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31.
The second field campaign of the Cloud Ice Mountain Experiment (CIME) project took place in February 1998 on the mountain Puy de Dôme in the centre of France. The content of residual aerosol particles, of H2O2 and NH3 in cloud droplets was evaluated by evaporating the drops larger than 5 μm in a Counterflow Virtual Impactor (CVI) and by measuring the residual particle concentration and the released gas content. The same trace species were studied behind a round jet impactor for the complementary interstitial aerosol particles smaller than 5 μm diameter. In a second step of experiments, the ambient supercooled cloud was converted to a mixed phase cloud by seeding the cloud with ice particles by the gas release from pressurised gas bottles. A comparison between the physical and chemical characteristics of liquid drops and ice particles allows a study of the fate of the trace constituents during the presence of ice crystals in the cloud.In the present paper, an overview is given of the CIME 98 experiment and the instrumentation deployed. The meteorological situation during the experiment was analysed with the help of a cloud scale model. The microphysics processes and the behaviour of the scavenged aerosol particles before and during seeding are analysed with the detailed microphysical model ExMix. The simulation results agreed well with the observations and confirmed the assumption that the Bergeron–Findeisen process was dominating during seeding and was influencing the partitioning of aerosol particles between drops and ice crystals. The results of the CIME 98 experiment give an insight on microphysical changes, redistribution of aerosol particles and cloud chemistry during the Bergeron–Findeisen process when acting also in natural clouds.  相似文献   
32.
The methodology developed for connecting Local Vertical Datums (LVD) was applied to the Australian Height Datum (AHD) and the North American Vertical Datum (NAVD88). The geopotential values at AHD and NAVD88 were computed and the corresponding vertical offset of 974 mm with rms 51 mm was obtained between the zero reference surfaces defined by AHD and NAVD88. The solution is based on the four primary geodetic parameters, the GPS/levelling sites and the geopotential model EGM96. The Global Height System (or the Major Vertical Datum) can be defined by a geoidal geopotential value used in the solution as the reference value, or by the geopotential value of the LVD, e.g. NAVD88.  相似文献   
33.
Geopotential values W of the mean equipotential surfaces representing the mean ocean topography were computed on the basis of four years (1993 - 1996) TOPEX/POSEIDON altimeter data: W = 62 636 854.10m 2 s –2 for the Pacific (P), W = 62 636 858.20m 2 s –2 for the Atlantic (A), W = 62 636 856.28m 2s–2 for the Indian (I) Oceans. The corresponding mean separations between the ocean levels were obtained as follows: A – P = – 42 cm, I– P = – 22 cm, I – A = 20 cm, the rms errors came out at about 0.3 cm. No sea surface topography model was used in the solution.  相似文献   
34.
HCl:SO2 mass ratios measured by open path Fourier transform spectroscopy (OP-FTIR) in the volcanic plume at Soufrière Hills Volcano, Montserrat, are presented for the second phase of dome building between November 1999 and November 2000. HCl:SO2 mass ratios of greater than 1 and HCl emission rates of greater than 400 t day–1 characterise periods of dome building for this volcano. The data suggest that chlorine partitions into a fluid phase as the magma decompresses and exsolves water during ascent. This is substantiated by a correlation between chlorine and water content in the melt (derived from the geochemical analysis of plagioclase melt inclusion and matrix glasses from phase I and II of dome growth). The matrix glass from the November 1999 and March 2000 domes indicate an open system degassing regime with a fluid-melt partition coefficient for chlorine of the order of 250–300. September 1997 glasses have higher chlorine contents and may indicate a switch to closed system degassing prior to explosive activity in September and October 1997. The OP-FTIR HCl time series suggests that HCl emission rate is strongly related to changes in eruption rate and we infer an emission rate of over 13.5 kt day–1 HCl during a period of high extrusion rate in September 2000. A calculation of the HCl emission rate expected for varying extrusion rates from the open-system degassing model suggests a HCl emission rate of the order of 1–4 kt day–1 is indicative of an extrusion rate of between 2 and 8 m3 s–1. Monitoring of HCl at Soufrière Hills Volcano provide a proxy for extrusion rate, with changes in ratio between HCl and SO2 occurring rapidly in the plume. Order of magnitude changes occur in HCl emission rates over the time-scale of hours to days, making these changes easy to detect during the day-to-day monitoring of the volcano. Mean water emission rates are calculated to range from 9–24 kt day–1 during dome building activity, calculated from the predicted mass ratio of H2O:HCl in the fluid at the surface and FTIR-derived HCl emission rates.  相似文献   
35.
