Leaching and differential recrystallization of metamict zircon under experimental hydrothermal conditions   总被引：14，自引：0，他引：14  

Thorsten Geisler  Marcus Ulonska  Helmut Schleicher  Robert T. Pidgeon  Wilhelm van Bronswijk 《Contributions to Mineralogy and Petrology》2001,141(1):53-65

We report results of hydrothermal experiments on four alluvial zircons from Sri Lanka, which cover a wide range of radiation damage, at 450 °C and 1.3 kbar for 744 h with 2 M CaCl₂ solution as reactive fluid. After the hydrothermal treatment, the most metamict samples show micrometer-thick reaction rims, which surround apparently unreacted zircon, as revealed by cathodoluminescence (CL) and Nomarski differential interference contrast (NDIC) images. These rims have sharp, curved, and transgressive boundaries with unreacted zircon and are, in some cases, spread out along cracks. The thickness of reaction rims increases with increasing cumulated !-dosage of the starting materials. The reaction rims are strongly enriched in Ca (up to 7000 ppm) and a water species and depleted in radiogenic Pb, Zr, and Si, as revealed by electron microprobe analyses. A significant Th loss from the reaction rims was detected in the case of the most metamict sample, whereas U remained in the structure. FT-infrared spectrometry and X-ray diffraction measurements revealed that the bulk run products were recrystallized. Using micro-Raman spectrometry, we were able to demonstrate that differential recrystallization took place. The reaction rims are strongly recrystallized, whereas the unreacted grain interiors underwent only minor recrystallization. Recrystallization of the rims is accompanied by an enhancement of the integral CL intensity. It is suggested that recrystallization in the reaction rims was catalyzed by water infiltration and ion exchange and prevented significant congruent zircon dissolution under the given experimental conditions. Previous zircon studies have shown that (1) a transgressive morphology, (2) a reduced Th-U ratio, and (3) an enhanced CL emission are also characteristics of rims in zircons from high-grade metamorphic rocks. Based on these similarities between natural and experimentally produced rims, it is suggested that leaching-catalyzed recrystallization is an important alteration process in zircon under wet geological conditions and can account for many complex core-rim structures found in natural zircons. Furthermore, the strong enrichment of Ca in the reaction rims supports previous assumptions that high Ca concentrations in natural zircons are of secondary origin. It is suggested that lower U-Pb concordia intercept ages obtained from single-phase zircons with high Ca contents date a leaching event.  相似文献   

SILTATION RATE IN A TRENCH DREDGED ON FLOODPLAIN IN ESTUARY     

FAN Jiahua Prof.  Senior Engineer  Inst. Water Conservancy  Hydroelectric Power Research  P.O. Box  Beijing  China 《国际泥沙研究》1993,(3)

I. INTRODUCTIONA discharge of 100--200 m3 / s is needed to be diverted from a tidal reach and utilized as cooling water for a Droposed power plant in the Yangtze Estuary. The diversionchannel is divided into two parts by a levee along the river bank, an open channel stretchinside the levee is connected with a trench dredged on the floodplain, as shown in Pig. 1.Since the flow and sediment regimes in these two stretches are different, analysis is madeseparately for each of them.11. ESTI…  相似文献   

Preliminary results of the modelling of the Mexico City valley with a two-dimensional boundary element method for the scattering of SH waves     

E. Reinoso  L.C. Wrobel  H. Power   《Soil Dynamics and Earthquake Engineering》1993,12(8):457-468

A numerical method is used for calculating the two-dimensional scattering of incident SH waves to try to explain some of the amplification patterns observed from recent data of the Mexico City's accelerometric array. The method is briefly presented and its efficiency is tested against analytical and other numerical solutions for canyons and alluvial valleys.

