Treatment of a Trifluraline Effluent by Means of Oxidation‐Coagulation with Fe(VI) and Combined Fenton Processes     

Ayrton F. Martins  Carla da S. Frank  Marcelo L. Wilde 《洁净——土壤、空气、水》2007,35(1):88-99

The amination water (AW) effluent stream from the industrial production of the trifluraline herbicide was submitted to an oxidation‐coagulation treatment with potassium ferrate, combined with advanced oxidation processes. The experimental results obtained by analysis of variance (ANOVA) for the oxidation‐coagulation‐Fenton process, evaluating the variables pH (A), Fe(VI) concentration (B), and H₂O₂ concentration (C), demonstrated that the regression equation resulting from the Response Surface Methodology (RSM) experimental design, for the quadratic model, was η_Abs (%) = 36.9– 21.58A + 8.37A² + 1.36B + 0.92B² + 1.08C + 1.52C² + 1.27AB – 1.34AC + 1.33BC. The maximum absorptiometric color reduction occurred at pH 3, with corresponding maximum amounts of iron and hydrogen peroxide. The absorptiometric color and COD reduction were 96% and 57%, respectively. For the oxidation‐coagulation‐photo‐Fenton process, the analyzed variables were pH (A), Fe(VI) concentration (B), H₂O₂ concentration (C), and temperature (D). The regression equation resulting from the quadratic model was η_Abs (%) = 38.3 – 20.2A + 8.12A² – 0.27B + 3.73B² + 0.3C + 3.6C² + 1.67D + 3.1D² + 1.72AB + 0.51AC – 1.82AD + 0.74BC – 1.11BD + 0.03CD. The ANOVA response showed that the highest absorptiometric color reduction occurred at pH 3, with respective maximum amounts of iron and hydrogen peroxide at 60°C. The maximum efficiencies achieved by the proposed treatment process for the trifluraline effluent stream were 95% and 85%, for absorptiometric color and COD reduction, respectively.  相似文献   

Leaf breakdown in two tropical streams: Differences between single and mixed species packs     

Marcelo Moretti  Jos Francisco Gonalves Jr.  Marcos Callisto 《Limnologica》2007,37(3):250-258

We assessed leaf breakdown of five native riparian species from Brazilian Cerrado (Myrcia guyanensis, Ocotea sp., Miconia chartacea, Protium brasiliense, and Protium heptaphyllum), incubated in single and mixed species packs in two headwater streams with different physico-chemical properties in the Espinhaço Mountain range (Southeastern Brazil). Leaves were placed in plastic litter bags (15 cm×20 cm, 10 mm mesh size) and the experiments were carried out during the dry seasons of 2003 and 2004. Leaf nitrogen and phosphorus contents were similar in all species, but polyphenolic contents were different (P<0.001). M. guyanensis showed higher polyphenolics content (8.48% g⁻¹ dry mass) and leaf toughness. Individually, higher breakdown rates were found in M. guyanensis at Indaiá stream (k=0.0063±0.0005 d⁻¹) and in Ocotea sp. at Garcia stream (k=0.0088±0.0006 d⁻¹). However, P. brasiliense and P. heptaphyllum showed lower breakdown rates at Indaiá and Garcia streams (Indaiá: k=0.0020±0.0002 and 0.0019±0.0001 d⁻¹; Garcia: k=0.0042±0.0001 and 0.0040±0.0002 d⁻¹). Single and mixed breakdown processes of each species were not statistically different on both streams. However, all species showed higher breakdown rates at Garcia stream (P<0.01). These results suggest that leaf breakdown is not altered when litter benthic patches are composed by a mixture of species in the same proportions that they occur on riparian leaf falls.  相似文献   

Experimental analysis and modelling of shallow landslides   总被引：1，自引：1，他引：1  

Lorella Montrasio  Roberto Valentino 《Landslides》2007,4(3):291-296

The paper presents the results of some experimental tests reproducing the triggering mechanism of a special kind of shallow landslides induced by rainfalls (soil slip) in a physical 1-g model. The experimental data have been employed to verify the capability of a simplified stability model to describe the phenomenon and to back-analyse its occurrence in a case history (Pizzo d’Alvano, Campania Region 1998). The method enables a direct correlation between the safety factor of a slope and rainfall intensity, as well as antecedent rainfalls.  相似文献   

