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81.
Gennaro Ventruti Giancarlo Della Ventura Nicola Corriero Daniele Malferrari Alessandro F. Gualtieri Umberto Susta Maria Lacalamita Emanuela Schingaro 《Physics and Chemistry of Minerals》2016,43(8):587-595
The thermal dehydration process of fibroferrite, FeOH(SO4)·5H2O, a secondary iron-bearing hydrous sulfate, was investigated by in situ high-temperature synchrotron X-ray powder diffraction (HT-XRPD), in situ high-temperature Fourier transform infrared spectroscopy (HT-FTIR) and thermal analysis (TGA-DTA) combined with evolved gas mass spectrometry. The data analysis allowed the determination of the stability fields and the reaction paths for this mineral as well as characterization of its high-temperature products. Five main endothermic peaks are observed in the DTA curve collected from room T up to 800 °C. Mass spectrometry of gases evolved during thermogravimetric analysis confirms that the first four mass loss steps are due to water emission, while the fifth is due to a dehydroxylation process; the final step is due to the decomposition of the remaining sulfate ion. The temperature behavior of the different phases occurring during the heating process was analyzed, and the induced structural changes are discussed. In particular, the crystal structure of a new phase, FeOH(SO4)·4H2O, appearing at about 80 °C due to release of one interstitial H2O molecule, was solved by ab initio real-space and reciprocal-space methods. This study contributes to further understanding of the dehydration mechanism and thermal stability of secondary sulfate minerals. 相似文献
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Life after death: shallow‐water Mediterranean invertebrate communities associated with mammal bones 下载免费PDF全文
Sergi Taboada Maria Bas Carlos Leiva Mariona Garriga Rafael Sardá Conxita Avila 《Marine Ecology》2016,37(1):164-178
Invertebrate and microbial marine communities associated with mammal bones are interesting and poorly understood habitats, mainly known from studies on deep‐water whale remains. In order to characterize these communities in the shallow‐water Mediterranean, we present here the results of a pioneering experiment using mammal bones. Minke whale, pig and cow bones were experimentally deployed on three different background communities: rocky substrate, soft‐bottom and a Posidonia oceanica meadow. Bones were deployed for a year at about 20 m depth and collected every 3 months, and the invertebrate fauna colonizing the bones was identified to the lowest possible taxonomic level. As expected, mammal bones showed remarkable differences when compared with background communities. Within bones, four different clusters could be identified, primarily on the basis of the polychaete fauna, the most abundant and diverse group in the survey. Clusters A1–A3 corresponded to high to moderately altered successional stages composed by a fauna closer to that of anthropogenically enriched shallow‐water environments. These clusters were characterized by the occurrence of the opportunist polychaetes Ophryotrocha puerilis, Neanthes caudata (Cluster A1), Protodorvillea kefersteini (Cluster A2) and Ophryotrocha alborana (Cluster A3). Cluster B was characterized by the presence of the polychaete Oxydromus pallidus together with typical invertebrate background fauna, which suggests that this community, after a year of deployment, was closer to that found in natural conditions. As opposed to similar shallow‐water studies in other geographic areas, no occurrence of the polychaete Osedax (commonly known as bone‐eating worms) was reported from our experiments. Apart from the study on the invertebrate communities, insights about the population dynamics of three of the most abundant species (O. puerilis, O. alborana, N. caudata) are given as well as remarks on a hypothetical trophic network based on fecal pellet analysis. 相似文献
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The influence of physical and biological processes on the ichthyoplankton communities in the Gulf of Sirte (Southern Mediterranean Sea) 下载免费PDF全文
Angela Cuttitta Sergio Bonomo Salem Zgozi Angelo Bonanno Bernardo Patti Enza Maria Quinci Marco Torri Mohamed Hamza Abdul Fatah Daw Haddoud Akram El Turki Abdul Bari Ramadan Simona Genovese Salvatore Mazzola 《Marine Ecology》2016,37(4):831-844
This paper reports on the first study on the ichthyoplankton community structure in the Gulf of Sirte and its spatial distribution in relation to environmental conditions and zooplankton abundance. The results make an important contribution to the future management of fisheries in this unexplored, but much exploited, area. Biological samples were collected in July 2008 using a Bongo40 net. In total, 1914 larvae were found and 1652 of these were identified. In particular, bathypelagic taxa were the most abundant, followed by demersal, mesopelagic, pelagic and epipelagic taxa. The ichthyoplankton community had a patchwork distribution influenced by oligotrophic conditions, the bottom depth and oceanographical features. The results suggest that environmental forcings were able to transport the ichthyoplankton to productive areas. Indeed, maximum fish egg densities were found in coastal stations in correspondence with the Atlantic Tunisian Current inflow, whereas larvae were mainly concentrated in the east side of the Gulf, probably as a result of advection by the anticyclonic circulation. Additionally, the distribution patterns of the total larvae density and the different assemblages were well matched with the abundance of the zooplankton, probably determining final larval survival, growth and recruitment. 相似文献
