Carbon fluxes through major phytoplankton groups during the spring bloom and post-bloom in the Northwestern Mediterranean Sea     

Andrés Gutiérrez-Rodríguez  Mikel Latasa  Marta Estrada  Montserrat Vidal  Celia Marrasé 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(4):486-500

The carbon flux through major phytoplankton groups, defined by their pigment markers, was estimated in two contrasting conditions of the Northwestern Mediterranean open ocean ecosystem: the spring bloom and post-bloom situations (hereafter Bloom and Post-bloom, respectively). During Bloom, surface chlorophyll a (Chl a) concentration was higher and dominated by diatoms (53% of Chl a), while during Post-bloom Synechococcus (42%) and Prymnesiophyceae (29%) became dominant. The seawater dilution technique, coupled to high pressure liquid chromatography (HPLC) analysis of pigments and flow cytometry (FCM), was used to estimate growth and grazing rates of major phytoplankton groups in surface waters. Estimated growth rates were corrected for photoacclimation based on FCM-detected changes in red fluorescence per cell. Given the 30% average decrease in the pigment content per cell between the beginning and the end of the incubations, overlooking photoacclimation would have resulted in a 0.40 d^?1 underestimation of phytoplankton growth rates. Corrected average growth rates (μ_o) were 0.90±0.20 (SD) and 0.40±0.14 d^?1 for Bloom and Post-bloom phytoplankton, respectively. Diatoms, Cryptophyceae and Synechococcus were identified as fast-growing groups and Prymnesiophyceae and Prasinophyceae as slow-growing groups across Bloom and Post-bloom conditions. The higher growth rate during Bloom was due to dominance of phytoplankton groups with higher growth rates than those dominating in Post-bloom. Average grazing rates (m) were 0.58±0.20 d^?1 (SD) and 0.31±0.07 d^?1. The proportion of phytoplankton growth consumed by microzooplankton grazing (m/μ_o) tended to be lower in Bloom (0.69±0.34) than in Post-bloom (0.80±0.08). The intensity of nutrient limitation experienced by phytoplankton indicated by μ_o/μ_n (where μ_n is the nutrient-amended growth rate), was similar during Bloom (0.78) and Post-bloom (0.73). Primary production from surface water (PP) was estimated with ¹⁴C incubations. A combination of PP and Chl a synthesis rate yielded C/Chl a ratios of 34±21 and 168±75 (g:g) for Bloom and Post-bloom, respectively. Transformation of group-specific Chl a fluxes into carbon equivalents confirmed the dominant role of diatoms during Bloom and Synechococcus and Prymnesiophyceae during Post-bloom.  相似文献   

HT-FTIR micro-spectroscopy of cordierite: the CO2 absorbance from in situ and quench experiments     

F. Radica  G. Della Ventura  F. Bellatreccia  M. Cestelli Guidi 《Physics and Chemistry of Minerals》2016,43(1):69-81

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In situ high-temperature X-ray diffraction and spectroscopic study of fibroferrite,FeOH(SO<Subscript>4</Subscript>)·5H<Subscript>2</Subscript>O     

Gennaro Ventruti  Giancarlo Della Ventura  Nicola Corriero  Daniele Malferrari  Alessandro F. Gualtieri  Umberto Susta  Maria Lacalamita  Emanuela Schingaro 《Physics and Chemistry of Minerals》2016,43(8):587-595

The thermal dehydration process of fibroferrite, FeOH(SO₄)·5H₂O, a secondary iron-bearing hydrous sulfate, was investigated by in situ high-temperature synchrotron X-ray powder diffraction (HT-XRPD), in situ high-temperature Fourier transform infrared spectroscopy (HT-FTIR) and thermal analysis (TGA-DTA) combined with evolved gas mass spectrometry. The data analysis allowed the determination of the stability fields and the reaction paths for this mineral as well as characterization of its high-temperature products. Five main endothermic peaks are observed in the DTA curve collected from room T up to 800 °C. Mass spectrometry of gases evolved during thermogravimetric analysis confirms that the first four mass loss steps are due to water emission, while the fifth is due to a dehydroxylation process; the final step is due to the decomposition of the remaining sulfate ion. The temperature behavior of the different phases occurring during the heating process was analyzed, and the induced structural changes are discussed. In particular, the crystal structure of a new phase, FeOH(SO₄)·4H₂O, appearing at about 80 °C due to release of one interstitial H₂O molecule, was solved by ab initio real-space and reciprocal-space methods. This study contributes to further understanding of the dehydration mechanism and thermal stability of secondary sulfate minerals.  相似文献   

Efficiency of methane fermentation of waste microalgae biomass (WMAB) collected in processes of reclamation of eutrophicated water reservoirs     

Marcin Dębowski  Marcin Zieliński  Marta Kisielewska  Mirosław Krzemieniewski 《Environmental Earth Sciences》2016,75(6):525

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Abundance and Taxonomic Diversity of Bacteria Inhabiting the Sediment-Water Interface in a Marine Harbor Channel     

Perliński  Piotr  Mudryk  Zbigniew J.  Zdanowicz  Marta 《Ocean Science Journal》2019,54(3):407-418

Ocean Science Journal - The abundance of bacteria inhabiting the sediment-water interface and their taxonomic composition were determined with the fluorescence in situ hybridization (FISH) method...  相似文献   

Uncoupled transport of chlorofluorocarbons and anthropogenic carbon in the subpolar North Atlantic     

Marta Álvarez  Claire Gourcuff 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(7):860-868

