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81.
Despite the long history of the continuum equation approach in hydrology, it is not a necessary approach to the formulation of a physically based representation of hillslope hydrology. The Multiple Interacting Pathways (MIPs) model is a discrete realization that allows hillslope response and transport to be simultaneously explored in a way that reflects the potential occurrence of preferential flows and lengths of pathways. The MIPs model uses random particle tracking methods to represent the flow of water within the subsurface alongside velocity distributions that acknowledge preferential flows and transition probability matrices, which control flow pathways. An initial realization of this model is presented here in application to a tracer experiment carried out in Gårdsjön, Sweden. The model is used as an exploratory tool, testing several hypotheses in relation to this experiment. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
82.
The Qaidam Basin is one of the most sensitive areas to climate change in China, owing to its unique geographical position and ecological condition. In this study, 32 surface‐soil pollen samples were collected to reveal the relationship between modern pollen assemblages, vegetation and precipitation in the eastern region of the Qaidam Basin. The results show that Chenopodiaceae (3.8–87%, average 48%), Artemisia (1.7–64.2%, average 17.5%) and Ephedra (0–90%, average 16.3%) are the dominant pollen types in all samples, and that different pollen assemblages correspond to different vegetation types. DCA and CCA of major pollen types demonstrate that precipitation is an important factor in the control of the distribution of vegetation in the study area. The content and concentration of the three major pollen types (Artemisia, Chenopodiaceae and Ephedra) change with the mean annual precipitation, and the optimum mean annual precipitation for Ephedra, Chenopodiaceae and Artemisia is <80, 80–200 and >160 mm, respectively. Correlation analysis between the variation in grain size of the three major pollen types and the main environmental variables shows that the grain size of the three pollen types is positively correlated with precipitation in the Qaidam Basin. The results confirm that precipitation is the most important environmental factor in the Qaidam Basin, and that it has an important effect on pollen grain size in the study area.  相似文献   
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Glaciostratigraphic investigations at one key locality (Haldum), 9 major and about 160 minor localities in East and Central Jutland, Denmark, together with laboratory work, have led to the establishment of a stratigraphy consisting of 10 till units, usually separated by meltwater deposits. The stratigraphy is in some degree supported by thermoluminescence datings. The complete sequence includes one till unit with associated meltwater deposits of Menapian age, three till units with intercalated meltwater deposits of Elsterian age, marine sediments deposited during the Holsteininan, and three till units with intercalated of Elsterian age, marine sediments deposited during the Holsteinian, and three till units with intercalated glaciofluvial sedimants of Saalian age. Eemian deposits are present above this level, and the whole sequence is capped by till and meltwater deposits related to three glacial advances during the Weichselian.  相似文献   
85.
Charcoal and fossil wood taken from palaeosols, sediments and artificial structures were analysed in order to evaluate the regional pedoanthracological potential and to obtain information on Holocene environmental changes, particularly on possible past tree occurrences in southern Tibet. This research was initiated by the question to what extent this area is influenced by past human impact. Even recent evaluations have perceived the present treeless desertic environment of southern Tibet as natural, and the previous Holocene palaeoenvironmental changes detected were predominantly interpreted to be climate-determined. The material analysed – comprising a total of 53 botanical spectra and 55 radiocarbon datings from 46 sampling sites (c. 3500–4700 m a.s.l.) – represents the largest systematically obtained data set of charcoal available from Tibet so far. 27 taxa were determined comprising trees, (dwarf-) shrubs and herbs as well as grasses. The predominant tree taxa were Juniperus, Hippophae, Salix and Betula. According to their present-day occurrence in the region, the genera Juniperus and Hippophae can be explicitly attributed to tree species. Further, less frequently detected tree taxa were Populus, Pinus, Quercus, Taxus and Pseudotsuga. Charcoal of Juniperus mainly occurred on southern exposures, whereas Betula was associated with northern exposures. In contrast, the (partly) phreatophytic taxa Hippophae and Salix showed no prevalent orientation. The distribution of radiocarbon ages on charcoal revealed a discontinuous record of burning events cumulating in the Late Holocene (c. 5700–0 cal BP). For southern Tibet, these results indicated a Late Holocene vegetation change from woodlands to the present desertic pastures. As agrarian economies in southern and south-eastern Tibet date back to c. 3700 and 5700 cal BP, respectively, and the present-day climate is suitable for tree growth up to c. 4600 m a.s.l., we concluded that the Late Holocene loss or thinning out of woodlands had been primarily caused by humans.  相似文献   
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88.