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Pedro Henrique Cipresso Pereira Isabela Carolina Silva Leal Maria Elisabeth de Araújo 《Marine Ecology》2016,37(4):760-769
Although underwater visual census (UVC) is the most frequently used technique for quantifying reef fish assemblages, remote video analysis has been gaining attention as a potential alternative. In the South Atlantic Ocean, Millepora spp. (class Hydrozoa) are the only branching coral species; however, little is known about the ecological role that they play for reef fish communities. We compared these two observation methods (remote video and UVC) to estimate reef fish abundance and species richness associated with colonies of the fire‐coral Millepora alcicornis at Tamandaré Reefs, Northeast Brazil. Additionally, the two different techniques were used to compare species behaviour in association with fire‐corals in order to examine the biases associated with each technique and provide useful information for behavioural ecologists studying fish–coral associations. There were no differences in reef fish abundance or species richness sampled by remote video or UVC. However, a significant difference in the behaviour of associated fish was recorded between the two methods. In the presence of a diver carrying out a UVC, fish were observed spending more time sheltered amongst the coral branches compared with passively swimming on coral colonies with the remote video technique. Specifically, on the remote video recordings agonistic interactions between fish and passive swimming accounted for 33.3% and 22.2% of the census time, respectively. By comparison, when observed by a diver fish spent 34.8% of their time sheltering amongst the coral branches. We demonstrate that both techniques are similarly effective for recording fish abundance and species richness associated with fire‐corals. However, differences were observed in the ability of each method to detect the behaviour of coral‐associated fishes. Our findings show that behavioural ecologists studying complex fish–coral associations need to ensure that their aims are clearly defined and that they choose the most appropriate technique for their study in order to minimize methodological biases. 相似文献
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Holger Frey Christian Huggel Yves Bühler Daniel Buis Maria Dulce Burga Walter Choquevilca Felipe Fernandez Javier García Hernández Claudia Giráldez Edwin Loarte Paul Masias Cesar Portocarrero Luis Vicuña Marco Walser 《Landslides》2016,13(6):1493-1507
The town of Santa Teresa (Cusco Region, Peru) has been affected by several large debris-flow events in the recent past, which destroyed parts of the town and resulted in a resettlement of the municipality. Here, we present a risk analysis and a risk management strategy for debris-flows and glacier lake outbursts in the Sacsara catchment. Data scarcity and limited understanding of both physical and social processes impede a full quantitative risk assessment. Therefore, a bottom-up approach is chosen in order to establish an integrated risk management strategy that is robust against uncertainties in the risk analysis. With the Rapid Mass Movement Simulation (RAMMS) model, a reconstruction of a major event from 1998 in the Sacsara catchment is calculated, including a sensitivity analysis for various model parameters. Based on the simulation results, potential future debris-flows scenarios of different magnitudes, including outbursts of two glacier lakes, are modeled for assessing the hazard. For the local communities in the catchment, the hazard assessment is complemented by the analysis of high-resolution satellite imagery and fieldwork. Physical, social, economic, and institutional vulnerability are considered for the vulnerability assessment, and risk is eventually evaluated by crossing the local hazard maps with the vulnerability. Based on this risk analysis, a risk management strategy is developed, consisting of three complementing elements: (i) standardized risk sheets for the communities; (ii) activities with the local population and authorities to increase social and institutional preparedness; and (iii) a simple Early Warning System. By combining scientific, technical, and social aspects, this work is an example of a framework for an integrated risk management strategy in a data scarce, remote mountain catchment in a developing country. 相似文献
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