Mineralogical sources of the buffer capacity in a granite catchment determined by strontium isotopes     

Christina Weyer  Gunnar Lischeid  Luc Aquilina  Anne-Catherine Pierson-Wickmann  Charlotte Martin 《Applied Geochemistry》2008

The role of different minerals in base cation release and thus the increase of buffering capacity of groundwater against acid deposition is controversially discussed in the literature. The ⁸⁷Sr/⁸⁶Sr ratios and base cation concentration were investigated in whole rock leachates, mineral separates, precipitation, soil solution, groundwater and stream water samples in the Lehstenbach catchment (Germany) to identify the weathering sequence of the granite bedrock. Three different approaches were followed in parallel. It was assumed that the contribution of different minerals to base cation supply of the groundwater with increasing weathering intensity would be observed by investigating (1) unweathered rock leachates, deep groundwater and shallow groundwater, (2) groundwater samples from new groundwater wells, reflecting the initial weathering of the drilled bedrock, and groundwater from wells that were drilled in 1988, (3) stream water during baseflow, dominated by deep groundwater, and stream water during high flow, being predominantly shallow groundwater. Whereas the first approach yielded consistent patterns, there was some evidence that groundwater from the new wells initially reflected contamination by the filter gravel rather than cation release in an initial stage of weathering. Time series samples of stream water and groundwater solute concentrations and isotope ratios turned out to reflect varying fractions of soil water and precipitation water at baseflow and high flow conditions rather than varying contributions of different minerals that prevail at different stages of granite weathering.  相似文献   

Stability at high-pressure,elastic behaviour and pressure-induced structural evolution of CsAlSi<Subscript>5</Subscript>O<Subscript>12</Subscript>, a potential host for nuclear waste     

G. Diego Gatta  Nicola Rotiroti  Martin Fisch  Milen Kadiyski  Thomas Armbruster 《Physics and Chemistry of Minerals》2008,35(9):521-533

The elastic and structural behaviour of the synthetic zeolite CsAlSi₅O₁₂ (a = 16.753(4), b = 13.797(3) and c = 5.0235(17) Å, space group Ama2, Z = 2) were investigated up to 8.5 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase-transition occurs within the P-range investigated. Fitting the volume data with a third-order Birch–Murnaghan equation-of-state gives: V ₀ = 1,155(4) ų, K _T0 = 20(1) GPa and K′ = 6.5(7). The “axial moduli” were calculated with a third-order “linearized” BM-EoS, substituting the cube of the individual lattice parameter (a ³, b ³, c ³) for the volume. The refined axial-EoS parameters are: a ₀ = 16.701(44) Å, K _T0a = 14(2) GPa (β_a = 0.024(3) GPa^?1), K′ _a = 6.2(8) for the a-axis; b ₀ = 13.778(20) Å, K _T0b = 21(3) GPa (β_b = 0.016(2) GPa^?1), K′ _b = 10(2) for the b-axis; c ₀ = 5.018(7) Å, K _T0c = 33(3) GPa (β_c = 0.010(1) GPa^?1), K′ _c = 3.2(8) for the c-axis (K _T0a:K _T0b:K _T0c = 1:1.50:2.36). The HP-crystal structure evolution was studied on the basis of several structural refinements at different pressures: 0.0001 GPa (with crystal in DAC without any pressure medium), 1.58(3), 1.75(4), 1.94(6), 3.25(4), 4.69(5), 7.36(6), 8.45(5) and 0.0001 GPa (after decompression). The main deformation mechanisms at high-pressure are basically driven by tetrahedral tilting, the tetrahedra behaving as rigid-units. A change in the compressional mechanisms was observed at P ≤ 2 GPa. The P-induced structural rearrangement up to 8.5 GPa is completely reversible. The high thermo-elastic stability of CsAlSi₅O_12, the immobility of Cs at HT/HP-conditions, the preservation of crystallinity at least up to 8.5 GPa and 1,000°C in elastic regime and the extremely low leaching rate of Cs from CsAlSi₅O₁₂ allow to consider this open-framework silicate as functional material potentially usable for fixation and deposition of Cs radioisotopes.  相似文献   

Variations in exospheric density at heights near 1100km, derived from satellite orbits     

G. E. Cook  Diana W. Scott 《Planetary and Space Science》1967,15(12):1933-1956

In an earlier paper, values of exospheric density were obtained from the orbit of Echo 2 for the years 1964–1965. The results indicated a semi-annual variation in density by a factor of between 2 and 3, considerably larger than predicted by existing atmospheric models.

These studies have now been extended to the beginning of 1967, using both Echo 2 and Calsphere 1, to show how the density is responding to increasing solar activity. Variations in density during 1964 have been analysed in more detail. The long-term variation associated with the solar cycle and the short-term variations associated with magnetic and solar disturbances agree with the variations expected on the basis of current models. The semi-annual variation is persisting to higher levels of solar activity, and although its amplitude is diminishing the factor of variation was still 1.6 in 1966.  相似文献   

Control strategies for the Clam Wave Energy Device   总被引：1，自引：0，他引：1  

Martin Greenhow  Jay H. Rosen  Mark Reed 《Applied Ocean Research》1984,6(4):197-206

