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11.
Miroslav Krs František Novák Marta Krsová Petr Pruner Jiří Jansa 《Studia Geophysica et Geodaetica》1993,37(4):382-400
Summary This study is a follow up of the investigation of some magnetic properties and metastability of greigite in samples obtained from Miocene claystones in the Kruné hory (Erzgebirge) Piedmont basins (Bohemia). Three different methods of upgrading the smythite were applied; the magnetic properties of the concentrates are compared. The thermal conversion of smythite sets in at 200°C while greigite converts at 250°C. The first intermediate products to be formed are iron sulphides, marcasite clearly dominating over pyrite and pyrrhotite. Apart from a Fe3+ sulphate with a composition of Fe2(SO4)3, oxidation of these sulphides gives rise to -Fe2O3. The result of the subsequent decomposition of the mentioned sulphate is the formation of -Fe2O3, which retains the sulphate structure. The final product of the thermal decomposition at 800°C is -Fe2O3. In the smythite concentrate the conversion to Fe3+ sulphate and -Fe2O3 is about twice as intensive as in greigite. No direct conversion to -Fe2O3 was found. During the thermal process self-reversals of remanence were observed, in various samples as many as four reversals in the temperature interval from 340 to 590°C. The occurrences of self-reversals of remanence were only observed at high degrees of thermal demagnetization, of the order of 10–2 down to 10–3 in the temperature interval of sulphide origin (below 400°C), and of the order of 10–4 down to 10–6 in the temperature interval of Fe-oxides origin (above 400°C).Presented at the 3rd Conference on New Trends in Geomagnetism, Castle of Smolenice, Czechoslovakia, June 22–29, 1992 相似文献
12.
F. Bella R. Bella P. F. Biagi M. Caputo G. Della Monica A. Ermini E. Pettinelli V. Sgrigna 《Pure and Applied Geophysics》1993,141(1):125-137
Prototype instrumentation, able to automatically measure groundwater radon content variations, is presented. The equipment is made of stainless steel and has spherical valves with automatic and pneumatic control. The deemanation of the gases from the water is obtained by evacuating a suitable expansion chamber. The instrumentation can make discrete sampling ranging from 1 per hour to 1 per 99 hours. The equipment was tested in the laboratory: the efficiency was measured by means of a266Ra solution. A mean value of (0.65±0.07) count/s/Bq was obtained. A calibration test was carried out by comparing countings from the automatic equipment with those obtained by the standard laboratory cell. Results of an operational check over a period of approximately one year indicate that variations in radon at the calibration site are attributable more to meteorological than to tectonic causes. 相似文献
13.
Summary A Mg-Al spinel from a xenolith found in the Sacrofano volcanic area (Latium, Italy) was investigated by X-ray single crystal diffraction and electron microprobe. Its main structural parameters were: a0 = 8.0922(3) Å and the oxygen coordinate u = 0.26213(4), which gave to tetrahedral and octahedral bond distances of 1.9220(6) Å and 1.9299(3) Å respectively. Cation distribution, obtained from structural and chemical data, showed a very high Mg-Al disorder, with an Al(T) content of 0.205 and an inversion parameter, i, of about 0.23. Comparison with the cation distribution of a spinel with similar chemical composition but occurring in chlorite schists (Shishimsk Mountains, Urals, Russia) with a0 = 8.1003(3) Å and u=0.26330(3), and with data from the literature concerning spinels from metamorphosed limestones (Kalkbro, Sweden) and websteritic dikes (Balmuccia, Italy), all characterized by much lower Mg-Al disorder (i about 0.13–0.12), suggests a completely different thermal history, with rapid cooling rates and consequent high closure temperature of intracrystalline exchange, consistent with the Sacrofano geological environment.
