeting to evaluate the local seismic response was performed in the eastern flank of Mt. Etna (southern Italy) using ambient noise measurements. The obtained spectral ratios were subdivided through cluster analysis into different classes of fundamental frequency permitting to draw an iso-frequency contour map. The analysis set into evidence the extreme heterogeneity of lava sequences, which makes difficult to identify a single seismic bedrock formation. Another important outcome, concerning the local seismic effects in terms of frequency and azimuth, is the important role played by the fracture fields associated with the main structural systems of the area. The existence of two zones with strong directional effects striking WNW–ESE and NW–SE, nearly orthogonal to the orientation of the main fracture fields, corroborate such hypothesis.

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