The T/P altimeter data 1993 – 1997 (cycles 11 – 194) has been analyzed with emphases on seasonal variations in sea surface topography (SST). The amplitude of the annual variations amounted to (5.9±0.3) mm when inverted barometer (IB) corrections were applied and (2.0±0.4) mm without any IB corrections. The amplitude of the semi-annual variations in SST was small with IB corrections applied: (0.6±0.3) mm. However, when no IB corrections were applied, it was (1.8±0.4) mm, i.e. the semiannual variations are at the same level as the annual variations with no IB corrections. The phase angle offset of the annual term has shifted by about 180° when IB correction was applied. The dynamics of the ocean-atmosphere system is discussed and it is concluded that it could, at least partly, be responsible for the above observed effects.  相似文献   
36.
Low-frequency current fluctuations in the deep central equatorial Atlantic are analyzed using current meter measurements recorded from November 1992 to November 1994. Current meters were located at about 14°W of longitude and 1° of latitude on both sides of the equator between 1,700 m depth and the ocean bottom. At all sampling depths, the velocity fluctuations are dominantly zonal and symmetrical with respect to the equator. At 1,700 and 2,000 m, the flow is dominated by annual period fluctuations, at 3,000 m, the velocity field amplitude presents a minimum, and at 3,750 and 3,950 m, the flow is modulated by annual and semiannual period variability. The annual signal exhibits an apparent upward phase propagation. When considering the phase and the amplitude of the seasonal fluctuations, the data compare well with the outputs of a realistic numerical simulation of the Atlantic Ocean. Together with a previous analysis of the model simulations, this supports the idea that the observed annual fluctuations are due to wind-forced vertically propagating Kelvin and Rossby waves. Data and model do not provide deciding evidences of the presence of semiannual equatorial waves deeper than 3,500 m depth in the central equatorial Atlantic Ocean.  相似文献   
37.
Infrared stimulated luminescence (IRSL) properties of the Old Crow tephra and bracketing loess from the Halfway House site in Central Alaska are investigated in order to test newly developed techniques, including SAR and recently proposed fading corrections. Loess samples investigated show a standard growth of luminescence with regenerative dose while the tephra sample is less sensitive by an order of magnitude and saturates at lower dose. The growth curves obtained using multiple-aliquots regeneration (MAR) saturate at a higher value than those with the single-aliquot regeneration (SAR) protocol. Fading rate determinations for these samples are shown to be imprecise and no noticeable difference was observed between loess and tephra materials. Anomalous fading corrections using an average g value of 5% are applied to the natural test dose signal intensity using the dose rate correction (DRC) method. IRSL ages obtained for loess are in agreement with the expected age while the tephra age is lower than expected, suggesting the measured fading rate is underestimated for this material.  相似文献   
38.
39.
A method has been developed to control ammonium fugacity, \(f_{{\text{NH}}_{3}}\), at elevated temperatures and pressures. The method uses an internal nitrogen buffer, the assemblage Cr + CrN, in conjunction with a traditional external hydrogen buffer. In this manner, all gas fugacities in the system N-O-H can be calculated.The Cr + CrN buffer has been applied to study equilibria between buddingtonite (ammonium feldspar), ammonium muscovite, sillimanite, and quartz at a constant gas pressure of 2,000 bars. Two of the five relevant reactions were measured experimentally; from these data, it is possible to calculate isothermal sections at 500, 600, and 700° C.Below 600° C, ammonium muscovite is stable even at extremely low levels of \(f_{{\text{NH}}_{3}}\), while buddingtonite requires \(f_{{\text{NH}}_{3}}\;\geqq\;10^4\) bars. Release of NH3 during progressive metamorphism can be achieved by three processes: thermal decomposition, dehydration, and cation exchange. Within the crust, \(f_{{\text{NH}}_{3}}\) predominates over \(f_{{\text{N}}_{2}}\) by several orders of magnitude; but on the surface, nitrogen released as NH3 by metamorphism will be oxidized to N2. Biological materials provide important intermediate storage for nitrogen compounds during the nitrogen cycle.  相似文献   
40.
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