Spectral ratios computed for transition and lake-bed zones of the Mexico City valley with respect to the average motion at hill-zone sites are also presented. The one-dimensional model is used to explain the amplifications observed at a site where the valley is relatively shallow, while the two-dimensional approach is employed at another site at the centre of the valley where irregular amplification patterns have been observed. Results in the time domain are also shown.  相似文献   

Trends in solar radiation over Germany and an assessment of the role of aerosols and sunshine duration   总被引：2，自引：1，他引：1  

H. C. Power 《Theoretical and Applied Climatology》2003,76(1-2):47-63

Summary ¶Global, diffuse, and horizontal direct (beam) irradiances have been evaluated for 13 stations in Germany where the time series vary between 11 and 48 years. Global irradiance has decreased significantly at two stations and increased at four stations. The mean trend in global is an increase of 1.94Wm^–2 or 1.83% per decade. Diffuse irradiance has decreased at five stations, with a mean reduction of 2.44Wm^–2 or 3.46% per decade, while horizontal direct irradiance has increased an average of 4.86Wm^–2 or 10.40% per decade at five stations. Increases in global and direct are most common at stations in the southwest region of Germany, decreases in global were observed in the southeast, and there was an absence of spatial homogeneity in the diffuse trends. Spatial variability in irradiance over Germany is higher in the direct component compared to variability in global and diffuse.Trend analyses of concomitant time series of radiation, bright sunshine duration, and modeled estimates of Ångströms turbidity coefficient suggest that long-term decreases in aerosols are the most likely cause of increases in global irradiance observed at Mannheim, Norderney, and Trier; decreases in diffuse at Hohenpeissenberg, Kassel, Mannheim, and Trier; and increases in direct irradiance at Bocholt, Kassel, Mannheim, and Trier. An increase in sunshine duration at Freiburg likely contributed to an increase in global and direct irradiance observed at that station.  相似文献   

Turbulent fluxes from Helipod flights above quasi-homogeneous patches within the LITFASS area     

Jens Bange  Thomas Spieß  Marcus Herold  Frank Beyrich  Barbara Hennemuth 《Boundary-Layer Meteorology》2006,121(1):127-151

Turbulent fluxes of sensible and latent heat were measured with the helicopter-borne turbulence probe Helipod over a heterogeneous landscape around the Meteorological Observatory Lindenberg during the STINHO-2 and LITFASS-2003 field experiments. Besides the determination of area-averaged heat fluxes, the analysis focused on different aspects of the response of the turbulent structure of the convective boundary layer (CBL) on the surface heterogeneity. A special flight pattern was designed to study flux profiles both over quasi-homogeneous sub-areas of the study region (representing the major land use types—forest, farmland, water) and over a typical mixture of the different surfaces. Significant differences were found between the heat fluxes over the individual surfaces along flight legs at about 80 m above ground level, in agreement with large-aperture scintillometer measurements. This flux separation was still present during some flights at levels near the middle of the CBL. Different scales for the blending height and horizontal heterogeneity were calculated, but none of them could be identified as a reliable indicator of the mixing state of the lower CBL. With the exception of the flights over water, the latent heat flux measurements generally showed a larger statistical error when compared with the sensible heat flux. Correlation coefficients a nd integral length scales were used to characterise the interplay between the vertical transport of sensible and latent heat, which was found to vary between ‘fairly correlated’ and ‘decoupled’, also depending on the soil moisture conditions.  相似文献   

Differences in trace metal concentrations among fluvial morphologic units and implications for sampling   总被引：2，自引：0，他引：2  

S. C. Ladd  W. A. Marcus  S. Cherry 《Environmental Geology》1998,36(3-4):259-270

 This study examines the segregation of trace metals within and between fluvial morphologic units in sand-sized and finer bed sediments in a cobble bed stream. The types of fluvial morphologic units sampled are low gradient riffles, high gradient riffles, glides, eddy drop zones, lateral scour pools, attached bars, and detached bars. Three to nine samples were collected from ten of each type of morphologic unit. All 12 metals show significantly different concentrations between some morphologic units in sediments smaller than 2 mm. Eddy drop zones and attached bars consistently have the highest metal concentrations, while low gradient riffles, high gradient riffles, and glides typically have the lowest concentrations. Metals showing the greatest between-unit variability are Al, Cr, Fe, Cu, and Ti, followed by Co, Mn, and Pb, while Mg, Mn, V, and Zn display relatively few differences between units. Lateral and longitudinal variations of metals within units are not significant, and there was no consistent, predictable variation in metal concentrations with distance downstream. Results indicate that metal studies in other gravel- and cobble-bed streams should include a reconnaissance survey to determine variations between morphologic units, stratify sampling by morphologic unit, and analyze spatial autocorrelation to determine sample spacing. Received: October 1997 · Accepted: 23 March 1998  相似文献   

