Comparative study of sampling methods and in situ and laboratory analysis for shallow-water submarine hydrothermal systems     

R.E. Villanueva  R.M. Prol-Ledesma  M.A. Torres-Vera  C. Canet  M.A. Armienta  C.E.J. de Ronde 《Journal of Geochemical Exploration》2006,89(1-3):414

A primary aim for sampling of submarine hydrothermal vents is to minimize inclusion of ambient seawater. Here, we compare the results of three different sampling methods (air displacement, two-valve bottle, and syringes) for shallow submarine systems. Mixing of hydrothermal fluid with seawater is unavoidable; however, calculations based on linear mixing models allow estimation of the hydrothermal fluid end-member composition. The results show that sampling with a two-valve bottle and syringes are the best options because they allow collection of samples with a large proportion of hydrothermal fluid. Additionally, we compare the results of in situ and laboratory analyses of the fluid samples, and demonstrate that determination of chemical composition in situ is the best option for some components, as re-equilibration affects some component concentrations (i.e. bicarbonate). Conversely, silica determination in situ usually underestimates the concentration in the fluid, as it does not account for polymeric silica. Other components can be measured either in the field or in the laboratory.  相似文献   

The bimodal rift-related Juscelândia volcanosedimentary sequence in central Brazil: Mesoproterozoic extension and Neoproterozoic metamorphism     

Renato Moraes  Reinhardt A. Fuck  Mrcio Martins Pimentel  Simone M.C.L. Gioia  Maria H.B.M. de Hollanda  Richard Armstrong 《Journal of South American Earth Sciences》2006,20(4):287-301

The Barro Alto Complex and Juscelândia volcanosedimentary sequence are exposed in the central part of the Neoproterozoic Brasília belt of central Brazil. The former is a large (approximately 150 km long), boomerang-shaped, mafic-ultramafic, layered complex formed by two different intrusions metamorphosed under granulite facies. These rocks are tectonically overlain by rocks of the Juscelândia volcanosedimentary sequence, represented mainly by biotite-gneiss and amphibolite, or amphibolite facies metamorphic equivalents of rhyolite and basalt, respectively. New SIMS U–Pb zircon data and Sm–Nd isochron data presented herein help clarify the igneous and metamorphic evolution of the Juscelândia volcanosedimentary sequence, as well as its relationship with the Barro Alto Complex. Zircon grains from two biotite gneisses were analyzed by SIMS (SHRIMP) and indicate Mesoproterozoic dates, approximately 1.28 Ga, interpreted as the time of bimodal volcanism in a tectonic setting transitional between a continental rift and an ocean basin. Metamorphism is constrained by Sm–Nd garnet-whole-rock isochrons for garnet amphibolite and pelitic schists of the Juscelândia sequence, as well as for clinopyroxene-garnet amphibolite and garnet granulite of the Barro Alto Complex, which give ages between 0.74 and 0.76 Ga, in agreement with SIMS dates for metamorphic zircon rims. These new data are significant, because they establish that a single metamorphic event affected both the Barro Alto Complex and the Juscelândia sequence. Based on these new data, we present a modified tectonic model for the Brasília belt.  相似文献   

An Albian–Cenomanian unconformity in the northern Andes: Evidence and tectonic significance     

Elsa Jaimes  Mario de Freitas 《Journal of South American Earth Sciences》2006,21(4):466