We have explored first-principles molecular dynamics simulation data for hydrous MgSiO3 liquid (with 10 wt% water) to gain insight into its structural and dynamical behavior as a function of pressure (0–150 GPa) and temperature (2,000–6,000 K). By visualizing/analyzing a number of parameters associated with short- and mid-range orders, we have shown that the melt structure changes substantially on compression. The speciation of the water component at low pressures is dominated by the isolated structures (with over 90% hydrogen participated) consisting of hydroxyls, water molecules, O–H–O bridging and four-atom (O–H–O–H and H–O–H–O) groups, where every oxygen atom may be a part of polyhedron or free (i.e., bound to only magnesium atom). Hydroxyls favor polyhedral sites over magnesium sites whereas molecular water is almost entirely bound to magnesium sites, and also interpolyhedral bridging (Si–O–H–O–Si) dominates other types of bridging. Water content is shown to enhance and suppress, respectively, the proportions of hydroxyls and molecular water. As compression increases, these isolated structures increasingly combine with each other to form extended structures involving a total of five or more O and H atoms and also containing threefold coordination species, which together consume over 80% hydrogen at the highest compression studied. Our results show that water lowers the mean coordination numbers of different types including all cation–anion environments. The hydrous melt tends to be more tetrahedrally coordinated but with the Si–Si network being more disrupted compared to the anhydrous melt. Protons increase the content of non-bridging oxygen and decrease the contents of bridging oxygen as well as oxygen triclusters (present at pressures above 10 GPa). The calculated self-diffusion coefficients of all atomic species are enhanced in the presence of water compared to those of the anhydrous melt. This is consistent with the prediction that water depolymerizes the melt structure at all pressures. Our analysis also suggests that proton diffusion involves two processes—the transfer of H atoms (requiring the rupture and formation of O–H bonds) and the motion of hydroxyls as hydrogen carriers (requiring the rupture and formation of Si–O and/or Mg–O bonds). Both the processes are operative at low compression whereas only the first process is operative at high compression.  相似文献   
89.
A number of different impurities are located in the open channels of natural beryl crystals. The rare Maxixe beryl contains an unusual amount of NO2. The isoelectronic CO2 radical is found in the irradiated Maxixe-type beryl. The NO2 radicals are distributed in the Be–Al plane of the crystal, with the nitrogen atom close to the oxygens of the beryl cavity wall. These oxygens repel the negative CO2 radical, which is located at the center of the beryl cavity and rotates around its O–O axis, which is parallel to the crystal c-axis. When there is a nearby alkali ion at the center of the beryl channel, it reorients the CO2 radical so that its bisector is parallel to the c-axis and points toward the positive ion. Different signals are analyzed for Li+, Na+, and another counter-ion, which probably is Cs+. The related NO3 and CO3 radicals are the color centers in the investigated deep blue beryls. The slow decay of the color, which makes these beryls useless as gem stones, is related to the decay of the hydrogen atoms which are present in these crystals. Evidence is given that NO3 is created in Maxixe beryl by a natural process, while CO3 in Maxixe-type beryl has been created by irradiation. The temperature dependence of the EPR signals of these two radicals was investigated, but a definitive proof that they rotate at the center of the beryl cavity could not be given. EPR signals from some other radicals in beryl have been observed and described.  相似文献   
90.
Cerussite (PbCO3) has been investigated by high-pressure and high-temperature Raman spectroscopy up to pressures of 17.2 GPa and temperatures of 723 K. Two pressure induced phase transitions were observed at about 8.0(2) and 16.0(2) GPa, respectively. The post-aragonite transition (PbCO3-II) at 8.0(2) GPa is accompanied by softening of the v 2-out-of-plane mode of the CO 3 2? group and disappearance of the B1g (v 4-in-plane band of the CO 3 2? group) mode. Stronger shifts of the carbonate group modes after the phase transition suggest that the new structure is more compressible. The formation of a second high-pressure polymorph begins at about 10 GPa. It is accompanied by the occurrence of three new bands at different pressures and splitting of the v 1-symmetric C–O stretching mode of the CO 3 2? group. The transitions are reversible on pressure release. A semi-quantitative phase diagram for PbCO3 as a function of pressure and temperature is proposed.  相似文献   
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