Equilibrium interface segregation in the diopside-forsterite system II: Applications of interface enrichment to mantle geochemistry     

Takehiko Hiraga  Marc M. Hirschmann 《Geochimica et cosmochimica acta》2007,71(5):1281-1289

Segregation of incompatible elements at grain interfaces may have considerable influence on the physical and chemical properties of mantle rocks. Using a recently developed predictive model to estimate the interface enrichment of elements based on their mineral/melt partitioning (Hiraga and Kohlstedt, companion paper), we consider interface enrichment for a simplified model peridotite consisting of olivine, orthopyroxene, and clinopyroxene. Our calculated results reveal the following: (1) Significant amounts of heavy alkali elements and rare gases likely reside at grain-grain interfaces, whereas interface concentrations of less incompatible are less pronounced. (2) The contribution of the chemical components stored at interfaces to whole-rock chemistry strongly depends on mineral mode and, most importantly, on grain size. (3) Grain size reduction resulting from dynamic recrystallization can increase the total storage of highly incompatible elements on grain interfaces and thereby will diminish their concentration in mineral grains. (4) Analysis of Cs concentrations in mantle clinopyroxenes potentially provides estimates of the grain size of mantle rocks. (5) Transport through peridotite will be dominated by diffusion along interfaces rather than through grain interiors for elements less compatible than Lu.  相似文献   

Spatial and temporal variability and drivers of net ecosystem metabolism in western Gulf of Mexico estuaries     

Marc J. Russell  Paul A. Montagna 《Estuaries and Coasts》2007,30(1):137-153

Net ecosystem metabolism (NEM) is becoming a commonly used ecological indicator of estuarine ecosystem metabolic rates. Estuarine ecosystem processes are spatially and temporally variable, but the corresponding variability in NEM has not been properly assessed. Spatial and temporal variability in NEM was assessed in four western Gulf of Mexico shallow water estuaries. NEM was calculated from high-frequency dissolved oxygen measurements. Interbay, intrabay, and water column spatial scales were assessed for NEM, gross primary production (GPP), and respiration (R) rate variability. Seasonal, monthly, and daily temporal scales in NEM, GPP, and R were also assessed. Environmental conditions were then compared to NEM to determine which factors were correlated with each temporal and spatial scale. There was significant NEM spatial variability on interbay, intrabay, and water column spatial scales. Significant spatial variability was ephemeral, so it was difficult to ascertain which environmental conditions were most influential at each spatial scale. Significant temporal variability in NEM on seasonal, monthly, and daily scales was found and it was correlated to temperature, salinity, and freshwater inflow, respectively. NEM correlated strongly with dissolved oxygen, temperature, and salinity, but the relationships where different in each bay. The dynamics of NEM on daily scales indicate that freshwater inflow events may be the main driver of NEM in the semiarid estuaries studied. The variable nature of NEM found here is further evidence that it is not valid to use single station monitoring deployments for assessment of whole estuarine ecosystem metabolic rates in large ecosystems. The relationship between NEM and temperature, salinity, and freshwater inflow events could drive predictive models assessing the potential influence of projected climate change and watershed development scenarios on estuarine metabolic rates.  相似文献   

North-south transfer zones and paleo-morphological reconstruction of the Xylokastro area (Corinth Gulf, Greece)     

Joachim Place  Yves Graud  Marc Diraison  Laurence Warr 《Tectonophysics》2007,440(1-4):121-139

A large number of studies have documented the structural and sedimentary architecture of the Corinth Gulf, especially the major E–W trending normal faults important in accommodating the main extensional strain and associated growth of the Gilbert fan deltas. However, the role of several N–S oriented structures that crop out at the surface and are detectable at depth by seismic reflection and gravity surveys are not clearly understood. Based on new geological data, collected near Xylokastro, we describe the N–S oriented tectonic activity of this area. The mapped inland faults correspond to off-shore structures identified in re-interpreted seismic lines and appear to have acted as a major transfer zone during the opening of the Corinth Gulf. Reconstruction of the paleo-topography based on sedimentary facies and the environment of clay mineral formation suggest these transfer zones played an important role in controlling both local structural relief and depositional conditions of the Gilbert fan deltas.  相似文献   

The Spatial and Temporal Characteristics of Pc3 Geomagnetic Activity over Canada in 2000, as a Guide to Planning the Times of Aeromagnetic Surveys     

Marc A. Vallée  Larry Newitt  Ian R. Mann  Mouhamed Moussaoui  Régis Dumont  Pierre Keating 《Pure and Applied Geophysics》2007,164(1):161-176