Kristallchemie eines stark ungeordneten, natürlichen Mg-Al-Spinells
Zusammenfassung Ein Mg-Al-Spinell aus einem Xenolith des Vulkangebiets von Sacrifano (Latium, Italien) wurde mit Röngten-Einkristallmethoden und der Elektronenmikrosonde untersucht. Die wichtigsten Strukturparameter sind ao = 8,0922(3) Å und die Sauerstoffkoordinate u = 0,26213(4), was zu den tetraedrischen und oktaedrischen Bindungsabständen von 1,9220(6) Å bzw. 1,9299(3) Å führt. Die aus den strukturellen und chemischen Daten erhaltene Kationenverteilung zeigt eine sehr starke Unordnung Mg-Al mit einem Al (T)-Gehalt von 0,205 und einem Inversionsparameteri von ca. 0,23. Der Vergleich mit der Kationenverteilung eines Spinells ähnlicher chemischer Zusammensetzung, aber aus Chloritschiefern (Schischimsk-Berge, Ural, Rußland) mit a0 = 8,1003(3) Å und u=0,26330(3), sowie mit Literaturdaten über Spinelle aus metamorphen Kalken (Kalkbro, Schweden) und websteritischen Gängen (Balmuccia, Italien), die alle durch eine viel geringere Mg-Al-Unordnung charakterisiert sind (i etwa 0,13–0,12), weist auf eine völlig andere thermische Geschichte hin, und zwar mit rascher Abkühlungsgeschwindigkeit und hoher Schließungstemperatur des intrakristallinen Austausches, was mit den geologischen Verhältnissen von Sacrofino in Übereinstimmung steht.相似文献
14.
F. Bella P. F. Biagi M. Caputo G. Della Monica A. Ermini P. V. Manjgaladze V. Sgrigna D. O. Zilpimiani 《Pure and Applied Geophysics》1995,144(2):277-300
Daily averaged tilt component data from two sites of the Central Apennines (Italy) and of the Southern Caucasus (Georgia), respectively, revealed intermediate-term tilts as possible precursors to earthquakes (M=3.0÷4.7) which occurred in the above-mentioned seismic areas within a distance of 50 km from the sites. A good temporal correlation as well as a fair spatial correspondence between these residual tilts (with amplitude and duration of some microradians and months, respectively) and main shocks were pointed out, by removing both secular trends and seasonal thermoelastic effects from the raw tilts. An attempt was made to justify the above-mentioned results, based on the assumption that the observed intermediate-term preseismic tilts are the manifestation of aseismic creep episodes of comparable duration in the fault materials of thrust faults close to the tilt sites. The mechanism refers to a strain field slowly propagating from the preparation focal area to the tilt site, through crustal blocks separated by weak transition zones. This propagation is thought to be the cause of the local aseismic fault slip recorded by the tiltmeters. Previously, both discrete structures and strain propagation effects were revealed in the Central Apennines and are thought also to exist in the Southern Caucasus. As in the past, the rheological properties of fault materials are revealed as viscoelastic ones. In fact, creep equations obtained by applying several viscoelastic models on our data, proved to fit quite well some of the observed tilt precursors, producing viscosity and rigidity values very similar to those reported in literature.Professor Petr Viktorovich Manjgaladze died during the writing of this paper 相似文献
15.
L. Bassani R. C. Butler A. J. Dean G. Di Cocco A. Della Ventura F. Perotti G. Villa 《Astrophysics and Space Science》1982,82(2):311-316
During a balloon flight in September 1979 of the MISO low-energy -ray telescope, the BL Lac-object MkN 501 was studied in the hard X-ray range above 30 keV and in the low energy -ray range up to 19 MeV. No statistically significant X- and -ray fluxes were detected. The implications of the upper limits obtained are discussed in the light of the relativistic jet theories recently proposed. 相似文献
16.