The Villeta Group of Colombia and equivalent stratigraphic units of Venezuela and Ecuador comprise marine sequences ranging from Albian to Santonian in age. Deposition of the Villeta Group was presumed to take place entirely in quiet tectonic conditions in a passive margin setting that occupied NW South America. From a large database of 2D/3D seismic, well, surface geology, and biostratigraphic data, we present evidence for intra-Villeta (mostly late Albian–Cenomanian) deformation in parts of the Upper Magdalena Valley and Eastern Cordillera of Colombia, controlled by transpressional fault reactivation, produced by transpressional fault reactivation and thrusting that resulted in an angular unconformity. This event has been largely unnoticed in the literature, but previously scattered evidence supports our observations, suggesting regionally extensive tectonism. Published fission-track age determinations and other geologic evidence from Colombia and Venezuela suggest significant uplifts around 80–100 m.y., which may reflect changes in the subduction regime, with compressional deformation in certain regions and extensional deformation in others. A late Albian onset of compressional deformation along the Colombian and Peruvian segments of the Andes may be related to the opening of the South Atlantic Ocean at equatorial latitudes. Identification of tectonic activity with development of an unconformity in intra-Villeta times provides new insights into understanding the evolution of the Upper Magdalena Valley and adjacent areas of Colombia and western Venezuela and creates new possibilities for hydrocarbon exploration, with additional trapping phases, better reservoir preservation by early migration and secondary porosity, and ultimately facies changes with stratigraphic potential.  相似文献   

Effects of magnetic interactions in anisotropy of magnetic susceptibility: Models, experiments and implications for igneous rock fabrics quantification     

Philippe Gaillot  Michel de Saint-Blanquat  Jean-Luc Bouchez   《Tectonophysics》2006,418(1-2):3

Besides granites of the ilmenite series, in which the anisotropy of magnetic susceptibility (AMS) is mainly controlled by paramagnetic minerals, the AMS of igneous rocks is commonly interpreted as the result of the shape-preferred orientation of unequant ferromagnetic grains. In a few instances, the anisotropy due to the distribution of ferromagnetic grains, irrespective of their shape, has also been proposed as an important AMS source. Former analytical models that consider infinite geometry of identical and uniformly magnetized and coaxial particles confirm that shape fabric may be overcome by dipolar contributions if neighboring grains are close enough to each other to magnetically interact. On these bases we present and experimentally validate a two-grain macroscopic numerical model in which each grain carries its own magnetic anisotropy, volume, orientation and location in space. Compared with analytical predictions and available experiments, our results allow to list and quantify the factors that affect the effects of magnetic interactions. In particular, we discuss the effects of (i) the infinite geometry used in the analytical models, (ii) the intrinsic shape anisotropy of the grains, (iii) the relative orientation in space of the grains, and (iv) the spatial distribution of grains with a particular focus on the inter-grain distance distribution. Using documented case studies, these findings are summarized and discussed in the framework of the generalized total AMS tensor recently introduced by Cañon-Tapia (Cañon-Tapia, E., 2001. Factors affecting the relative importance of shape and distribution anisotropy in rocks: theory and experiments. Tectonophysics, 340, 117–131.). The most important result of our work is that analytical models far overestimate the role of magnetic interaction in rock fabric quantification. Considering natural rocks as an assemblage of interacting and non-interacting grains, and that the effects of interaction are reduced by (i) the finite geometry of the interacting clusters, (ii) the relative orientation between interacting grains, (iii) their heterogeneity in orientation, shape and bulk susceptibility, and (iv) their inter-distance distribution, we reconcile analytical models and experiments with real case studies that minimize the role of magnetic interaction onto the measured AMS. Limitations of our results are discussed and guidelines are provided for the use of AMS in geological interpretation of igneous rock fabrics where magnetic interactions are likely to occur.  相似文献   

Modèles géostatistiques de concentrations ou de débits le long des cours d'eau     

Chantal de Fouquet  Caroline Bernard-Michel 《Comptes Rendus Geoscience》2006,338(5):307-318

Estimating concentrations or flow rates along a stream network requires specific models. Two classes of models, recently proposed in the literature, are generalized, to the intrinsic case in particular. We present a global construction by ‘streams’, i.e. on the whole set of paths between sources and outlet. Combining stationary or intrinsic one-dimensional random functions leads to stationary or intrinsic models on segments, with discontinuities at the forks. A construction from outlet to sources, leads to stationary or intrinsic models on each stream, without any discontinuity at the forks. The linear variogram is found as a particular case. The extension to the linear model of coregionalization is immediate, allowing a multivariate modelling of concentrations. To cite this article: C. de Fouquet, C. Bernard-Michel, C. R. Geoscience 338 (2006).  相似文献   