Geomagnetic activity affects aeromagnetic surveys. Geomagnetic variations are quite complex and can be quantified in different ways. A measure of geomagnetic activity that is useful for planning aeromagnetic surveys is the Pc3 pulsation index developed by the Australian Space Weather Agency. Purposeful to developing guidelines for planning aeromagnetic surveys in Canada, we study the variations in Pc3 index amplitude over Canada in 2000. This study shows distinct patterns associated with the sub-auroral zone, the auroral zone, and the polar cap. Average Pc3 index activity is higher during the months of February, July, September, and November in the auroral and sub-auroral zones. The station in the polar cap exhibits maximum activity near midday during the summer months. Detailed analysis of a magnetic storm shows that Pc3 index amplitude during the beginning of the solar storm is least important at the polar cap. The mean Pc3 index also relates to solar wind parameters such as the solar wind velocity and the vertical polarity of the interplanetary magnetic field. Analysis of the morning maximum of the Pc3 index observed in the auroral zone can be used to develop guidelines for planning aeromagnetic surveys in Canada and other areas of the world affected by auroral zones.  相似文献   

Large-eddy simulation of plant canopy flows using plant-scale representation     

Wusi Yue  Marc B. Parlange  Charles Meneveau  Weihong Zhu  René van Hout  Joseph Katz 《Boundary-Layer Meteorology》2007,124(2):183-203

Turbulent flow in a corn canopy is simulated using large-eddy simulation (LES) with a Lagrangian dynamic Smagorinsky model. A new numerical representation of plant canopies is presented that resolves approximately the local structure of plants and takes into account their spatial arrangement. As a validation, computational results are compared with experimental data from recent field particle image velocimetry (PIV) measurements and two previous experimental campaigns. Numerical simulation using the traditional modelling method to represent the canopy (field-scale approach) is also conducted as a comparison to the plant-scale approach. The combination of temporal PIV data, LES and spatial PIV data allows us to couple a wide range of relevant turbulence scales. There is good agreement between experimental data and numerical predictions using the plant-scale approach in terms of various turbulence statistics. Within the canopy, the plant-scale approach also allows the capture of more details than the field-scale approach, including instantaneous gusts that penetrate deep inside the canopy.  相似文献   

Concentration profiles of particles settling in the neutral and stratified atmospheric boundary layer     

Marcelo Chamecki  René van Hout  Charles Meneveau  Marc B. Parlange 《Boundary-Layer Meteorology》2007,125(1):25-38

An expression for the vertical equilibrium concentration profile of heavy particles, including the effects of canopy on the eddy diffusivity as well as corrections for atmospheric stability, is proposed. This expression is validated against measurements of vertical concentration profiles of corn pollen above a corn field. The fitted theoretical profiles show that particle settling is correctly accounted for. The sensitivity to variations in the turbulent Schmidt number, settling velocity and stability corrections are explicitly characterized. The importance of independent measurements of the surface flux of pollen in future experiments is noted.  相似文献   

Spatial Breakdown Point of Variogram Estimators     

Marc G. Genton 《Mathematical Geology》1998,30(7):853-871

In the context of robust statistics, the breakdown point of an estimator is an important feature of reliability. It measures the highest fraction of contamination in the data that an estimator can support before being destroyed. In geostatistics, variogram estimators are based on measurements taken at various spatial locations. The classical notion of breakdown point needs to be extended to a spatial one, depending on the construction of most unfavorable configurations of perturbation. Explicit upper and lower bounds are available for the spatial breakdown point in the regular unidimensional case. The difficulties arising in the multidimensional case are presented on an easy example in IR² , as well as some simulations on irregular grids. In order to study the global effects of perturbations on variogram estimators, further simulations are carried out on data located on a regular or irregular bidimensional grid. Results show that if variogram estimation is performed with a 50% classical breakdown point scale estimator, the number of initial data likely to be contaminated before destruction of the estimator is roughly 30% on average. Theoretical results confirm the previous statement on data in IR^d , d 1.  相似文献   

Petrology and geochronology of basalt breccia from the 1996 earthquake swarm of Loihi seamount, Hawaii: magmatic history of its 1996 eruption     

Michael O. Garcia  Ken H. Rubin  Marc D. Norman  J. Michael Rhodes  David W. Graham  David W. Muenow  Khalil Spencer 《Bulletin of Volcanology》1998,59(8):577-592

