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The concentrations of titanium and rare earth elements (REE) in olivines, orthopyroxenes, clinopyroxenes and spinels from four anhydrous, spinel-bearing peridotite xenoliths have been determined. The distribution of titanium (used as an analogue for the high field strength elements: HFSE) relative to the REE between clinopyroxenes and orthopyroxenes varies as a function of the whole rock composition and modal mineralogy. The distribution coefficients for titanium and the REE in these peridotites do not reflect mineral-melt equilibria. It is believed that subsolidus distribution coefficients for HFSE relative to REE vary with temperature. Ratios of various incompatible elements (e.g., Ti/Eu, Zr/Sm, Hf/Sm and P/Nd) in peridotite minerals differ from those in most primary basalts. However, the abundance ratios of incompatible elements in the bulk peridotite are comparable to those found in modern basalts. Given this and the differing contribution of melt from each phase during melting, near constant ratios of such incompatible elements in primary and primitive basalts and komatiites reflect the buffering of the melt by its residue. These ratios are fixed in the magma during the initial stages of melting because of similar and low distribution coefficients between melt and bulk residue for these element pairs. Differences in the relative abundances of titanium and REE in clinopyroxenes and orthopyroxenes demonstrate that mantle normalized abundance patterns for clinopyroxene are not equivalent to those of the whole rock. Therefore, claims of a widespread HFSE-depleted reservoir in the upper mantle base solely on the relative abundances of incompatible elements in peridotitic clinopyroxenes are invalid.  相似文献   
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Sustainability scientists argue that diverse knowledge holders should work together in social learning processes to co-produce knowledge in support of sustainability. Yet, how to co-produce such knowledge remains unexplored. A multi-year, national knowledge sharing partnership among Canadian biosphere reserve practitioners, academic researchers and policy advisors revealed that a skilled facilitator was necessary for successful knowledge co-production. We draw attention to the multiple barriers to learning and knowledge co-production, and to the skills required of the facilitator to address them. The facilitator helped draw together local and formalized western knowledge systems (weaving) and diffuse innovations across local sites (out-scaling) and between local sites and the broader program network (up-scaling). Our experience reveals that simply bringing parties together will not generate transformative change for sustainability. Rather, multi-lateral facilitators are needed to ensure deliberate and managed interventions and to institutionalize learning across a diverse collective.  相似文献   
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We investigated the matrix mineralogy in primitive EH3 chondrites Sahara 97072, ALH 84170, and LAR 06252 with transmission electron microscopy; measured the trace and major element compositions of Sahara 97072 matrix and ferromagnesian chondrules with laser‐ablation, inductively coupled, plasma mass spectrometry (LA‐ICPMS); and analyzed the bulk composition of Sahara 97072 with LA‐ICPMS, solution ICPMS, and inductively coupled plasma atomic emission spectroscopy. The fine‐grained matrix of EH3 chondrites is unlike that in other chondrite groups, consisting primarily of enstatite, cristobalite, troilite, and kamacite with a notable absence of olivine. Matrix and pyroxene‐rich chondrule compositions differ from one another and are distinct from the bulk meteorite. Refractory lithophile elements are enriched by a factor of 1.5–3 in chondrules relative to matrix, whereas the matrix is enriched in moderately volatile elements. The compositional relation between the chondrules and matrix is reminiscent of the difference between EH3 pyroxene‐rich chondrules and EH3 Si‐rich, highly sulfidized chondrules. Similar refractory element ratios between the matrix and the pyroxene‐rich chondrules suggest the fine‐grained material primarily consists of the shattered, sulfidized remains of the formerly pyroxene‐rich chondrules with the minor addition of metal clasts. The matrix, chondrule, and metal‐sulfide nodule compositions are probably complementary, suggesting all the components of the EH3 chondrites came from the same nebular reservoir.  相似文献   