Chlorofluorocarbon (CFC) 11 and 12 transports across the transoceanic World Ocean Circulation Experiment (WOCE) A25 section in the subpolar North Atlantic are derived from an inverse model using hydrographic and ADCP data (Lherminier et al., 2007). CFC and anthropogenic carbon (C_ANT) advective transports contrary to expected are uncoupled: C_ANT is transported northeastwards (82±39 kmol s^?1) mainly within the overturning circulation, while CFC-11 and CFC-12 are transported southwestwards (?24±4 and ?11±2 mol s^?1, respectively) as part of the large-scale horizontal circulation. The main reason for this uncoupled behaviour is the complex CFC vs. C_ANT relation in the ocean, which stems from the contrasting temperature relation for both tracers: more C_ANT dissolves in warmer waters with a low Revelle factor, while CFC’s solubility is higher in cold waters. These results point to C_ANT and CFC having different routes of uptake, accumulation and transport within the ocean, and hence: C_ANT transport would be more sensitive to changes in the overturning circulation strength, while CFC to changes in the East Greenland Current and Labrador Sea Water formation in the Irminger Sea. Additionally, C_ANT and CFCs would have different sensitivities to circulation and climate changes derived from global warming as the slowdown of the overturning circulation, increase stratification due to warming and changes in wind stress.  相似文献   

Mg---NH₄ exchange on humic acid: A radiotracer technique for conditional exchange constants in a seawater medium     

Marta T. Von Breymann  C. Andr  Ungerer  Erwin Suess 《Chemical Geology》1988,70(4):349-357

A radiotracer technique, employing ²⁷Mg, is used to determine the Mg released by ammonium exchange on undis-solved humic acid in a seawater medium. This new method allows for the measurement of exchangeable Mg on the solid phase surface, which eliminates the problem caused by the high-Mg background in the seawater matrix. The precision calculated from the counting statistics is better than ±2%; the reproducibility among repeated counts ranged from ±1% to ±3%. The higher sensitivity of the method allows for monitoring the Mg---NH₄ exchange at concentrations as low as 30 mM NH₄. This is a major improvement relative to the data obtained with the analytical methods used so far, which allow detection of exchangeable Mg only at NH₄ concentrations higher than 1 M. The lower experimental concentrations are more in accordance with the natural ammonium levels found in anoxic marine sediments. For the undissolved humic acid used in this experiment, the amount of exchangeable Mg in apparent equilibrium with an ammonium-free seawater matrix was found to be 96.6 ± 0.4 meq/100g. The Mg---NH₄ exchange on humic acid in seawater comes to a steady-state value in < 18 min. The conditional equilibrium constant obtained for this reaction, K_cond = 0.039 ± 0.001 M⁻¹. The technique can be expanded to other geochemical solid phases in seawater and it can be modified to study the behavior of the major cations by using ²⁴Na, ⁴²K and ⁴⁹Ca.  相似文献   

Dissolution mechanisms of silicate minerals yielded by intercomparison with glasses and radiation damage studies     

J. -C. Petit  J. -C. Dran  G. Della Mea  A. Paccagnella 《Chemical Geology》1989,78(3-4):219-227

The behaviour of two silicates (albite and olivine) toward aqueous dissolution has been investigated with emphasis to two aspects: (1) similarities and differences with silicate glasses; and (2) influence of ion bombardment which transforms the initially crystalline structure to a glass-like one. The occurrence on leached materials of hydrated layers enriched with metallic elements is checked by using high-energy ion beam analytical techniques.

It is shown that for both amorphous and crystalline silicates, dissolution involves competing processes responsible for either hydrated-layer generation (hydration by ion exchange and/or water permeation), or its destruction (hydrolysis of siloxane bonds and detachment of silica units). At moderate temperature ( 100°C), the latter processes dominate for crystalline silicates and the resulting dissolution is congruent. However, these silicates tend to behave like glasses upon ion bombardment above a critical dose. At higher temperature (> 200°C), hydration is markedly enhanced and thick altered layers are generated even on undamaged minerals such as albite and orthoclase, where alkali cations are easily exchangeable.  相似文献   

Temperature,composition, and f O2 effects on intersite distribution of Mg and Fe2+ in olivines     

G. Ottonello  F. Princivalle  A. Della Giusta 《Physics and Chemistry of Minerals》1990,17(4):301-312

Single-crystal X-ray structure refinement of natural olivines equilibrated at high temperature under controlled oxygen fugacity (f _O2) conditions, coupled with a structure-energy model were used to establish the influence of T, f _O2 and bulk chemistry on intracrystalline disorder.The results are: 1) The k _D (k _D = [(Fe M1·Mg M2)/(Fe M2·Mg M1)]) factor describing site population on M1, M2 polyhedra increases from values lower than 1 at T below 400–600° C (depending on composition) to values higher than 1 at higher temperature. 2) The increase of k _D with T is quite regular. 3) At constant temperature and pressure, k _D increases with increasing fayalite content in the mixture; 4) Contrary to previous observations (Will and Nover 1979; Nover and Will 1981) varying f _O2, within the stability range of the substance, has a negligible influence on intracrystalline disorder. 5) As ancillary results, the model confirms the defect scheme of Nakamura and Schmalzried (1983) for the investigated solids. Moreover, it shows that cationic vacancies are always created on M 1 site at the expense of Mg ions, while trivalent iron is always stabilized on M2 site. This explains the marked anisotropies observed in Fe-Mg interdiffusion (Buening and Busek 1973; Misener 1974; Schock et al. 1989).  相似文献   

A study of the electromagnetic field of a magnetic vertical dipole on the model of homogeneous half-space with a spherical cavity     

Karel Faldus  Václav Petr  Oldřich Praus  Marta Tobyášová 《Studia Geophysica et Geodaetica》1963,7(4):372-395

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