An abandoned estuary within Marajó Island: Implications for late Quaternary paleogeography of northern Brazil   总被引：1，自引：0，他引：1  

Dilce F. Rossetti  Márcio M. Valeriano  Marcelo Thales 《Estuaries and Coasts》2007,30(5):813-826

Several previous studies have recognized paleochannels as the most typical geomorphologic features imprinted in the modern landscape of Marajó Island, northern Brazil. A characterization of these paleochannels by detailed mapping has not yet been accomplished, despite their great potential for helping reconstructing the succession of events responsible for the origin and evolution of the drainage system at the mouth of the Amazon River during the Quaternary. The present study aims to provide a detailed mapping and characterization of these paleochannels using remote sensing (i.e., SRTM, Landsat 5-TM, and Landsat 7-ETM+), integrated with sedimentological and radiocarbon data obtained from outcrops and cores. The mapped paleochannels allowed for the first time correlation of the channel-like morphologies with fining-upward sedimentary successions, typical of channel deposits. The study focuses on the Lake Arari area located in the northeast of Marajó Island, where a complex fluvial network dominated by a funnel-shaped structure attributed to a Late Pleistocene paleoestuarine system was recognized. The inner estuary was connected to three fluvial channels that ran from the east-southeast throughout an area currently occupied by Marajó Bay, implying that this bay did not exist when the estuarine system was active. Separation of the eastern side of Marajó Island due to tectonic causes related to capture of Tocantins River by northeastward-orientated faults would have interrupted the fluvial inflow, ultimately causing the abandonment of the estuarine system. Today, the central part of the funnel-shaped structure related to the Late Pleistocene paleoestuary is occupied by Lake Arari, where sediments started to accumulate no earlier than the mid-Holocene. It is proposed that this lake might have developed from the Late Pleistocene estuary as the fluvial inflow was cut off during the detachment of Marajó Island. Marajó Island serves as an example of a very dynamic site of changing landscapes throughout the Quaternary as a result of tectonic activity.  相似文献   

Far-Ultraviolet Stellar Emission Measurements from UVSTAR     

Roberto Stalio  Anna Gregorio 《Astrophysics and Space Science》2001,276(1):197-209

We present the relevant results from three UVSTAR missions on STS69,STS85 and STS95. In particular we discuss three hot sub-dwarf star and CMa (500–1250 Å) observations.  相似文献   

B,V, and DDO photometric observations of red variable stars     

T. Storchi Bergmann  Silvia H. B. Livi  Roberto D. D. Costa 《Astrophysics and Space Science》1984,100(1-2):341-349

Light curves of the red variables L₂ Puppis, R Carinae, and S Carinae in the region of the spectrum covered by theB, V, and DDO photometry are presented. The behavior of the DDO color indices and their meaning for this type of star are discussed. S Carinae shows a different behavior from the other two stars that seems to be due to a population effect.  相似文献   

Phosphorus dynamics in water and sediments in urbanized and non-urbanized rivers in Southern Brazil   总被引：1，自引：0，他引：1  

Pagliosa PR  Fonseca A  Bosquilha GE  Braga ES  Barbosa FA 《Marine pollution bulletin》2005,50(9):965-974