Book reviews     

Anne Marie de Grosbois 《Environmental Geology》2006,49(4):642-643

  相似文献   

Origin of fluids in iron oxide–copper–gold deposits: constraints from δ 37Cl, 87Sr/86Sri and Cl/Br     

Massimo Chiaradia  Dave Banks  Robert Cliff  Robert Marschik  Antoine de Haller 《Mineralium Deposita》2006,41(6):565-573

The origin of the hypersaline fluids (magmatic or basinal brine?), associated with iron oxide (Cu–U–Au–REE) deposits, is controversial. We report the first chlorine and strontium isotope data combined with Cl/Br ratios of fluid inclusions from selected iron oxide–copper–gold (IOCG) deposits (Candelaria, Raúl–Condestable, Sossego), a deposit considered to represent a magmatic end member of the IOCG class of deposit (Gameleira), and a magnetite–apatite deposit (El Romeral) from South America. Our data indicate mixing of a high δ ³⁷Cl magmatic fluid with near 0‰ δ ³⁷Cl basinal brines in the Candelaria, Raúl–Condestable, and Sossego IOCG deposits and leaching of a few weight percent of evaporites by magmatic-hydrothermal (?) fluids at Gameleira and El Romeral. The Sr isotopic composition of the inclusion fluids of Candelaria, Raúl–Condestable, and El Romeral confirms the presence of a non-magmatic fluid component in these deposits. The heavy chlorine isotope signatures of fluids from the IOCG deposits (Candelaria, Raúl–Condestable, Sossego), reflecting the magmatic-hydrothermal component of these fluids, contrast with the near 0‰ δ ³⁷Cl values of porphyry copper fluids known from the literature. The heavy chlorine isotope compositions of fluids of the investigated IOCG deposits may indicate a prevailing mantle Cl component in contrast to porphyry copper fluids, an argument also supported by Os isotopes, or could result from differential Cl isotope fractionation processes (e.g. phase separation) in fluids of IOCG and porphyry Cu deposits.  相似文献   

Planning for source water protection in Ontario   总被引：2，自引：0，他引：2  

J.L. Ivey  R.C. de Loë  R.D. Kreutzwiser 《Applied geography (Sevenoaks, England)》2006,26(3-4):192-209

Ontario began developing a drinking water source protection planning process in 2000, after a rural community's water supply was contaminated by pathogens from agricultural runoff. An expert committee report has recommended legislating a new source protection “sphere of jurisdiction” for municipalities; however, no specific new municipal tools or authorities have been proposed as yet. This paper reports findings from an evaluation of the extent to which existing institutional arrangements for land use planning and water management facilitate or constrain source protection by municipalities. A case study of the Regional Municipality of Waterloo suggests there is the potential to link land use planning more strongly to water management through creative use of existing tools, forgoing the need for major institutional changes.  相似文献   

The origin of the Pedra Furada sandstone tubular structures (South of Lisbon, Portugal)     

T.M. Azevêdo  M.M. Abreu  M. Azevedo Coutinho  J. Figueiras 《Geomorphology》2006,82(3-4):245-254

The Pedra Furada is a 12 m wide, 18 m high outcrop feature showing hundreds of ferruginised sandy tubes and looking in part like a giant organ. In this paper the origin of the tubes is explained on the basis of geochemical, petrographic and microscopic (optical and electronic) analytical data. The tubes are considered to represent vertical escape channels for overpressured water, exhibiting inward decreasing grain size due to water velocity gradients inside the escape channels. The ferruginisation is due to iron oxides associated with colloidal/clayey fine sediments and to goethite formed from solution. The overpressure of water may be due to seismically fluidised beds below the Pedra Furada outcrop or to artesian water ascent. In both cases, fault rupturing may have played a major role in the focussing of the ascending flow.  相似文献   

Fault plane orientations of small earthquakes of the 1997 Umbria-Marche (Italy) seismic sequence from P-wave polarities and rise times     

Marilena Filippucci  Salvatore de Lorenzo  Enzo Boschi 《Geophysical Journal International》2006,166(1):322-338

  相似文献