Details of Hydrochemical Variations in Flowing Wells     

J. Marcus Marsh  John W. Lloyd 《Ground water》1980,18(4):366-373

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The activities of potassium chloride and of water in Dead Sea brine     

Y Marcus 《Geochimica et cosmochimica acta》1977,41(12):1739-1744

The activities of KCl and of H₂O in Dead Sea water were estimated according to several approaches dealing with multicomponent electrolyte solutions. The activity of H₂O, both measured directly via its vapor pressure and calculated theoretically, is 0.754 ± 0.004 for brine of density 1.207 ± 0.003gcm^?3 at 25°C. The mean ionic activity of KCl in this brine ranges from 0.876 to 1.199 according to various treatments. These correspond to binary aqueous solutions 8.6–12.1 times richer than the brine. The brine cannot be simultaneously in equilibrium with respect to both H₂O and KCl with such binary solutions, so a hypothetically perfect semipermeable membrane cannot lead to a state of equilibrium between the brine and aqueous KCl of any concentration.  相似文献   

Quantifying the response of cotton production in eastern Australia to climate change   总被引：1，自引：0，他引：1  

Allyson Williams  Neil White  Shahbaz Mushtaq  Geoff Cockfield  Brendan Power  Louis Kouadio 《Climatic change》2015,129(1-2):183-196

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The eastward shift of the Walker Circulation in response to global warming and its relationship to ENSO variability   总被引：1，自引：1，他引：0  

Tobias Bayr  Dietmar Dommenget  Thomas Martin  Scott B. Power 《Climate Dynamics》2014,43(9-10):2747-2763

This study investigates the global warming response of the Walker Circulation and the other zonal circulation cells (represented by the zonal stream function), in CMIP3 and CMIP5 climate models. The changes in the mean state are presented as well as the changes in the modes of variability. The mean zonal circulation weakens in the multi model ensembles nearly everywhere along the equator under both the RCP4.5 and SRES A1B scenarios. Over the Pacific the Walker Circulation also shows a significant eastward shift. These changes in the mean circulation are very similar to the leading mode of interannual variability in the tropical zonal circulation cells, which is dominated by El Niño Southern Oscillation variability. During an El Niño event the circulation weakens and the rising branch over the Maritime Continent shifts to the east in comparison to neutral conditions (vice versa for a La Niña event). Two-thirds of the global warming forced trend of the Walker Circulation can be explained by a long-term trend in this interannual variability pattern, i.e. a shift towards more El Niño-like conditions in the multi-model mean under global warming. Further, interannual variability in the zonal circulation exhibits an asymmetry between El Niño and La Niña events. El Niño anomalies are located more to the east compared with La Niña anomalies. Consistent with this asymmetry we find a shift to the east of the dominant mode of variability of zonal stream function under global warming. All these results vary among the individual models, but the multi model ensembles of CMIP3 and CMIP5 show in nearly all aspects very similar results, which underline the robustness of these results. The observed data (ERA Interim reanalysis) from 1979 to 2012 shows a westward shift and strengthening of the Walker Circulation. This is opposite to what the results in the CMIP models reveal. However, 75 % of the trend of the Walker Circulation can again be explained by a shift of the dominant mode of variability, but here towards more La Niña-like conditions. Thus in both climate change projections and observations the long-term trends of the Walker Circulation seem to follow to a large part the pre-existing dominant mode of internal variability.  相似文献