 Samples of basalt were collected during the Rapid Response cruise to Loihi seamount from a breccia that was probably created by the July to August 1996 Loihi earthquake swarm, the largest swarm ever recorded from a Hawaiian volcano. ²¹⁰Po–²¹⁰Pb dating of two fresh lava blocks from this breccia indicates that they were erupted during the first half of 1996, making this the first documented historical eruption of Loihi. Sonobuoys deployed during the August 1996 cruise recorded popping noises north of the breccia site, indicating that the eruption may have been continuing during the swarm. All of the breccia lava fragments are tholeiitic, like the vast majority of Loihi's most recent lavas. Reverse zoning at the rim of clinopyroxene phenocrysts, and the presence of two chemically distinct olivine phenocryst populations, indicate that the magma for the lavas was mixed just prior to eruption. The trace element geochemistry of these lavas indicates there has been a reversal in Loihi's temporal geochemical trend. Although the new Loihi lavas are similar isotopically and geochemically to recent Kilauea lavas and the mantle conduits for these two volcanoes appear to converge at depth, distinct trace element ratios for their recent lavas preclude common parental magmas for these two active volcanoes. The mineralogy of Loihi's recent tholeiitic lavas signify that they crystallized at moderate depths (∼8–9 km) within the volcano, which is approximately 1 km below the hypocenters for earthquakes from the 1996 swarm. Taken together, the petrological and seismic evidence indicates that Loihi's current magma chamber is considerably deeper than the shallow magma chamber (∼3–4 km) in the adjoining active shield volcanoes. Received: 21 August 1997 / Accepted: 15 February 1998  相似文献   

The kinematics of the ionized gas in the Circinus galaxy     

Marc Elmouttie  Bärbel Koribalski  Scott Gordon  Keith Taylor  Sally Houghton  Tracy Lavezzi  Raymond Haynes  & Keith Jones 《Monthly notices of the Royal Astronomical Society》1998,297(1):49-68

The TAURUS-2 Fabry–Perot interferometer, mounted on the 3.9-m Anglo-Australian Telescope, has been used to observe the Circinus galaxy. We have mapped the intensity and velocity distribution of the ionized hydrogen in the galaxy using the Balmer series Hα spectral line.
The semiresolved core (observed with a seeing disc of 30 pc) appears amorphous in shape, which is commonly observed in Seyfert 2 galaxies. Its peak coincides with the core position measured in the radio continuum, suggesting that ionized gas surrounds a non-thermal source.
A circumnuclear ring or spiral of radius 220 pc and a rotational velocity of 350 km s⁻¹ (assuming circular motions) surrounds the core. The inclination angle of this feature, i =40°±10°, is less than that of the previously observed radio continuum disc. The velocity channel maps obtained for the Hα ring show that the kinematics resemble those of a rotating ring and the intensity displays a complex structure indicative of several, unresolved, H II regions. We believe the ring to represent a circumnuclear starburst.
Our Hα data also show the presence of the previously detected [O III ] ionization cone to the north-west of the core, measuring more than 400 pc in length. We suggest that the ionization cone lies in a different plane from that of the starburst ring and is directed away from us. Several kinematic components of the core are derived and we calculate an outflow velocity in excess of 150–200 km s⁻¹ for gas above the core of Circinus. We also present evidence for inflowing ionized gas at the centre of Circinus.
The correlation of the Hα and radio continuum features is discussed, as well as the possible presence of a starburst-driven superwind in the Circinus galaxy.  相似文献   

Chemical and isotopic prediction of aquifer temperatures in the geothermal system at Long Valley, California     

R.O. Fournier  M.L. Sorey  R.H. Mariner  A.H. Truesdell 《Journal of Volcanology and Geothermal Research》1979,5(1-2)

Temperatures of aquifers feeding thermal springs and wells in Long Valley, California, estimated using silica and Na-K-Ca geothermometers and warm spring mixing models, range from 160/dg to about 220°C. This information was used to construct a diagram showing enthalpy-chloride relations for the various thermal waters in the Long Valley region. The enthalpy-chloride information suggests that a 282 ± 10°C aquifer with water containing about 375 mg chloride per kilogram of water is present somewhere deep in the system. That deep water would be related to 220°C Casa Diablo water by mixing with cold water, and to Hot Creek water by first boiling with steam loss and then mixing with cold water. Oxygen and deuterium isotopic data are consistent with that interpretation. An aquifer at 282°C with 375 mg/kg chloride implies a convective heat flow in Long Valley of 6.6 × 10⁷ cal/s.  相似文献