This paper presents an improved generalisation of cation distribution determination based on an accurate fit of all crystal-chemical
parameters. Cations are assigned to the tetrahedral and octahedral sites of the structure according to their scattering power
and a set of bond distances optimised for spinel structure. A database of 295 spinels was prepared from the literature and
unpublished data. Selected compositions include the following cations: Mg2+, Al3+, Si4+, Ti4+, V3+, Cr3+, Mn2+, Mn3+, Fe2+, Fe3+, Co2+, Ni2+, Zn2+ and vacancies. Bond distance optimisation reveals a definite lengthening in tetrahedral distance when large amounts of Fe3+ or Ni2+ are present in the octahedral site. This means that these cations modify the octahedral angle and hence the shared octahedral
edge, causing an increase in the tetrahedral distance with respect to the size of the cations entering it. Some applications
to published data are discussed, showing the capacity and limitations of the method for calculating cation distribution, and
for identifying inconsistencies and inaccuracies in experimental data.
Received: 19 February 2001 / Accepted: 1 June 2001 相似文献
17.
Daily geomagnetic variations on the Iberian Peninsula 总被引:2,自引:0,他引:2
18.
An avulsion of the lower Saskatchewan River in the 1870s inundated a large segment of peat-covered floodplain that subsequently has become aggraded with a broad (500 km2) belt of alluvium deposited by the redirected flow. Routing of water and sediment discharge through the avulsion-affected area has been accomplished mainly by networks of sandy bedded anastomosed channels that have formed, evolved, and abandoned as the alluvial belt prograded down the floodplain slope. These processes continue today, though at a much-reduced rate. New channels, formed by crevassing and basinward extension of distributaries, are initially small and shallow, with bottom elevations situated within the avulsive alluvium but above the pre-avulsion peat (floodplain) surface. Subsequent enlargement and downcutting of many of these channels eventually uncovers the underlying peat layer whose resistance to erosion exerts significant influence on cross-sectional shape and further channel development. Peat-floored channels tend to have rectangular cross-sections, high ratios of average to maximum depth (D/Dmax), and a large range of width-to-depth ratios. If the channel continues to enlarge, the peat layer eventually becomes breached, commonly leading to temporarily irregular cross-sections caused by localized scouring at the breach sites. Eventually, the peat layer is completely eroded from the channel floor by undercutting and slumping, after which channel shape becomes governed mainly by other perimeter characteristics. Channels unaffected by peat, either before the peat layer is encountered during early channel development or after it is entirely removed, tend to have low width/depth ratios and a large range of D/Dmax values. 相似文献
19.
Gianluca Iezzi Mario Tribaudino Giancarlo Della Ventura Fabrizio Nestola Fabio Bellatreccia 《Physics and Chemistry of Minerals》2005,32(7):515-523
The synthetic amphibole Na0.95(Li0.95Mg1.05)Mg5Si8O22(OH)2 was studied in situ at high-T, using IR OH-stretching spectroscopy and synchrotron X-ray powder diffraction. At room-T the sample has P21
/m symmetry, as shown by the FTIR spectrum. It shows in the OH region two well-defined and intense absorptions at 3,748 and
3,712 cm−1, respectively, and two minor bands at 3,667 and 3,687 cm−1. The main bands are assigned to the two independent O–H groups in the primitive structure. The two minor bands evidencing
the presence of small amount of vacant A-site (A□0.05). With increasing T, these bands shift continuously and merge into a unique absorption at high temperature. A change as a function of increasing
T is revealed by the evolution of the refined unit-cell parameters, whose trend shows a transition to C2/m at about 320–330°C. The spontaneous scalar strain, fitted with a tricritical 2–6 Landau potential, gives a T
c of 325(10)°C (β parameter = 0.27). Comparison with the second-order P21
/m ⇔ C2/m phase transition at 255°C for synthetic amphibole ANa0.8B(Na0.8Mg1.2)CMg5Si8O22(OH)2 indicates that the substitution of Na with Li at the B-sites strongly affects the thermodynamic character and the T
c of the phase transition. The comparison of LNMSH amphiboles with cummingtonitic ones shows that the high-T thermodynamic behaviour is affected by A-site occupancy. 相似文献