Phosphorus flux models show that the removal tends to be a common feature in polluted estuarine systems whereas the release of P to the adjacent coastal area occurs in pristine environments. This study analyzes the distribution of P in water and sediments along six rivers in the south coast of Brazil. Three rivers located inside protected areas were considered non-polluted and used as a control of urbanization. The other three, situated within urbanized areas, were considered as having highly elevated concentrations of P. Results showed a different behavior of P in water and sediments located in urbanized and non-urbanized areas. The concentrations of dissolved organic (P-org) and inorganic (P-inorg) phosphorus in water, and the total phosphorus (P-tot) and polyphosphate (P-poly) in sediments where higher in the urbanized rivers compared to the non-urbanized ones. Both P of punctual origin and of diffuse origin contributed to the maintenance of elevated concentrations and disturbed the natural fluxes along the polluted rivers. The minimum and maximum concentrations in urbanized areas varied from 0.39 to 12.45 (microM) for P-org and 0.00 to 5.92 (microM) for P-inorg in water, and in sediments from 89.90 to 808.16 (microM g(-1)) for P-tot and 0.00 to 76.51 (microM g(-1)) for P-poly. In non-urbanized areas concentrations in water varied from 0.22 to 1.20 (microM) for P-inorg and 4.43 to 5.56 (microM) for P-org, and in sediments from 45.91 to 652.26 (microM g(-1)) for P-tot and 0.00 to 8.61 (microM g(-1)) for P-poly. Using a hierarchical sampling design and a simple model of variation of P (K(d) model) it was possible to demonstrate that urbanized and non-urbanized estuaries may act as sinks or sources of P. The variation of P analysis in different points along each of the six rivers showed that release and removal areas may occur within a same river independently of its urbanization.  相似文献   

First lead isotopic data for cinnabar in the Almadén district (Spain): implications for the genesis of the mercury deposits     

Pablo Higueras  José Munhá  Roberto Oyarzun  Colombo C. G. Tassinari  Izabel R. Ruiz 《Mineralium Deposita》2005,40(1):115-122

The Almadén district constitutes the largest and probably the most intriguing mercury concentration in the world. Two types of mineralization are recognized: 1) stratabound, of Lower Silurian age, well represented by the large Almadén deposit; and 2) fully discordant mercury deposits of minor importance in terms of size, and exemplified by the deposit of Las Cuevas. The latter ones can be found at different positions along the Almadén stratigraphic column. Both types of deposits are always associated with the so-called frailesca rocks (diatremes of alkali basaltic composition). This paper reports the first lead isotope compositions of cinnabar in the district. Whole samples and stepwise leaching cinnabar aliquots display relatively homogeneous isotopic compositions (²⁰⁶Pb/²⁰⁴Pb = 18.112–18.460; ²⁰⁷Pb/²⁰⁴Pb = 15.635–15.705; ²⁰⁸Pb/²⁰⁴Pb = 38.531–38.826). Taken together with Jébrak et al.s (2002) pyrite lead isotope results, the new cinnabar isotopic data define a steep array trend on the ²⁰⁷Pb/²⁰⁴Pb– ²⁰⁶Pb/²⁰⁴Pb diagram, indicating a mixed contribution of lead and probably mercury from different sedimentary sources in the Almadén basin. The Almadén Hg deposits are related to a contemporaneous mafic magmatism that might have provided part of the mercury. Hydrothermal leaching of organic matter from sedimentary rocks and formation of Hg organic complexes enhanced metal solubility, promoting transport from and within the volcanic units.Editorial handling: M. Chiaradia  相似文献   

Comparing different methods of calculating volume-weighted hypolimnetic oxygen (VWHO) in lakes     

Roberto Quinlan  Andrew M. Paterson  John P. Smol  Marianne S. V. Douglas  Bev J. Clark 《Aquatic Sciences - Research Across Boundaries》2005,67(1):97-103

  相似文献   

The NW Scotland earthquake swarm of 1974   总被引：1，自引：0，他引：1  

Marcelo Assumçã 《Geophysical Journal International》1981,67(3):577-586

Summary. A swarm of earthquakes occurred in the Kintail area of NW Scotland in 1974 August with magnitudes up to M_L = 4.6 and reported intensities up to VI MM. One earthquake of the series was recorded by about 60 temporary stations of the LISPB refraction experiment in addition to the permanent LOWNET network. This allowed the determination of an accurate epicentre for that event which was then used as a control event to locate other earthquakes of the Kintail series. The events of that swarm had a strikeslip focal mechanism and seemed to be associated with the Strathconon Fault.  相似文献