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61.
Techniques for characterizing the hydraulic properties and groundwater flow processes of aquifers are essential to design hydrogeologic conceptual models. In this study, rapid time series temperature profiles within open‐groundwater wells in fractured rock were measured using fiber optic distributed temperature sensing (FO‐DTS). To identify zones of active groundwater flow, two continuous electrical heating cables were installed alongside a FO‐DTS cable to heat the column of water within the well and to create a temperature difference between the ambient temperature of the groundwater in the aquifer and that within the well. Additional tests were performed to examine the effects of pumping on hydraulic fracture interconnectivity around the well and to identify zones of increased groundwater flow. High‐ and low‐resolution FO‐DTS cable configurations were examined to test the sensitivities of the technique and compared with downhole video footage and geophysical logging to confirm the zones of active groundwater flow. Two examples are presented to demonstrate the usefulness of this new technique for rapid characterization of fracture zones in open boreholes. The combination of the FO‐DTS and heating cable has excellent scope as a rapid appraisal tool for borehole construction design and improving hydrogeologic conceptual models. 相似文献
62.
Elizabeth A. McHuron James T. Harvey J. Margaret Castellini Craig A. Stricker Todd M. O’Hara 《Marine pollution bulletin》2014
We measured total selenium and total mercury concentrations ([TSe] and [THg]) in hair (n = 138) and blood (n = 73) of harbor seals (Phoca vitulina) from California to assess variation by geography and sex, and inferred feeding relationships based on carbon, nitrogen, and sulfur stable isotopes. Harbor seals from Hg-contaminated sites had significantly greater [THg], and lesser [TSe] and TSe:THg molar ratios than seals from a relatively uncontaminated site. Males had significantly greater [THg] than females at all locations. Sulfur stable isotope values explained approximately 25% of the variability in [THg], indicating increased Hg exposure for seals with a greater use of estuarine prey species. Decreased [TSe] in harbor seals from Hg-contaminated regions may indicate a relative Se deficiency to mitigate the toxic effects of Hg. Further investigation into the Se status and the potential negative impact of Hg on harbor seals from Hg-contaminated sites is warranted. 相似文献
63.
This paper describes the in situ response of groundwater biofilms in an alluvial gravel aquifer system on the Canterbury Plains, New Zealand. Biofilms were developed on aquifer gravel, encased in fine mesh bags and suspended in protective columns in monitoring wells for at least 20 weeks. Four sites were selected in the same groundwater system where previous analyses indicated a gradient of increasing nitrate down the hydraulic gradient from Sites 1 to 4. Measurements during the current study classified the groundwater as oligotrophic. Biofilm responses to the nutrient gradients were assessed using bioassays, with biomass determined using protein and cellular and nucleic acid staining and biofilm activity using enzyme assays for lipid, carbohydrate, phosphate metabolism, and cell viability. In general, biofilm activity decreased as nitrate levels increased from Sites 1 to 4, with the opposite relationship for carbon and phosphorus concentrations. These results showed that the groundwater system supported biofilm growth and that the upper catchment supported efficient and productive biofilms (high ratio of activity per unit biomass). 相似文献
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Radiocarbon dating of soils and sediments is notoriously problematic for the purposes of dating a specific event due to their heterogeneous mix of multiple organic fractions, each of which may have a different radiocarbon age. Numerous studies have failed to agree on which sedimentary fraction or radiocarbon pre-treatment method, if any, provides the closest agreement between the age of a sedimentary fraction and that of associated plant macrofossils or charcoal. We tested the stepped-combustion method of McGeehin et al. (2001), as well as standard radiocarbon humin and humic extraction techniques, using samples from a chronologically well-constrained perennially-frozen site at Quartz Creek, Yukon Territory, Canada. The ages in closest agreement with associated radiocarbon-dated plant macrofossils and with the overlying Dawson tephra were given by the humic and humin fractions, but even these were still older than the macrofossil ages by up to 4195 ± 260 radiocarbon years. The low temperature (LT) humin method recommended by McGeehin et al. (2001) yielded ages older than the macrofossils by up to nearly 4425 ± 240 radiocarbon years. These fractions, while still providing information on the mobility and potential residence times of carbon in soils and sediments, should not be relied upon to provide consistently accurate site chronologies. 相似文献
67.
Katherine C. Filippino Peter W. Bernhardt Margaret R. Mulholland 《Estuaries and Coasts》2009,32(3):410-424
To determine the effects of the Chesapeake Bay outflow plume on the coastal ocean, nutrient concentrations and climatology
were evaluated in conjunction with nitrogen (N) and carbon (C) uptake rates during a 3-year field study. Sixteen cruises included
all seasons and captured high- and low-flow freshwater input scenarios. Event-scale disturbances in freshwater flow and wind
speed and direction strongly influenced the location and type of plume present and thus the biological uptake of N and C.
As expected, volumetric primary productivity rates did not always correlate with chlorophyll a concentrations, suggesting that high freshwater flow does not translate into high productivity in the coastal zone; rather,
high productivity was observed during periods where recycling processes may have dominated. Results suggest that timing of
meteorological events, with respect to upwelling or downwelling favorable conditions, plays a crucial role in determining
the impact of the estuarine plume on the coastal ocean. 相似文献
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69.
Margaret A. McManus Jeff C. Sevadjian Kelly J. Benoit-Bird Olivia M. Cheriton Amanda H. V. Timmerman Chad M. Waluk 《Estuaries and Coasts》2012,35(4):1119-1127
Thin layers of plankton have been documented in a wide variety of environments. The growing body of observations indicates that these features are a critical component of marine ecosystem dynamics and functioning. In the past two decades, much of the research on thin layers was undertaken in temperate coastal waters. Here, we report the first known observations of thin layers of phytoplankton in tropical Hawaiian waters. We conducted an overnight shipboard study during which time we made high-resolution observations of physical and optical structure in the water column. During the overnight cruise, we observed the greatest number of thin layers in the early evening hours when thermal stratification was strongest and most persistent due to a combination of warm air and surface water, as well as light winds. A comparison of these observations with those from temperate regions leads us to hypothesize that the nature and persistence of the physical structure is very important in determining the persistence of thin layered structures. Because plankton biomass is generally lower in tropical regions, the heterogeneous aggregation of food in thin subsurface layers may be more critical to the marine ecosystem than it is in temperate regions where plankton are generally more abundant. 相似文献
70.
Adrian Spence David J. Mcnally Margaret V. McCaul Brett Paull 《Geochimica et cosmochimica acta》2011,75(10):2571-2581
Soil microbial biomass is a primary source of soil organic carbon (SOC) and therefore plays a fundamental role in carbon and nitrogen cycling. However, little is known about the fate and transformations of microbial biomass in soil. Here we employ HR-MAS NMR spectroscopy to monitor 13C and 15N labeled soil microbial biomass and leachate degradation over time. As expected, there is a rapid loss of carbohydrate structures. However, diffusion edited HR-MAS NMR data reveals that macromolecular carbohydrates are more resistant to degradation and are found in the leachate. Aromatic components survive as dissolved species in the leachate while aliphatic components persist in both the biomass and leachate. Dissolved protein and peptidoglycan accumulate in the leachate and recalcitrant amide nitrogen and lipoprotein persists in both the degraded biomass and leachate. Cross-peaks that appear in 1H-15N HR-MAS NMR spectra after degradation suggest that specific peptides are either selectively preserved or used for the synthesis of unknown structures. The overall degradation pathways reported here are similar to that of decomposing plant material degraded under similar conditions suggesting that the difference between recalcitrant carbon from different sources is negligible after decomposition. 相似文献