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Knowledge of cloud vertical structure is important for meteorological and climate studies due to the impact of clouds on both the Earth’s radiation budget and atmospheric adiabatic heating. Yet it is among the most difficult quantities to observe. In this study, we develop a long-term (10 years) radiosonde-based cloud profile product over the Southern Great Plains and along with ground-based and space-borne remote sensing products, use it to evaluate cloud layer distributions simulated by the National Centers for Environmental Prediction global forecast system (GFS) model. The primary objective of this study is to identify advantages and limitations associated with different cloud layer detection methods and model simulations. Cloud occurrence frequencies are evaluated on monthly, annual, and seasonal scales. Cloud vertical distributions from all datasets are bimodal with a lower peak located in the boundary layer and an upper peak located in the high troposphere. In general, radiosonde low-level cloud retrievals bear close resemblance to the ground-based remote sensing product in terms of their variability and gross spatial patterns. The ground-based remote sensing approach tends to underestimate high clouds relative to the radiosonde-based estimation and satellite products which tend to underestimate low clouds. As such, caution must be exercised to use any single product. Overall, the GFS model simulates less low-level and more high-level clouds than observations. In terms of total cloud cover, GFS model simulations agree fairly well with the ground-based remote sensing product. A large wet bias is revealed in GFS-simulated relative humidity fields at high levels in the atmosphere.  相似文献   
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A seasonal study on coastal microplankton was conducted in surface waters near Boothbay Harbor, Maine. Phytoplankton biomass, particulate production and extracellular organic release were examined in conjunction with microheterotrophic biomass and the uptake and respiration of amino acids. In situ dissolved free amino acid (DFAA) concentrations were also determined. Several phytoplankton blooms occurred throughout the year, in mid-summer, late autumn and in mid-winter. Heterotrophic activity and biomass paralleled phytoplankton extracellular release more closely than either phytoplankton particulate production or biomass. DFAA concentrations were not wholly dependent on extracellular release. Heterotrophic uptake did not appear to be dependent on DFAA concentrations but rather on rates of production of DOC by phytoplankton.  相似文献   
59.
Fossil beetles from two last interglacial lake deposits from southern Wairarapa, central New Zealand are provisionally ascribed to marine oxygen isotope stages (MIS) 5a-e. Both assemblages represent ecological successions from lake margins to forest. The lower sample (MIS 5e) is characterized by species found today in northern New Zealand. These species, including Lorelus crassicornis, ‘Dasytes’ laticeps, Cryptobius nitidius, ‘Stenomalium’ sulcithorax, Psilocnaeia nana, and Microbrontes lineatus, represent a southward displacement from modern distributions by up to 700 km. Climate reconstruction indicates that temperatures at the time of deposition were 1.6-2.5°C warmer in the summer (January) and 2.3-3.2°C warmer in the winter (July) than at present. These results match local and regional pollen and phytolith findings of warmer, wetter conditions at the thermal maximum of the last interglaciation. In contrast, the upper sample is characterized by species that have widespread modern-day distributions. This indicates that modern conditions were attained later in MIS5, after the MIS 5e thermal maximum.  相似文献   
60.
Forest inventories and remote sensing are the two principal data sources used to estimate carbon (C) stocks and fluxes for large forest regions. National governments have historically relied on forest inventories for assessments but developments in remote sensing technology provide additional opportunities for operational C monitoring. The estimate of total C stock in live forest biomass modeled from Landsat imagery for the St. Petersburg region was consistent with estimates derived from forest inventory data for the early 1990s (272 and 269 TgC, respectively). The estimates of mean C sink in live forest biomass also agreed well (0.36 and 0.34 Mg C ha–1 yr–1). Virtually all forest lands were accumulating C in live biomass, however when the net change in total ecosystem C stock was considered, 19% of the forest area were a net source of C. The average net C sink in total ecosystem biomass is quite weak (0.08 MgC ha–1 yr–1 and could be reversed by minor increases in harvest rates or a small decline in biomass growth rates.  相似文献   
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