A promising wave energy device being currently investigated is the ‘clam’. The clam extracts energy by pumping air through a specially designed (Wells) turbine. Although operation of the Wells turbine does not require a rectified air flow, some additional control will be necessary to optimize the phase of the clam motion for good efficiencies. An examination of the equation of motion in the time domain suggests the possibility of phase control by mechanical, power take-off, or pneumatic latching. Latching can be shown to increase the efficiency of the device in the longer wavelengths of the wave spectrum, i.e. those of high incident wave power. Equivalently latching could be used to keep the device efficiency high while reducing its size, possibly resulting in cheaper power extraction.  相似文献   

Industrialised embayments and their environmental problems; a case study of Swansea Bay: Edited by M.B. COLLINS, F.T. BANNER, P.A. TYLER, S.J. WAKEFIELD and A.E. JAMES Pergamon Press (1980) $84.00 (£35.00) 632 pp., 266 illustrations     

Martin Angel 《Progress in Oceanography》1980,9(4):245-247

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Using the Mellor–Yamada mixing scheme in seasonally ice-covered seas—Corrigendum to: Parameterization of vertical mixing in the Weddell Sea [Ocean Modelling 6 (2004) 83–100]     

Ralph Timmermann  Martin Losch 《Ocean Modelling》2005,10(3-4):369-372

A coding error in the s-Coordinate Primitive Equation Model (SPEM) has led to misleading statements about the behaviour of the Mellor–Yamada level 2 parameterization of vertical mixing. It has been claimed that the scheme removes static instability only very slowly and preserves statically unstable stratifications for an unrealistic long time. This note corrects this statement by demonstrating that the Mellor–Yamada mixing scheme, if implemented correctly, tends to overestimate rather than underestimate vertical mixing in seasonally ice-covered seas. Similar to other mixing schemes with the same behaviour, this leads to spurious open ocean deep convection, an unrealistic homogenization of the water column, and a significant reduction of sea ice volume.  相似文献   

Cyclone and bioturbation effects on sediments from coral reef lagoons     

Martin J. Riddle 《Estuarine, Coastal and Shelf Science》1988,27(6)

Despite the severity of tropical cyclone ‘Winifred’, which crossed the Great Barrier Reef on 1 February 1986, there were little long-term effects on lagoon surface sediments from reefs in its path. Short-term effects were apparent only at one particularly exposed area. These were: an increase in proportion of the coarse fraction, the establishment of sand ripples, and the destruction of the mounds produced by callianassid shrimps (normally the dominant topographic feature). Within six weeks this area was indistinguishable from a typical reef lagoon. This is probably the result of sediment reworking by callianassid shrimp, involving selective burial of the coarse fragments and transport to the surface of finer particles. Sediment turnover rates by callianassids are commensurate with change to the sediment within the relatively short period observed. The sediment fauna responded quickly to the changes in sediment type. Immediately after the cyclone the disturbed area supported a fauna typical of the coarse sediments on the shallow reef flat, as the sediment reverted to a more normal type so the fauna changed back to that typical of a reef lagoon.  相似文献   

On the structural evolution of the Central Trough in the Norwegian and Danish sectors of the North Sea     

Martin B. Gowers  Asbjrn Sbe 《Marine and Petroleum Geology》1985,2(4):298-318

The Central Trough of the North Sea is not a simple rift graben. It is an elongated area of regional subsidence which was initiated in mid Cretaceous times and continued to subside through to the late Tertiary. Its form is not representative of pre-mid Cretaceous tectonics.In Late Permian times the North Sea was divided into a northern and southern Zechstein basin by the E-W trending Mid North Sea-Ringkøbing-Fyn High. The latter was dissected by a narrow graben trending NNW through the Tail End Graben and the Søgne Basin. The Feda Graben was a minor basin on the northern flank of the Mid North Sea High at this time. This structural configuration persisted until end Middle Jurassic times when a new WNW trend separated the Tail End Graben from the Søgne Basin. Right lateral wrench movement on this new trend caused excessive subsudence in the Tail End and Feda Grabens while the Søgne Basin became inactive.Upper Jurassic subsidence trends continued during the Early Cretaceous causing the deposition of large thicknesses of sediments in local areas along the trend. From mid Cretaceous times the regional subsidence of the Central Trough was dominant but significant structural inversions occurred in those areas of maximum Early Cretaceous and Late Jurassic subsidence.  相似文献   

Accumulation and effects of organotin compounds in oysters and mussels: Correlation with serum biochemical and cytological factors and tissue burdens     

George V. Pickwell  Scott A. Steinert 《Marine environmental research》1988,24(1-4)

Oysters and mussels exposed to a concentration of 0·7 ppb (μg/liter) tributyltin from painted panels in flowing seawater accumulated tin in the digestive glands to comparable levels. The mussels experienced approximately 50% mortality during the 60-day test period, but the oysters suffered virtually no deaths. There was no evidence from either bivalve of elevated numbers of hemocytes during the test period and no evidence for cellular disruption as detected by increased levels of serum lysosomal hydrolases. Serum protein of exposed mussels relative to controls increased with time of exposure to the toxicant, while oyster serum protein, normally 10 x higher than in mussels, did not. No evidence was found for elevated stress proteins (heat shock proteins) or metallothioneins in the serum hemocytes of either bivalve. Responses by these animals to fatal or near fatal doses of TBT were thus very different from responses to copper that we have reported elsewhere.^1,2  相似文献   

Ten-year record of Thalassiosira nordenskioeldii population dynamics: comparison of aquaculture and non-aquaculture sites in the Quoddy Region     

Smith  Aaron C.; Martin  Jennifer L.; Ehrman  James M.; Kaczmarska  Irena 《ICES Journal of Marine Science》2001,58(2):391-397

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